dev2.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 84, "width": 1224, "height": 1196, "file_name": "ja063878k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [821.8, 4.3, 302.59, 162.36], "category_id": 1}, {"id": 1, "bbox": [440.3, 136.63, 20.69, 28.47], "category_id": 3}, {"id": 2, "bbox": [159.99, 133.51, 76.71, 31.59], "category_id": 3}, {"id": 3, "bbox": [5.8, 203.59, 1210.47, 986.21], "category_id": 4}, {"id": 4, "bbox": [578.9, 88.35, 146.82, 81.42], "category_id": 2}, {"id": 5, "bbox": [507.26, 30.73, 297.89, 31.57], "category_id": 2}, {"id": 6, "bbox": [300.14, 8.9, 212.24, 154.64], "category_id": 1}, {"id": 7, "bbox": [36.96, 10.49, 182.64, 157.72], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [5, 4], "products": [0]}], "corefs": [[7, 2], [6, 1]], "caption": "Table 3. Alkenylation with 2,2-Disubstituted Vinylsilanes", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 357, 76], "ImageBB": [89, 77, 395, 376]}, "diagram_type": "single"}, {"id": 464, "width": 1356, "height": 1568, "file_name": "op200005e-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [844.01, 310.98, 321.59, 50.44], "category_id": 2}, {"id": 1, "bbox": [60.0, 1020.0, 246.0, 57.0], "category_id": 2}, {"id": 2, "bbox": [1089.0, 1006.0, 223.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [301.0, 495.0, 398.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [361.0, 183.0, 215.0, 117.0], "category_id": 2}, {"id": 5, "bbox": [1022.67, 716.64, 321.59, 44.14], "category_id": 2}, {"id": 6, "bbox": [499.3, 1069.75, 502.35, 90.39], "category_id": 2}, {"id": 7, "bbox": [63.0, 917.0, 238.0, 66.0], "category_id": 2}, {"id": 8, "bbox": [0.0, 624.0, 203.0, 58.0], "category_id": 3}, {"id": 9, "bbox": [1023.0, 670.0, 59.2, 45.8], "category_id": 3}, {"id": 10, "bbox": [853.2, 266.0, 62.9, 43.2], "category_id": 3}, {"id": 11, "bbox": [166.0, 1461.0, 332.0, 107.0], "category_id": 2}, {"id": 12, "bbox": [371.5, 17.0, 221.5, 140.0], "category_id": 1}, {"id": 13, "bbox": [395.5, 800.0, 683.3, 213.0], "category_id": 1}, {"id": 14, "bbox": [139.6, 804.4, 111.7, 103.3], "category_id": 1}, {"id": 15, "bbox": [0.0, 1219.0, 687.6, 210.7], "category_id": 1}, {"id": 16, "bbox": [637.2, 35.5, 494.7, 206.9], "category_id": 1}, {"id": 17, "bbox": [245.8, 521.0, 49.2, 66.0], "category_id": 3}, {"id": 18, "bbox": [1089.0, 925.0, 195.0, 62.7], "category_id": 2}, {"id": 19, "bbox": [123.0, 280.0, 54.0, 49.9], "category_id": 3}, {"id": 20, "bbox": [298.31, 576.0, 350.0, 60.0], "category_id": 2}, {"id": 21, "bbox": [5.0, 35.5, 311.4, 212.8], "category_id": 1}, {"id": 22, "bbox": [0.0, 459.9, 187.6, 156.1], "category_id": 1}, {"id": 23, "bbox": [763.6, 430.3, 592.4, 210.7], "category_id": 1}, {"id": 24, "bbox": [498.0, 1023.0, 52.7, 44.6], "category_id": 3}], "reactions": [{"reactants": [21], "conditions": [12, 4], "products": [16]}, {"reactants": [22, 17], "conditions": [3, 20], "products": [23]}, {"reactants": [23], "conditions": [14, 7, 1], "products": [13]}, {"reactants": [13], "conditions": [18, 2], "products": [15]}], "corefs": [[21, 19], [16, 10], [23, 9], [13, 24]], "caption": "Figure 4. Second generation scale-up synthesis of 1 3 HCl 3 H2O.", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 691, 378, 710], "ImageBB": [71, 285, 410, 677]}, "diagram_type": "multiple"}, {"id": 1282, "width": 1344, "height": 772, "file_name": "op100335q-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.76, 284.95, 252.8, 114.25], "category_id": 3}, {"id": 1, "bbox": [28.91, 237.91, 289.78, 61.09], "category_id": 3}, {"id": 2, "bbox": [882.78, 19.8, 217.83, 210.72], "category_id": 1}, {"id": 3, "bbox": [47.06, 418.02, 328.78, 254.04], "category_id": 1}, {"id": 4, "bbox": [703.94, 81.99, 57.82, 45.7], "category_id": 3}, {"id": 5, "bbox": [606.45, 421.38, 388.61, 252.02], "category_id": 1}, {"id": 6, "bbox": [689.82, 163.31, 80.68, 44.36], "category_id": 2}, {"id": 7, "bbox": [748.31, 674.74, 60.51, 51.75], "category_id": 3}, {"id": 8, "bbox": [211.79, 14.79, 224.56, 106.85], "category_id": 2}, {"id": 9, "bbox": [63.2, 109.55, 163.38, 92.07], "category_id": 1}, {"id": 10, "bbox": [178.17, 671.38, 66.56, 53.77], "category_id": 3}, {"id": 11, "bbox": [429.62, 236.56, 256.84, 118.96], "category_id": 3}, {"id": 12, "bbox": [601.07, 24.87, 233.3, 88.04], "category_id": 1}, {"id": 13, "bbox": [452.48, 24.19, 207.08, 168.69], "category_id": 1}, {"id": 14, "bbox": [408.11, 448.26, 194.3, 53.77], "category_id": 2}], "caption": "Scheme 3. Synthesis of imidazoles from acetamidic esters", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 340, 392, 355], "ImageBB": [71, 365, 407, 558]}, "reactions": [{"reactants": [9], "conditions": [8], "products": [13]}, {"reactants": [13, 12], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "diagram_type": "multiple"}, {"id": 72, "width": 2800, "height": 1320, "file_name": "ja206047h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1094.02, 100.07, 196.89, 116.43], "category_id": 1}, {"id": 1, "bbox": [952.76, 250.26, 21.67, 35.97], "category_id": 3}, {"id": 2, "bbox": [734.63, 250.26, 212.98, 41.34], "category_id": 2}, {"id": 3, "bbox": [1405.13, 189.47, 309.53, 78.88], "category_id": 2}, {"id": 4, "bbox": [1830.67, 98.28, 234.44, 179.01], "category_id": 1}, {"id": 5, "bbox": [1451.62, 5.31, 216.55, 170.07], "category_id": 1}, {"id": 6, "bbox": [739.99, 98.28, 232.65, 139.68], "category_id": 1}, {"id": 7, "bbox": [5.13, 337.87, 2789.47, 982.13], "category_id": 4}, {"id": 8, "bbox": [1916.49, 257.41, 25.25, 32.59], "category_id": 3}, {"id": 9, "bbox": [1161.96, 252.05, 87.82, 35.95], "category_id": 3}], "reactions": [{"reactants": [6, 0], "conditions": [5, 3], "products": [4]}], "corefs": [[6, 1], [0, 9], [4, 8]], "caption": "Table 3. Scope of Diaryliodonium Salt Component in the Copper-Catalyzed Enantioselective Arylationa,b", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 654, 109], "ImageBB": [72, 117, 772, 447]}, "diagram_type": "single"}, {"id": 1117, "width": 1140, "height": 856, "file_name": "jo9901541-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1017.39, 419.13, 98.66, 59.3], "category_id": 2}, {"id": 1, "bbox": [480.75, 27.37, 422.58, 331.31], "category_id": 1}, {"id": 2, "bbox": [131.74, 127.73, 212.71, 58.74], "category_id": 2}, {"id": 3, "bbox": [628.45, 420.27, 57.6, 47.33], "category_id": 3}, {"id": 4, "bbox": [531.51, 500.1, 396.34, 272.0], "category_id": 1}, {"id": 5, "bbox": [116.34, 219.54, 256.63, 59.88], "category_id": 2}, {"id": 6, "bbox": [626.74, 796.62, 178.5, 53.61], "category_id": 3}, {"id": 7, "bbox": [0.0, 177.91, 57.6, 49.62], "category_id": 3}, {"id": 8, "bbox": [102.65, 799.48, 175.65, 52.46], "category_id": 3}, {"id": 9, "bbox": [5.13, 537.17, 415.17, 236.64], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 208, 636, 222], "ImageBB": [466, 228, 751, 442]}, "reactions": [{"reactants": [7], "conditions": [2, 5], "products": [1]}, {"reactants": [1], "conditions": [0], "products": [4, 9]}], "diagram_type": "tree"}, {"id": 493, "width": 1348, "height": 2308, "file_name": "ol060246u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [203.0, 237.0, 34.0, 33.0], "category_id": 3}, {"id": 1, "bbox": [50.0, 0.0, 234.0, 270.0], "category_id": 1}, {"id": 2, "bbox": [344.0, 95.0, 354.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [909.0, 245.0, 29.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1260.0, 234.0, 34.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [11.0, 359.0, 1337.0, 1939.0], "category_id": 4}, {"id": 6, "bbox": [1053.7, 24.7, 251.3, 271.3], "category_id": 1}, {"id": 7, "bbox": [710.5, 12.4, 348.5, 279.8], "category_id": 1}, {"id": 8, "bbox": [378.0, 197.7, 188.0, 81.3], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [2], "products": [7, 6]}], "corefs": [[1, 0], [7, 3], [6, 4]], "caption": "Table 1. Effect of Base, Solvent, Temperature, and Reactant Ratio on the Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 760, 104], "ImageBB": [439, 113, 776, 690]}, "diagram_type": "single"}, {"id": 332, "width": 1344, "height": 748, "file_name": "ol300387f-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [200.0, 232.0, 47.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [853.0, 229.0, 109.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [1099.0, 231.0, 45.0, 35.0], "category_id": 3}, {"id": 3, "bbox": [121.0, 18.0, 160.0, 192.2], "category_id": 1}, {"id": 4, "bbox": [11.0, 303.0, 1327.0, 437.0], "category_id": 4}, {"id": 5, "bbox": [809.0, 18.0, 170.0, 193.0], "category_id": 1}, {"id": 6, "bbox": [301.0, 3.0, 419.0, 115.0], "category_id": 2}, {"id": 7, "bbox": [1022.0, 20.0, 203.0, 191.0], "category_id": 1}, {"id": 8, "bbox": [298.0, 151.0, 477.0, 112.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [6, 8], "products": [5, 7]}], "corefs": [[3, 0], [5, 1], [7, 2]], "caption": "Table 3. Kinetic Resolution of 1e Followed by 1,4-Addition of Remaining (S)-1e ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 770, 403, 797], "ImageBB": [71, 808, 407, 995]}, "diagram_type": "single"}, {"id": 727, "width": 1352, "height": 3776, "file_name": "ol016693l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [286.0, 2507.0, 42.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 1406.0, 1347.0, 642.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 1182.0, 1338.0, 117.0], "category_id": 2}, {"id": 3, "bbox": [540.0, 2503.0, 55.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [100.0, 2.0, 1143.0, 1133.0], "category_id": 4}, {"id": 5, "bbox": [2.0, 2989.0, 1350.0, 787.0], "category_id": 2}, {"id": 6, "bbox": [741.0, 2260.0, 288.0, 61.0], "category_id": 2}, {"id": 7, "bbox": [724.0, 2593.0, 200.0, 199.0], "category_id": 1}, {"id": 8, "bbox": [462.0, 2591.0, 200.0, 206.0], "category_id": 1}, {"id": 9, "bbox": [485.0, 2289.0, 216.0, 191.0], "category_id": 1}, {"id": 10, "bbox": [240.0, 2277.0, 201.0, 210.0], "category_id": 1}, {"id": 11, "bbox": [727.0, 2442.0, 344.0, 57.0], "category_id": 2}, {"id": 12, "bbox": [725.0, 2396.0, 365.0, 55.0], "category_id": 2}, {"id": 13, "bbox": [825.0, 2321.0, 157.0, 50.0], "category_id": 2}, {"id": 14, "bbox": [517.0, 2813.0, 46.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [10, 9], "conditions": [6, 13, 12, 11], "products": [8, 7]}], "corefs": [[10, 0], [9, 3], [8, 14]], "caption": "Table 2. Cleavage of N-Alloc Carbamate Using Ni(0) Catalysis ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 726, 104], "ImageBB": [439, 106, 777, 1050]}, "diagram_type": "multiple"}, {"id": 745, "width": 1320, "height": 1316, "file_name": "jo991700t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.9, 522.0, 122.5, 129.0], "category_id": 2}, {"id": 1, "bbox": [24.6, 1007.5, 482.8, 163.9], "category_id": 3}, {"id": 2, "bbox": [797.2, 729.1, 326.3, 250.7], "category_id": 1}, {"id": 3, "bbox": [91.1, 751.2, 291.3, 230.2], "category_id": 1}, {"id": 4, "bbox": [113.6, 199.1, 314.8, 250.1], "category_id": 1}, {"id": 5, "bbox": [502.0, 826.3, 176.0, 61.4], "category_id": 2}, {"id": 6, "bbox": [701.0, 1008.0, 619.0, 308.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [5], "products": [2]}], "corefs": [], "caption": "Table 3. Hydrogen Transfer Reduction of Acetophenone                Using Ligands 16-22ba ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [75, 376, 408, 401], "ImageBB": [74, 35, 404, 364]}, "diagram_type": "tree"}, {"id": 504, "width": 1344, "height": 816, "file_name": "ol051920v-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.0, 215.0, 42.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [437.0, 233.0, 58.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [76.3, 11.6, 235.2, 189.0], "category_id": 1}, {"id": 3, "bbox": [651.4, 147.0, 190.6, 47.8], "category_id": 2}, {"id": 4, "bbox": [379.1, 41.8, 198.8, 180.2], "category_id": 1}, {"id": 5, "bbox": [1023.28, 209.09, 52.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [617.0, 66.1, 271.3, 53.9], "category_id": 2}, {"id": 7, "bbox": [956.0, 1.8, 315.9, 196.1], "category_id": 1}, {"id": 8, "bbox": [0.0, 319.7, 1344.0, 496.3], "category_id": 4}], "reactions": [{"reactants": [2, 4], "conditions": [6, 3], "products": [7]}], "corefs": [[2, 0], [4, 1], [7, 5]], "caption": "Table 3. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with 3-Benzylpenta-3,4-dien-2-one 2b (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at Room Temperature ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 402, 120], "ImageBB": [74, 125, 410, 329]}, "diagram_type": "single"}, {"id": 641, "width": 1348, "height": 280, "file_name": "ol501019y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 194.0, 1340.0, 86.0], "category_id": 4}, {"id": 1, "bbox": [426.6, 4.6, 275.2, 102.4], "category_id": 2}, {"id": 2, "bbox": [441.5, 128.1, 233.0, 53.7], "category_id": 2}, {"id": 3, "bbox": [755.2, 43.3, 406.0, 120.6], "category_id": 1}, {"id": 4, "bbox": [186.7, 44.5, 179.9, 120.3], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [1, 2], "products": [3]}], "corefs": [], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 450, 716, 471], "ImageBB": [449, 477, 786, 547]}, "diagram_type": "single"}, {"id": 101, "width": 1348, "height": 632, "file_name": "ja026703t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [232.99, 11.3, 158.67, 124.09], "category_id": 1}, {"id": 1, "bbox": [474.1, 15.37, 426.24, 91.53], "category_id": 2}, {"id": 2, "bbox": [965.48, 8.25, 158.72, 125.1], "category_id": 1}, {"id": 3, "bbox": [6.65, 224.95, 1337.05, 407.05], "category_id": 4}, {"id": 4, "bbox": [511.74, 150.68, 309.24, 40.66], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [2]}], "corefs": [], "caption": "Table 3. Transfer Hydrogenation Catalyzed by C-6 and C-8a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 63, 745, 76], "ImageBB": [439, 82, 776, 240]}, "diagram_type": "single"}, {"id": 1194, "width": 1752, "height": 1076, "file_name": "ol501424f-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [550.4, 516.89, 369.86, 56.07], "category_id": 2}, {"id": 1, "bbox": [184.93, 75.34, 261.18, 129.66], "category_id": 1}, {"id": 2, "bbox": [1018.42, 5.26, 317.27, 209.38], "category_id": 1}, {"id": 3, "bbox": [1119.21, 667.58, 42.95, 47.3], "category_id": 3}, {"id": 4, "bbox": [300.62, 214.64, 59.6, 46.43], "category_id": 3}, {"id": 5, "bbox": [186.68, 707.88, 402.29, 97.24], "category_id": 2}, {"id": 6, "bbox": [1147.26, 222.53, 56.09, 46.43], "category_id": 3}, {"id": 7, "bbox": [945.68, 707.88, 441.72, 97.24], "category_id": 2}, {"id": 8, "bbox": [758.12, 49.94, 262.05, 94.61], "category_id": 2}, {"id": 9, "bbox": [889.58, 334.66, 262.94, 54.32], "category_id": 2}, {"id": 10, "bbox": [601.24, 584.35, 191.06, 56.94], "category_id": 2}, {"id": 11, "bbox": [942.17, 459.94, 392.65, 207.64], "category_id": 1}, {"id": 12, "bbox": [300.62, 647.43, 40.31, 42.05], "category_id": 3}, {"id": 13, "bbox": [184.93, 467.83, 302.37, 183.98], "category_id": 1}, {"id": 14, "bbox": [604.74, 212.89, 67.49, 49.06], "category_id": 3}, {"id": 15, "bbox": [486.42, 49.94, 268.19, 131.41], "category_id": 1}, {"id": 16, "bbox": [808.95, 155.94, 148.12, 47.31], "category_id": 2}], "caption": "Scheme 2. Transformation of (S)-1,3,4-Oxadiazin-6-ones into (S)-\u03b1-Amino Acid Ester ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 811, 784, 841], "ImageBB": [421, 858, 859, 1127]}, "reactions": [{"reactants": [1, 15], "conditions": [8, 16], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [11]}, {"reactants": [11], "conditions": [0, 10], "products": [13]}], "diagram_type": "tree"}, {"id": 455, "width": 1356, "height": 668, "file_name": "op200052z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1317.1, 80.0, 36.9, 60.9], "category_id": 3}, {"id": 1, "bbox": [423.0, 12.0, 272.0, 120.0], "category_id": 2}, {"id": 2, "bbox": [3.0, 2.0, 408.0, 219.0], "category_id": 1}, {"id": 3, "bbox": [492.0, 188.1, 132.0, 56.81], "category_id": 2}, {"id": 4, "bbox": [736.5, 3.1, 485.2, 219.8], "category_id": 1}, {"id": 5, "bbox": [935.07, 236.07, 61.7, 58.9], "category_id": 3}, {"id": 6, "bbox": [7.0, 364.0, 1339.0, 300.0], "category_id": 4}, {"id": 7, "bbox": [140.0, 235.0, 62.0, 56.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [1, 3], "products": [4, 0]}], "corefs": [[2, 7], [4, 5]], "caption": "Table 3. Thermal stability study of 6a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 438, 647, 459], "ImageBB": [436, 469, 775, 636]}, "diagram_type": "single"}, {"id": 1175, "width": 1344, "height": 680, "file_name": "ol202381m-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [24.88, 12.11, 236.66, 172.23], "category_id": 1}, {"id": 1, "bbox": [301.21, 0.0, 345.58, 123.79], "category_id": 2}, {"id": 2, "bbox": [365.75, 410.39, 179.51, 78.04], "category_id": 2}, {"id": 3, "bbox": [803.44, 308.8, 256.83, 82.75], "category_id": 2}, {"id": 4, "bbox": [301.21, 140.61, 239.35, 76.69], "category_id": 2}, {"id": 5, "bbox": [728.14, 220.0, 58.49, 43.05], "category_id": 3}, {"id": 6, "bbox": [567.45, 532.16, 289.78, 96.21], "category_id": 3}, {"id": 7, "bbox": [89.42, 530.82, 52.44, 46.42], "category_id": 3}, {"id": 8, "bbox": [602.41, 280.54, 187.58, 240.86], "category_id": 1}, {"id": 9, "bbox": [1122.8, 528.12, 55.13, 51.81], "category_id": 3}, {"id": 10, "bbox": [665.61, 12.78, 207.75, 200.49], "category_id": 1}, {"id": 11, "bbox": [362.39, 314.86, 247.42, 82.75], "category_id": 2}, {"id": 12, "bbox": [806.8, 406.35, 159.35, 71.99], "category_id": 2}, {"id": 13, "bbox": [1056.91, 280.54, 262.21, 251.62], "category_id": 1}, {"id": 14, "bbox": [908.33, 148.01, 233.97, 75.35], "category_id": 2}, {"id": 15, "bbox": [24.2, 279.87, 342.22, 275.84], "category_id": 1}, {"id": 16, "bbox": [89.42, 219.32, 59.84, 43.73], "category_id": 3}, {"id": 17, "bbox": [909.17, 16.21, 35.47, 47.63], "category_id": 2}, {"id": 18, "bbox": [928.42, 74.99, 184.47, 38.52], "category_id": 2}, {"id": 19, "bbox": [949.9, 16.15, 310.73, 48.44], "category_id": 1}], "caption": "Scheme 2. Synthesis of Curtius Rearrangement Precursor 10", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 305, 757, 318], "ImageBB": [437, 329, 773, 499]}, "reactions": [{"reactants": [0], "conditions": [1, 4], "products": [10]}, {"reactants": [10, 19], "conditions": [18, 14], "products": [15]}, {"reactants": [15], "conditions": [11, 2], "products": [8]}, {"reactants": [8], "conditions": [3, 12], "products": [13]}], "diagram_type": "multiple"}, {"id": 1372, "width": 1260, "height": 836, "file_name": "op980079g-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [758.27, 572.61, 426.09, 119.19], "category_id": 2}, {"id": 1, "bbox": [709.71, 441.67, 42.02, 47.41], "category_id": 2}, {"id": 2, "bbox": [958.57, 790.73, 88.34, 43.09], "category_id": 2}, {"id": 3, "bbox": [402.77, 214.41, 167.03, 43.52], "category_id": 2}, {"id": 4, "bbox": [1210.84, 530.36, 41.6, 51.08], "category_id": 3}, {"id": 5, "bbox": [692.72, 10.09, 546.48, 225.76], "category_id": 1}, {"id": 6, "bbox": [81.94, 703.78, 95.81, 54.86], "category_id": 2}, {"id": 7, "bbox": [998.42, 498.82, 44.75, 44.78], "category_id": 3}, {"id": 8, "bbox": [159.47, 203.69, 44.12, 49.19], "category_id": 3}, {"id": 9, "bbox": [972.58, 202.43, 39.08, 47.93], "category_id": 3}, {"id": 10, "bbox": [383.86, 146.31, 201.07, 56.12], "category_id": 2}, {"id": 11, "bbox": [422.31, 634.41, 41.6, 50.45], "category_id": 3}, {"id": 12, "bbox": [359.91, 8.2, 255.28, 104.68], "category_id": 1}, {"id": 13, "bbox": [5.67, 420.63, 213.68, 115.4], "category_id": 2}, {"id": 14, "bbox": [298.77, 439.55, 361.17, 227.02], "category_id": 1}, {"id": 15, "bbox": [710.37, 710.71, 338.47, 54.24], "category_id": 2}, {"id": 16, "bbox": [5.67, 575.13, 196.66, 106.58], "category_id": 2}, {"id": 17, "bbox": [5.67, 9.46, 323.35, 182.25], "category_id": 1}, {"id": 18, "bbox": [763.2, 419.37, 381.45, 89.54], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 420, 501, 434], "ImageBB": [450, 439, 765, 648]}, "reactions": [{"reactants": [17, 12], "conditions": [10, 3], "products": [5]}, {"reactants": [5], "conditions": [13, 16, 6], "products": [14]}, {"reactants": [14, 18], "conditions": [0, 15, 2], "products": [4]}], "diagram_type": "multiple"}, {"id": 406, "width": 1356, "height": 1112, "file_name": "op400278d-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [289.6, 239.0, 189.9, 57.0], "category_id": 2}, {"id": 1, "bbox": [538.0, 0.0, 333.0, 177.1], "category_id": 2}, {"id": 2, "bbox": [114.0, 632.0, 212.0, 89.0], "category_id": 2}, {"id": 3, "bbox": [652.0, 592.0, 61.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [1100.0, 589.0, 58.0, 49.0], "category_id": 3}, {"id": 5, "bbox": [187.0, 587.0, 65.0, 50.0], "category_id": 3}, {"id": 6, "bbox": [369.0, 947.0, 56.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [958.0, 946.0, 61.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [878.0, 986.0, 221.0, 87.0], "category_id": 2}, {"id": 9, "bbox": [289.0, 989.0, 219.0, 88.0], "category_id": 2}, {"id": 10, "bbox": [574.0, 628.0, 217.0, 94.0], "category_id": 2}, {"id": 11, "bbox": [1020.0, 626.0, 215.0, 91.0], "category_id": 2}, {"id": 12, "bbox": [43.0, 250.0, 166.0, 46.0], "category_id": 2}, {"id": 13, "bbox": [496.0, 189.0, 395.0, 106.0], "category_id": 2}, {"id": 14, "bbox": [46.0, 26.0, 185.0, 216.0], "category_id": 1}, {"id": 15, "bbox": [309.0, 22.0, 181.0, 218.0], "category_id": 1}, {"id": 16, "bbox": [899.0, 63.0, 454.0, 196.0], "category_id": 1}, {"id": 17, "bbox": [15.0, 358.0, 475.0, 244.0], "category_id": 1}, {"id": 18, "bbox": [458.0, 354.0, 458.0, 262.0], "category_id": 1}, {"id": 19, "bbox": [927.0, 342.0, 429.0, 250.0], "category_id": 1}, {"id": 20, "bbox": [183.0, 729.0, 554.0, 253.0], "category_id": 1}, {"id": 21, "bbox": [765.0, 734.0, 468.0, 255.0], "category_id": 1}], "reactions": [{"reactants": [14, 15], "conditions": [1, 13], "products": [16]}], "corefs": [[17, 5], [18, 3], [19, 4], [20, 6], [21, 7]], "caption": "Table 5. Comparative study of Pd-PEPPSI-IPr (2) and Pd- PEPPSI-IPent (1) in aryl aminations with electron-de\ufb01cient anilines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 94, 784, 139], "ImageBB": [448, 146, 787, 424]}, "diagram_type": "single"}, {"id": 1192, "width": 1356, "height": 1276, "file_name": "ol500444z-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [300.0, 553.68, 647.64, 52.42], "category_id": 2}, {"id": 1, "bbox": [374.44, 1059.19, 645.1, 150.63], "category_id": 2}, {"id": 2, "bbox": [974.77, 656.82, 94.97, 43.43], "category_id": 3}, {"id": 3, "bbox": [1069.74, 1155.54, 223.85, 54.28], "category_id": 2}, {"id": 4, "bbox": [1203.37, 656.82, 44.77, 43.43], "category_id": 3}, {"id": 5, "bbox": [1010.73, 6.11, 189.93, 273.45], "category_id": 1}, {"id": 6, "bbox": [362.23, 209.67, 644.43, 52.92], "category_id": 2}, {"id": 7, "bbox": [1069.74, 264.63, 59.02, 41.39], "category_id": 3}, {"id": 8, "bbox": [974.77, 701.6, 99.04, 48.18], "category_id": 2}, {"id": 9, "bbox": [1172.17, 700.25, 103.79, 53.6], "category_id": 2}, {"id": 10, "bbox": [88.7, 961.9, 228.3, 142.4], "category_id": 1}, {"id": 11, "bbox": [85.8, 452.3, 229.63, 154.31], "category_id": 1}, {"id": 12, "bbox": [148.6, 1102.61, 56.94, 45.59], "category_id": 3}, {"id": 13, "bbox": [112.7, 111.8, 229.5, 152.15], "category_id": 1}, {"id": 14, "bbox": [317.4, 352.2, 214.2, 174.1], "category_id": 1}, {"id": 15, "bbox": [1167.6, 1110.08, 35.77, 42.75], "category_id": 3}, {"id": 16, "bbox": [163.2, 264.63, 60.65, 46.27], "category_id": 3}, {"id": 17, "bbox": [942.4, 388.5, 179.2, 268.1], "category_id": 1}, {"id": 18, "bbox": [133.63, 604.57, 61.05, 48.83], "category_id": 3}, {"id": 19, "bbox": [529.38, 980.34, 568.3, 47.49], "category_id": 2}, {"id": 20, "bbox": [1039.47, 309.41, 116.42, 52.08], "category_id": 2}, {"id": 21, "bbox": [42.26, 972.68, 50.55, 52.09], "category_id": 2}, {"id": 22, "bbox": [1103.81, 847.08, 185.35, 263.47], "category_id": 1}, {"id": 23, "bbox": [316.5, 851.67, 209.81, 174.63], "category_id": 1}, {"id": 24, "bbox": [1129.85, 390.6, 186.88, 268.06], "category_id": 1}, {"id": 25, "bbox": [529.38, 484.04, 433.5, 47.48], "category_id": 2}, {"id": 26, "bbox": [36.13, 490.16, 55.15, 49.02], "category_id": 2}, {"id": 27, "bbox": [52.98, 134.78, 58.21, 49.02], "category_id": 2}, {"id": 28, "bbox": [550.82, 136.32, 456.48, 44.42], "category_id": 2}, {"id": 29, "bbox": [342.5, 6.11, 211.39, 173.1], "category_id": 1}], "caption": "Scheme 2. Optimization of Conditions for the Synthesis of Tetrahydroquinoxaline 4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 471, 782, 501], "ImageBB": [448, 507, 787, 826]}, "reactions": [{"reactants": [13, 29], "conditions": [28, 6], "products": [5]}, {"reactants": [11, 14], "conditions": [25, 0], "products": [17, 24]}, {"reactants": [10, 23], "conditions": [19, 1], "products": [22]}], "diagram_type": "multiple"}, {"id": 456, "width": 1344, "height": 620, "file_name": "op200052z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [749.0, 50.4, 473.9, 227.6], "category_id": 1}, {"id": 1, "bbox": [974.0, 327.1, 44.9, 46.9], "category_id": 3}, {"id": 2, "bbox": [180.01, 328.97, 44.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [1285.89, 153.04, 32.1, 51.0], "category_id": 3}, {"id": 4, "bbox": [23.2, 64.4, 401.8, 236.6], "category_id": 1}, {"id": 5, "bbox": [9.0, 460.0, 1335.0, 160.0], "category_id": 4}, {"id": 6, "bbox": [452.0, 206.0, 235.0, 121.0], "category_id": 2}, {"id": 7, "bbox": [438.0, 3.0, 273.0, 176.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 6], "products": [0, 3]}], "corefs": [[4, 2], [0, 1]], "caption": "Table 2. Results of di\ufb02uoromethylation of 5", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 444, 317, 459], "ImageBB": [71, 469, 407, 624]}, "diagram_type": "single"}, {"id": 1105, "width": 1348, "height": 1392, "file_name": "jo980058k-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [616.2, 717.93, 33.42, 46.66], "category_id": 2}, {"id": 1, "bbox": [739.21, 1318.4, 110.29, 48.46], "category_id": 2}, {"id": 2, "bbox": [709.13, 1320.07, 26.74, 48.46], "category_id": 2}, {"id": 3, "bbox": [272.98, 1340.12, 347.58, 46.79], "category_id": 3}, {"id": 4, "bbox": [272.98, 1296.68, 275.73, 43.44], "category_id": 3}, {"id": 5, "bbox": [272.98, 1248.22, 466.23, 51.8], "category_id": 3}, {"id": 6, "bbox": [161.02, 1323.41, 36.76, 43.45], "category_id": 2}, {"id": 7, "bbox": [161.02, 1269.94, 35.09, 46.79], "category_id": 2}, {"id": 8, "bbox": [832.79, 543.03, 35.09, 45.11], "category_id": 2}, {"id": 9, "bbox": [600.51, 780.32, 90.24, 46.79], "category_id": 2}, {"id": 10, "bbox": [949.76, 564.75, 193.85, 43.45], "category_id": 3}, {"id": 11, "bbox": [45.26, 781.3, 84.25, 48.75], "category_id": 2}, {"id": 12, "bbox": [45.26, 1059.84, 84.25, 52.92], "category_id": 2}, {"id": 13, "bbox": [45.26, 418.51, 89.82, 51.53], "category_id": 2}, {"id": 14, "bbox": [184.51, 890.63, 290.35, 104.45], "category_id": 3}, {"id": 15, "bbox": [192.17, 0.0, 416.37, 176.87], "category_id": 1}, {"id": 16, "bbox": [45.26, 178.27, 51.52, 45.95], "category_id": 3}, {"id": 17, "bbox": [0.0, 6.27, 132.29, 149.71], "category_id": 1}, {"id": 18, "bbox": [45.26, 419.9, 87.03, 50.14], "category_id": 2}, {"id": 19, "bbox": [884.27, 274.36, 346.74, 231.19], "category_id": 1}, {"id": 20, "bbox": [297.31, 176.18, 57.09, 46.65], "category_id": 3}, {"id": 21, "bbox": [45.26, 725.59, 54.31, 41.09], "category_id": 2}, {"id": 22, "bbox": [799.32, 4.18, 487.4, 155.28], "category_id": 1}, {"id": 23, "bbox": [646.14, 108.63, 84.95, 45.96], "category_id": 2}, {"id": 24, "bbox": [731.09, 354.44, 42.47, 39.0], "category_id": 2}, {"id": 25, "bbox": [232.56, 1002.05, 453.97, 231.88], "category_id": 1}, {"id": 26, "bbox": [184.51, 654.57, 294.53, 229.1], "category_id": 1}, {"id": 27, "bbox": [570.95, 522.26, 251.05, 101.67], "category_id": 2}, {"id": 28, "bbox": [949.72, 513.21, 325.28, 52.69], "category_id": 3}, {"id": 29, "bbox": [27.15, 1174.74, 164.55, 207.26], "category_id": 2}, {"id": 30, "bbox": [731.09, 1126.69, 80.07, 49.44], "category_id": 2}, {"id": 31, "bbox": [984.53, 1249.94, 61.97, 48.75], "category_id": 3}, {"id": 32, "bbox": [948.33, 169.91, 61.27, 48.05], "category_id": 3}, {"id": 33, "bbox": [848.76, 995.08, 492.27, 231.89], "category_id": 1}, {"id": 34, "bbox": [763.12, 647.6, 584.88, 234.67], "category_id": 1}, {"id": 35, "bbox": [276.42, 535.49, 60.58, 52.23], "category_id": 3}, {"id": 36, "bbox": [59.88, 355.83, 43.17, 48.05], "category_id": 2}, {"id": 37, "bbox": [735.27, 1073.07, 48.04, 36.91], "category_id": 2}, {"id": 38, "bbox": [194.26, 284.81, 478.34, 231.88], "category_id": 1}, {"id": 39, "bbox": [966.43, 894.81, 58.49, 50.13], "category_id": 3}, {"id": 40, "bbox": [646.84, 48.74, 53.61, 37.61], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 183, 275, 197], "ImageBB": [74, 204, 411, 552]}, "reactions": [{"reactants": [17, 15], "conditions": [40, 23], "products": [22]}, {"reactants": [22], "conditions": [36, 18], "products": [38]}, {"reactants": [38], "conditions": [24], "products": [19]}, {"reactants": [19], "conditions": [21, 11], "products": [26]}, {"reactants": [26], "conditions": [0, 9], "products": [34]}, {"reactants": [34], "conditions": [12], "products": [25]}, {"reactants": [25], "conditions": [37, 30], "products": [33]}], "diagram_type": "multiple"}, {"id": 536, "width": 996, "height": 1456, "file_name": "jo000585f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [169.6, 1140.0, 340.8, 225.1], "category_id": 1}, {"id": 1, "bbox": [656.0, 328.0, 296.0, 64.9], "category_id": 3}, {"id": 2, "bbox": [172.0, 323.2, 283.0, 76.2], "category_id": 3}, {"id": 3, "bbox": [223.32, 1392.56, 160.6, 59.17], "category_id": 3}, {"id": 4, "bbox": [219.09, 893.84, 133.14, 61.28], "category_id": 3}, {"id": 5, "bbox": [277.0, 487.0, 111.8, 52.2], "category_id": 2}, {"id": 6, "bbox": [163.0, 79.0, 335.2, 234.0], "category_id": 1}, {"id": 7, "bbox": [158.6, 639.5, 347.5, 222.7], "category_id": 1}, {"id": 8, "bbox": [648.0, 75.0, 345.0, 236.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [], "products": [8]}, {"reactants": [6], "conditions": [5], "products": [7]}, {"reactants": [7], "conditions": [], "products": [0]}], "corefs": [[6, 2], [8, 1], [7, 4], [0, 3]], "caption": "  Table 1. Phosphoramidate-Aminophosphonate Rearrangement of (R)-[1-2H1]6c Induced by s-BuLi or               LDA in Et2O or THF ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 440, 761, 478], "ImageBB": [424, 63, 673, 427]}, "diagram_type": "tree"}, {"id": 1016, "width": 1324, "height": 1040, "file_name": "ja992608h-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [312.62, 617.33, 55.64, 49.02], "category_id": 3}, {"id": 1, "bbox": [0.0, 708.74, 517.94, 289.46], "category_id": 1}, {"id": 2, "bbox": [947.8, 608.72, 56.96, 49.68], "category_id": 3}, {"id": 3, "bbox": [312.62, 982.96, 63.58, 49.02], "category_id": 3}, {"id": 4, "bbox": [0.0, 347.08, 532.51, 286.81], "category_id": 1}, {"id": 5, "bbox": [448.4, 82.13, 84.11, 51.01], "category_id": 2}, {"id": 6, "bbox": [1037.87, 989.59, 54.98, 47.69], "category_id": 3}, {"id": 7, "bbox": [1123.31, 82.13, 125.18, 52.33], "category_id": 2}, {"id": 8, "bbox": [186.78, 262.96, 43.71, 47.69], "category_id": 3}, {"id": 9, "bbox": [647.1, 333.17, 529.86, 284.16], "category_id": 1}, {"id": 10, "bbox": [735.85, 723.31, 514.63, 286.81], "category_id": 1}, {"id": 11, "bbox": [592.12, 2.65, 510.0, 281.51], "category_id": 1}, {"id": 12, "bbox": [553.05, 445.78, 70.87, 57.63], "category_id": 2}, {"id": 13, "bbox": [610.67, 838.57, 30.47, 43.71], "category_id": 2}, {"id": 14, "bbox": [902.76, 270.91, 43.71, 44.38], "category_id": 3}, {"id": 15, "bbox": [15.9, 21.86, 394.08, 207.32], "category_id": 1}, {"id": 16, "bbox": [1235.91, 443.13, 43.71, 49.68], "category_id": 2}], "caption": "Scheme 3a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 135, 78], "ImageBB": [76, 84, 407, 344]}, "reactions": [{"reactants": [15], "conditions": [5], "products": [11]}, {"reactants": [11], "conditions": [7], "products": [4]}, {"reactants": [4], "conditions": [12], "products": [9]}, {"reactants": [9], "conditions": [16], "products": [1]}, {"reactants": [1], "conditions": [13], "products": [10]}], "diagram_type": "multiple"}, {"id": 572, "width": 1348, "height": 1064, "file_name": "acs.orglett.5b00805-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [501.09, 253.91, 54.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [957.2, 3.0, 316.3, 238.2], "category_id": 1}, {"id": 2, "bbox": [133.3, 35.1, 219.9, 207.6], "category_id": 1}, {"id": 3, "bbox": [461.4, 391.3, 299.5, 305.7], "category_id": 1}, {"id": 4, "bbox": [906.3, 366.5, 432.7, 334.5], "category_id": 1}, {"id": 5, "bbox": [16.4, 388.1, 247.6, 306.9], "category_id": 1}, {"id": 6, "bbox": [620.0, 91.0, 339.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [420.82, 69.5, 166.78, 109.64], "category_id": 1}, {"id": 8, "bbox": [616.0, 159.0, 237.3, 42.8], "category_id": 2}, {"id": 9, "bbox": [1048.0, 245.0, 61.0, 55.0], "category_id": 3}, {"id": 10, "bbox": [32.0, 988.0, 1314.0, 76.0], "category_id": 4}, {"id": 11, "bbox": [23.0, 701.0, 323.0, 90.0], "category_id": 3}, {"id": 12, "bbox": [50.0, 237.0, 397.0, 135.0], "category_id": 3}, {"id": 13, "bbox": [1101.0, 701.0, 212.0, 84.0], "category_id": 3}, {"id": 14, "bbox": [429.0, 695.0, 514.0, 275.0], "category_id": 3}], "reactions": [{"reactants": [2, 7], "conditions": [6, 8], "products": [1]}], "corefs": [[2, 12], [7, 0], [1, 9], [5, 11], [3, 14], [4, 13]], "caption": "Table 1. Enantioselective Addition of Cumene Hydroperoxide 2a to Ketimines 1a\u2212c Derived from Isatins Using Various Chiral Organocatalysts 3,4a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 174, 414, 219], "ImageBB": [82, 226, 419, 492]}, "diagram_type": "single"}, {"id": 927, "width": 1416, "height": 1020, "file_name": "acs.oprd.5b00144-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1289.2, 286.95, 126.8, 126.82], "category_id": 2}, {"id": 1, "bbox": [451.93, 0.0, 401.64, 165.79], "category_id": 1}, {"id": 2, "bbox": [784.86, 252.94, 494.43, 291.9], "category_id": 1}, {"id": 3, "bbox": [1367.12, 181.38, 40.38, 46.05], "category_id": 3}, {"id": 4, "bbox": [1117.07, 662.46, 298.93, 230.97], "category_id": 1}, {"id": 5, "bbox": [885.44, 0.0, 223.84, 57.39], "category_id": 2}, {"id": 6, "bbox": [495.85, 446.36, 256.42, 118.32], "category_id": 2}, {"id": 7, "bbox": [981.78, 569.64, 55.25, 53.85], "category_id": 3}, {"id": 8, "bbox": [927.24, 730.47, 134.58, 60.94], "category_id": 2}, {"id": 9, "bbox": [534.1, 339.38, 201.88, 77.22], "category_id": 1}, {"id": 10, "bbox": [625.48, 926.73, 46.75, 49.6], "category_id": 3}, {"id": 11, "bbox": [448.39, 667.42, 461.85, 226.01], "category_id": 1}, {"id": 12, "bbox": [1126.99, 0.0, 289.01, 165.79], "category_id": 1}, {"id": 13, "bbox": [1291.33, 930.27, 46.75, 48.18], "category_id": 3}], "caption": "Scheme 1. Initial Synthesis of 1, Lorcaserin", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 322, 110], "ImageBB": [82, 129, 436, 384]}, "reactions": [{"reactants": [1], "conditions": [5], "products": [12]}, {"reactants": [], "conditions": [9, 6], "products": [2]}, {"reactants": [11], "conditions": [8], "products": [4]}], "diagram_type": "multiple"}, {"id": 144, "width": 1352, "height": 1560, "file_name": "op700274v-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [240.2, 19.0, 278.8, 251.3], "category_id": 1}, {"id": 1, "bbox": [528.0, 117.0, 257.0, 72.8], "category_id": 2}, {"id": 2, "bbox": [841.8, 19.0, 271.2, 202.9], "category_id": 1}, {"id": 3, "bbox": [512.0, 2.0, 273.0, 87.0], "category_id": 2}, {"id": 4, "bbox": [937.0, 227.0, 64.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [5.0, 301.0, 1347.0, 1241.0], "category_id": 4}, {"id": 6, "bbox": [345.0, 230.0, 54.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 1], "products": [2]}], "corefs": [[0, 6], [2, 4]], "caption": "Table 1. N-Detosylationa of N-tosyl-7-azaindole (1a)", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 343, 59], "ImageBB": [58, 60, 396, 450]}, "diagram_type": "single"}, {"id": 362, "width": 1344, "height": 1348, "file_name": "ol1030487-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [391.6, 365.2, 106.4, 95.99], "category_id": 1}, {"id": 1, "bbox": [538.0, 385.0, 267.0, 154.0], "category_id": 1}, {"id": 2, "bbox": [1032.0, 411.0, 256.0, 164.0], "category_id": 1}, {"id": 3, "bbox": [1258.0, 185.0, 43.0, 34.0], "category_id": 3}, {"id": 4, "bbox": [549.05, 298.06, 108.42, 43.37], "category_id": 2}, {"id": 5, "bbox": [101.0, 22.0, 240.5, 200.2], "category_id": 1}, {"id": 6, "bbox": [79.0, 361.0, 39.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [213.0, 579.0, 41.0, 35.0], "category_id": 3}, {"id": 8, "bbox": [658.0, 549.0, 41.0, 34.0], "category_id": 3}, {"id": 9, "bbox": [1213.0, 553.0, 40.0, 34.0], "category_id": 3}, {"id": 10, "bbox": [404.0, 473.0, 79.0, 46.0], "category_id": 2}, {"id": 11, "bbox": [130.0, 192.0, 33.0, 27.0], "category_id": 3}, {"id": 12, "bbox": [857.0, 481.0, 84.0, 34.0], "category_id": 2}, {"id": 13, "bbox": [738.0, 231.0, 23.0, 36.0], "category_id": 3}, {"id": 14, "bbox": [729.0, 79.0, 39.0, 32.0], "category_id": 3}, {"id": 15, "bbox": [220.0, 293.0, 107.0, 70.0], "category_id": 2}, {"id": 16, "bbox": [578.0, 181.0, 201.0, 47.0], "category_id": 1}, {"id": 17, "bbox": [1229.0, 354.0, 46.0, 38.0], "category_id": 3}, {"id": 18, "bbox": [1148.0, 299.5, 195.0, 57.9], "category_id": 1}, {"id": 19, "bbox": [3.6, 300.6, 188.4, 62.4], "category_id": 1}, {"id": 20, "bbox": [707.5, 984.9, 324.9, 357.7], "category_id": 1}, {"id": 21, "bbox": [843.0, 373.0, 103.0, 91.0], "category_id": 1}, {"id": 22, "bbox": [1029.19, 20.4, 281.0, 196.8], "category_id": 1}, {"id": 23, "bbox": [80.0, 395.2, 258.5, 162.6], "category_id": 1}, {"id": 24, "bbox": [1022.0, 302.39, 111.0, 74.0], "category_id": 2}, {"id": 25, "bbox": [576.0, 21.7, 186.7, 62.3], "category_id": 1}, {"id": 26, "bbox": [307.7, 932.7, 372.1, 399.7], "category_id": 1}], "reactions": [{"reactants": [25, 16], "conditions": [4], "products": [1]}, {"reactants": [1], "conditions": [0, 10], "products": [23]}, {"reactants": [23], "conditions": [19, 15], "products": [5]}, {"reactants": [1], "conditions": [21, 12], "products": [2]}, {"reactants": [2], "conditions": [24, 18], "products": [22]}], "corefs": [[25, 14], [16, 13], [1, 8], [23, 7], [19, 6], [5, 11], [22, 3], [18, 17], [2, 9]], "caption": "Figure 1. Stereo plots of the X-ray crystal structures of (\u00fe)-9: C, gray; N, blue; O, red. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 994, 405, 1021], "ImageBB": [71, 644, 407, 981]}, "diagram_type": "tree"}, {"id": 147, "width": 1352, "height": 3428, "file_name": "op700249f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [936.44, 215.89, 131.36, 51.95], "category_id": 3}, {"id": 1, "bbox": [97.82, 216.63, 83.86, 51.21], "category_id": 3}, {"id": 2, "bbox": [0.0, 3253.22, 1351.28, 151.64], "category_id": 2}, {"id": 3, "bbox": [382.06, 17.0, 318.38, 86.83], "category_id": 2}, {"id": 4, "bbox": [4.89, 266.35, 1346.39, 2973.05], "category_id": 4}, {"id": 5, "bbox": [5.05, 3.64, 302.05, 206.32], "category_id": 1}, {"id": 6, "bbox": [811.76, 5.12, 428.96, 249.36], "category_id": 1}, {"id": 7, "bbox": [316.75, 147.62, 466.81, 101.67], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [3, 7], "products": [6]}], "corefs": [[5, 1], [6, 0]], "caption": "Table 1. Scope of CuAAC to prepare N-triazole-linked glycosidic amino acids and peptides ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 361, 73], "ImageBB": [58, 81, 396, 938]}, "diagram_type": "single"}, {"id": 902, "width": 1316, "height": 820, "file_name": "acs.joc.5b02382-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [541.0, 360.0, 258.0, 99.0], "category_id": 3}, {"id": 1, "bbox": [483.5, 203.0, 403.7, 147.7], "category_id": 1}, {"id": 2, "bbox": [7.0, 244.2, 443.9, 114.5], "category_id": 1}, {"id": 3, "bbox": [865.8, 465.4, 405.7, 105.5], "category_id": 1}, {"id": 4, "bbox": [479.9, 465.1, 381.7, 105.0], "category_id": 1}, {"id": 5, "bbox": [608.0, 34.3, 255.2, 54.6], "category_id": 2}, {"id": 6, "bbox": [907.9, 212.5, 399.8, 144.5], "category_id": 1}, {"id": 7, "bbox": [878.0, 29.5, 338.4, 124.5], "category_id": 1}, {"id": 8, "bbox": [281.3, 0.0, 304.7, 150.5], "category_id": 1}, {"id": 9, "bbox": [38.9, 10.6, 196.1, 141.1], "category_id": 1}, {"id": 10, "bbox": [876.3, 639.0, 346.8, 124.2], "category_id": 1}, {"id": 11, "bbox": [434.5, 638.4, 320.2, 122.6], "category_id": 1}, {"id": 12, "bbox": [74.0, 375.0, 281.0, 356.5], "category_id": 3}, {"id": 13, "bbox": [1002.0, 588.0, 119.0, 50.0], "category_id": 3}, {"id": 14, "bbox": [542.0, 768.0, 151.0, 46.0], "category_id": 3}, {"id": 15, "bbox": [981.0, 138.0, 35.0, 29.0], "category_id": 3}, {"id": 16, "bbox": [408.0, 127.0, 52.0, 42.0], "category_id": 3}, {"id": 17, "bbox": [111.0, 127.0, 36.0, 35.0], "category_id": 3}, {"id": 18, "bbox": [539.0, 582.0, 140.0, 48.0], "category_id": 3}, {"id": 19, "bbox": [989.0, 374.0, 147.0, 54.0], "category_id": 3}, {"id": 20, "bbox": [1002.0, 771.0, 130.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [9, 8], "conditions": [5], "products": [7]}], "corefs": [[9, 17], [8, 16], [7, 15], [2, 12], [1, 0], [4, 18], [11, 14], [6, 19], [3, 13], [10, 20]], "caption": "Table 2. Substrate Scope of the Propargylic Amidesa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 274, 748, 295], "ImageBB": [453, 300, 782, 505]}, "diagram_type": "single"}, {"id": 1054, "width": 1356, "height": 944, "file_name": "jo2001534-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [971.38, 53.59, 284.9, 170.26], "category_id": 1}, {"id": 1, "bbox": [27.13, 309.32, 281.51, 42.73], "category_id": 3}, {"id": 2, "bbox": [147.88, 590.15, 276.08, 139.06], "category_id": 1}, {"id": 3, "bbox": [165.51, 769.23, 210.97, 51.55], "category_id": 3}, {"id": 4, "bbox": [203.5, 836.38, 124.82, 107.62], "category_id": 2}, {"id": 5, "bbox": [1001.23, 305.93, 246.91, 46.8], "category_id": 3}, {"id": 6, "bbox": [1082.63, 553.52, 269.3, 175.69], "category_id": 1}, {"id": 7, "bbox": [30.53, 4.07, 242.16, 299.82], "category_id": 1}, {"id": 8, "bbox": [1050.07, 373.08, 120.07, 109.21], "category_id": 2}, {"id": 9, "bbox": [1143.68, 835.02, 128.21, 108.98], "category_id": 2}, {"id": 10, "bbox": [567.77, 369.01, 126.85, 113.28], "category_id": 2}, {"id": 11, "bbox": [710.86, 836.31, 103.13, 105.39], "category_id": 2}, {"id": 12, "bbox": [693.94, 767.87, 123.46, 48.16], "category_id": 3}, {"id": 13, "bbox": [495.87, 314.75, 267.26, 47.48], "category_id": 3}, {"id": 14, "bbox": [100.39, 369.01, 119.39, 113.28], "category_id": 2}, {"id": 15, "bbox": [1176.24, 769.23, 71.9, 46.8], "category_id": 3}, {"id": 16, "bbox": [617.29, 592.86, 277.44, 139.06], "category_id": 1}, {"id": 17, "bbox": [466.02, 10.85, 287.61, 221.82], "category_id": 1}], "caption": "Scheme 5. Computational Simulation of the 7-Endo-Trig Cyclization of the Anion 1a- To Give Anion 7a- as a Model Reaction for the Formation of Type 6 Compounds for the Gas Phase and SCRF-CPCM(UAKS) Solution-Phase Simulations (THF) (Relative Energies: SCS-MP2/6-311\u00feG(d,p)// B3LYP/6-31\u00feG(d,p) (Corrected for Zero-Point Energies) [kcal/mol]; See the Supporting Information for Optimized Structures) ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 310, 771, 431], "ImageBB": [436, 442, 775, 678]}, "reactions": [{"reactants": [7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [], "products": [7]}, {"reactants": [17], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [17]}, {"reactants": [0], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [0]}, {"reactants": [2], "conditions": [], "products": [16]}, {"reactants": [16], "conditions": [], "products": [2]}, {"reactants": [16], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [16]}], "diagram_type": "multiple"}, {"id": 149, "width": 1356, "height": 816, "file_name": "op7001886-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [268.0, 144.0, 192.0, 93.0], "category_id": 2}, {"id": 1, "bbox": [308.0, 66.0, 113.0, 52.0], "category_id": 2}, {"id": 2, "bbox": [41.41, 275.34, 55.69, 44.46], "category_id": 3}, {"id": 3, "bbox": [7.0, 326.8, 1342.0, 476.2], "category_id": 4}, {"id": 4, "bbox": [1242.4, 276.0, 57.2, 41.9], "category_id": 3}, {"id": 5, "bbox": [2.0, 23.0, 255.4, 212.7], "category_id": 1}, {"id": 6, "bbox": [950.75, 275.62, 58.4, 41.57], "category_id": 3}, {"id": 7, "bbox": [1070.62, 1.25, 280.0, 264.0], "category_id": 1}, {"id": 8, "bbox": [771.16, 1.53, 286.0, 271.0], "category_id": 1}, {"id": 9, "bbox": [480.38, 2.72, 300.0, 269.0], "category_id": 1}, {"id": 10, "bbox": [554.75, 277.09, 65.7, 40.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [9, 8, 7]}], "corefs": [[5, 2], [9, 10], [8, 6], [7, 4]], "caption": "Table 1", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 441, 471, 455], "ImageBB": [424, 456, 763, 660]}, "diagram_type": "single"}, {"id": 746, "width": 1344, "height": 544, "file_name": "jo991283k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [251.3, 59.1, 173.6, 137.9], "category_id": 1}, {"id": 1, "bbox": [844.4, 60.0, 179.3, 135.8], "category_id": 1}, {"id": 2, "bbox": [787.0, 4.0, 311.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [3.0, 254.0, 1340.0, 290.0], "category_id": 4}, {"id": 4, "bbox": [546.0, 66.0, 152.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [501.0, 134.0, 254.0, 84.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [4, 5], "products": [1]}], "corefs": [], "caption": "Table 2. Effect of Bulkiness of the Group Adjacent to    the Carbonyl Moiety on Stereoselectivity in the           Reduction by the APG4 Systema ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [84, 342, 399, 379], "ImageBB": [74, 385, 410, 521]}, "diagram_type": "single"}, {"id": 305, "width": 1344, "height": 1400, "file_name": "ol303154k-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [286.0, 232.0, 154.0, 49.0], "category_id": 2}, {"id": 1, "bbox": [919.8, 1050.8, 332.0, 224.6], "category_id": 1}, {"id": 2, "bbox": [579.4, 92.2, 273.6, 205.0], "category_id": 1}, {"id": 3, "bbox": [586.0, 343.8, 301.6, 202.6], "category_id": 1}, {"id": 4, "bbox": [343.0, 575.8, 136.0, 145.2], "category_id": 1}, {"id": 5, "bbox": [26.4, 261.6, 168.0, 163.2], "category_id": 1}, {"id": 6, "bbox": [224.2, 102.6, 262.2, 122.6], "category_id": 1}, {"id": 7, "bbox": [1254.2, 189.0, 57.8, 66.0], "category_id": 3}, {"id": 8, "bbox": [901.6, 399.0, 372.4, 112.0], "category_id": 2}, {"id": 9, "bbox": [893.0, 175.6, 330.2, 109.8], "category_id": 2}, {"id": 10, "bbox": [174.0, 0.0, 162.3, 46.0], "category_id": 2}, {"id": 11, "bbox": [547.0, 1338.0, 410.0, 62.0], "category_id": 2}, {"id": 12, "bbox": [995.0, 1341.0, 233.0, 56.0], "category_id": 2}, {"id": 13, "bbox": [115.0, 1338.0, 353.0, 62.0], "category_id": 2}, {"id": 14, "bbox": [1008.0, 1272.0, 187.0, 58.0], "category_id": 2}, {"id": 15, "bbox": [534.0, 573.0, 441.0, 87.0], "category_id": 2}, {"id": 16, "bbox": [515.4, 1054.6, 397.6, 263.4], "category_id": 1}, {"id": 17, "bbox": [296.0, 355.0, 159.0, 54.0], "category_id": 2}, {"id": 18, "bbox": [1266.0, 422.0, 67.0, 54.0], "category_id": 3}, {"id": 19, "bbox": [233.0, 427.0, 307.0, 125.0], "category_id": 1}, {"id": 20, "bbox": [95.0, 939.0, 381.0, 394.0], "category_id": 1}, {"id": 21, "bbox": [338.25, 3.58, 124.48, 37.89], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [6, 0], "products": [2]}, {"reactants": [5], "conditions": [19, 17], "products": [3]}], "corefs": [[20, 13], [16, 11], [1, 12]], "caption": "Figure 1. Bioactive spiro-tetrahydroquinolines.", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 492, 321, 505], "ImageBB": [71, 130, 407, 480]}, "diagram_type": "tree"}, {"id": 600, "width": 1356, "height": 416, "file_name": "acs.oprd.6b00095-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1064.0, 38.0, 205.0, 306.0], "category_id": 1}, {"id": 1, "bbox": [361.3, 39.5, 209.7, 311.5], "category_id": 1}, {"id": 2, "bbox": [4.0, 42.0, 213.0, 308.0], "category_id": 1}, {"id": 3, "bbox": [706.0, 51.0, 207.0, 308.0], "category_id": 1}, {"id": 4, "bbox": [46.0, 368.0, 136.0, 43.7], "category_id": 2}, {"id": 5, "bbox": [1142.0, 363.0, 214.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [778.0, 362.0, 238.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [403.0, 353.0, 222.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [[2, 4], [1, 7], [3, 6], [0, 5]], "caption": "Figure 1. Catalytic oxidation of glucose to glucaric acid.", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 612, 715, 626], "ImageBB": [448, 499, 787, 603]}, "diagram_type": "single"}, {"id": 474, "width": 1896, "height": 396, "file_name": "op100108j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [910.81, 342.44, 54.34, 53.56], "category_id": 3}, {"id": 1, "bbox": [1617.17, 341.01, 51.47, 51.48], "category_id": 3}, {"id": 2, "bbox": [241.64, 339.58, 47.18, 52.91], "category_id": 3}, {"id": 3, "bbox": [653.4, 9.0, 565.3, 361.3], "category_id": 1}, {"id": 4, "bbox": [1333.3, 2.0, 560.1, 362.5], "category_id": 1}, {"id": 5, "bbox": [2.6, 35.9, 541.9, 328.6], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [], "products": [3, 4]}], "corefs": [[5, 2], [3, 0], [4, 1]], "caption": "Figure 1. Structures of (+)-catechin (1) and its B-ring fission lactone products, 2 and 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 148, 540, 162], "ImageBB": [173, 46, 647, 145]}, "diagram_type": "single"}, {"id": 1340, "width": 1352, "height": 936, "file_name": "op700009t-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [812.96, 890.59, 45.31, 43.28], "category_id": 3}, {"id": 1, "bbox": [421.36, 173.11, 39.9, 40.58], "category_id": 3}, {"id": 2, "bbox": [587.74, 526.78, 327.35, 367.19], "category_id": 1}, {"id": 3, "bbox": [1043.59, 175.82, 39.23, 41.25], "category_id": 3}, {"id": 4, "bbox": [986.78, 526.78, 365.22, 367.87], "category_id": 1}, {"id": 5, "bbox": [654.7, 132.54, 116.33, 43.28], "category_id": 2}, {"id": 6, "bbox": [0.0, 664.73, 39.9, 48.69], "category_id": 3}, {"id": 7, "bbox": [650.64, 61.54, 132.56, 45.98], "category_id": 2}, {"id": 8, "bbox": [342.9, 615.37, 127.83, 56.12], "category_id": 2}, {"id": 9, "bbox": [365.9, 253.58, 311.79, 219.78], "category_id": 1}, {"id": 10, "bbox": [705.42, 378.01, 132.56, 50.72], "category_id": 2}, {"id": 11, "bbox": [185.99, 181.23, 48.02, 44.63], "category_id": 3}, {"id": 12, "bbox": [83.87, 570.73, 201.54, 198.81], "category_id": 1}, {"id": 13, "bbox": [456.53, 461.86, 38.55, 40.58], "category_id": 3}, {"id": 14, "bbox": [1140.98, 894.65, 34.5, 40.57], "category_id": 3}, {"id": 15, "bbox": [305.03, 697.19, 229.95, 92.64], "category_id": 2}, {"id": 16, "bbox": [119.71, 279.96, 166.38, 51.39], "category_id": 2}, {"id": 17, "bbox": [73.04, 2.7, 241.46, 208.96], "category_id": 1}, {"id": 18, "bbox": [1030.06, 446.99, 34.5, 40.57], "category_id": 3}, {"id": 19, "bbox": [332.76, 29.08, 264.45, 154.85], "category_id": 1}, {"id": 20, "bbox": [926.58, 244.12, 313.15, 218.42], "category_id": 1}, {"id": 21, "bbox": [140.0, 357.72, 118.36, 44.63], "category_id": 2}, {"id": 22, "bbox": [202.9, 776.31, 45.32, 43.95], "category_id": 3}, {"id": 23, "bbox": [860.3, 10.82, 374.02, 217.07], "category_id": 1}, {"id": 24, "bbox": [707.45, 304.98, 131.89, 52.74], "category_id": 2}], "caption": "Scheme 1. Original synthetic route for 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 460, 672, 474], "ImageBB": [439, 479, 777, 713]}, "reactions": [{"reactants": [17, 19], "conditions": [7, 5], "products": [23]}, {"reactants": [23], "conditions": [16, 21], "products": [9]}, {"reactants": [9], "conditions": [24, 10], "products": [20]}, {"reactants": [6, 12], "conditions": [8, 15], "products": [2]}], "diagram_type": "multiple"}, {"id": 1278, "width": 1356, "height": 856, "file_name": "op100197g-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [112.6, 369.23, 48.84, 50.9], "category_id": 3}, {"id": 1, "bbox": [649.17, 465.61, 265.91, 104.52], "category_id": 2}, {"id": 2, "bbox": [977.49, 420.13, 378.51, 294.57], "category_id": 1}, {"id": 3, "bbox": [55.62, 316.97, 165.52, 50.9], "category_id": 2}, {"id": 4, "bbox": [468.37, 673.07, 210.66, 45.21], "category_id": 2}, {"id": 5, "bbox": [259.13, 735.74, 362.91, 48.87], "category_id": 2}, {"id": 6, "bbox": [643.74, 595.92, 301.19, 50.23], "category_id": 2}, {"id": 7, "bbox": [1107.05, 799.54, 50.87, 56.33], "category_id": 3}, {"id": 8, "bbox": [319.5, 22.4, 202.14, 95.7], "category_id": 2}, {"id": 9, "bbox": [360.2, 800.22, 50.87, 55.65], "category_id": 3}, {"id": 10, "bbox": [4.07, 6.11, 316.11, 289.81], "category_id": 1}, {"id": 11, "bbox": [257.77, 417.42, 316.1, 299.99], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 210, 486, 224], "ImageBB": [424, 228, 763, 442]}, "reactions": [{"reactants": [10], "conditions": [8], "products": [11]}, {"reactants": [11], "conditions": [1, 6], "products": [2]}], "diagram_type": "multiple"}, {"id": 838, "width": 2820, "height": 1636, "file_name": "jo202571h-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [938.0, 69.0, 335.0, 75.0], "category_id": 2}, {"id": 1, "bbox": [758.0, 305.0, 24.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [2077.0, 301.0, 41.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [1786.0, 1578.0, 296.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [1548.0, 303.0, 48.0, 56.0], "category_id": 3}, {"id": 5, "bbox": [481.0, 1269.0, 195.0, 101.0], "category_id": 3}, {"id": 6, "bbox": [1935.0, 426.2, 330.3, 283.8], "category_id": 1}, {"id": 7, "bbox": [1554.6, 429.4, 335.4, 278.6], "category_id": 1}, {"id": 8, "bbox": [1690.0, 643.0, 74.0, 46.0], "category_id": 3}, {"id": 9, "bbox": [977.0, 171.0, 255.0, 55.0], "category_id": 2}, {"id": 10, "bbox": [1309.0, 990.0, 80.0, 48.0], "category_id": 3}, {"id": 11, "bbox": [1540.0, 710.0, 345.0, 345.0], "category_id": 1}, {"id": 12, "bbox": [1020.0, 1419.0, 101.0, 115.0], "category_id": 3}, {"id": 13, "bbox": [1892.0, 1450.0, 142.0, 92.0], "category_id": 3}, {"id": 14, "bbox": [4.0, 1077.0, 2721.0, 72.0], "category_id": 2}, {"id": 15, "bbox": [902.0, 643.0, 72.0, 55.0], "category_id": 3}, {"id": 16, "bbox": [630.0, 650.0, 70.0, 41.0], "category_id": 3}, {"id": 17, "bbox": [1314.0, 643.0, 77.0, 44.0], "category_id": 3}, {"id": 18, "bbox": [1186.0, 715.0, 321.0, 349.0], "category_id": 1}, {"id": 19, "bbox": [700.0, 732.0, 130.0, 70.0], "category_id": 2}, {"id": 20, "bbox": [1682.0, 990.0, 75.0, 46.0], "category_id": 3}, {"id": 21, "bbox": [2061.0, 990.0, 62.0, 48.0], "category_id": 3}, {"id": 22, "bbox": [1928.0, 715.0, 340.0, 335.0], "category_id": 1}, {"id": 23, "bbox": [1983.0, 1196.6, 345.3, 316.4], "category_id": 1}, {"id": 24, "bbox": [1598.2, 1195.8, 307.8, 314.2], "category_id": 1}, {"id": 25, "bbox": [495.0, 430.9, 289.0, 279.1], "category_id": 1}, {"id": 26, "bbox": [1825.5, 7.0, 497.4, 280.6], "category_id": 1}, {"id": 27, "bbox": [1295.8, 4.0, 464.6, 289.1], "category_id": 1}, {"id": 28, "bbox": [468.0, 7.0, 423.5, 281.9], "category_id": 1}, {"id": 29, "bbox": [779.0, 432.0, 258.3, 277.0], "category_id": 1}, {"id": 30, "bbox": [1181.5, 430.0, 329.5, 280.0], "category_id": 1}, {"id": 31, "bbox": [2075.0, 643.0, 70.0, 60.0], "category_id": 3}, {"id": 32, "bbox": [839.0, 1587.0, 306.0, 49.0], "category_id": 2}, {"id": 33, "bbox": [1107.5, 1213.6, 303.3, 327.7], "category_id": 1}, {"id": 34, "bbox": [624.2, 1216.0, 342.8, 323.0], "category_id": 1}], "reactions": [{"reactants": [28], "conditions": [0, 9], "products": [27, 26]}], "corefs": [[28, 1], [27, 4], [26, 2], [25, 16], [29, 15], [30, 17], [7, 8], [6, 31], [18, 10], [11, 20], [22, 21]], "caption": "Figure 1. Mutual orientation of the neighboring aromatic rings in S-alkylated thiacalix[4]arenes and the assignment of the stereochemistry of S-alkyl groups. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 535, 784, 563], "ImageBB": [82, 116, 787, 525]}, "diagram_type": "single"}, {"id": 38, "width": 1352, "height": 1820, "file_name": "ja5080739-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.1, 319.71, 1347.62, 1469.75], "category_id": 4}, {"id": 1, "bbox": [577.8, 2.68, 380.09, 157.0], "category_id": 1}, {"id": 2, "bbox": [845.52, 16.77, 112.38, 60.71], "category_id": 1}, {"id": 3, "bbox": [608.33, 178.81, 321.38, 124.12], "category_id": 2}, {"id": 4, "bbox": [799.21, 138.58, 173.99, 40.7], "category_id": 2}, {"id": 5, "bbox": [284.25, 115.4, 297.9, 164.04], "category_id": 1}, {"id": 6, "bbox": [21.23, 82.53, 208.66, 114.72], "category_id": 1}, {"id": 7, "bbox": [1083.85, 222.43, 26.94, 33.82], "category_id": 3}, {"id": 8, "bbox": [624.63, 120.52, 46.72, 34.25], "category_id": 3}, {"id": 9, "bbox": [80.71, 220.71, 22.2, 35.54], "category_id": 3}, {"id": 10, "bbox": [1009.9, 82.53, 257.98, 114.72], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [1, 2, 3], "products": [10]}], "corefs": [[6, 9], [1, 8], [10, 7]], "caption": "Table 2. Scope of the Racemic Reactiona,b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 166, 325, 187], "ImageBB": [82, 193, 420, 648]}, "diagram_type": "single"}, {"id": 575, "width": 1172, "height": 940, "file_name": "acs.orglett.5b00663-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [799.91, 2.36, 102.0, 39.0], "category_id": 2}, {"id": 1, "bbox": [402.0, 64.0, 266.5, 44.2], "category_id": 2}, {"id": 2, "bbox": [181.0, 849.5, 285.0, 85.5], "category_id": 1}, {"id": 3, "bbox": [187.0, 730.0, 185.9, 98.5], "category_id": 1}, {"id": 4, "bbox": [584.0, 743.0, 120.0, 71.9], "category_id": 1}, {"id": 5, "bbox": [579.6, 880.4, 147.2, 38.2], "category_id": 1}, {"id": 6, "bbox": [190.0, 95.27, 33.0, 36.0], "category_id": 3}, {"id": 7, "bbox": [706.0, 771.0, 51.0, 68.0], "category_id": 3}, {"id": 8, "bbox": [578.0, 620.0, 111.0, 88.0], "category_id": 1}, {"id": 9, "bbox": [581.0, 523.0, 131.0, 58.0], "category_id": 1}, {"id": 10, "bbox": [570.0, 433.0, 162.0, 57.0], "category_id": 1}, {"id": 11, "bbox": [573.0, 331.0, 154.0, 57.0], "category_id": 1}, {"id": 12, "bbox": [571.0, 243.0, 161.0, 53.0], "category_id": 1}, {"id": 13, "bbox": [184.0, 617.0, 139.0, 88.0], "category_id": 1}, {"id": 14, "bbox": [183.0, 515.0, 206.0, 71.0], "category_id": 1}, {"id": 15, "bbox": [189.0, 416.0, 222.0, 77.0], "category_id": 1}, {"id": 16, "bbox": [192.0, 321.0, 222.0, 78.0], "category_id": 1}, {"id": 17, "bbox": [183.0, 219.0, 240.0, 80.0], "category_id": 1}, {"id": 18, "bbox": [468.0, 892.0, 49.0, 48.0], "category_id": 3}, {"id": 19, "bbox": [371.0, 790.0, 52.0, 54.0], "category_id": 3}, {"id": 20, "bbox": [320.0, 666.0, 52.0, 51.0], "category_id": 3}, {"id": 21, "bbox": [391.0, 554.0, 48.0, 58.0], "category_id": 3}, {"id": 22, "bbox": [414.0, 456.0, 42.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [411.0, 358.0, 48.0, 44.0], "category_id": 3}, {"id": 24, "bbox": [416.0, 263.0, 46.0, 45.0], "category_id": 3}, {"id": 25, "bbox": [721.0, 876.0, 57.0, 47.0], "category_id": 3}, {"id": 26, "bbox": [689.0, 663.0, 43.0, 50.0], "category_id": 3}, {"id": 27, "bbox": [713.0, 538.0, 53.0, 57.0], "category_id": 3}, {"id": 28, "bbox": [724.0, 442.0, 53.0, 64.0], "category_id": 3}, {"id": 29, "bbox": [730.0, 348.0, 44.0, 53.0], "category_id": 3}, {"id": 30, "bbox": [727.0, 250.0, 43.0, 46.0], "category_id": 3}, {"id": 31, "bbox": [10.0, 154.0, 1154.0, 786.0], "category_id": 4}, {"id": 32, "bbox": [321.0, 0.0, 426.0, 52.0], "category_id": 2}, {"id": 33, "bbox": [990.0, 84.0, 33.0, 39.0], "category_id": 3}, {"id": 34, "bbox": [132.0, 13.0, 155.0, 58.0], "category_id": 1}, {"id": 35, "bbox": [965.24, 24.56, 85.95, 42.29], "category_id": 2}], "reactions": [{"reactants": [34], "conditions": [32, 1, 0], "products": [35]}], "corefs": [[34, 6], [35, 33], [17, 24], [12, 30], [16, 23], [11, 29], [15, 22], [10, 28], [14, 21], [9, 27], [13, 20], [8, 26], [3, 19], [4, 7], [2, 18], [5, 25]], "caption": "Table 4. Substrate Scope for the Debenzylation Reactiona", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 403, 109], "ImageBB": [104, 116, 397, 351]}, "diagram_type": "single"}, {"id": 823, "width": 1912, "height": 2060, "file_name": "jo400755q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [104.0, 1435.0, 254.0, 58.0], "category_id": 3}, {"id": 1, "bbox": [1409.0, 915.0, 274.0, 71.0], "category_id": 3}, {"id": 2, "bbox": [943.0, 913.0, 253.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [531.0, 915.0, 248.0, 61.0], "category_id": 3}, {"id": 4, "bbox": [112.0, 911.0, 242.0, 60.0], "category_id": 3}, {"id": 5, "bbox": [276.0, 10.0, 340.0, 310.0], "category_id": 1}, {"id": 6, "bbox": [924.0, 6.0, 336.0, 302.0], "category_id": 1}, {"id": 7, "bbox": [1081.0, 300.0, 73.0, 47.0], "category_id": 3}, {"id": 8, "bbox": [299.0, 292.0, 183.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [596.0, 43.0, 295.0, 84.0], "category_id": 2}, {"id": 10, "bbox": [1308.0, 77.0, 319.0, 52.0], "category_id": 2}, {"id": 11, "bbox": [1565.0, 1433.0, 77.0, 52.0], "category_id": 3}, {"id": 12, "bbox": [559.0, 1433.0, 265.0, 65.0], "category_id": 3}, {"id": 13, "bbox": [600.0, 144.0, 313.0, 98.0], "category_id": 2}, {"id": 14, "bbox": [112.2, 1505.0, 312.0, 440.8], "category_id": 1}, {"id": 15, "bbox": [1262.3, 1585.5, 478.2, 321.7], "category_id": 1}, {"id": 16, "bbox": [1207.22, 1433.1, 289.95, 60.75], "category_id": 2}, {"id": 17, "bbox": [863.0, 995.0, 408.7, 419.0], "category_id": 1}, {"id": 18, "bbox": [675.4, 1512.5, 341.4, 440.0], "category_id": 1}, {"id": 19, "bbox": [464.2, 977.3, 403.0, 442.7], "category_id": 1}, {"id": 20, "bbox": [1323.0, 1004.0, 411.1, 407.2], "category_id": 1}, {"id": 21, "bbox": [672.0, 1947.0, 254.4, 69.0], "category_id": 3}, {"id": 22, "bbox": [443.5, 447.6, 391.5, 421.4], "category_id": 1}, {"id": 23, "bbox": [110.1, 423.8, 306.2, 364.2], "category_id": 1}, {"id": 24, "bbox": [17.8, 995.8, 400.5, 410.0], "category_id": 1}, {"id": 25, "bbox": [1269.0, 449.0, 476.7, 454.5], "category_id": 1}, {"id": 26, "bbox": [887.0, 447.0, 373.0, 418.0], "category_id": 1}, {"id": 27, "bbox": [1258.0, 1947.0, 250.0, 72.5], "category_id": 3}, {"id": 28, "bbox": [1118.48, 1419.48, 54.2, 69.5], "category_id": 3}, {"id": 29, "bbox": [117.0, 1953.24, 248.0, 58.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [9, 13], "products": [6]}], "corefs": [[5, 8], [6, 7], [23, 4], [22, 3], [26, 2], [25, 1], [24, 0], [19, 12], [17, 28], [20, 11], [14, 29], [18, 21], [15, 27]], "caption": "Table 3. Ortho-Chlorination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 530, 111], "ImageBB": [195, 116, 673, 631]}, "diagram_type": "single"}, {"id": 1233, "width": 1340, "height": 1052, "file_name": "op0155211-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [923.72, 732.2, 357.29, 230.62], "category_id": 1}, {"id": 1, "bbox": [346.56, 450.25, 87.15, 58.96], "category_id": 2}, {"id": 2, "bbox": [1181.13, 144.05, 85.13, 55.62], "category_id": 2}, {"id": 3, "bbox": [967.29, 322.28, 180.99, 149.92], "category_id": 1}, {"id": 4, "bbox": [451.0, 733.67, 142.5, 151.53], "category_id": 1}, {"id": 5, "bbox": [1262.91, 817.42, 77.09, 58.96], "category_id": 2}, {"id": 6, "bbox": [968.02, 492.53, 181.85, 47.99], "category_id": 2}, {"id": 7, "bbox": [91.17, 377.22, 258.07, 161.47], "category_id": 1}, {"id": 8, "bbox": [1053.1, 994.98, 65.02, 54.27], "category_id": 3}, {"id": 9, "bbox": [701.84, 416.75, 89.83, 44.22], "category_id": 2}, {"id": 10, "bbox": [450.22, 895.4, 164.18, 50.52], "category_id": 2}, {"id": 11, "bbox": [700.5, 489.11, 95.86, 49.58], "category_id": 2}, {"id": 12, "bbox": [700.5, 788.61, 91.17, 43.55], "category_id": 2}, {"id": 13, "bbox": [700.5, 116.58, 89.15, 49.58], "category_id": 2}, {"id": 14, "bbox": [0.0, 720.27, 286.23, 231.16], "category_id": 1}, {"id": 15, "bbox": [700.5, 182.24, 98.54, 44.9], "category_id": 2}, {"id": 16, "bbox": [698.49, 862.31, 100.55, 48.24], "category_id": 2}, {"id": 17, "bbox": [242.66, 557.45, 59.66, 50.93], "category_id": 3}, {"id": 18, "bbox": [1054.44, 558.12, 59.66, 50.26], "category_id": 3}, {"id": 19, "bbox": [162.22, 994.98, 61.67, 54.27], "category_id": 3}, {"id": 20, "bbox": [904.95, 85.76, 251.38, 151.43], "category_id": 1}, {"id": 21, "bbox": [1054.44, 237.19, 58.99, 52.93], "category_id": 3}, {"id": 22, "bbox": [10.06, 96.48, 175.62, 142.72], "category_id": 1}, {"id": 23, "bbox": [373.38, 87.77, 136.07, 151.43], "category_id": 1}, {"id": 24, "bbox": [500.07, 999.0, 58.32, 50.25], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 553, 501, 567], "ImageBB": [441, 571, 776, 834]}, "reactions": [{"reactants": [22, 23], "conditions": [13, 15], "products": [20, 2]}, {"reactants": [7, 1], "conditions": [9, 11], "products": [3, 6]}, {"reactants": [14, 4], "conditions": [12, 16], "products": [0, 5]}], "diagram_type": "multiple"}, {"id": 80, "width": 1348, "height": 1980, "file_name": "ja075824w-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [819.65, 328.36, 153.56, 38.23], "category_id": 2}, {"id": 1, "bbox": [564.09, 148.83, 316.56, 40.54], "category_id": 2}, {"id": 2, "bbox": [192.34, 367.65, 593.82, 171.09], "category_id": 2}, {"id": 3, "bbox": [196.07, 283.1, 193.47, 39.3], "category_id": 2}, {"id": 4, "bbox": [528.03, 5.84, 389.92, 92.77], "category_id": 2}, {"id": 5, "bbox": [175.9, 105.6, 96.6, 37.6], "category_id": 2}, {"id": 6, "bbox": [1035.34, 328.78, 185.62, 36.97], "category_id": 2}, {"id": 7, "bbox": [332.07, 106.85, 144.4, 36.14], "category_id": 2}, {"id": 8, "bbox": [37.92, 604.8, 1276.8, 1341.6], "category_id": 4}, {"id": 9, "bbox": [318.72, 168.0, 184.8, 45.6], "category_id": 2}], "reactions": [{"reactants": [5, 7], "conditions": [4, 1, 3, 2], "products": [0, 6]}], "corefs": [], "caption": "Table 2. DMAP-Catalyzed Esterification of Alcohols and Carboxylic Acids under Base- and Solvent-Free Conditions ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 735, 88], "ImageBB": [439, 88, 776, 583]}, "diagram_type": "multiple"}, {"id": 658, "width": 1344, "height": 632, "file_name": "ol402981z-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [866.85, 300.0, 113.0, 60.8], "category_id": 2}, {"id": 1, "bbox": [1017.0, 230.0, 308.0, 248.6], "category_id": 1}, {"id": 2, "bbox": [490.8, 212.7, 336.0, 267.4], "category_id": 1}, {"id": 3, "bbox": [26.3, 291.9, 263.0, 157.7], "category_id": 1}, {"id": 4, "bbox": [845.86, 169.15, 105.0, 86.0], "category_id": 2}, {"id": 5, "bbox": [874.28, 387.0, 96.1, 50.0], "category_id": 2}, {"id": 6, "bbox": [247.0, 521.0, 596.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [300.0, 288.0, 133.0, 69.0], "category_id": 2}, {"id": 8, "bbox": [315.0, 396.0, 101.0, 87.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 8], "products": [2]}, {"reactants": [2], "conditions": [0, 5], "products": [1]}], "corefs": [], "caption": "Figure 1. Concept behind enantioselective halonium ion-initiated Wagner Meerwein transposition of allylic alcohols. Hal = F, Cl, Br, or I. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 568, 405, 612], "ImageBB": [71, 400, 407, 558]}, "diagram_type": "single"}, {"id": 921, "width": 1356, "height": 396, "file_name": "acs.joc.5b02237-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1315.3, 133.73, 36.63, 48.2], "category_id": 3}, {"id": 1, "bbox": [671.56, 8.82, 285.58, 286.47], "category_id": 1}, {"id": 2, "bbox": [974.1, 47.52, 324.92, 97.07], "category_id": 2}, {"id": 3, "bbox": [455.84, 93.68, 213.0, 58.38], "category_id": 2}, {"id": 4, "bbox": [166.19, 4.07, 287.62, 263.39], "category_id": 1}, {"id": 5, "bbox": [68.51, 95.72, 67.84, 42.08], "category_id": 2}, {"id": 6, "bbox": [789.59, 306.15, 57.66, 46.84], "category_id": 3}, {"id": 7, "bbox": [287.62, 306.15, 50.87, 43.45], "category_id": 3}, {"id": 8, "bbox": [4.07, 133.73, 34.6, 46.16], "category_id": 3}], "caption": "Scheme 7. Proposed Mechanism of the Photorearrangement", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 563, 784, 578], "ImageBB": [448, 584, 787, 683]}, "reactions": [{"reactants": [8], "conditions": [5], "products": [4]}, {"reactants": [4], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [0]}], "diagram_type": "single"}, {"id": 1283, "width": 2808, "height": 652, "file_name": "op2000089-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1098.48, 56.1, 60.4, 57.5], "category_id": 2}, {"id": 1, "bbox": [1331.66, 274.89, 106.76, 99.58], "category_id": 1}, {"id": 2, "bbox": [434.05, 552.59, 623.69, 54.69], "category_id": 2}, {"id": 3, "bbox": [1702.5, 0.0, 247.23, 124.82], "category_id": 2}, {"id": 4, "bbox": [974.86, 148.67, 318.87, 58.9], "category_id": 2}, {"id": 5, "bbox": [1772.73, 329.59, 105.36, 65.92], "category_id": 2}, {"id": 6, "bbox": [656.0, 284.71, 276.72, 232.81], "category_id": 1}, {"id": 7, "bbox": [2129.53, 287.51, 243.01, 230.01], "category_id": 1}, {"id": 8, "bbox": [1097.07, 335.2, 68.83, 60.31], "category_id": 2}, {"id": 9, "bbox": [686.9, 64.52, 248.63, 131.83], "category_id": 1}, {"id": 10, "bbox": [2005.91, 14.03, 370.85, 234.21], "category_id": 1}, {"id": 11, "bbox": [1009.98, 424.96, 243.01, 96.77], "category_id": 2}, {"id": 12, "bbox": [434.05, 199.16, 181.21, 123.42], "category_id": 1}, {"id": 13, "bbox": [1349.3, 67.32, 298.42, 129.68], "category_id": 1}, {"id": 14, "bbox": [1372.39, 298.73, 279.54, 234.22], "category_id": 1}], "caption": "Scheme 2. Competitive reactions for the in situ borylation with 1 through a magnesium-halide exchange", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 257, 655, 272], "ImageBB": [71, 282, 773, 445]}, "reactions": [{"reactants": [12, 9], "conditions": [0, 4], "products": [13]}, {"reactants": [13], "conditions": [3], "products": [10]}, {"reactants": [12, 6], "conditions": [8, 11], "products": [1, 14]}, {"reactants": [14], "conditions": [5], "products": [7]}], "diagram_type": "multiple"}, {"id": 609, "width": 2820, "height": 920, "file_name": "acs.oprd.5b00339-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2011.0, 424.0, 235.0, 68.0], "category_id": 2}, {"id": 1, "bbox": [1225.9, 426.7, 352.3, 137.4], "category_id": 1}, {"id": 2, "bbox": [367.8, 0.0, 929.3, 238.0], "category_id": 1}, {"id": 3, "bbox": [798.62, 271.62, 68.0, 81.0], "category_id": 3}, {"id": 4, "bbox": [797.75, 826.87, 51.4, 48.5], "category_id": 3}, {"id": 5, "bbox": [1977.0, 826.0, 58.6, 58.3], "category_id": 3}, {"id": 6, "bbox": [1967.24, 272.49, 65.0, 81.0], "category_id": 3}, {"id": 7, "bbox": [370.3, 390.9, 857.7, 416.1], "category_id": 1}, {"id": 8, "bbox": [1560.0, 517.4, 902.9, 290.3], "category_id": 1}, {"id": 9, "bbox": [1518.0, 0.0, 961.0, 247.0], "category_id": 1}, {"id": 10, "bbox": [1384.43, 563.1, 48.92, 51.05], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [1], "products": [7]}], "corefs": [[2, 3], [9, 6], [8, 5], [1, 10], [7, 4]], "caption": "Table 1. Asymmetric Hydrogenation of Ketone 4 with Optimizing Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 346, 581, 367], "ImageBB": [82, 116, 787, 346]}, "diagram_type": "tree"}, {"id": 321, "width": 1344, "height": 1704, "file_name": "ol301863j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [957.8, 32.6, 341.7, 188.6], "category_id": 1}, {"id": 1, "bbox": [726.0, 238.0, 204.6, 92.0], "category_id": 2}, {"id": 2, "bbox": [42.0, 464.6, 1293.0, 1236.4], "category_id": 4}, {"id": 3, "bbox": [26.2, 2.0, 365.6, 249.6], "category_id": 1}, {"id": 4, "bbox": [1008.3, 291.87, 252.3, 51.93], "category_id": 3}, {"id": 5, "bbox": [1004.0, 227.0, 318.6, 55.8], "category_id": 3}, {"id": 6, "bbox": [580.0, 47.0, 140.0, 66.0], "category_id": 2}, {"id": 7, "bbox": [463.0, 124.0, 437.0, 109.0], "category_id": 2}, {"id": 8, "bbox": [159.0, 219.0, 76.0, 77.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [6, 7], "products": [0]}, {"reactants": [5], "conditions": [1], "products": [4]}], "corefs": [[3, 8], [0, 5], [0, 4]], "caption": "Table 2. Efficient Preparation of Glycosyloxyamines", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 351, 100], "ImageBB": [71, 112, 407, 538]}, "diagram_type": "tree"}, {"id": 106, "width": 1340, "height": 816, "file_name": "ja001164i-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [648.68, 384.33, 92.15, 37.12], "category_id": 2}, {"id": 1, "bbox": [498.83, 483.84, 360.24, 253.71], "category_id": 1}, {"id": 2, "bbox": [963.61, 97.5, 330.97, 253.71], "category_id": 1}, {"id": 3, "bbox": [489.46, 97.5, 359.08, 253.71], "category_id": 1}, {"id": 4, "bbox": [599.51, 769.5, 34.78, 28.93], "category_id": 3}, {"id": 5, "bbox": [236.58, 627.84, 203.37, 69.91], "category_id": 2}, {"id": 6, "bbox": [240.1, 241.5, 202.19, 69.9], "category_id": 2}, {"id": 7, "bbox": [600.68, 384.33, 40.64, 30.1], "category_id": 3}, {"id": 8, "bbox": [11.8, 596.23, 179.96, 35.96], "category_id": 2}, {"id": 9, "bbox": [248.29, 167.75, 42.01, 37.12], "category_id": 3}, {"id": 10, "bbox": [14.15, 209.89, 181.12, 38.3], "category_id": 2}, {"id": 11, "bbox": [294.11, 555.04, 139.46, 40.42], "category_id": 2}, {"id": 12, "bbox": [297.14, 167.99, 139.46, 38.4], "category_id": 2}, {"id": 13, "bbox": [245.95, 555.26, 42.85, 39.46], "category_id": 3}, {"id": 14, "bbox": [648.68, 769.5, 109.71, 35.95], "category_id": 2}, {"id": 15, "bbox": [1086.54, 383.16, 90.97, 37.12], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [9, 12, 6], "products": [3, 2]}, {"reactants": [8], "conditions": [13, 11, 5], "products": [1]}], "corefs": [[3, 7], [1, 4]], "caption": "Table 8. Comparison of the Reactivities of LBAs in the Protonation of 3a to 4aa ", "pdf": {"Page": 5, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 298, 721, 323], "ImageBB": [439, 82, 775, 286]}, "diagram_type": "multiple"}, {"id": 391, "width": 1352, "height": 868, "file_name": "op500224x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [885.0, 153.0, 84.0, 50.0], "category_id": 2}, {"id": 1, "bbox": [547.0, 514.0, 276.0, 282.0], "category_id": 1}, {"id": 2, "bbox": [104.0, 595.0, 37.0, 52.0], "category_id": 3}, {"id": 3, "bbox": [637.0, 814.0, 56.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [1163.0, 815.0, 47.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [1169.0, 344.0, 46.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [653.0, 347.0, 38.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [207.0, 690.0, 313.0, 54.0], "category_id": 2}, {"id": 8, "bbox": [312.0, 233.0, 154.0, 52.0], "category_id": 2}, {"id": 9, "bbox": [361.0, 153.0, 59.0, 59.0], "category_id": 2}, {"id": 10, "bbox": [1053.0, 514.9, 293.3, 287.1], "category_id": 1}, {"id": 11, "bbox": [555.29, 44.98, 272.71, 281.12], "category_id": 1}, {"id": 12, "bbox": [1061.8, 47.6, 290.2, 280.4], "category_id": 1}, {"id": 13, "bbox": [0.0, 301.0, 267.3, 281.5], "category_id": 1}, {"id": 14, "bbox": [880.0, 622.0, 80.7, 51.9], "category_id": 2}, {"id": 15, "bbox": [360.0, 625.0, 57.8, 46.2], "category_id": 2}], "reactions": [{"reactants": [13], "conditions": [9, 8], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [12]}, {"reactants": [13], "conditions": [15, 7], "products": [1]}, {"reactants": [1], "conditions": [14], "products": [10]}], "corefs": [[13, 2], [11, 6], [12, 5], [1, 3], [10, 4]], "caption": "Figure 3. Piperidines generated via kinetic and thermodynamic iminiums. ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 984, 417, 1012], "ImageBB": [82, 758, 420, 975]}, "diagram_type": "tree"}, {"id": 50, "width": 1348, "height": 372, "file_name": "ja408031s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [7.13, 297.36, 1333.76, 72.18], "category_id": 4}, {"id": 1, "bbox": [188.28, 218.4, 72.58, 42.46], "category_id": 3}, {"id": 2, "bbox": [46.25, 131.46, 358.36, 63.98], "category_id": 1}, {"id": 3, "bbox": [1004.31, 227.87, 28.68, 40.74], "category_id": 3}, {"id": 4, "bbox": [453.4, 3.21, 231.83, 134.56], "category_id": 2}, {"id": 5, "bbox": [770.17, 80.68, 531.39, 112.18], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4], "products": [5]}], "corefs": [[2, 1], [5, 3]], "caption": "Table 1. Optimization of Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 343, 110], "ImageBB": [82, 116, 419, 209]}, "diagram_type": "single"}, {"id": 1014, "width": 1032, "height": 2176, "file_name": "ja983111v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [409.42, 1609.96, 25.04, 33.74], "category_id": 2}, {"id": 1, "bbox": [754.59, 124.09, 277.41, 342.9], "category_id": 1}, {"id": 2, "bbox": [323.4, 2136.81, 35.93, 39.19], "category_id": 3}, {"id": 3, "bbox": [52.27, 4.35, 614.12, 446.31], "category_id": 1}, {"id": 4, "bbox": [82.75, 587.81, 700.15, 396.23], "category_id": 1}, {"id": 5, "bbox": [827.55, 485.49, 54.44, 42.45], "category_id": 3}, {"id": 6, "bbox": [0.0, 1702.48, 844.97, 473.52], "category_id": 1}, {"id": 7, "bbox": [319.04, 402.76, 33.76, 38.1], "category_id": 3}, {"id": 8, "bbox": [359.33, 1510.9, 29.4, 40.28], "category_id": 3}, {"id": 9, "bbox": [359.33, 490.93, 32.67, 33.75], "category_id": 2}, {"id": 10, "bbox": [388.73, 1028.67, 30.49, 41.37], "category_id": 2}, {"id": 11, "bbox": [245.0, 1137.53, 547.7, 385.34], "category_id": 1}, {"id": 12, "bbox": [803.59, 719.53, 196.0, 183.96], "category_id": 1}], "caption": "Scheme 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 133, 78], "ImageBB": [113, 84, 371, 628]}, "reactions": [{"reactants": [3, 1], "conditions": [9], "products": [4]}, {"reactants": [4, 12], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [0], "products": [6]}], "diagram_type": "tree"}, {"id": 943, "width": 1356, "height": 652, "file_name": "acs.orglett.5b01872-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [65.8, 0.0, 291.01, 152.61], "category_id": 2}, {"id": 1, "bbox": [274.73, 77.7, 414.77, 213.28], "category_id": 1}, {"id": 2, "bbox": [917.79, 38.66, 419.89, 249.61], "category_id": 1}, {"id": 3, "bbox": [525.71, 220.44, 51.56, 46.8], "category_id": 3}, {"id": 4, "bbox": [381.9, 352.7, 254.38, 141.09], "category_id": 1}, {"id": 5, "bbox": [1170.14, 221.12, 48.84, 46.12], "category_id": 3}, {"id": 6, "bbox": [507.4, 478.19, 40.7, 40.69], "category_id": 3}, {"id": 7, "bbox": [733.28, 181.1, 182.48, 151.26], "category_id": 2}, {"id": 8, "bbox": [960.53, 322.86, 220.46, 90.21], "category_id": 2}, {"id": 9, "bbox": [246.92, 475.47, 59.01, 48.16], "category_id": 3}, {"id": 10, "bbox": [1170.14, 493.79, 44.77, 45.44], "category_id": 3}, {"id": 11, "bbox": [0.0, 545.33, 870.99, 61.05], "category_id": 2}, {"id": 12, "bbox": [79.37, 341.17, 272.01, 169.57], "category_id": 1}, {"id": 13, "bbox": [150.59, 178.39, 116.68, 122.09], "category_id": 2}, {"id": 14, "bbox": [1203.37, 290.98, 144.49, 156.68], "category_id": 2}, {"id": 15, "bbox": [10.85, 140.4, 52.24, 47.48], "category_id": 3}, {"id": 16, "bbox": [733.28, 6.1, 189.94, 56.3], "category_id": 1}, {"id": 17, "bbox": [695.35, 74.92, 266.9, 70.56], "category_id": 2}], "caption": "Scheme 3. Synthesis of the Divinyl Intermediate", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 722, 110], "ImageBB": [448, 116, 787, 279]}, "reactions": [{"reactants": [15], "conditions": [0, 13], "products": [1]}, {"reactants": [1], "conditions": [16, 17, 7], "products": [2]}, {"reactants": [2], "conditions": [8, 14], "products": [10]}], "diagram_type": "tree"}, {"id": 1128, "width": 1696, "height": 800, "file_name": "jo991524o-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1426.2, 68.7, 269.8, 240.02], "category_id": 1}, {"id": 1, "bbox": [1153.01, 232.38, 273.19, 55.98], "category_id": 2}, {"id": 2, "bbox": [207.86, 598.77, 126.42, 59.37], "category_id": 2}, {"id": 3, "bbox": [869.63, 78.88, 267.26, 232.38], "category_id": 1}, {"id": 4, "bbox": [987.57, 323.98, 58.54, 49.19], "category_id": 3}, {"id": 5, "bbox": [48.36, 340.1, 60.24, 46.64], "category_id": 3}, {"id": 6, "bbox": [207.86, 686.98, 132.36, 50.88], "category_id": 2}, {"id": 7, "bbox": [156.11, 251.04, 204.47, 50.04], "category_id": 2}, {"id": 8, "bbox": [0.0, 102.62, 137.44, 232.39], "category_id": 1}, {"id": 9, "bbox": [242.65, 186.59, 62.78, 43.25], "category_id": 3}, {"id": 10, "bbox": [1034.23, 739.56, 63.63, 50.89], "category_id": 3}, {"id": 11, "bbox": [377.55, 426.6, 111.14, 55.98], "category_id": 2}, {"id": 12, "bbox": [15.27, 540.25, 183.26, 195.92], "category_id": 1}, {"id": 13, "bbox": [48.36, 753.13, 77.21, 45.8], "category_id": 3}, {"id": 14, "bbox": [474.27, 334.16, 61.09, 44.1], "category_id": 3}, {"id": 15, "bbox": [544.69, 424.06, 195.14, 61.06], "category_id": 2}, {"id": 16, "bbox": [188.35, 0.0, 156.96, 175.56], "category_id": 1}, {"id": 17, "bbox": [644.8, 238.32, 182.41, 56.83], "category_id": 2}, {"id": 18, "bbox": [649.04, 589.44, 219.75, 65.31], "category_id": 2}, {"id": 19, "bbox": [647.35, 142.48, 219.74, 59.37], "category_id": 2}, {"id": 20, "bbox": [1153.01, 137.4, 223.13, 64.45], "category_id": 2}, {"id": 21, "bbox": [1543.28, 317.2, 65.33, 48.34], "category_id": 3}, {"id": 22, "bbox": [853.51, 537.71, 429.31, 223.9], "category_id": 1}, {"id": 23, "bbox": [367.37, 90.75, 267.25, 224.75], "category_id": 1}, {"id": 24, "bbox": [414.88, 550.43, 202.77, 185.74], "category_id": 1}, {"id": 25, "bbox": [491.24, 744.65, 63.63, 47.49], "category_id": 3}], "caption": "Scheme 6", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [213, 85, 637, 285]}, "reactions": [{"reactants": [8, 16], "conditions": [7], "products": [23]}, {"reactants": [23], "conditions": [19, 17], "products": [3]}, {"reactants": [3], "conditions": [20, 1], "products": [0]}, {"reactants": [23], "conditions": [15], "products": [24]}, {"reactants": [24], "conditions": [11], "products": [23]}, {"reactants": [12], "conditions": [2, 6], "products": [24]}, {"reactants": [24], "conditions": [18], "products": [22]}], "diagram_type": "tree"}, {"id": 817, "width": 1348, "height": 404, "file_name": "jo4014707-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [637.0, 4.0, 262.0, 108.0], "category_id": 2}, {"id": 1, "bbox": [1034.0, 13.0, 186.0, 202.0], "category_id": 1}, {"id": 2, "bbox": [134.3, 13.0, 110.3, 187.0], "category_id": 1}, {"id": 3, "bbox": [179.0, 213.0, 29.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [1060.0, 217.0, 102.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [370.0, 211.0, 52.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [25.0, 289.0, 1311.0, 111.0], "category_id": 4}, {"id": 7, "bbox": [316.0, 92.0, 182.0, 60.0], "category_id": 2}, {"id": 8, "bbox": [644.0, 134.0, 251.0, 96.0], "category_id": 2}], "reactions": [{"reactants": [2, 7], "conditions": [0, 8], "products": [1]}], "corefs": [[2, 3], [7, 5], [1, 4]], "caption": "Table 2. Asymmetric 1,4-Addition at Low Temperaturea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 400, 661], "ImageBB": [82, 667, 419, 768]}, "diagram_type": "single"}, {"id": 516, "width": 1348, "height": 572, "file_name": "jo025690z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [985.5, 5.0, 225.5, 199.6], "category_id": 1}, {"id": 1, "bbox": [1070.56, 217.0, 35.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [413.0, 282.0, 677.0, 290.0], "category_id": 4}, {"id": 3, "bbox": [526.0, 32.0, 375.0, 49.0], "category_id": 2}, {"id": 4, "bbox": [71.0, 220.0, 23.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [338.0, 221.0, 43.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [274.0, 75.0, 140.0, 56.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 32.0, 234.0, 141.0], "category_id": 1}, {"id": 8, "bbox": [586.0, 121.0, 251.0, 45.0], "category_id": 2}], "reactions": [{"reactants": [7, 6], "conditions": [3, 8], "products": [0]}], "corefs": [[7, 4], [6, 5], [0, 1]], "caption": "Table 3.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 620, 124, 634], "ImageBB": [75, 648, 412, 791]}, "diagram_type": "single"}, {"id": 605, "width": 1348, "height": 788, "file_name": "acs.oprd.5b00379-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [526.71, 647.43, 30.0, 44.0], "category_id": 3}, {"id": 1, "bbox": [67.6, 0.0, 923.4, 621.0], "category_id": 1}, {"id": 2, "bbox": [1249.57, 286.0, 37.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [5.0, 717.0, 1336.0, 71.0], "category_id": 4}, {"id": 4, "bbox": [747.0, 310.0, 281.0, 51.0], "category_id": 2}, {"id": 5, "bbox": [747.0, 231.0, 406.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [5, 4], "products": [2]}], "corefs": [[1, 0]], "caption": "Table 3. Optimization of the C18 Puri\ufb01cation Procedure", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 579, 403, 594], "ImageBB": [82, 601, 419, 798]}, "diagram_type": "single"}, {"id": 733, "width": 1344, "height": 884, "file_name": "ol016212y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [108.0, 273.0, 334.0, 67.0], "category_id": 2}, {"id": 1, "bbox": [3.0, 365.0, 1341.0, 519.0], "category_id": 4}, {"id": 2, "bbox": [919.0, 275.0, 330.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [437.38, 164.71, 382.75, 98.36], "category_id": 2}, {"id": 4, "bbox": [911.9, 3.6, 317.8, 237.0], "category_id": 1}, {"id": 5, "bbox": [398.48, 95.56, 470.1, 55.7], "category_id": 2}, {"id": 6, "bbox": [100.0, 0.0, 266.0, 233.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 3], "products": [4]}], "corefs": [], "caption": "Table 1. Comparison of the Fiber-Supported Titanium TADDOLate Derived from P1 with P1B and 4 in the Addition of Et2Zn to PhCHO ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 180, 399, 224], "ImageBB": [74, 226, 410, 447]}, "diagram_type": "single"}, {"id": 709, "width": 1348, "height": 1100, "file_name": "ol0349920-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [620.94, 356.85, 191.69, 87.0], "category_id": 1}, {"id": 1, "bbox": [113.0, 159.0, 316.0, 244.0], "category_id": 1}, {"id": 2, "bbox": [440.99, 22.38, 114.95, 44.7], "category_id": 2}, {"id": 3, "bbox": [600.64, 440.67, 122.93, 49.49], "category_id": 2}, {"id": 4, "bbox": [520.81, 373.61, 100.58, 57.48], "category_id": 2}, {"id": 5, "bbox": [527.0, 313.0, 265.8, 47.5], "category_id": 2}, {"id": 6, "bbox": [442.0, 7.0, 439.0, 298.0], "category_id": 1}, {"id": 7, "bbox": [896.0, 200.0, 339.0, 206.0], "category_id": 1}, {"id": 8, "bbox": [837.0, 249.0, 36.0, 51.0], "category_id": 3}, {"id": 9, "bbox": [5.0, 516.0, 1343.0, 583.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [6, 5, 4, 0, 3], "products": [7]}], "corefs": [[6, 8]], "caption": "Table 1. Enantioselective Deuteride Reduction of Various Aldimines or Their Equivalents Derived from p-Phenylbenzaldehydea ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 747, 120], "ImageBB": [439, 125, 776, 400]}, "diagram_type": "single"}, {"id": 846, "width": 1196, "height": 900, "file_name": "jo201478d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.2, 313.2, 1195.8, 586.8], "category_id": 4}, {"id": 1, "bbox": [584.0, 14.0, 176.0, 100.0], "category_id": 2}, {"id": 2, "bbox": [23.0, 700.0, 143.0, 134.0], "category_id": 1}, {"id": 3, "bbox": [438.0, 834.0, 55.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [1003.0, 171.0, 33.0, 41.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 436.0, 172.0, 127.0], "category_id": 1}, {"id": 6, "bbox": [831.0, 1.0, 365.0, 218.0], "category_id": 1}, {"id": 7, "bbox": [440.0, 567.0, 52.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [87.0, 835.0, 53.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [373.0, 52.0, 197.0, 130.0], "category_id": 1}, {"id": 10, "bbox": [445.0, 171.0, 31.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [2.0, 24.0, 357.0, 183.0], "category_id": 1}, {"id": 12, "bbox": [87.0, 567.0, 55.0, 39.0], "category_id": 3}, {"id": 13, "bbox": [309.0, 408.0, 351.0, 152.0], "category_id": 1}, {"id": 14, "bbox": [622.0, 126.0, 152.0, 98.0], "category_id": 2}, {"id": 15, "bbox": [152.0, 173.0, 54.0, 39.0], "category_id": 3}, {"id": 16, "bbox": [309.0, 686.0, 314.0, 197.0], "category_id": 1}], "reactions": [{"reactants": [11, 9], "conditions": [1, 14], "products": [6]}], "corefs": [[11, 15], [9, 10], [6, 4], [5, 12], [13, 7], [2, 8], [16, 3]], "caption": "Table 2. Epoxide Rearrangement Followed by Addition and ISMS Using the Unprotected \u03b4-Hydroxyalkenylsilanes ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 770, 123], "ImageBB": [455, 133, 754, 358]}, "diagram_type": "single"}, {"id": 1018, "width": 1356, "height": 552, "file_name": "jacs.5b05596-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [47.48, 21.01, 355.45, 135.58], "category_id": 1}, {"id": 1, "bbox": [41.38, 246.75, 368.34, 199.98], "category_id": 1}, {"id": 2, "bbox": [206.22, 455.54, 40.7, 48.81], "category_id": 3}, {"id": 3, "bbox": [915.76, 205.4, 54.94, 35.25], "category_id": 2}, {"id": 4, "bbox": [1225.76, 427.75, 70.55, 49.48], "category_id": 3}, {"id": 5, "bbox": [777.38, 429.78, 52.91, 50.84], "category_id": 3}, {"id": 6, "bbox": [528.43, 4.07, 321.53, 499.6], "category_id": 1}, {"id": 7, "bbox": [206.22, 170.15, 40.7, 44.74], "category_id": 3}, {"id": 8, "bbox": [993.09, 2.03, 324.24, 496.89], "category_id": 1}], "caption": "Scheme 7. Catenation of Two Cyclopentane-1,3-diyls", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 736, 749, 751], "ImageBB": [448, 757, 787, 895]}, "reactions": [{"reactants": [0, 1], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [3], "products": [8]}, {"reactants": [8], "conditions": [], "products": [6]}], "diagram_type": "single"}, {"id": 1017, "width": 1352, "height": 1096, "file_name": "jacs.5b00936-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [651.31, 140.63, 81.16, 32.45], "category_id": 2}, {"id": 1, "bbox": [110.24, 283.28, 294.89, 276.52], "category_id": 1}, {"id": 2, "bbox": [1087.55, 726.79, 188.02, 118.99], "category_id": 1}, {"id": 3, "bbox": [61.55, 101.41, 318.55, 53.41], "category_id": 1}, {"id": 4, "bbox": [94.69, 174.43, 241.45, 37.19], "category_id": 3}, {"id": 5, "bbox": [674.31, 782.91, 194.78, 54.76], "category_id": 2}, {"id": 6, "bbox": [418.65, 84.51, 116.33, 36.51], "category_id": 2}, {"id": 7, "bbox": [828.51, 85.86, 126.48, 36.51], "category_id": 2}, {"id": 8, "bbox": [443.0, 171.05, 72.37, 30.42], "category_id": 2}, {"id": 9, "bbox": [1101.75, 856.6, 165.71, 41.92], "category_id": 3}, {"id": 10, "bbox": [808.9, 278.55, 503.87, 325.87], "category_id": 1}, {"id": 11, "bbox": [484.93, 283.28, 302.33, 258.27], "category_id": 1}, {"id": 12, "bbox": [333.43, 835.64, 157.59, 52.06], "category_id": 2}, {"id": 13, "bbox": [690.51, 710.51, 157.89, 48.69], "category_id": 2}, {"id": 14, "bbox": [858.27, 171.05, 73.72, 30.42], "category_id": 2}, {"id": 15, "bbox": [1003.01, 58.14, 279.33, 91.95], "category_id": 1}, {"id": 16, "bbox": [630.35, 519.91, 41.25, 41.24], "category_id": 3}, {"id": 17, "bbox": [73.72, 718.0, 140.48, 103.45], "category_id": 1}, {"id": 18, "bbox": [1000.98, 167.67, 258.36, 39.21], "category_id": 3}, {"id": 19, "bbox": [564.07, 38.54, 242.13, 60.56], "category_id": 1}, {"id": 20, "bbox": [72.37, 839.7, 153.53, 48.0], "category_id": 2}, {"id": 21, "bbox": [628.99, 79.78, 122.42, 35.83], "category_id": 2}, {"id": 22, "bbox": [952.28, 957.34, 366.58, 134.54], "category_id": 1}, {"id": 23, "bbox": [244.83, 523.29, 35.17, 38.54], "category_id": 3}, {"id": 24, "bbox": [828.51, 128.46, 133.92, 28.39], "category_id": 2}, {"id": 25, "bbox": [417.98, 125.75, 135.26, 30.43], "category_id": 2}, {"id": 26, "bbox": [550.54, 955.31, 320.58, 126.43], "category_id": 1}, {"id": 27, "bbox": [10.15, 957.34, 412.56, 122.37], "category_id": 1}, {"id": 28, "bbox": [356.32, 747.35, 110.52, 46.05], "category_id": 2}], "caption": "Scheme 1. Hydroboration of 1-Octyne with 1 and 2 along with Solid State Structure of 2 at 30% Probability Ellipsoids ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 405]}, "reactions": [{"reactants": [19, 0], "conditions": [6, 25], "products": [3]}, {"reactants": [19, 0], "conditions": [7, 24], "products": [15]}, {"reactants": [17, 28], "conditions": [13, 5], "products": [2]}], "diagram_type": "multiple"}, {"id": 673, "width": 1344, "height": 1892, "file_name": "ol401812h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [161.19, 25.63, 311.71, 147.97], "category_id": 1}, {"id": 1, "bbox": [264.0, 216.0, 193.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [6.0, 701.0, 1331.0, 1160.0], "category_id": 4}, {"id": 3, "bbox": [875.2, 6.3, 308.3, 172.0], "category_id": 1}, {"id": 4, "bbox": [502.0, 0.0, 302.5, 87.0], "category_id": 1}, {"id": 5, "bbox": [1020.0, 216.1, 56.0, 58.9], "category_id": 3}, {"id": 6, "bbox": [503.74, 104.69, 333.66, 146.01], "category_id": 1}, {"id": 7, "bbox": [795.4, 398.1, 180.7, 238.3], "category_id": 3}, {"id": 8, "bbox": [373.0, 320.8, 404.1, 316.2], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [4, 6], "products": [3]}], "corefs": [[0, 1], [3, 5]], "caption": "Table 1. Screening of Reaction Conditions", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 298, 100], "ImageBB": [71, 112, 407, 585]}, "diagram_type": "single"}, {"id": 832, "width": 1348, "height": 400, "file_name": "jo4004426-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [546.0, 207.0, 375.0, 51.0], "category_id": 2}, {"id": 1, "bbox": [291.0, 32.0, 181.8, 268.0], "category_id": 1}, {"id": 2, "bbox": [49.0, 36.0, 128.0, 265.0], "category_id": 1}, {"id": 3, "bbox": [169.0, 238.0, 30.0, 39.0], "category_id": 3}, {"id": 4, "bbox": [460.0, 238.0, 32.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [959.0, 6.0, 336.0, 291.0], "category_id": 1}, {"id": 6, "bbox": [1129.0, 234.0, 31.0, 47.0], "category_id": 3}, {"id": 7, "bbox": [541.0, 44.0, 384.0, 107.9], "category_id": 2}], "reactions": [{"reactants": [2, 1], "conditions": [7, 0], "products": [5]}], "corefs": [[2, 3], [1, 4], [5, 6]], "caption": "Table 1. Optimization Studies with a Homogeneous Metal Source ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 412, 125], "ImageBB": [82, 131, 419, 231]}, "diagram_type": "single"}, {"id": 917, "width": 2820, "height": 676, "file_name": "acs.joc.5b01547-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [643.28, 229.62, 57.84, 53.53], "category_id": 3}, {"id": 1, "bbox": [1965.11, 5.63, 320.23, 190.17], "category_id": 1}, {"id": 2, "bbox": [2122.4, 239.21, 91.45, 72.31], "category_id": 1}, {"id": 3, "bbox": [1697.08, 38.03, 122.73, 61.99], "category_id": 2}, {"id": 4, "bbox": [1654.76, 494.45, 128.37, 54.94], "category_id": 2}, {"id": 5, "bbox": [529.01, 8.45, 344.22, 188.77], "category_id": 1}, {"id": 6, "bbox": [884.51, 50.71, 349.86, 59.17], "category_id": 2}, {"id": 7, "bbox": [1423.4, 228.21, 62.07, 49.3], "category_id": 3}, {"id": 8, "bbox": [1697.08, 126.78, 134.02, 56.35], "category_id": 2}, {"id": 9, "bbox": [1323.24, 12.68, 324.46, 184.54], "category_id": 1}, {"id": 10, "bbox": [1262.58, 580.38, 153.77, 52.12], "category_id": 3}, {"id": 11, "bbox": [891.57, 125.37, 299.07, 111.29], "category_id": 2}, {"id": 12, "bbox": [1602.56, 259.2, 335.75, 211.3], "category_id": 1}, {"id": 13, "bbox": [1086.24, 349.35, 438.73, 219.76], "category_id": 1}, {"id": 14, "bbox": [1965.11, 397.25, 313.18, 184.54], "category_id": 1}], "caption": "Scheme 2. Formation of 4 with Excess Sodium Trichloroacetate", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 442, 110], "ImageBB": [82, 116, 787, 285]}, "reactions": [{"reactants": [5], "conditions": [6, 11], "products": [9]}, {"reactants": [9], "conditions": [3, 8], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [14]}, {"reactants": [14], "conditions": [12, 4], "products": [13]}], "diagram_type": "tree"}, {"id": 916, "width": 1356, "height": 920, "file_name": "acs.joc.5b01204-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 584.31, 966.63, 284.34], "category_id": 1}, {"id": 1, "bbox": [276.76, 523.91, 60.37, 37.32], "category_id": 3}, {"id": 2, "bbox": [213.0, 232.77, 31.2, 36.65], "category_id": 3}, {"id": 3, "bbox": [820.11, 407.86, 363.59, 41.4], "category_id": 2}, {"id": 4, "bbox": [893.37, 186.62, 311.36, 111.98], "category_id": 2}, {"id": 5, "bbox": [39.34, 2.71, 341.89, 269.42], "category_id": 1}, {"id": 6, "bbox": [560.99, 4.07, 341.88, 268.06], "category_id": 1}, {"id": 7, "bbox": [963.92, 724.1, 282.19, 76.01], "category_id": 2}, {"id": 8, "bbox": [1283.42, 695.6, 48.16, 38.01], "category_id": 3}, {"id": 9, "bbox": [99.04, 295.89, 770.59, 266.02], "category_id": 1}, {"id": 10, "bbox": [362.23, 179.84, 149.92, 40.04], "category_id": 2}, {"id": 11, "bbox": [1042.61, 655.56, 127.53, 46.83], "category_id": 2}, {"id": 12, "bbox": [172.3, 838.79, 63.76, 39.36], "category_id": 3}, {"id": 13, "bbox": [330.35, 101.8, 211.64, 45.46], "category_id": 2}, {"id": 14, "bbox": [733.28, 232.77, 47.49, 39.36], "category_id": 3}, {"id": 15, "bbox": [816.04, 475.05, 341.88, 75.32], "category_id": 2}, {"id": 16, "bbox": [895.41, 77.36, 352.73, 80.08], "category_id": 2}], "caption": "Scheme 3. Synthesis of Probe 5b", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 477, 636, 492], "ImageBB": [448, 498, 787, 728]}, "reactions": [{"reactants": [5], "conditions": [13, 10], "products": [6]}, {"reactants": [6], "conditions": [16, 4], "products": [9]}, {"reactants": [9], "conditions": [3, 15], "products": [0]}, {"reactants": [0], "conditions": [11, 7], "products": [8]}], "diagram_type": "multiple"}, {"id": 398, "width": 1352, "height": 468, "file_name": "op500102h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [49.0, 326.0, 55.0, 47.9], "category_id": 3}, {"id": 1, "bbox": [1062.0, 114.4, 287.0, 208.6], "category_id": 1}, {"id": 2, "bbox": [1.0, 166.3, 228.0, 130.5], "category_id": 1}, {"id": 3, "bbox": [494.2, 146.2, 214.8, 183.8], "category_id": 1}, {"id": 4, "bbox": [770.41, 4.98, 265.39, 115.92], "category_id": 1}, {"id": 5, "bbox": [268.0, 158.1, 164.0, 56.9], "category_id": 2}, {"id": 6, "bbox": [248.0, 231.0, 187.9, 49.8], "category_id": 2}, {"id": 7, "bbox": [5.0, 391.0, 1339.0, 77.0], "category_id": 4}, {"id": 8, "bbox": [747.0, 130.0, 297.0, 90.0], "category_id": 2}, {"id": 9, "bbox": [760.0, 240.0, 275.0, 89.0], "category_id": 2}, {"id": 10, "bbox": [552.0, 326.0, 52.0, 39.0], "category_id": 3}, {"id": 11, "bbox": [1188.0, 325.0, 35.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [3], "conditions": [4, 8, 9], "products": [1]}], "corefs": [[2, 0], [3, 10], [1, 11]], "caption": "Table 1. Reaction of activated TFEDMA with \u03b2-keto esters and hydrazines ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 367, 783, 401], "ImageBB": [448, 407, 786, 524]}, "diagram_type": "single"}, {"id": 115, "width": 1328, "height": 1268, "file_name": "op9802071-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [584.0, 84.0, 339.0, 208.0], "category_id": 1}, {"id": 1, "bbox": [15.0, 343.0, 47.0, 59.0], "category_id": 3}, {"id": 2, "bbox": [1125.0, 337.0, 86.0, 51.0], "category_id": 3}, {"id": 3, "bbox": [716.0, 328.0, 80.0, 62.0], "category_id": 3}, {"id": 4, "bbox": [132.0, 290.0, 364.0, 77.0], "category_id": 2}, {"id": 5, "bbox": [719.0, 703.0, 81.0, 60.0], "category_id": 3}, {"id": 6, "bbox": [705.0, 891.0, 415.0, 235.0], "category_id": 1}, {"id": 7, "bbox": [828.0, 1154.0, 261.0, 114.0], "category_id": 3}, {"id": 8, "bbox": [1003.1, 79.3, 321.6, 220.0], "category_id": 1}, {"id": 9, "bbox": [234.27, 996.73, 42.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [1125.0, 711.0, 93.4, 56.8], "category_id": 3}, {"id": 11, "bbox": [332.0, 953.9, 330.0, 61.1], "category_id": 2}, {"id": 12, "bbox": [999.8, 457.0, 326.2, 222.7], "category_id": 1}, {"id": 13, "bbox": [584.0, 454.2, 337.4, 211.8], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [4], "products": [0, 8, 13, 12]}, {"reactants": [9], "conditions": [11], "products": [6]}], "corefs": [[0, 3], [8, 2], [13, 5], [12, 10], [6, 7]], "caption": "Table 1. Reduction of 3 with borohydrides", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 382, 310, 396], "ImageBB": [74, 52, 406, 369]}, "diagram_type": "multiple"}, {"id": 871, "width": 1352, "height": 620, "file_name": "ol7019636-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 0.0, 261.0, 140.0], "category_id": 1}, {"id": 1, "bbox": [656.0, 31.0, 68.0, 43.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 172.0, 1352.0, 444.0], "category_id": 4}, {"id": 3, "bbox": [241.0, 0.0, 265.0, 142.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1], "products": [0]}], "corefs": [], "caption": "Table 3. Preparation of Some Diazeniumdiolate Prodrug Forms ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 373, 104], "ImageBB": [73, 108, 411, 263]}, "diagram_type": "single"}, {"id": 405, "width": 1352, "height": 1228, "file_name": "op400278d-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [52.9, 43.0, 172.1, 202.0], "category_id": 1}, {"id": 1, "bbox": [555.0, 866.0, 243.0, 116.0], "category_id": 2}, {"id": 2, "bbox": [44.0, 1088.0, 462.0, 108.0], "category_id": 2}, {"id": 3, "bbox": [149.0, 595.0, 254.0, 110.0], "category_id": 2}, {"id": 4, "bbox": [973.0, 610.0, 243.0, 112.0], "category_id": 2}, {"id": 5, "bbox": [524.0, 211.0, 344.0, 100.0], "category_id": 2}, {"id": 6, "bbox": [285.0, 250.0, 194.0, 64.0], "category_id": 2}, {"id": 7, "bbox": [27.0, 259.0, 205.0, 59.0], "category_id": 2}, {"id": 8, "bbox": [491.0, 2.0, 423.0, 205.0], "category_id": 2}, {"id": 9, "bbox": [1055.0, 1079.0, 71.0, 53.0], "category_id": 3}, {"id": 10, "bbox": [241.0, 1027.0, 66.0, 53.0], "category_id": 3}, {"id": 11, "bbox": [642.0, 817.0, 66.0, 45.0], "category_id": 3}, {"id": 12, "bbox": [239.0, 544.0, 74.0, 51.0], "category_id": 3}, {"id": 13, "bbox": [1055.0, 558.0, 71.0, 47.0], "category_id": 3}, {"id": 14, "bbox": [110.0, 792.0, 329.0, 217.0], "category_id": 1}, {"id": 15, "bbox": [934.0, 723.0, 316.0, 329.0], "category_id": 1}, {"id": 16, "bbox": [449.0, 564.0, 480.0, 278.0], "category_id": 1}, {"id": 17, "bbox": [43.0, 357.0, 497.0, 188.0], "category_id": 1}, {"id": 18, "bbox": [888.0, 347.0, 464.0, 253.0], "category_id": 1}, {"id": 19, "bbox": [919.0, 78.0, 433.0, 190.0], "category_id": 1}, {"id": 20, "bbox": [305.0, 57.0, 174.0, 199.0], "category_id": 1}], "reactions": [{"reactants": [0, 20], "conditions": [8, 5], "products": [19]}], "corefs": [[17, 12], [18, 13], [16, 11], [14, 10], [15, 9]], "caption": "Table 6. Comparative study of Pd-PEPPSI-IPent (1) and Pd- PEPPSI-IPentCl (84) in aryl aminations with electron- de\ufb01cient anilines and electron-rich aryl chlorides ", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 141, 417, 186], "ImageBB": [82, 193, 420, 500]}, "diagram_type": "single"}, {"id": 720, "width": 1348, "height": 904, "file_name": "ol026156g-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [407.5, 2.4, 326.7, 295.0], "category_id": 1}, {"id": 1, "bbox": [1132.0, 356.0, 61.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [1139.29, 308.97, 48.47, 47.26], "category_id": 2}, {"id": 3, "bbox": [55.5, 86.0, 274.8, 131.5], "category_id": 1}, {"id": 4, "bbox": [517.3, 354.6, 88.7, 46.4], "category_id": 3}, {"id": 5, "bbox": [825.2, 167.0, 92.8, 95.5], "category_id": 2}, {"id": 6, "bbox": [0.0, 439.3, 1344.0, 464.7], "category_id": 4}, {"id": 7, "bbox": [837.0, 81.8, 61.6, 59.2], "category_id": 2}, {"id": 8, "bbox": [1018.9, 9.7, 284.1, 282.3], "category_id": 1}, {"id": 9, "bbox": [490.98, 308.97, 155.11, 50.89], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [7, 5], "products": [8]}], "corefs": [[0, 4], [8, 1]], "caption": "Table 1. Effects of R-Amino Acids in 2 on Catalytic Asymmetric Coupling of 2-Naphthol in CCl4 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 478, 721, 510], "ImageBB": [439, 520, 776, 746]}, "diagram_type": "single"}, {"id": 311, "width": 1356, "height": 1976, "file_name": "ol302400p-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [583.0, 135.0, 215.0, 90.0], "category_id": 2}, {"id": 1, "bbox": [996.0, 167.0, 93.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [563.0, 35.0, 267.0, 84.0], "category_id": 2}, {"id": 3, "bbox": [81.0, 3.0, 250.0, 148.0], "category_id": 1}, {"id": 4, "bbox": [853.0, 26.0, 433.0, 139.0], "category_id": 1}, {"id": 5, "bbox": [272.0, 59.0, 275.0, 123.0], "category_id": 1}, {"id": 6, "bbox": [15.0, 279.0, 1341.0, 1697.0], "category_id": 4}], "reactions": [{"reactants": [3, 5], "conditions": [2, 0], "products": [4]}], "corefs": [[4, 1]], "caption": "Table 3. Pd-Catalyzed Dehydrogenative Olefination of Terminal Alkynes with Allyl Phenyl Ethersa,b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 439, 728, 466], "ImageBB": [436, 477, 775, 971]}, "diagram_type": "single"}, {"id": 214, "width": 884, "height": 800, "file_name": "op034064g-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.5, 398.0, 300.8, 45.6], "category_id": 2}, {"id": 1, "bbox": [258.1, 360.0, 609.9, 45.0], "category_id": 2}, {"id": 2, "bbox": [394.1, 6.0, 484.9, 149.4], "category_id": 1}, {"id": 3, "bbox": [138.78, 154.0, 53.0, 51.0], "category_id": 3}, {"id": 4, "bbox": [62.22, 486.86, 51.0, 53.0], "category_id": 3}, {"id": 5, "bbox": [472.0, 202.0, 388.0, 53.6], "category_id": 2}, {"id": 6, "bbox": [0.0, 570.1, 573.7, 192.9], "category_id": 1}, {"id": 7, "bbox": [1.0, 331.1, 196.8, 142.8], "category_id": 1}, {"id": 8, "bbox": [212.0, 752.0, 62.2, 48.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 15.4, 302.1, 145.9], "category_id": 1}, {"id": 10, "bbox": [78.0, 204.0, 148.8, 46.3], "category_id": 2}], "reactions": [{"reactants": [9, 2], "conditions": [7, 1, 0], "products": [6]}], "corefs": [[9, 3], [7, 4], [6, 8]], "caption": "Table 4. Alkylation of resorcinol monobenzoate", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 294, 702, 308], "ImageBB": [424, 81, 645, 281]}, "diagram_type": "tree"}, {"id": 954, "width": 1352, "height": 2036, "file_name": "acs.orglett.6b00661-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.07, 16.3, 351.46, 422.68], "category_id": 1}, {"id": 1, "bbox": [120.21, 1329.15, 460.45, 67.23], "category_id": 3}, {"id": 2, "bbox": [535.84, 503.14, 236.34, 104.91], "category_id": 2}, {"id": 3, "bbox": [1016.67, 736.38, 77.43, 61.11], "category_id": 3}, {"id": 4, "bbox": [875.07, 845.36, 178.28, 158.89], "category_id": 2}, {"id": 5, "bbox": [116.13, 1849.61, 462.5, 70.28], "category_id": 3}, {"id": 6, "bbox": [122.25, 1048.05, 576.59, 428.79], "category_id": 1}, {"id": 7, "bbox": [122.25, 1564.43, 578.62, 437.96], "category_id": 1}, {"id": 8, "bbox": [162.99, 1455.45, 228.19, 112.04], "category_id": 2}, {"id": 9, "bbox": [309.69, 92.68, 142.62, 100.84], "category_id": 2}, {"id": 10, "bbox": [911.75, 226.11, 302.55, 152.78], "category_id": 2}, {"id": 11, "bbox": [613.26, 886.1, 188.47, 106.95], "category_id": 2}, {"id": 12, "bbox": [775.24, 435.92, 575.57, 445.09], "category_id": 1}, {"id": 13, "bbox": [1013.62, 143.61, 77.42, 63.15], "category_id": 3}, {"id": 14, "bbox": [239.4, 736.38, 92.7, 61.11], "category_id": 3}, {"id": 15, "bbox": [562.33, 647.77, 190.5, 204.72], "category_id": 2}, {"id": 16, "bbox": [911.75, 1329.15, 302.55, 71.3], "category_id": 3}, {"id": 17, "bbox": [613.26, 287.22, 81.5, 71.3], "category_id": 3}, {"id": 18, "bbox": [775.24, 1048.05, 572.51, 365.64], "category_id": 1}, {"id": 19, "bbox": [0.0, 456.29, 590.85, 424.72], "category_id": 1}, {"id": 20, "bbox": [309.69, 228.15, 157.9, 157.87], "category_id": 2}, {"id": 21, "bbox": [538.9, 16.3, 340.25, 423.7], "category_id": 1}, {"id": 22, "bbox": [1066.59, 886.1, 190.5, 115.09], "category_id": 2}, {"id": 23, "bbox": [871.0, 0.0, 405.44, 208.79], "category_id": 1}, {"id": 24, "bbox": [83.53, 282.13, 82.52, 81.48], "category_id": 3}], "caption": "Scheme 5. Synthesis of Gardnerine (1), Hydroxygardnerine (2), and Hydroxygardnutine (3) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 417, 125], "ImageBB": [82, 131, 420, 640]}, "reactions": [{"reactants": [0], "conditions": [9, 20], "products": [21]}, {"reactants": [21], "conditions": [23, 10], "products": [19]}, {"reactants": [19], "conditions": [2, 15], "products": [12]}, {"reactants": [12], "conditions": [4, 11], "products": [6]}, {"reactants": [6], "conditions": [8], "products": [7]}, {"reactants": [12], "conditions": [4, 22], "products": [18]}], "diagram_type": "tree"}, {"id": 592, "width": 1356, "height": 348, "file_name": "acs.oprd.6b00180-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [94.0, 249.0, 139.0, 38.7], "category_id": 2}, {"id": 1, "bbox": [528.0, 285.0, 633.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [98.0, 217.0, 131.0, 33.0], "category_id": 2}, {"id": 3, "bbox": [1038.0, 38.4, 314.9, 204.8], "category_id": 1}, {"id": 4, "bbox": [7.0, 65.6, 253.0, 137.4], "category_id": 1}, {"id": 5, "bbox": [327.2, 65.3, 301.8, 123.5], "category_id": 1}, {"id": 6, "bbox": [650.0, 35.0, 348.7, 89.2], "category_id": 2}, {"id": 7, "bbox": [719.5, 146.2, 190.8, 124.1], "category_id": 2}, {"id": 8, "bbox": [397.0, 209.0, 148.6, 43.8], "category_id": 2}, {"id": 9, "bbox": [1217.91, 229.75, 84.88, 46.01], "category_id": 2}], "reactions": [{"reactants": [4, 5], "conditions": [6, 7], "products": [3]}], "corefs": [], "caption": "Figure 3. Suzuki reaction of 4-bromoanisole with 3-aminophenylbor- onic acid using Pd(OAc)2/K3PO4/H2O in the absence of added ligand. ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 746, 784, 788], "ImageBB": [448, 650, 787, 737]}, "diagram_type": "single"}, {"id": 60, "width": 1352, "height": 948, "file_name": "ja402810t-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1119.49, 849.23, 73.55, 29.87], "category_id": 2}, {"id": 1, "bbox": [746.48, 589.9, 218.02, 194.7], "category_id": 1}, {"id": 2, "bbox": [7.56, 139.43, 563.91, 308.49], "category_id": 1}, {"id": 3, "bbox": [682.33, 137.05, 562.72, 307.31], "category_id": 1}, {"id": 4, "bbox": [12.31, 507.7, 588.86, 308.49], "category_id": 1}, {"id": 5, "bbox": [1033.31, 528.63, 310.26, 304.51], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [1, 5]}], "corefs": [], "caption": "Figure 2. Fragmentation patterns observed following CID of singly protonated PRAGS-derivatized (a) and FRAGS-derivatized (c) maltoheptaose and CID spectra of singly protonated PRAGS- derivatized (b) and FRAGS-derivatized (d) maltoheptaose. The parent ion refers to the protonated molecular ion. The possible fragmentation of the reducing terminus glycan subunit is not observed because of the low mass cuto\ufb00. ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 614, 417, 711], "ImageBB": [82, 716, 420, 953]}, "diagram_type": "multiple"}, {"id": 875, "width": 1352, "height": 680, "file_name": "ol701624y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [267.0, 278.0, 78.0, 35.0], "category_id": 3}, {"id": 1, "bbox": [604.0, 218.0, 86.0, 33.0], "category_id": 2}, {"id": 2, "bbox": [106.0, 44.0, 365.0, 212.0], "category_id": 1}, {"id": 3, "bbox": [883.0, 3.0, 364.0, 279.0], "category_id": 1}, {"id": 4, "bbox": [529.0, 20.0, 262.0, 101.0], "category_id": 2}, {"id": 5, "bbox": [582.0, 155.0, 165.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [8.0, 344.0, 1333.0, 322.0], "category_id": 4}, {"id": 7, "bbox": [907.0, 281.0, 73.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 5, 1], "products": [3]}], "corefs": [[2, 0], [3, 7]], "caption": "Table 3.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 486, 89], "ImageBB": [439, 93, 777, 263]}, "diagram_type": "single"}, {"id": 1321, "width": 1356, "height": 940, "file_name": "op3003097-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [259.8, 176.38, 335.78, 60.37], "category_id": 2}, {"id": 1, "bbox": [392.76, 543.38, 295.75, 59.02], "category_id": 2}, {"id": 2, "bbox": [144.49, 850.01, 159.41, 46.81], "category_id": 3}, {"id": 3, "bbox": [1025.65, 171.63, 50.87, 49.52], "category_id": 3}, {"id": 4, "bbox": [31.2, 128.89, 217.75, 209.62], "category_id": 1}, {"id": 5, "bbox": [690.55, 404.99, 38.66, 46.13], "category_id": 3}, {"id": 6, "bbox": [16.28, 459.26, 388.01, 371.08], "category_id": 1}, {"id": 7, "bbox": [594.9, 113.97, 261.16, 278.81], "category_id": 1}, {"id": 8, "bbox": [404.29, 635.64, 238.78, 107.19], "category_id": 2}, {"id": 9, "bbox": [128.88, 400.24, 42.74, 44.78], "category_id": 3}, {"id": 10, "bbox": [690.55, 455.87, 388.69, 374.47], "category_id": 1}, {"id": 11, "bbox": [894.05, 852.05, 29.17, 43.41], "category_id": 3}, {"id": 12, "bbox": [896.76, 269.32, 335.1, 134.32], "category_id": 2}, {"id": 13, "bbox": [875.74, 8.82, 392.75, 131.6], "category_id": 1}, {"id": 14, "bbox": [277.44, 267.28, 277.44, 152.64], "category_id": 2}], "caption": "Scheme 4. Process for the preparation of puri\ufb01ed 8", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 741, 110], "ImageBB": [448, 116, 787, 351]}, "reactions": [{"reactants": [4], "conditions": [0, 14], "products": [7]}, {"reactants": [7, 13], "conditions": [12], "products": [6]}, {"reactants": [6], "conditions": [1, 8], "products": [10]}], "diagram_type": "multiple"}, {"id": 155, "width": 2816, "height": 1752, "file_name": "op700160a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [14.0, 340.0, 2798.0, 895.0], "category_id": 4}, {"id": 1, "bbox": [24.0, 1235.0, 2792.0, 127.0], "category_id": 2}, {"id": 2, "bbox": [379.9, 1370.4, 322.1, 304.8], "category_id": 1}, {"id": 3, "bbox": [911.0, 258.3, 61.3, 54.4], "category_id": 3}, {"id": 4, "bbox": [635.0, 259.0, 46.4, 51.0], "category_id": 3}, {"id": 5, "bbox": [1871.39, 1510.0, 176.51, 57.0], "category_id": 2}, {"id": 6, "bbox": [772.3, 24.1, 317.7, 180.8], "category_id": 1}, {"id": 7, "bbox": [165.0, 1486.0, 190.6, 60.0], "category_id": 2}, {"id": 8, "bbox": [1468.8, 1402.2, 368.9, 249.1], "category_id": 1}, {"id": 9, "bbox": [1303.0, 1499.0, 154.3, 63.0], "category_id": 2}, {"id": 10, "bbox": [2094.1, 1392.1, 393.5, 266.0], "category_id": 1}, {"id": 11, "bbox": [738.0, 1497.0, 187.5, 59.0], "category_id": 2}, {"id": 12, "bbox": [950.2, 1388.8, 307.5, 273.8], "category_id": 1}, {"id": 13, "bbox": [1969.4, 0.0, 238.5, 232.6], "category_id": 1}, {"id": 14, "bbox": [1258.1, 42.8, 189.6, 51.2], "category_id": 2}, {"id": 15, "bbox": [2037.36, 258.35, 105.68, 63.41], "category_id": 3}, {"id": 16, "bbox": [1139.0, 128.0, 437.0, 63.3], "category_id": 2}, {"id": 17, "bbox": [1727.35, 258.35, 96.29, 61.06], "category_id": 3}, {"id": 18, "bbox": [607.1, 46.8, 116.2, 135.1], "category_id": 1}, {"id": 19, "bbox": [1660.3, 3.0, 238.2, 231.8], "category_id": 1}], "reactions": [{"reactants": [18, 6], "conditions": [14, 16], "products": [19, 13]}], "corefs": [[18, 4], [6, 3], [19, 17], [13, 15]], "caption": "Table 2. Chiral lanthanide camphorate catalysts in bisfuran alcohol formationa", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 45, 493, 59], "ImageBB": [58, 74, 762, 512]}, "diagram_type": "single"}, {"id": 486, "width": 1344, "height": 1060, "file_name": "ol0610183-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [35.0, 2.2, 243.3, 305.8], "category_id": 1}, {"id": 1, "bbox": [511.6, 15.0, 246.4, 299.0], "category_id": 1}, {"id": 2, "bbox": [1182.58, 343.74, 34.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [1071.58, 35.0, 240.0, 288.0], "category_id": 1}, {"id": 4, "bbox": [627.0, 341.0, 27.0, 40.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 423.0, 1342.0, 637.0], "category_id": 4}, {"id": 6, "bbox": [339.0, 135.0, 89.0, 42.0], "category_id": 2}, {"id": 7, "bbox": [312.0, 204.0, 162.0, 62.0], "category_id": 2}, {"id": 8, "bbox": [856.0, 137.0, 86.0, 38.0], "category_id": 2}, {"id": 9, "bbox": [820.0, 204.0, 158.0, 51.0], "category_id": 2}, {"id": 10, "bbox": [141.0, 339.0, 36.0, 35.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 7], "products": [1]}, {"reactants": [1], "conditions": [8, 9], "products": [3]}], "corefs": [[0, 10], [1, 4], [3, 2]], "caption": "Table 1. Substitution of 1 with Aromatic Compounds", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 624, 359, 637], "ImageBB": [74, 642, 410, 907]}, "diagram_type": "single"}, {"id": 289, "width": 1344, "height": 1288, "file_name": "ol702044z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [170.0, 0.0, 282.0, 243.0], "category_id": 1}, {"id": 1, "bbox": [1025.0, 250.0, 43.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [485.0, 173.0, 342.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [510.0, 108.0, 291.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [886.0, 30.0, 286.0, 212.0], "category_id": 1}, {"id": 5, "bbox": [8.0, 354.0, 1336.0, 934.0], "category_id": 4}, {"id": 6, "bbox": [242.0, 247.0, 50.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [3, 2], "products": [4]}], "corefs": [[0, 6], [4, 1]], "caption": "Table 1. Reaction Development for the Conversion 1 f 2a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 298, 387, 314], "ImageBB": [74, 317, 410, 639]}, "diagram_type": "single"}, {"id": 852, "width": 1344, "height": 1168, "file_name": "jo2008675-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [416.0, 224.0, 32.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [92.0, 211.0, 97.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [334.0, 82.0, 233.0, 117.0], "category_id": 1}, {"id": 3, "bbox": [973.0, 37.0, 368.0, 177.0], "category_id": 1}, {"id": 4, "bbox": [3.0, 2.0, 241.0, 204.0], "category_id": 1}, {"id": 5, "bbox": [5.0, 336.0, 1339.0, 832.0], "category_id": 4}, {"id": 6, "bbox": [615.0, 159.0, 291.0, 47.0], "category_id": 2}, {"id": 7, "bbox": [610.0, 97.0, 273.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [1142.0, 216.0, 102.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 2], "conditions": [7, 6], "products": [3]}], "corefs": [[4, 1], [2, 0], [3, 8]], "caption": "Table 3. Synthesis of Di\ufb00erently Substituted 2, 3-Dihydrobenzofuransa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 698, 122], "ImageBB": [437, 133, 773, 425]}, "diagram_type": "single"}, {"id": 76, "width": 2808, "height": 3076, "file_name": "ja200818w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [880.17, 204.77, 174.32, 44.69], "category_id": 2}, {"id": 1, "bbox": [1105.28, 150.43, 745.63, 138.57], "category_id": 2}, {"id": 2, "bbox": [488.68, 426.6, 1828.42, 2501.25], "category_id": 4}, {"id": 3, "bbox": [568.79, 58.12, 222.28, 146.19], "category_id": 1}, {"id": 4, "bbox": [885.2, 118.2, 158.2, 44.5], "category_id": 1}, {"id": 5, "bbox": [590.63, 210.98, 170.45, 45.47], "category_id": 2}, {"id": 6, "bbox": [1109.16, 42.53, 510.43, 92.05], "category_id": 2}, {"id": 7, "bbox": [1872.2, 7.6, 367.61, 200.72], "category_id": 1}], "reactions": [{"reactants": [3, 4], "conditions": [6, 1], "products": [7]}], "corefs": [[3, 5], [4, 0]], "caption": "Table 1. Palladium-Catalyzed Carbonylations Using 25 and *25a", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 428, 108], "ImageBB": [71, 117, 773, 886]}, "diagram_type": "single"}, {"id": 791, "width": 1204, "height": 988, "file_name": "jo501785d-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [363.0, 168.0, 56.0, 40.0], "category_id": 3}, {"id": 1, "bbox": [7.0, 233.0, 1174.0, 749.0], "category_id": 4}, {"id": 2, "bbox": [579.0, 104.0, 271.0, 113.0], "category_id": 2}, {"id": 3, "bbox": [119.0, 164.0, 37.0, 49.0], "category_id": 3}, {"id": 4, "bbox": [168.0, 844.0, 155.0, 137.0], "category_id": 1}, {"id": 5, "bbox": [600.0, 1.0, 221.0, 96.0], "category_id": 2}, {"id": 6, "bbox": [944.0, 165.6, 38.7, 49.4], "category_id": 3}, {"id": 7, "bbox": [17.9, 22.9, 226.8, 170.8], "category_id": 1}, {"id": 8, "bbox": [867.3, 3.0, 322.7, 206.7], "category_id": 1}, {"id": 9, "bbox": [281.6, 28.2, 274.8, 124.6], "category_id": 1}], "reactions": [{"reactants": [7, 9], "conditions": [5, 2], "products": [8]}], "corefs": [[7, 3], [9, 0], [8, 6]], "caption": "Table 2. Scope with Respect to Triazole 1a,b", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 336, 110], "ImageBB": [100, 116, 401, 363]}, "diagram_type": "single"}, {"id": 698, "width": 1368, "height": 2072, "file_name": "ol047761h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [860.0, 0.0, 274.0, 213.0], "category_id": 1}, {"id": 1, "bbox": [32.0, 228.1, 1308.1, 1843.9], "category_id": 4}, {"id": 2, "bbox": [218.0, 24.0, 229.0, 131.0], "category_id": 1}, {"id": 3, "bbox": [469.0, 24.0, 320.0, 67.0], "category_id": 2}, {"id": 4, "bbox": [730.0, 283.0, 268.0, 201.0], "category_id": 1}, {"id": 5, "bbox": [1045.0, 171.0, 92.0, 48.0], "category_id": 3}, {"id": 6, "bbox": [330.0, 171.0, 37.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [827.0, 478.0, 73.0, 62.0], "category_id": 3}, {"id": 8, "bbox": [1164.0, 476.0, 71.0, 64.0], "category_id": 3}, {"id": 9, "bbox": [471.0, 114.0, 320.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [1065.0, 287.0, 268.0, 187.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [3, 9], "products": [0]}], "corefs": [[2, 6], [0, 5], [4, 7], [10, 8]], "caption": "Table 2. Ring Opening of Bn2N-R-Me-Ser-\u03b2-Lactone with Various Grignard-Derived Organocuprates ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 421, 385, 449], "ImageBB": [73, 450, 415, 968]}, "diagram_type": "single"}, {"id": 352, "width": 1348, "height": 1832, "file_name": "ol201201a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [309.0, 66.3, 255.6, 196.7], "category_id": 1}, {"id": 1, "bbox": [624.0, 175.09, 256.0, 47.0], "category_id": 2}, {"id": 2, "bbox": [1100.0, 260.0, 83.0, 50.1], "category_id": 3}, {"id": 3, "bbox": [423.0, 260.0, 45.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [622.0, 106.0, 265.0, 57.0], "category_id": 2}, {"id": 5, "bbox": [2.0, 7.0, 187.0, 241.0], "category_id": 1}, {"id": 6, "bbox": [951.0, 11.0, 382.0, 256.0], "category_id": 1}, {"id": 7, "bbox": [47.0, 265.0, 59.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [10.0, 365.0, 1338.0, 1467.0], "category_id": 4}], "reactions": [{"reactants": [5, 0], "conditions": [4, 1], "products": [6]}], "corefs": [[5, 7], [0, 3], [6, 2]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 185, 688, 201], "ImageBB": [436, 211, 773, 669]}, "diagram_type": "single"}, {"id": 1097, "width": 1040, "height": 564, "file_name": "jo961365y-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [382.39, 214.32, 113.42, 56.18], "category_id": 3}, {"id": 1, "bbox": [331.41, 329.8, 226.83, 165.94], "category_id": 1}, {"id": 2, "bbox": [816.81, 214.32, 112.37, 55.14], "category_id": 3}, {"id": 3, "bbox": [775.19, 4.68, 264.81, 245.01], "category_id": 1}, {"id": 4, "bbox": [835.02, 507.7, 104.57, 53.58], "category_id": 3}, {"id": 5, "bbox": [338.69, 36.41, 222.67, 159.7], "category_id": 1}, {"id": 6, "bbox": [382.39, 507.18, 111.34, 54.1], "category_id": 3}, {"id": 7, "bbox": [774.67, 290.78, 265.33, 247.61], "category_id": 1}, {"id": 8, "bbox": [0.0, 380.78, 132.67, 58.26], "category_id": 3}, {"id": 9, "bbox": [0.0, 380.78, 132.67, 58.26], "category_id": 3}, {"id": 10, "bbox": [0.0, 110.8, 132.67, 60.86], "category_id": 3}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [206, 49, 269, 63], "ImageBB": [111, 68, 371, 209]}, "reactions": [{"reactants": [10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [3]}, {"reactants": [9], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [7]}], "diagram_type": "multiple"}, {"id": 296, "width": 1344, "height": 1196, "file_name": "ol400025a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [686.0, 106.0, 186.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [418.0, 251.0, 54.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [1.0, 317.0, 1343.0, 879.0], "category_id": 4}, {"id": 3, "bbox": [1004.0, 248.0, 67.5, 45.9], "category_id": 3}, {"id": 4, "bbox": [352.1, 48.0, 299.4, 182.3], "category_id": 1}, {"id": 5, "bbox": [924.8, 1.5, 299.1, 241.4], "category_id": 1}, {"id": 6, "bbox": [663.6, 173.2, 241.8, 44.2], "category_id": 2}, {"id": 7, "bbox": [181.0, 246.6, 59.0, 50.4], "category_id": 3}, {"id": 8, "bbox": [126.3, 104.3, 205.2, 126.9], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [0, 6], "products": [5]}], "corefs": [[8, 7], [4, 1], [5, 3]], "caption": "Table 2. Screening of Squaramide Catalytsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 544, 303, 560], "ImageBB": [71, 571, 407, 870]}, "diagram_type": "single"}, {"id": 37, "width": 1348, "height": 1676, "file_name": "ja5080739-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [389.55, 50.69, 140.17, 38.61], "category_id": 2}, {"id": 1, "bbox": [107.07, 106.48, 43.91, 34.27], "category_id": 3}, {"id": 2, "bbox": [1023.27, 5.47, 270.66, 108.04], "category_id": 1}, {"id": 3, "bbox": [594.93, 32.72, 265.63, 33.01], "category_id": 2}, {"id": 4, "bbox": [1123.86, 106.48, 46.43, 35.11], "category_id": 3}, {"id": 5, "bbox": [594.09, 70.02, 320.95, 74.93], "category_id": 2}, {"id": 6, "bbox": [0.0, 168.74, 1344.96, 1504.99], "category_id": 4}, {"id": 7, "bbox": [51.31, 6.55, 218.26, 106.25], "category_id": 1}], "reactions": [{"reactants": [7, 0], "conditions": [3, 5], "products": [2]}], "corefs": [[7, 1], [2, 4]], "caption": "Table 3. Optimization of the Asymmetric Varianta", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 734, 110], "ImageBB": [449, 116, 786, 535]}, "diagram_type": "single"}, {"id": 844, "width": 1352, "height": 3144, "file_name": "jo201489z-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [827.0, 603.0, 441.0, 408.0], "category_id": 1}, {"id": 1, "bbox": [280.0, 220.0, 184.0, 106.0], "category_id": 2}, {"id": 2, "bbox": [135.0, 1822.0, 151.0, 66.0], "category_id": 2}, {"id": 3, "bbox": [775.0, 524.0, 127.0, 61.0], "category_id": 2}, {"id": 4, "bbox": [736.0, 477.0, 66.0, 31.0], "category_id": 3}, {"id": 5, "bbox": [734.0, 942.0, 59.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1128.0, 1501.0, 71.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [586.0, 1487.0, 95.0, 65.0], "category_id": 3}, {"id": 8, "bbox": [72.0, 1851.0, 47.0, 68.0], "category_id": 3}, {"id": 9, "bbox": [608.0, 2037.0, 82.0, 51.0], "category_id": 3}, {"id": 10, "bbox": [1130.0, 2021.0, 83.0, 59.0], "category_id": 3}, {"id": 11, "bbox": [543.0, 85.0, 442.0, 399.0], "category_id": 1}, {"id": 12, "bbox": [316.0, 599.0, 445.0, 406.0], "category_id": 1}, {"id": 13, "bbox": [293.0, 1163.0, 438.0, 385.0], "category_id": 1}, {"id": 14, "bbox": [807.0, 1156.0, 435.0, 402.0], "category_id": 1}, {"id": 15, "bbox": [817.0, 1677.0, 418.0, 402.0], "category_id": 1}, {"id": 16, "bbox": [300.0, 1670.0, 421.0, 416.0], "category_id": 1}, {"id": 17, "bbox": [145.0, 2267.0, 540.0, 550.0], "category_id": 1}, {"id": 18, "bbox": [636.0, 2231.0, 566.0, 570.0], "category_id": 1}, {"id": 19, "bbox": [277.0, 2811.0, 388.0, 319.0], "category_id": 1}, {"id": 20, "bbox": [748.0, 2794.0, 401.0, 333.0], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [3], "products": [12, 0]}, {"reactants": [12], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [16]}, {"reactants": [0], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [15]}, {"reactants": [16], "conditions": [2], "products": [8]}], "corefs": [[11, 4], [12, 5], [0, 5], [13, 7], [14, 6], [16, 9], [15, 10]], "caption": "Figure 2. DFT calculated structures IIB (left) and IIIA (right), shown above the expansions of the key bipyrrolic fragments. ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [70, 875, 405, 903], "ImageBB": [69, 81, 407, 867]}, "diagram_type": "tree"}, {"id": 206, "width": 1348, "height": 924, "file_name": "op034181b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 442.0, 1342.0, 458.0], "category_id": 4}, {"id": 1, "bbox": [655.14, 116.09, 154.1, 54.31], "category_id": 2}, {"id": 2, "bbox": [1140.9, 234.12, 47.07, 54.49], "category_id": 3}, {"id": 3, "bbox": [285.02, 262.6, 45.83, 56.98], "category_id": 3}, {"id": 4, "bbox": [141.0, 108.0, 334.0, 161.9], "category_id": 1}, {"id": 5, "bbox": [536.0, 224.0, 377.0, 42.0], "category_id": 2}, {"id": 6, "bbox": [876.0, 0.0, 335.0, 413.0], "category_id": 1}, {"id": 7, "bbox": [527.0, 43.0, 327.0, 156.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [7, 1, 5], "products": [6]}], "corefs": [[4, 3], [6, 2]], "caption": "Table 1. Nucleophilic aromatic substitution of 4-fluoro-3-nitroaniline with phenethylamine ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 697, 81], "ImageBB": [439, 84, 776, 315]}, "diagram_type": "single"}, {"id": 33, "width": 1348, "height": 796, "file_name": "ja511913h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [353.78, 651.64, 160.62, 36.6], "category_id": 2}, {"id": 1, "bbox": [122.0, 653.68, 150.46, 34.56], "category_id": 2}, {"id": 2, "bbox": [929.82, 506.46, 314.24, 98.54], "category_id": 1}, {"id": 3, "bbox": [318.7, 534.19, 232.07, 60.54], "category_id": 1}, {"id": 4, "bbox": [95.82, 513.64, 197.15, 97.52], "category_id": 1}, {"id": 5, "bbox": [584.72, 605.06, 290.61, 82.11], "category_id": 2}, {"id": 6, "bbox": [582.67, 487.97, 293.69, 82.11], "category_id": 2}, {"id": 7, "bbox": [725.86, 49.82, 370.03, 382.24], "category_id": 1}, {"id": 8, "bbox": [7.13, 722.81, 1333.77, 73.19], "category_id": 4}, {"id": 9, "bbox": [980.0, 651.64, 216.54, 36.6], "category_id": 2}], "reactions": [{"reactants": [4, 3], "conditions": [6, 5], "products": [2]}], "corefs": [[4, 1], [3, 0], [2, 9]], "caption": "Table 1. Optimization of the Decarboxylative Ole\ufb01nationa", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 89, 773, 111], "ImageBB": [449, 116, 786, 315]}, "diagram_type": "single"}, {"id": 421, "width": 2820, "height": 2272, "file_name": "op300341n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [750.2, 79.1, 199.6, 128.7], "category_id": 1}, {"id": 1, "bbox": [976.4, 96.1, 855.0, 269.7], "category_id": 1}, {"id": 2, "bbox": [240.4, 1481.6, 1216.6, 790.4], "category_id": 4}, {"id": 3, "bbox": [1507.5, 1414.2, 981.8, 845.2], "category_id": 4}, {"id": 4, "bbox": [246.5, 540.2, 1156.5, 756.5], "category_id": 4}, {"id": 5, "bbox": [2296.4, 293.1, 148.4, 202.8], "category_id": 1}, {"id": 6, "bbox": [2097.6, 0.0, 713.3, 191.2], "category_id": 1}, {"id": 7, "bbox": [1401.3, 542.6, 1167.7, 760.2], "category_id": 4}, {"id": 8, "bbox": [14.2, 120.0, 750.8, 205.7], "category_id": 1}, {"id": 9, "bbox": [1461.0, 377.0, 67.0, 52.0], "category_id": 3}, {"id": 10, "bbox": [2461.0, 431.0, 62.0, 48.0], "category_id": 3}, {"id": 11, "bbox": [364.0, 364.0, 63.0, 81.0], "category_id": 3}, {"id": 12, "bbox": [2540.0, 128.0, 44.0, 64.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [0], "products": [1]}, {"reactants": [1], "conditions": [], "products": [6, 5]}], "corefs": [[8, 11], [1, 9], [6, 12], [5, 10]], "caption": "Figure 2. Distillation phase diagrams for chloroacetonitrile, TFA, and 2-butanol.", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 693, 471, 707], "ImageBB": [82, 116, 787, 684]}, "diagram_type": "single"}, {"id": 58, "width": 1352, "height": 1404, "file_name": "ja406383h-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [552.62, 434.38, 186.73, 190.26], "category_id": 1}, {"id": 1, "bbox": [427.9, 740.04, 108.06, 49.14], "category_id": 2}, {"id": 2, "bbox": [198.98, 763.4, 169.14, 107.56], "category_id": 1}, {"id": 3, "bbox": [556.14, 1025.54, 199.05, 177.94], "category_id": 1}, {"id": 4, "bbox": [126.84, 444.94, 158.59, 63.58], "category_id": 1}, {"id": 5, "bbox": [288.45, 1075.89, 184.66, 35.88], "category_id": 2}, {"id": 6, "bbox": [854.59, 1075.4, 129.67, 35.88], "category_id": 2}, {"id": 7, "bbox": [303.18, 641.84, 167.97, 78.1], "category_id": 2}, {"id": 8, "bbox": [906.26, 237.33, 170.9, 123.4], "category_id": 1}, {"id": 9, "bbox": [198.98, 233.81, 169.14, 123.4], "category_id": 1}, {"id": 10, "bbox": [1004.78, 1030.82, 250.08, 190.26], "category_id": 1}, {"id": 11, "bbox": [930.9, 759.87, 167.37, 109.33], "category_id": 1}, {"id": 12, "bbox": [123.48, 555.57, 172.49, 52.13], "category_id": 1}, {"id": 13, "bbox": [56.47, 1020.27, 200.81, 184.97], "category_id": 1}, {"id": 14, "bbox": [817.28, 640.36, 260.76, 72.71], "category_id": 2}, {"id": 15, "bbox": [806.47, 734.64, 60.44, 30.97], "category_id": 2}, {"id": 16, "bbox": [677.34, 276.03, 220.01, 77.13], "category_id": 2}, {"id": 17, "bbox": [329.21, 449.36, 126.72, 72.7], "category_id": 2}, {"id": 18, "bbox": [414.64, 278.49, 85.48, 73.21], "category_id": 2}], "reactions": [{"reactants": [9], "conditions": [18], "products": [0]}, {"reactants": [8], "conditions": [16], "products": [0]}, {"reactants": [4, 12], "conditions": [17], "products": [0]}, {"reactants": [2], "conditions": [7, 1], "products": [0]}, {"reactants": [11], "conditions": [14, 15], "products": [0]}, {"reactants": [13], "conditions": [5], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [10]}], "corefs": [], "caption": "Figure 2. Some examples of natural and pharmaceutical products containing an enamide group. ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 267, 417, 295], "ImageBB": [82, 298, 420, 649]}, "diagram_type": "tree"}, {"id": 651, "width": 1348, "height": 964, "file_name": "ol5000692-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [230.1, 5.5, 282.9, 189.8], "category_id": 1}, {"id": 1, "bbox": [294.2, 196.0, 110.8, 56.5], "category_id": 3}, {"id": 2, "bbox": [540.5, 34.7, 202.5, 55.3], "category_id": 2}, {"id": 3, "bbox": [945.7, 200.5, 114.6, 53.3], "category_id": 3}, {"id": 4, "bbox": [541.0, 105.0, 216.8, 105.8], "category_id": 2}, {"id": 5, "bbox": [784.0, 0.0, 363.0, 188.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 280.0, 1339.0, 684.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [2, 4], "products": [5]}], "corefs": [[0, 1], [5, 3]], "caption": "Table 2. Cyclization of 2 to 3 Catalyzed by 1a", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 737, 345, 758], "ImageBB": [82, 764, 419, 1005]}, "diagram_type": "single"}, {"id": 1156, "width": 1356, "height": 812, "file_name": "ol0513995-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 58.35, 259.13, 115.35], "category_id": 1}, {"id": 1, "bbox": [1043.96, 264.63, 279.48, 50.89], "category_id": 2}, {"id": 2, "bbox": [845.89, 0.0, 263.87, 175.06], "category_id": 1}, {"id": 3, "bbox": [1010.05, 183.88, 40.02, 52.93], "category_id": 3}, {"id": 4, "bbox": [366.3, 558.43, 442.28, 54.96], "category_id": 2}, {"id": 5, "bbox": [1043.96, 312.8, 307.97, 139.78], "category_id": 2}, {"id": 6, "bbox": [124.81, 481.08, 192.65, 215.77], "category_id": 1}, {"id": 7, "bbox": [284.9, 16.28, 523.68, 93.64], "category_id": 2}, {"id": 8, "bbox": [214.36, 707.03, 42.05, 46.82], "category_id": 3}, {"id": 9, "bbox": [845.21, 479.04, 266.59, 219.17], "category_id": 1}, {"id": 10, "bbox": [113.96, 187.27, 31.88, 43.43], "category_id": 3}, {"id": 11, "bbox": [1010.05, 705.67, 40.02, 48.18], "category_id": 3}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 547, 265, 560], "ImageBB": [73, 565, 412, 768]}, "reactions": [{"reactants": [0], "conditions": [7], "products": [2]}, {"reactants": [2], "conditions": [1, 5], "products": [9]}, {"reactants": [9], "conditions": [4], "products": [6]}], "diagram_type": "tree"}, {"id": 1290, "width": 2040, "height": 1424, "file_name": "op200112g-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 1112.94, 667.41, 262.41], "category_id": 1}, {"id": 1, "bbox": [253.09, 255.26, 312.27, 215.44], "category_id": 1}, {"id": 2, "bbox": [811.31, 0.0, 319.42, 215.44], "category_id": 1}, {"id": 3, "bbox": [1374.63, 621.82, 665.37, 226.67], "category_id": 1}, {"id": 4, "bbox": [271.46, 0.0, 302.07, 217.48], "category_id": 1}, {"id": 5, "bbox": [632.72, 1122.13, 651.08, 250.15], "category_id": 1}, {"id": 6, "bbox": [676.6, 38.8, 60.21, 50.03], "category_id": 2}, {"id": 7, "bbox": [527.6, 689.2, 56.13, 53.1], "category_id": 2}, {"id": 8, "bbox": [1257.27, 205.23, 59.19, 51.05], "category_id": 2}, {"id": 9, "bbox": [1709.35, 459.47, 51.03, 47.99], "category_id": 2}, {"id": 10, "bbox": [628.63, 606.5, 642.93, 283.85], "category_id": 1}, {"id": 11, "bbox": [194.92, 992.45, 54.08, 51.06], "category_id": 2}, {"id": 12, "bbox": [1308.29, 700.44, 47.97, 52.07], "category_id": 2}, {"id": 13, "bbox": [956.22, 1378.41, 31.63, 40.84], "category_id": 3}, {"id": 14, "bbox": [676.6, 332.86, 46.94, 46.97], "category_id": 2}, {"id": 15, "bbox": [812.33, 265.47, 379.63, 219.53], "category_id": 1}, {"id": 16, "bbox": [554.14, 1171.14, 45.92, 52.07], "category_id": 2}, {"id": 17, "bbox": [1374.63, 138.86, 665.37, 222.59], "category_id": 1}, {"id": 18, "bbox": [0.0, 613.65, 563.32, 266.49], "category_id": 1}], "caption": "Scheme 4. Previous1 biomimetic route to the key iso\ufb02av-3-ene intermediate 8a", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 508, 108], "ImageBB": [167, 116, 677, 472]}, "reactions": [{"reactants": [4], "conditions": [6], "products": [2]}, {"reactants": [1], "conditions": [14], "products": [15]}, {"reactants": [2, 15], "conditions": [8], "products": [17]}, {"reactants": [17], "conditions": [9], "products": [3]}, {"reactants": [3], "conditions": [12], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [18]}, {"reactants": [18], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [16], "products": [5]}], "diagram_type": "tree"}, {"id": 872, "width": 1352, "height": 632, "file_name": "ol701624y-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 347.0, 1346.0, 284.0], "category_id": 4}, {"id": 1, "bbox": [925.0, 222.0, 82.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [575.18, 31.0, 197.0, 111.0], "category_id": 2}, {"id": 3, "bbox": [852.0, 0.0, 354.0, 251.2], "category_id": 1}, {"id": 4, "bbox": [154.0, 219.0, 82.0, 52.0], "category_id": 3}, {"id": 5, "bbox": [150.8, 2.0, 366.2, 326.0], "category_id": 1}, {"id": 6, "bbox": [575.18, 185.55, 210.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [2, 6], "products": [3]}], "corefs": [[5, 4], [3, 1]], "caption": "Table 6.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 260, 486, 273], "ImageBB": [439, 276, 777, 434]}, "diagram_type": "single"}, {"id": 634, "width": 1348, "height": 1044, "file_name": "ol501165h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [231.4, 33.63, 39.02, 56.51], "category_id": 3}, {"id": 1, "bbox": [924.0, 553.1, 353.3, 359.6], "category_id": 1}, {"id": 2, "bbox": [976.0, 27.0, 180.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [562.0, 1.0, 362.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [847.0, 452.0, 247.0, 81.0], "category_id": 3}, {"id": 5, "bbox": [64.0, 815.0, 312.0, 127.0], "category_id": 3}, {"id": 6, "bbox": [502.0, 848.0, 276.0, 96.0], "category_id": 3}, {"id": 7, "bbox": [21.0, 971.0, 1319.0, 66.0], "category_id": 4}, {"id": 8, "bbox": [220.0, 550.0, 265.0, 360.0], "category_id": 1}, {"id": 9, "bbox": [940.0, 793.0, 103.0, 57.0], "category_id": 3}, {"id": 10, "bbox": [302.2, 34.0, 196.8, 56.0], "category_id": 1}, {"id": 11, "bbox": [519.69, 63.0, 452.0, 89.0], "category_id": 2}, {"id": 12, "bbox": [558.0, 428.69, 88.0, 50.0], "category_id": 3}, {"id": 13, "bbox": [162.0, 442.69, 228.0, 91.0], "category_id": 3}, {"id": 14, "bbox": [218.0, 237.1, 286.7, 236.9], "category_id": 1}, {"id": 15, "bbox": [553.0, 230.1, 280.0, 243.9], "category_id": 1}, {"id": 16, "bbox": [874.9, 207.4, 330.4, 296.0], "category_id": 1}, {"id": 17, "bbox": [546.8, 550.0, 300.2, 313.0], "category_id": 1}], "reactions": [{"reactants": [0, 10], "conditions": [3, 11], "products": [2]}], "corefs": [[14, 13], [15, 12], [16, 4], [8, 5], [17, 6], [1, 9]], "caption": "Table 2. Cyclocarbopalladation/Suzuki\u2212Miyaura Coupling", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 411, 110], "ImageBB": [82, 116, 419, 377]}, "diagram_type": "single"}, {"id": 495, "width": 1348, "height": 1244, "file_name": "ol0600584-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [786.0, 15.0, 220.3, 135.0], "category_id": 1}, {"id": 1, "bbox": [568.7, 1.0, 201.3, 98.3], "category_id": 2}, {"id": 2, "bbox": [345.0, 16.0, 208.0, 133.0], "category_id": 1}, {"id": 3, "bbox": [10.0, 195.0, 1338.0, 1049.0], "category_id": 4}, {"id": 4, "bbox": [608.0, 109.0, 136.0, 42.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Table 1. Enantioselective Borane Reduction of Acetophenonea", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 500, 770, 514], "ImageBB": [439, 523, 776, 834]}, "diagram_type": "single"}, {"id": 94, "width": 1348, "height": 620, "file_name": "ja053368a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1105.08, 5.53, 228.7, 168.72], "category_id": 1}, {"id": 1, "bbox": [7.16, 205.8, 1336.74, 407.6], "category_id": 4}, {"id": 2, "bbox": [438.19, 113.29, 553.0, 39.61], "category_id": 2}, {"id": 3, "bbox": [15.29, 47.21, 93.5, 93.5], "category_id": 1}, {"id": 4, "bbox": [148.46, 42.13, 163.64, 97.56], "category_id": 1}, {"id": 5, "bbox": [337.55, 36.03, 754.28, 40.63], "category_id": 2}], "reactions": [{"reactants": [3, 4], "conditions": [5, 2], "products": [0]}], "corefs": [], "caption": "Table 1. DA Reaction of Cyclopentadiene with Methacroleina", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 470, 747, 483], "ImageBB": [439, 488, 776, 643]}, "diagram_type": "single"}, {"id": 577, "width": 1148, "height": 1892, "file_name": "acs.orglett.5b00663-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [251.6, 140.9, 26.9, 36.6], "category_id": 3}, {"id": 1, "bbox": [493.0, 103.0, 157.0, 40.0], "category_id": 2}, {"id": 2, "bbox": [878.0, 142.0, 28.0, 31.0], "category_id": 3}, {"id": 3, "bbox": [375.0, 10.0, 418.0, 78.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 203.0, 1143.0, 1685.0], "category_id": 4}, {"id": 5, "bbox": [835.0, 17.0, 120.0, 103.0], "category_id": 1}, {"id": 6, "bbox": [185.0, 8.0, 154.0, 108.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [3, 1], "products": [5]}], "corefs": [[6, 0], [5, 2]], "caption": "Table 2. Substrate Scope Screeninga", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 91, 652, 109], "ImageBB": [474, 116, 761, 589]}, "diagram_type": "single"}, {"id": 1179, "width": 2808, "height": 1700, "file_name": "ol301852m-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1293.73, 886.38, 212.11, 74.46], "category_id": 2}, {"id": 1, "bbox": [1057.74, 171.38, 209.3, 74.45], "category_id": 2}, {"id": 2, "bbox": [1894.94, 1223.52, 119.4, 43.55], "category_id": 2}, {"id": 3, "bbox": [1893.54, 890.6, 136.25, 85.69], "category_id": 2}, {"id": 4, "bbox": [920.08, 1116.76, 417.2, 314.66], "category_id": 1}, {"id": 5, "bbox": [1354.13, 1223.52, 92.71, 43.55], "category_id": 2}, {"id": 6, "bbox": [793.66, 1272.69, 154.51, 78.66], "category_id": 2}, {"id": 7, "bbox": [823.16, 1224.92, 80.06, 42.15], "category_id": 2}, {"id": 8, "bbox": [622.28, 0.0, 501.48, 309.04], "category_id": 1}, {"id": 9, "bbox": [823.16, 629.32, 43.54, 40.74], "category_id": 3}, {"id": 10, "bbox": [1063.36, 502.89, 75.85, 42.15], "category_id": 2}, {"id": 11, "bbox": [1163.09, 365.23, 431.25, 304.83], "category_id": 1}, {"id": 12, "bbox": [1293.73, 1275.49, 214.92, 82.88], "category_id": 2}, {"id": 13, "bbox": [823.16, 840.03, 81.47, 43.54], "category_id": 2}, {"id": 14, "bbox": [1472.13, 726.25, 428.43, 309.04], "category_id": 1}, {"id": 15, "bbox": [823.16, 629.32, 43.54, 40.74], "category_id": 3}, {"id": 16, "bbox": [2201.17, 1168.74, 51.97, 46.35], "category_id": 3}, {"id": 17, "bbox": [1942.7, 632.13, 39.34, 47.76], "category_id": 3}, {"id": 18, "bbox": [1569.05, 557.68, 200.87, 75.85], "category_id": 2}, {"id": 19, "bbox": [581.55, 758.55, 42.14, 40.74], "category_id": 3}, {"id": 20, "bbox": [1678.62, 1397.71, 46.35, 49.16], "category_id": 3}, {"id": 21, "bbox": [920.08, 722.03, 412.98, 311.85], "category_id": 1}, {"id": 22, "bbox": [1764.31, 0.0, 373.65, 278.14], "category_id": 1}, {"id": 23, "bbox": [1472.13, 1125.19, 431.24, 313.25], "category_id": 1}, {"id": 24, "bbox": [1354.13, 838.62, 87.09, 44.95], "category_id": 2}, {"id": 25, "bbox": [1670.19, 995.95, 43.55, 46.36], "category_id": 3}, {"id": 26, "bbox": [1894.94, 844.24, 118.0, 39.33], "category_id": 2}, {"id": 27, "bbox": [2036.82, 932.74, 377.86, 273.92], "category_id": 1}, {"id": 28, "bbox": [1106.91, 1393.49, 53.37, 44.95], "category_id": 3}, {"id": 29, "bbox": [1894.94, 1272.69, 141.88, 84.28], "category_id": 2}, {"id": 30, "bbox": [481.81, 439.68, 184.02, 96.93], "category_id": 1}, {"id": 31, "bbox": [656.0, 380.68, 369.43, 272.52], "category_id": 1}, {"id": 32, "bbox": [1472.13, 726.25, 428.43, 311.85], "category_id": 1}, {"id": 33, "bbox": [1216.47, 0.0, 502.89, 311.85], "category_id": 1}, {"id": 34, "bbox": [1102.69, 986.12, 59.0, 47.76], "category_id": 3}, {"id": 35, "bbox": [577.33, 1165.93, 54.79, 49.16], "category_id": 3}, {"id": 36, "bbox": [793.66, 886.38, 154.51, 74.46], "category_id": 2}, {"id": 37, "bbox": [398.19, 61.27, 273.17, 93.18], "category_id": 1}, {"id": 38, "bbox": [1745.01, 374.68, 421.41, 292.24], "category_id": 1}, {"id": 39, "bbox": [1831.84, 321.74, 116.47, 38.12], "category_id": 2}, {"id": 40, "bbox": [1967.36, 323.86, 192.71, 33.88], "category_id": 2}, {"id": 41, "bbox": [1035.6, 563.15, 139.76, 63.53], "category_id": 2}, {"id": 42, "bbox": [1626.42, 508.09, 72.0, 33.89], "category_id": 2}, {"id": 43, "bbox": [1440.07, 247.62, 33.88, 44.47], "category_id": 3}, {"id": 44, "bbox": [1116.07, 116.33, 78.35, 42.35], "category_id": 2}, {"id": 45, "bbox": [1358.4, 631.4, 56.8, 42.2], "category_id": 3}, {"id": 46, "bbox": [842.2, 248.64, 54.7, 43.56], "category_id": 3}, {"id": 47, "bbox": [622.28, 838.62, 130.64, 76.08], "category_id": 2}, {"id": 48, "bbox": [419.4, 802.1, 186.03, 94.12], "category_id": 1}, {"id": 49, "bbox": [419.4, 925.72, 367.23, 272.51], "category_id": 1}, {"id": 50, "bbox": [481.81, 171.38, 144.69, 73.22], "category_id": 2}, {"id": 51, "bbox": [404.55, 330.11, 23.15, 47.09], "category_id": 3}, {"id": 52, "bbox": [1942.7, 245.83, 39.34, 44.95], "category_id": 3}, {"id": 53, "bbox": [481.81, 557.68, 144.69, 71.64], "category_id": 2}], "caption": "Scheme 2. Synthetic Routes of Butterfly-Shaped Fused Heteroacenes 1 6", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 463, 102], "ImageBB": [71, 113, 773, 538]}, "reactions": [{"reactants": [51, 37], "conditions": [50], "products": [8]}, {"reactants": [8], "conditions": [44, 1], "products": [33]}, {"reactants": [51, 30], "conditions": [53], "products": [31]}, {"reactants": [31], "conditions": [10, 41], "products": [11]}, {"reactants": [11], "conditions": [42, 18], "products": [38]}, {"reactants": [38], "conditions": [39, 40], "products": [22]}, {"reactants": [19, 48], "conditions": [47], "products": [49]}, {"reactants": [49], "conditions": [13, 36], "products": [21]}, {"reactants": [21], "conditions": [24, 0], "products": [32]}, {"reactants": [32], "conditions": [26, 3], "products": [27]}, {"reactants": [49], "conditions": [6, 7], "products": [4]}, {"reactants": [4], "conditions": [5, 12], "products": [23]}, {"reactants": [23], "conditions": [2, 29], "products": [27]}], "diagram_type": "graph"}, {"id": 1213, "width": 1352, "height": 1012, "file_name": "ol802297h-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [984.75, 795.87, 44.64, 53.42], "category_id": 3}, {"id": 1, "bbox": [331.41, 903.39, 41.93, 48.01], "category_id": 3}, {"id": 2, "bbox": [283.39, 250.19, 31.78, 43.28], "category_id": 3}, {"id": 3, "bbox": [820.4, 0.0, 436.91, 246.13], "category_id": 1}, {"id": 4, "bbox": [769.67, 499.7, 489.0, 303.61], "category_id": 1}, {"id": 5, "bbox": [331.41, 606.54, 44.63, 45.98], "category_id": 3}, {"id": 6, "bbox": [89.28, 0.0, 440.29, 254.92], "category_id": 1}, {"id": 7, "bbox": [186.67, 456.43, 236.04, 144.02], "category_id": 1}, {"id": 8, "bbox": [161.64, 692.42, 409.19, 216.38], "category_id": 1}, {"id": 9, "bbox": [988.13, 248.16, 38.55, 48.69], "category_id": 3}], "caption": "Scheme 1. Retrosynthesis of Tagetitoxin", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [121, 74, 332, 89], "ImageBB": [58, 96, 396, 349]}, "reactions": [{"reactants": [6], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [7, 8]}], "diagram_type": "tree"}, {"id": 481, "width": 1344, "height": 608, "file_name": "ol0619157-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [83.1, 1.0, 320.9, 147.9], "category_id": 1}, {"id": 1, "bbox": [940.0, 5.0, 344.0, 146.9], "category_id": 1}, {"id": 2, "bbox": [459.0, 11.0, 432.0, 64.0], "category_id": 2}, {"id": 3, "bbox": [491.0, 86.0, 359.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [219.0, 172.0, 65.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [7.0, 265.0, 1337.0, 343.0], "category_id": 4}, {"id": 6, "bbox": [1036.0, 171.0, 131.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [2, 3], "products": [1]}], "corefs": [[0, 4], [1, 6]], "caption": "Table 1. Optimization of the Reaction Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 339, 557], "ImageBB": [74, 562, 410, 714]}, "diagram_type": "single"}, {"id": 292, "width": 1344, "height": 1668, "file_name": "ol401042b-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [778.6, 4.4, 493.1, 211.9], "category_id": 1}, {"id": 1, "bbox": [261.6, 381.9, 392.4, 210.8], "category_id": 1}, {"id": 2, "bbox": [864.4, 354.0, 276.2, 186.6], "category_id": 1}, {"id": 3, "bbox": [1027.6, 784.0, 273.4, 181.1], "category_id": 1}, {"id": 4, "bbox": [270.7, 267.1, 411.0, 99.2], "category_id": 3}, {"id": 5, "bbox": [460.5, 692.0, 439.5, 288.7], "category_id": 1}, {"id": 6, "bbox": [1018.9, 219.3, 176.5, 108.7], "category_id": 3}, {"id": 7, "bbox": [292.0, 763.0, 193.1, 84.4], "category_id": 3}, {"id": 8, "bbox": [233.6, 3.0, 436.5, 246.4], "category_id": 1}, {"id": 9, "bbox": [854.0, 888.0, 192.0, 80.0], "category_id": 3}, {"id": 10, "bbox": [422.66, 1407.98, 397.65, 257.94], "category_id": 1}, {"id": 11, "bbox": [876.2, 1543.4, 45.14, 55.89], "category_id": 3}, {"id": 12, "bbox": [1119.09, 958.74, 120.37, 53.76], "category_id": 2}, {"id": 13, "bbox": [957.88, 535.29, 116.07, 47.29], "category_id": 2}, {"id": 14, "bbox": [478.54, 950.14, 126.82, 47.29], "category_id": 2}, {"id": 15, "bbox": [285.09, 535.29, 122.52, 53.74], "category_id": 2}, {"id": 16, "bbox": [285.09, 210.72, 124.67, 51.59], "category_id": 2}, {"id": 17, "bbox": [181.92, 853.41, 124.67, 51.59], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [1], "conditions": [4], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [2]}, {"reactants": [17], "conditions": [7], "products": [5]}, {"reactants": [5], "conditions": [9], "products": [3]}, {"reactants": [5], "conditions": [], "products": [17]}], "corefs": [[8, 16], [1, 15], [2, 13], [5, 14], [3, 12]], "caption": "Figure 2. Substrate with blocked s-trans configuration.", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 542, 728, 555], "ImageBB": [437, 112, 773, 529]}, "diagram_type": "tree"}, {"id": 1228, "width": 1008, "height": 636, "file_name": "op010073i-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [137.16, 204.24, 35.8, 42.86], "category_id": 3}, {"id": 1, "bbox": [777.56, 592.03, 32.77, 39.84], "category_id": 3}, {"id": 2, "bbox": [631.83, 232.48, 40.34, 42.36], "category_id": 3}, {"id": 3, "bbox": [0.0, 2.02, 304.57, 167.92], "category_id": 1}, {"id": 4, "bbox": [618.21, 327.28, 313.65, 232.98], "category_id": 1}, {"id": 5, "bbox": [196.66, 546.65, 34.79, 40.34], "category_id": 3}, {"id": 6, "bbox": [62.53, 400.91, 327.26, 89.26], "category_id": 1}, {"id": 7, "bbox": [518.37, 4.54, 324.74, 221.38], "category_id": 1}], "caption": "Scheme 2. Synthetic plan", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 224, 67], "ImageBB": [116, 72, 368, 231]}, "reactions": [{"reactants": [3], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [4]}], "diagram_type": "multiple"}, {"id": 993, "width": 1356, "height": 944, "file_name": "ja3058138-Scheme-c13.png", "license": 0, "bboxes": [{"id": 0, "bbox": [693.26, 855.37, 63.77, 44.77], "category_id": 3}, {"id": 1, "bbox": [1103.66, 315.42, 59.69, 44.77], "category_id": 3}, {"id": 2, "bbox": [512.15, 553.52, 396.82, 223.85], "category_id": 1}, {"id": 3, "bbox": [879.81, 365.62, 309.32, 73.94], "category_id": 2}, {"id": 4, "bbox": [1005.98, 667.48, 304.57, 50.87], "category_id": 3}, {"id": 5, "bbox": [510.11, 0.0, 364.95, 338.49], "category_id": 1}, {"id": 6, "bbox": [191.1, 315.3, 183.7, 78.1], "category_id": 3}, {"id": 7, "bbox": [164.8, 521.64, 348.5, 341.2], "category_id": 1}, {"id": 8, "bbox": [966.63, 0.0, 354.77, 340.9], "category_id": 1}, {"id": 9, "bbox": [33.24, 133.63, 154.26, 76.47], "category_id": 2}, {"id": 10, "bbox": [319.89, 820.45, 137.12, 43.06], "category_id": 2}, {"id": 11, "bbox": [596.94, 769.91, 192.65, 75.29], "category_id": 2}, {"id": 12, "bbox": [142.45, 0.0, 307.97, 303.89], "category_id": 1}, {"id": 13, "bbox": [77.37, 713.92, 152.99, 77.06], "category_id": 2}, {"id": 14, "bbox": [1134.86, 856.05, 53.59, 44.09], "category_id": 3}, {"id": 15, "bbox": [1005.98, 750.91, 307.28, 120.74], "category_id": 1}, {"id": 16, "bbox": [994.45, 499.93, 330.35, 171.62], "category_id": 1}, {"id": 17, "bbox": [255.73, 858.77, 50.2, 41.37], "category_id": 3}, {"id": 18, "bbox": [636.28, 352.05, 63.09, 50.88], "category_id": 3}], "caption": "Scheme 13. Retrosynthetic Analysis of Goniomitine", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 575, 740, 590], "ImageBB": [448, 597, 787, 833]}, "reactions": [{"reactants": [12], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [3], "products": [7]}, {"reactants": [7], "conditions": [13, 10], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [16, 15]}], "diagram_type": "multiple"}, {"id": 1374, "width": 1040, "height": 448, "file_name": "op990049t-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [575.93, 0.0, 206.47, 59.6], "category_id": 2}, {"id": 1, "bbox": [0.0, 0.0, 164.7, 56.7], "category_id": 2}, {"id": 2, "bbox": [189.8, 0.0, 232.95, 56.16], "category_id": 2}, {"id": 3, "bbox": [805.49, 1.25, 135.69, 56.48], "category_id": 2}, {"id": 4, "bbox": [866.67, 107.92, 137.25, 59.61], "category_id": 2}, {"id": 5, "bbox": [843.86, 380.97, 196.14, 67.03], "category_id": 2}, {"id": 6, "bbox": [395.4, 102.01, 172.1, 64.79], "category_id": 2}, {"id": 7, "bbox": [0.0, 104.61, 223.19, 69.22], "category_id": 2}, {"id": 8, "bbox": [705.47, 108.5, 139.43, 59.1], "category_id": 2}], "caption": "Scheme 5. Processes lovering reactivity of ethylmagnesium chloride 8 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 405, 81], "ImageBB": [112, 86, 372, 198]}, "reactions": [{"reactants": [1, 2], "conditions": [], "products": [0, 3]}, {"reactants": [6], "conditions": [], "products": [7]}, {"reactants": [6], "conditions": [], "products": [4, 8]}, {"reactants": [4], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 525, "width": 1352, "height": 708, "file_name": "jo0109321-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [579.0, 4.0, 165.0, 107.0], "category_id": 2}, {"id": 1, "bbox": [7.0, 230.0, 1345.0, 478.0], "category_id": 4}, {"id": 2, "bbox": [1002.0, 17.0, 247.0, 42.0], "category_id": 2}, {"id": 3, "bbox": [1000.0, 82.8, 352.0, 49.2], "category_id": 2}, {"id": 4, "bbox": [5.1, 76.4, 526.9, 78.6], "category_id": 1}, {"id": 5, "bbox": [572.0, 136.0, 219.0, 36.0], "category_id": 2}, {"id": 6, "bbox": [993.0, 167.0, 332.0, 49.9], "category_id": 2}, {"id": 7, "bbox": [897.7, 56.0, 62.3, 46.0], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [0, 5, 7], "products": [2, 3, 6]}], "corefs": [], "caption": "Table 2. Effect of Catalyst on the Hydroboration of          1-Octene with BH3-THF in THFa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [455, 296, 758, 322], "ImageBB": [439, 330, 777, 507]}, "diagram_type": "single"}, {"id": 300, "width": 2808, "height": 1024, "file_name": "ol303482k-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1795.0, 523.0, 203.0, 107.0], "category_id": 2}, {"id": 1, "bbox": [1845.0, 432.0, 53.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [1688.0, 679.0, 691.0, 264.0], "category_id": 1}, {"id": 3, "bbox": [2123.0, 265.0, 268.0, 141.0], "category_id": 1}, {"id": 4, "bbox": [16.0, 162.0, 1310.0, 806.0], "category_id": 1}, {"id": 5, "bbox": [2082.0, 544.0, 560.0, 60.0], "category_id": 2}, {"id": 6, "bbox": [2235.0, 408.0, 51.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [2068.0, 824.0, 175.0, 98.0], "category_id": 3}, {"id": 8, "bbox": [1462.5, 114.0, 1072.5, 67.0], "category_id": 2}, {"id": 9, "bbox": [1625.0, 212.6, 462.0, 260.4], "category_id": 1}, {"id": 10, "bbox": [2088.4, 965.0, 441.6, 57.0], "category_id": 2}], "reactions": [{"reactants": [9, 3], "conditions": [0, 5], "products": [2]}], "corefs": [[9, 1], [3, 6], [2, 7]], "caption": "Figure 2. X-ray crystal structure of imide 15d.", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 314, 315, 327], "ImageBB": [71, 59, 773, 315]}, "diagram_type": "tree"}, {"id": 55, "width": 1176, "height": 1372, "file_name": "ja406383h-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [909.29, 183.74, 24.35, 34.67], "category_id": 3}, {"id": 1, "bbox": [305.81, 180.3, 153.3, 41.55], "category_id": 2}, {"id": 2, "bbox": [87.46, 27.28, 177.37, 122.36], "category_id": 1}, {"id": 3, "bbox": [3.21, 262.83, 1165.97, 1107.51], "category_id": 4}, {"id": 4, "bbox": [328.16, 35.88, 129.23, 117.19], "category_id": 1}, {"id": 5, "bbox": [835.35, 30.72, 251.3, 158.46], "category_id": 1}, {"id": 6, "bbox": [493.21, 4.93, 294.28, 84.53], "category_id": 2}, {"id": 7, "bbox": [534.5, 113.25, 237.5, 125.75], "category_id": 2}, {"id": 8, "bbox": [145.92, 183.74, 26.07, 31.23], "category_id": 3}], "reactions": [{"reactants": [2, 4], "conditions": [6, 7], "products": [5]}], "corefs": [[2, 8], [5, 0]], "caption": "Table 3. Direct C\u2212H Amidation of Other Chelate Group- Containing Substratesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 410, 202], "ImageBB": [104, 208, 398, 551]}, "diagram_type": "single"}, {"id": 46, "width": 1232, "height": 560, "file_name": "ja410533y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [299.94, 197.65, 140.44, 131.14], "category_id": 1}, {"id": 1, "bbox": [49.08, 197.65, 145.08, 120.92], "category_id": 1}, {"id": 2, "bbox": [49.08, 4.39, 145.08, 121.86], "category_id": 1}, {"id": 3, "bbox": [325.03, 342.59, 41.95, 32.66], "category_id": 3}, {"id": 4, "bbox": [264.64, 384.4, 163.66, 37.3], "category_id": 2}, {"id": 5, "bbox": [1001.42, 341.66, 39.16, 32.66], "category_id": 3}, {"id": 6, "bbox": [515.5, 152.12, 285.37, 79.12], "category_id": 2}, {"id": 7, "bbox": [487.62, 258.04, 339.27, 206.4], "category_id": 2}, {"id": 8, "bbox": [21.21, 138.18, 201.76, 37.31], "category_id": 3}, {"id": 9, "bbox": [24.92, 325.86, 195.26, 36.38], "category_id": 3}, {"id": 10, "bbox": [3.56, 515.4, 237.99, 37.31], "category_id": 3}, {"id": 11, "bbox": [815.6, 384.4, 408.02, 122.78], "category_id": 2}, {"id": 12, "bbox": [909.44, 161.41, 198.97, 132.08], "category_id": 1}, {"id": 13, "bbox": [61.16, 386.26, 123.71, 119.99], "category_id": 1}], "reactions": [{"reactants": [2, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [1, 0], "conditions": [6, 7], "products": [12]}, {"reactants": [13, 0], "conditions": [6, 7], "products": [12]}], "corefs": [[2, 8], [1, 9], [13, 10], [0, 3], [12, 5]], "caption": "Table 3. Redox Level-Independent Formation of Lactone 3fa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 417, 110], "ImageBB": [97, 116, 405, 256]}, "diagram_type": "single"}, {"id": 281, "width": 1344, "height": 872, "file_name": "ol800288b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [432.0, 0.0, 212.0, 48.0], "category_id": 2}, {"id": 1, "bbox": [330.0, 129.0, 453.0, 45.0], "category_id": 2}, {"id": 2, "bbox": [71.0, 20.0, 249.0, 67.0], "category_id": 1}, {"id": 3, "bbox": [809.0, 1.0, 464.0, 92.0], "category_id": 1}, {"id": 4, "bbox": [366.0, 68.0, 390.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [12.0, 225.0, 1332.0, 647.0], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0, 4, 1], "products": [3]}], "corefs": [], "caption": "Table 2. Aziridination of 1-Hexene Catalyzed by Various Copper-carbene Complexesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 426, 379, 454], "ImageBB": [74, 459, 410, 677]}, "diagram_type": "single"}, {"id": 650, "width": 1352, "height": 696, "file_name": "ol500121z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [903.0, 477.0, 74.0, 43.0], "category_id": 3}, {"id": 1, "bbox": [195.0, 350.0, 55.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [495.0, 163.0, 186.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [808.0, 344.0, 456.0, 107.0], "category_id": 1}, {"id": 4, "bbox": [811.0, 5.0, 386.0, 183.0], "category_id": 1}, {"id": 5, "bbox": [896.0, 191.0, 71.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [84.0, 176.0, 287.0, 110.0], "category_id": 1}, {"id": 7, "bbox": [2.0, 541.0, 1350.0, 155.0], "category_id": 4}, {"id": 8, "bbox": [412.0, 235.0, 351.1, 139.5], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [2, 8], "products": [4, 3]}], "corefs": [[6, 1], [4, 5], [3, 0]], "caption": "Table 1. Palladium Catalysts for the Alkylation of 1a with 2aa ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 533, 775, 563], "ImageBB": [449, 569, 787, 743]}, "diagram_type": "single"}, {"id": 1178, "width": 1344, "height": 732, "file_name": "ol301114z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.84, 14.79, 266.25, 233.31], "category_id": 1}, {"id": 1, "bbox": [406.09, 88.75, 155.31, 111.61], "category_id": 1}, {"id": 2, "bbox": [115.64, 455.85, 424.25, 226.58], "category_id": 1}, {"id": 3, "bbox": [984.97, 39.67, 322.72, 223.22], "category_id": 1}, {"id": 4, "bbox": [726.8, 164.05, 78.66, 49.08], "category_id": 2}, {"id": 5, "bbox": [896.22, 455.18, 423.58, 226.58], "category_id": 1}, {"id": 6, "bbox": [327.43, 299.19, 161.36, 93.46], "category_id": 2}, {"id": 7, "bbox": [936.56, 303.23, 155.99, 92.11], "category_id": 2}, {"id": 8, "bbox": [679.73, 0.0, 151.28, 135.81], "category_id": 1}], "caption": "Scheme 1. Proposed Annulation of 2,3-Disubstituted Indole with MVK Catalyzed by Chiral Primary Amine ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 756, 116], "ImageBB": [437, 127, 773, 310]}, "reactions": [{"reactants": [0, 1], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [5]}, {"reactants": [0, 1, 8], "conditions": [4], "products": [3]}, {"reactants": [5], "conditions": [7], "products": [3]}], "diagram_type": "graph"}, {"id": 310, "width": 1252, "height": 1592, "file_name": "ol302668y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [609.9, 190.0, 325.1, 92.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 106.3, 272.0, 108.7], "category_id": 1}, {"id": 2, "bbox": [306.2, 107.4, 317.8, 110.6], "category_id": 1}, {"id": 3, "bbox": [383.91, 217.53, 184.64, 53.34], "category_id": 2}, {"id": 4, "bbox": [19.0, 430.0, 1233.0, 1162.0], "category_id": 4}, {"id": 5, "bbox": [1025.0, 253.0, 58.0, 64.0], "category_id": 3}, {"id": 6, "bbox": [443.1, 280.7, 63.2, 46.9], "category_id": 3}, {"id": 7, "bbox": [607.7, 0.0, 327.3, 167.3], "category_id": 2}, {"id": 8, "bbox": [83.0, 218.0, 72.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [941.0, 34.0, 311.0, 277.0], "category_id": 1}], "reactions": [{"reactants": [1, 2], "conditions": [7, 0], "products": [9]}], "corefs": [[1, 8], [2, 6], [9, 5]], "caption": "Table 1. Synthesis of the Various 5-Substituents of 2-(4-Cyanopheyl)-1,3a,6a-triazapentalenes ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 549, 340, 576], "ImageBB": [83, 587, 396, 985]}, "diagram_type": "single"}, {"id": 972, "width": 1192, "height": 912, "file_name": "ja040054z-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [683.95, 513.95, 475.85, 329.12], "category_id": 1}, {"id": 1, "bbox": [496.72, 199.14, 125.22, 50.68], "category_id": 2}, {"id": 2, "bbox": [648.18, 0.0, 516.39, 334.48], "category_id": 1}, {"id": 3, "bbox": [0.0, 0.0, 500.29, 335.68], "category_id": 1}, {"id": 4, "bbox": [104.35, 418.55, 136.75, 55.45], "category_id": 2}, {"id": 5, "bbox": [277.45, 423.72, 91.97, 48.18], "category_id": 2}, {"id": 6, "bbox": [778.89, 427.01, 93.06, 49.26], "category_id": 2}, {"id": 7, "bbox": [32.2, 518.2, 468.09, 327.85], "category_id": 1}, {"id": 8, "bbox": [521.16, 606.96, 115.09, 55.45], "category_id": 2}, {"id": 9, "bbox": [239.12, 350.58, 45.31, 50.68], "category_id": 3}, {"id": 10, "bbox": [229.57, 857.97, 51.88, 54.03], "category_id": 3}, {"id": 11, "bbox": [872.38, 347.0, 71.56, 50.68], "category_id": 3}, {"id": 12, "bbox": [921.88, 425.3, 258.12, 52.1], "category_id": 2}], "caption": "Scheme 6", "pdf": {"Page": 9, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 125, 76], "ImageBB": [93, 80, 391, 308]}, "reactions": [{"reactants": [3], "conditions": [1], "products": [2]}, {"reactants": [3], "conditions": [4, 5], "products": [7]}, {"reactants": [7], "conditions": [8], "products": [0]}, {"reactants": [0], "conditions": [6, 12], "products": [2]}], "diagram_type": "graph"}, {"id": 370, "width": 1348, "height": 1220, "file_name": "ol102738b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [665.83, 63.84, 178.25, 44.15], "category_id": 2}, {"id": 1, "bbox": [7.0, 273.0, 1341.0, 947.0], "category_id": 4}, {"id": 2, "bbox": [178.64, 180.73, 65.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [396.3, 21.9, 255.1, 124.6], "category_id": 1}, {"id": 4, "bbox": [142.3, 19.5, 207.7, 157.2], "category_id": 1}, {"id": 5, "bbox": [485.63, 170.0, 72.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [667.46, 119.44, 168.45, 44.16], "category_id": 2}, {"id": 7, "bbox": [871.0, 0.0, 339.0, 232.0], "category_id": 1}, {"id": 8, "bbox": [911.0, 178.0, 68.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [0, 6], "products": [7]}], "corefs": [[4, 2], [3, 5], [7, 8]], "caption": "Table 1. Optimization of Conditions on the Model Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 762, 101], "ImageBB": [436, 112, 773, 417]}, "diagram_type": "single"}, {"id": 233, "width": 2508, "height": 1716, "file_name": "op000111i-Figure-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [794.5, 612.5, 288.5, 272.8], "category_id": 1}, {"id": 1, "bbox": [314.0, 932.1, 755.8, 103.9], "category_id": 2}, {"id": 2, "bbox": [290.1, 637.9, 261.6, 245.2], "category_id": 1}, {"id": 3, "bbox": [1176.6, 659.4, 642.2, 723.8], "category_id": 1}, {"id": 4, "bbox": [226.0, 1092.0, 535.1, 247.1], "category_id": 2}, {"id": 5, "bbox": [571.0, 671.3, 215.9, 75.7], "category_id": 2}, {"id": 6, "bbox": [524.0, 385.0, 636.0, 177.0], "category_id": 2}, {"id": 7, "bbox": [892.0, 1636.0, 893.0, 80.0], "category_id": 2}, {"id": 8, "bbox": [1309.38, 1134.46, 68.55, 84.04], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [5], "products": [0]}], "corefs": [[3, 8]], "caption": "Figure 10. Continuous reduction of tetralone, applying polysiloxane-bound oxazaborolidine as catalyst.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 495, 642, 509], "ImageBB": [112, 55, 739, 484]}, "diagram_type": "single"}, {"id": 304, "width": 1344, "height": 1608, "file_name": "ol303154k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [372.0, 279.0, 49.0, 47.0], "category_id": 3}, {"id": 1, "bbox": [332.0, 598.0, 53.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [25.2, 350.3, 226.5, 217.6], "category_id": 1}, {"id": 3, "bbox": [909.0, 273.5, 417.7, 349.5], "category_id": 1}, {"id": 4, "bbox": [459.2, 357.7, 183.7, 172.0], "category_id": 1}, {"id": 5, "bbox": [296.4, 0.0, 334.5, 281.9], "category_id": 1}, {"id": 6, "bbox": [302.2, 344.1, 124.7, 235.8], "category_id": 1}, {"id": 7, "bbox": [504.0, 598.0, 54.0, 51.0], "category_id": 3}, {"id": 8, "bbox": [1101.0, 605.0, 95.0, 50.0], "category_id": 3}, {"id": 9, "bbox": [702.0, 420.0, 186.0, 56.0], "category_id": 2}, {"id": 10, "bbox": [642.0, 490.0, 321.0, 65.0], "category_id": 2}, {"id": 11, "bbox": [0.0, 672.0, 1344.0, 936.0], "category_id": 4}, {"id": 12, "bbox": [132.0, 602.0, 52.0, 44.0], "category_id": 3}, {"id": 13, "bbox": [649.0, 64.0, 391.0, 231.8], "category_id": 3}], "reactions": [{"reactants": [2, 6, 4], "conditions": [9, 10], "products": [3]}], "corefs": [[5, 0], [5, 13], [2, 12], [6, 1], [4, 7], [3, 8]], "caption": "Table 1. Optimization of Reaction Conditionsa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 322, 101], "ImageBB": [71, 112, 407, 514]}, "diagram_type": "single"}, {"id": 1157, "width": 1352, "height": 552, "file_name": "ol0514606-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [20.97, 0.0, 431.5, 154.95], "category_id": 1}, {"id": 1, "bbox": [93.33, 304.49, 433.54, 153.6], "category_id": 1}, {"id": 2, "bbox": [915.76, 157.66, 29.08, 38.57], "category_id": 3}, {"id": 3, "bbox": [1034.8, 438.46, 27.73, 36.54], "category_id": 3}, {"id": 4, "bbox": [280.68, 454.03, 29.08, 37.89], "category_id": 3}, {"id": 5, "bbox": [785.9, 252.39, 448.42, 182.69], "category_id": 1}, {"id": 6, "bbox": [538.37, 418.84, 232.66, 51.42], "category_id": 2}, {"id": 7, "bbox": [657.4, 8.8, 432.18, 124.5], "category_id": 1}, {"id": 8, "bbox": [1104.46, 98.79, 211.02, 46.69], "category_id": 2}, {"id": 9, "bbox": [1104.46, 10.83, 220.49, 49.39], "category_id": 2}, {"id": 10, "bbox": [438.27, 54.81, 190.72, 46.69], "category_id": 2}, {"id": 11, "bbox": [253.63, 163.07, 54.1, 41.95], "category_id": 3}, {"id": 12, "bbox": [539.72, 331.55, 204.25, 52.78], "category_id": 2}, {"id": 13, "bbox": [434.21, 142.77, 189.37, 85.26], "category_id": 2}], "caption": "Scheme 5", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 712, 631, 725], "ImageBB": [439, 730, 777, 868]}, "reactions": [{"reactants": [0], "conditions": [10, 13], "products": [7]}, {"reactants": [7], "conditions": [9, 8], "products": [1]}, {"reactants": [1], "conditions": [12, 6], "products": [5]}], "diagram_type": "multiple"}, {"id": 1101, "width": 1324, "height": 1256, "file_name": "jo9708497-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 388.79, 218.49], "category_id": 1}, {"id": 1, "bbox": [87.43, 1021.6, 443.1, 115.21], "category_id": 2}, {"id": 2, "bbox": [42.39, 472.73, 105.97, 53.63], "category_id": 2}, {"id": 3, "bbox": [774.93, 1205.0, 62.26, 50.32], "category_id": 3}, {"id": 4, "bbox": [170.88, 236.37, 41.73, 48.99], "category_id": 3}, {"id": 5, "bbox": [1074.3, 843.5, 249.7, 98.65], "category_id": 3}, {"id": 6, "bbox": [201.35, 843.5, 208.63, 99.98], "category_id": 3}, {"id": 7, "bbox": [466.28, 664.74, 456.35, 109.9], "category_id": 2}, {"id": 8, "bbox": [184.79, 346.93, 443.1, 213.86], "category_id": 1}, {"id": 9, "bbox": [11.92, 409.83, 141.08, 49.0], "category_id": 2}, {"id": 10, "bbox": [779.56, 8.61, 439.13, 218.49], "category_id": 1}, {"id": 11, "bbox": [586.16, 973.27, 392.77, 227.1], "category_id": 1}, {"id": 12, "bbox": [923.95, 612.43, 400.05, 225.77], "category_id": 1}, {"id": 13, "bbox": [747.77, 385.34, 416.61, 113.21], "category_id": 2}, {"id": 14, "bbox": [408.66, 554.17, 48.35, 50.98], "category_id": 3}, {"id": 15, "bbox": [530.53, 172.14, 92.72, 52.97], "category_id": 2}, {"id": 16, "bbox": [466.94, 30.46, 272.22, 115.2], "category_id": 2}, {"id": 17, "bbox": [1015.35, 241.0, 49.02, 50.32], "category_id": 3}, {"id": 18, "bbox": [0.0, 619.72, 441.77, 219.15], "category_id": 1}], "caption": "Scheme 1. Synthesis of Azido Triflate 14", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [470, 49, 741, 63], "ImageBB": [442, 69, 773, 383]}, "reactions": [{"reactants": [0], "conditions": [16, 15], "products": [10]}, {"reactants": [10], "conditions": [9, 2], "products": [8]}, {"reactants": [8], "conditions": [13], "products": [18]}, {"reactants": [18], "conditions": [7], "products": [12]}, {"reactants": [12], "conditions": [1], "products": [11]}], "diagram_type": "multiple"}, {"id": 290, "width": 1348, "height": 1000, "file_name": "ol401042b-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.0, 191.6, 156.4, 70.6], "category_id": 1}, {"id": 1, "bbox": [95.0, 330.0, 191.3, 47.8], "category_id": 2}, {"id": 2, "bbox": [640.0, 176.9, 261.0, 56.1], "category_id": 2}, {"id": 3, "bbox": [907.0, 74.6, 417.7, 215.1], "category_id": 1}, {"id": 4, "bbox": [675.4, 250.2, 143.7, 54.4], "category_id": 2}, {"id": 5, "bbox": [27.1, 1.0, 329.8, 309.2], "category_id": 1}, {"id": 6, "bbox": [480.0, 282.0, 77.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [3.0, 417.0, 1345.0, 581.0], "category_id": 4}, {"id": 8, "bbox": [1076.0, 276.0, 86.0, 51.0], "category_id": 3}, {"id": 9, "bbox": [158.0, 279.0, 65.0, 46.0], "category_id": 3}, {"id": 10, "bbox": [461.0, 333.0, 123.0, 48.0], "category_id": 2}], "reactions": [{"reactants": [5, 0], "conditions": [2, 4], "products": [3]}], "corefs": [[5, 9], [0, 6], [3, 8]], "caption": "Table 2. Scope of Aldehydes for Organocatalytic Annulationa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 579, 766, 595], "ImageBB": [436, 606, 773, 856]}, "diagram_type": "single"}, {"id": 756, "width": 1348, "height": 1044, "file_name": "jo990528q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [212.0, 2.0, 237.2, 144.0], "category_id": 1}, {"id": 1, "bbox": [810.0, 362.2, 354.0, 190.2], "category_id": 1}, {"id": 2, "bbox": [293.6, 136.4, 26.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [914.4, 532.0, 102.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [493.2, 344.0, 244.8, 109.8], "category_id": 1}, {"id": 5, "bbox": [212.8, 390.2, 180.2, 145.2], "category_id": 1}, {"id": 6, "bbox": [568.0, 483.0, 119.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [696.0, 351.0, 89.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [282.0, 537.0, 37.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [319.0, 200.0, 203.0, 144.0], "category_id": 2}, {"id": 10, "bbox": [21.0, 620.0, 1327.0, 419.0], "category_id": 4}], "reactions": [{"reactants": [0], "conditions": [9], "products": [5]}, {"reactants": [5], "conditions": [4, 6], "products": [1]}], "corefs": [[0, 2], [5, 8], [4, 7], [1, 3]], "caption": "Table 1. Reaction of 2 with r,\u03b2-Unsaturated thioester                         3a-e ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [449, 353, 765, 380], "ImageBB": [439, 390, 776, 651]}, "diagram_type": "tree"}, {"id": 721, "width": 1324, "height": 1152, "file_name": "ol0173127-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [9.0, 506.0, 1315.0, 646.0], "category_id": 4}, {"id": 1, "bbox": [383.0, 47.0, 294.0, 98.0], "category_id": 1}, {"id": 2, "bbox": [806.0, 199.0, 469.0, 293.0], "category_id": 1}, {"id": 3, "bbox": [361.0, 152.0, 370.0, 198.0], "category_id": 2}, {"id": 4, "bbox": [47.0, 1.0, 240.0, 198.0], "category_id": 1}, {"id": 5, "bbox": [368.0, 364.0, 376.0, 105.0], "category_id": 2}], "reactions": [{"reactants": [4, 1], "conditions": [3, 5], "products": [2]}], "corefs": [], "caption": "Table 3. Friedel-Crafts Alkylation of Indol Derivatives in a CO2/1a System ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 395, 104], "ImageBB": [77, 111, 408, 399]}, "diagram_type": "multiple"}, {"id": 222, "width": 1184, "height": 3316, "file_name": "op0255478-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [3.0, 79.0, 274.0, 121.0], "category_id": 1}, {"id": 1, "bbox": [5.0, 275.5, 1175.0, 3040.5], "category_id": 4}, {"id": 2, "bbox": [715.0, 151.0, 76.0, 57.0], "category_id": 2}, {"id": 3, "bbox": [300.6, 130.0, 155.4, 43.6], "category_id": 1}, {"id": 4, "bbox": [651.0, 94.0, 239.0, 55.0], "category_id": 2}, {"id": 5, "bbox": [886.0, 13.0, 295.0, 240.0], "category_id": 1}, {"id": 6, "bbox": [482.0, 79.0, 197.0, 132.0], "category_id": 1}], "reactions": [{"reactants": [0, 3, 6], "conditions": [4, 2], "products": [5]}], "corefs": [], "caption": "Table 1. Synthesis of dihydropyrimidinones without any solvent and catalyst ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 383, 81], "ImageBB": [95, 88, 391, 917]}, "diagram_type": "single"}, {"id": 862, "width": 1356, "height": 2208, "file_name": "jo2003264-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1218.0, 179.0, 42.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [77.0, 175.0, 38.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [461.0, 140.0, 287.0, 98.5], "category_id": 2}, {"id": 3, "bbox": [385.0, 0.0, 761.0, 120.1], "category_id": 2}, {"id": 4, "bbox": [248.0, 108.0, 159.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [1158.2, 48.0, 197.8, 131.0], "category_id": 1}, {"id": 6, "bbox": [290.0, 179.0, 47.0, 51.0], "category_id": 3}, {"id": 7, "bbox": [30.0, 291.0, 1326.0, 1917.0], "category_id": 4}, {"id": 8, "bbox": [7.0, 97.59, 201.0, 65.8], "category_id": 1}], "reactions": [{"reactants": [8, 4], "conditions": [3, 2], "products": [5]}], "corefs": [[8, 1], [4, 6], [5, 0]], "caption": "Table 3. Oxidative Methyl Esteri\ufb01cation of Primary Alcohols (1) with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 405, 122], "ImageBB": [69, 133, 408, 685]}, "diagram_type": "single"}, {"id": 1065, "width": 1356, "height": 808, "file_name": "jo300771f-Scheme-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [562.41, 1.6, 195.32, 46.02], "category_id": 1}, {"id": 1, "bbox": [214.71, 343.15, 160.56, 45.0], "category_id": 1}, {"id": 2, "bbox": [665.69, 720.5, 201.46, 38.86], "category_id": 3}, {"id": 3, "bbox": [185.86, 553.73, 223.86, 54.97], "category_id": 2}, {"id": 4, "bbox": [666.13, 668.41, 233.37, 46.89], "category_id": 3}, {"id": 5, "bbox": [531.82, 59.3, 253.7, 89.99], "category_id": 2}, {"id": 6, "bbox": [163.48, 394.5, 264.55, 142.27], "category_id": 2}, {"id": 7, "bbox": [434.14, 667.06, 138.38, 98.39], "category_id": 2}, {"id": 8, "bbox": [609.83, 169.65, 101.75, 54.29], "category_id": 2}, {"id": 9, "bbox": [286.26, 251.08, 59.69, 46.82], "category_id": 3}, {"id": 10, "bbox": [1015.47, 249.04, 63.77, 49.54], "category_id": 3}, {"id": 11, "bbox": [879.81, 34.61, 337.81, 202.22], "category_id": 1}, {"id": 12, "bbox": [530.46, 352.87, 284.23, 293.15], "category_id": 1}, {"id": 13, "bbox": [246.92, 48.86, 187.22, 177.79], "category_id": 1}], "caption": "Scheme 12. Preparation of 12b", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 415, 625, 430], "ImageBB": [448, 436, 787, 638]}, "reactions": [{"reactants": [13], "conditions": [0, 5, 8], "products": [11]}, {"reactants": [11], "conditions": [1, 6, 3], "products": [12]}, {"reactants": [4], "conditions": [7], "products": [2]}], "diagram_type": "multiple"}, {"id": 122, "width": 1220, "height": 1384, "file_name": "op970113b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [783.0, 97.0, 333.0, 114.0], "category_id": 2}, {"id": 1, "bbox": [812.0, 648.0, 324.4, 79.7], "category_id": 2}, {"id": 2, "bbox": [0.0, 0.0, 647.1, 287.3], "category_id": 1}, {"id": 3, "bbox": [0.0, 435.1, 584.4, 312.6], "category_id": 1}, {"id": 4, "bbox": [16.1, 957.5, 588.7, 300.8], "category_id": 1}, {"id": 5, "bbox": [187.0, 765.0, 170.0, 80.7], "category_id": 2}, {"id": 6, "bbox": [174.0, 1314.0, 168.0, 70.0], "category_id": 2}, {"id": 7, "bbox": [818.0, 547.0, 179.0, 77.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [7, 1], "products": [4]}], "corefs": [], "caption": "Table 1. Scale-up of benzoyl migration method and comparison to original Sharpless methoda,b ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 427, 361, 455], "ImageBB": [112, 69, 417, 415]}, "diagram_type": "multiple"}, {"id": 1057, "width": 1344, "height": 1140, "file_name": "jo200666z-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.88, 500.74, 284.4, 86.71], "category_id": 2}, {"id": 1, "bbox": [512.32, 807.91, 130.43, 49.07], "category_id": 2}, {"id": 2, "bbox": [976.23, 284.32, 177.5, 49.73], "category_id": 2}, {"id": 3, "bbox": [941.27, 1047.19, 140.52, 47.73], "category_id": 3}, {"id": 4, "bbox": [924.46, 288.35, 41.01, 41.0], "category_id": 3}, {"id": 5, "bbox": [732.85, 667.43, 535.85, 379.09], "category_id": 1}, {"id": 6, "bbox": [83.37, 343.46, 290.45, 270.2], "category_id": 1}, {"id": 7, "bbox": [168.76, 591.48, 55.8, 44.36], "category_id": 3}, {"id": 8, "bbox": [839.75, 373.71, 307.93, 229.2], "category_id": 1}, {"id": 9, "bbox": [810.84, 34.28, 379.2, 210.38], "category_id": 1}, {"id": 10, "bbox": [508.96, 431.51, 141.19, 50.41], "category_id": 2}, {"id": 11, "bbox": [169.43, 290.36, 43.03, 42.35], "category_id": 3}, {"id": 12, "bbox": [459.88, 196.26, 245.4, 51.76], "category_id": 2}, {"id": 13, "bbox": [87.4, 674.16, 385.25, 352.2], "category_id": 1}, {"id": 14, "bbox": [459.88, 868.4, 289.1, 46.38], "category_id": 2}, {"id": 15, "bbox": [459.88, 83.35, 287.09, 93.42], "category_id": 2}, {"id": 16, "bbox": [171.45, 1004.18, 50.42, 47.05], "category_id": 3}, {"id": 17, "bbox": [83.37, 4.03, 328.1, 345.48], "category_id": 1}, {"id": 18, "bbox": [923.12, 600.89, 224.56, 47.05], "category_id": 3}], "caption": "Scheme 1. Removing the Directing Group", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 308, 107], "ImageBB": [71, 117, 407, 402]}, "reactions": [{"reactants": [17], "conditions": [15, 12], "products": [9]}, {"reactants": [6], "conditions": [10, 0], "products": [8]}, {"reactants": [13], "conditions": [1, 14], "products": [5]}], "diagram_type": "multiple"}, {"id": 935, "width": 1356, "height": 616, "file_name": "acs.orglett.5b00663-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1104.4, 276.79, 92.03, 29.65], "category_id": 2}, {"id": 1, "bbox": [341.88, 410.09, 162.02, 50.84], "category_id": 1}, {"id": 2, "bbox": [508.21, 423.02, 94.08, 35.79], "category_id": 2}, {"id": 3, "bbox": [613.54, 208.27, 261.79, 128.85], "category_id": 1}, {"id": 4, "bbox": [589.48, 14.91, 266.58, 130.83], "category_id": 1}, {"id": 5, "bbox": [904.9, 205.38, 169.59, 133.54], "category_id": 1}, {"id": 6, "bbox": [980.2, 338.24, 33.24, 33.21], "category_id": 3}, {"id": 7, "bbox": [1096.2, 84.05, 99.03, 40.67], "category_id": 2}, {"id": 8, "bbox": [157.37, 530.75, 39.35, 31.18], "category_id": 3}, {"id": 9, "bbox": [1120.62, 328.75, 65.12, 36.6], "category_id": 2}, {"id": 10, "bbox": [652.56, 336.89, 104.47, 38.63], "category_id": 3}, {"id": 11, "bbox": [341.88, 290.11, 240.81, 73.21], "category_id": 2}, {"id": 12, "bbox": [77.33, 437.21, 235.38, 84.72], "category_id": 1}, {"id": 13, "bbox": [890.66, 68.46, 167.55, 56.26], "category_id": 1}, {"id": 14, "bbox": [674.95, 140.31, 45.45, 31.18], "category_id": 3}, {"id": 15, "bbox": [636.28, 399.25, 259.13, 128.11], "category_id": 1}, {"id": 16, "bbox": [674.95, 530.07, 99.71, 32.53], "category_id": 3}, {"id": 17, "bbox": [379.19, 199.96, 139.74, 84.05], "category_id": 1}, {"id": 18, "bbox": [951.71, 414.84, 200.79, 98.28], "category_id": 1}, {"id": 19, "bbox": [1040.57, 534.14, 66.48, 35.24], "category_id": 2}, {"id": 20, "bbox": [324.92, 471.1, 308.65, 71.17], "category_id": 2}, {"id": 21, "bbox": [341.88, 4.07, 198.08, 93.54], "category_id": 1}, {"id": 22, "bbox": [324.92, 102.35, 239.46, 67.79], "category_id": 2}, {"id": 23, "bbox": [75.97, 47.45, 236.74, 86.76], "category_id": 1}, {"id": 24, "bbox": [75.97, 240.63, 236.07, 86.77], "category_id": 1}, {"id": 25, "bbox": [157.37, 335.53, 40.71, 31.86], "category_id": 3}, {"id": 26, "bbox": [157.37, 137.6, 38.67, 31.86], "category_id": 3}], "caption": "Scheme 2. Investigations of the Role of Ester", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 699, 110], "ImageBB": [448, 116, 787, 270]}, "reactions": [{"reactants": [23], "conditions": [21, 22], "products": [4, 13, 7]}, {"reactants": [24], "conditions": [17, 11], "products": [3, 5, 0]}, {"reactants": [12], "conditions": [1, 2, 20], "products": [15, 18]}], "diagram_type": "multiple"}, {"id": 640, "width": 1332, "height": 2248, "file_name": "ol501019y-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [224.0, 127.0, 42.8, 41.9], "category_id": 3}, {"id": 1, "bbox": [783.4, 0.0, 377.6, 120.1], "category_id": 1}, {"id": 2, "bbox": [171.7, 2.9, 182.3, 124.1], "category_id": 1}, {"id": 3, "bbox": [411.0, 77.0, 290.0, 91.0], "category_id": 2}, {"id": 4, "bbox": [375.0, 15.0, 368.0, 50.0], "category_id": 2}, {"id": 5, "bbox": [3.0, 189.0, 1329.0, 2059.0], "category_id": 4}, {"id": 6, "bbox": [950.0, 117.0, 48.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 3], "products": [1]}], "corefs": [[2, 0], [1, 6]], "caption": "Table 2. Palladium-Catalyzed Homocoupling of 2- Substituted Furansa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 248, 366, 278], "ImageBB": [84, 285, 417, 847]}, "diagram_type": "single"}, {"id": 874, "width": 1344, "height": 608, "file_name": "ol701624y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [845.0, 46.0, 400.0, 201.9], "category_id": 1}, {"id": 1, "bbox": [212.71, 171.85, 104.0, 41.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 313.0, 1340.0, 295.0], "category_id": 4}, {"id": 3, "bbox": [1039.0, 254.0, 94.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [503.0, 0.0, 275.0, 105.0], "category_id": 2}, {"id": 5, "bbox": [506.0, 126.9, 291.0, 119.9], "category_id": 2}, {"id": 6, "bbox": [102.3, 37.6, 363.2, 124.3], "category_id": 1}, {"id": 7, "bbox": [845.37, 192.42, 140.75, 55.79], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[6, 1], [0, 3]], "caption": "Table 4.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 362, 120, 375], "ImageBB": [74, 378, 410, 530]}, "diagram_type": "single"}, {"id": 1204, "width": 1352, "height": 756, "file_name": "ol7019636-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [813.63, 186.76, 271.22, 250.37], "category_id": 1}, {"id": 1, "bbox": [516.05, 81.2, 225.22, 87.97], "category_id": 2}, {"id": 2, "bbox": [514.02, 0.0, 214.4, 55.49], "category_id": 2}, {"id": 3, "bbox": [261.74, 426.31, 165.03, 47.37], "category_id": 2}, {"id": 4, "bbox": [276.62, 241.57, 237.4, 149.55], "category_id": 1}, {"id": 5, "bbox": [541.75, 523.75, 120.39, 45.34], "category_id": 2}, {"id": 6, "bbox": [813.63, 442.55, 190.73, 43.98], "category_id": 2}, {"id": 7, "bbox": [511.99, 653.67, 92.66, 46.02], "category_id": 2}], "caption": "Scheme 1. PROLI/NO, a Nitric Oxide Donor", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [484, 811, 730, 824], "ImageBB": [439, 828, 777, 1017]}, "reactions": [{"reactants": [4], "conditions": [2, 1], "products": [0]}, {"reactants": [0], "conditions": [6, 5], "products": [3, 4, 7]}], "diagram_type": "graph"}, {"id": 1305, "width": 1356, "height": 816, "file_name": "op300059b-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [246.24, 211.68, 168.9, 160.12], "category_id": 1}, {"id": 1, "bbox": [177.05, 609.27, 121.42, 46.14], "category_id": 2}, {"id": 2, "bbox": [32.56, 459.33, 37.31, 40.71], "category_id": 3}, {"id": 3, "bbox": [362.91, 6.11, 143.13, 48.85], "category_id": 2}, {"id": 4, "bbox": [391.4, 113.98, 134.99, 50.21], "category_id": 2}, {"id": 5, "bbox": [158.73, 6.78, 151.95, 43.43], "category_id": 2}, {"id": 6, "bbox": [423.96, 323.63, 33.92, 44.1], "category_id": 3}, {"id": 7, "bbox": [1187.09, 696.79, 34.6, 40.03], "category_id": 3}, {"id": 8, "bbox": [4.07, 324.99, 172.98, 126.2], "category_id": 1}, {"id": 9, "bbox": [1122.65, 176.4, 233.35, 150.62], "category_id": 1}, {"id": 10, "bbox": [417.25, 529.98, 229.24, 177.71], "category_id": 1}, {"id": 11, "bbox": [747.53, 464.08, 37.99, 42.06], "category_id": 3}, {"id": 12, "bbox": [1126.72, 533.28, 223.17, 171.65], "category_id": 1}, {"id": 13, "bbox": [1183.7, 328.38, 34.6, 41.39], "category_id": 3}, {"id": 14, "bbox": [518.25, 731.39, 33.92, 40.71], "category_id": 3}, {"id": 15, "bbox": [569.13, 274.78, 337.13, 180.48], "category_id": 1}], "caption": "Scheme 2. Reaction mechanism for the formation of 2 and 8", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 689, 784, 704], "ImageBB": [448, 710, 787, 914]}, "reactions": [{"reactants": [5, 3], "conditions": [], "products": [4, 0]}, {"reactants": [8, 0], "conditions": [6], "products": [15]}, {"reactants": [15], "conditions": [], "products": [9]}, {"reactants": [15], "conditions": [], "products": [12]}, {"reactants": [8, 1], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [12]}], "diagram_type": "graph"}, {"id": 278, "width": 1348, "height": 1008, "file_name": "ol800527p-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [997.0, 144.0, 333.0, 238.0], "category_id": 1}, {"id": 1, "bbox": [412.0, 213.0, 141.0, 41.0], "category_id": 2}, {"id": 2, "bbox": [372.0, 294.0, 219.0, 91.0], "category_id": 2}, {"id": 3, "bbox": [765.0, 316.0, 54.0, 46.0], "category_id": 3}, {"id": 4, "bbox": [159.0, 321.0, 51.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [14.0, 145.0, 335.0, 162.3], "category_id": 1}, {"id": 6, "bbox": [503.85, 140.27, 58.46, 54.56], "category_id": 3}, {"id": 7, "bbox": [0.0, 419.0, 1348.0, 531.0], "category_id": 4}, {"id": 8, "bbox": [1073.0, 311.0, 54.0, 47.0], "category_id": 3}, {"id": 9, "bbox": [312.0, 3.0, 338.0, 203.0], "category_id": 1}, {"id": 10, "bbox": [625.0, 92.0, 330.0, 216.0], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [9, 1, 2], "products": [10, 0]}], "corefs": [[5, 4], [9, 6], [10, 3], [0, 8]], "caption": "Table 1. Regioselectivity of the Introduction of a Cyanomethyl Group ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 345, 752, 372], "ImageBB": [425, 381, 762, 633]}, "diagram_type": "single"}, {"id": 465, "width": 1344, "height": 968, "file_name": "op100335q-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [986.0, 599.0, 176.0, 271.0], "category_id": 1}, {"id": 1, "bbox": [559.0, 578.0, 262.0, 276.0], "category_id": 1}, {"id": 2, "bbox": [90.0, 573.0, 200.0, 311.0], "category_id": 1}, {"id": 3, "bbox": [71.0, 191.0, 337.0, 302.0], "category_id": 1}, {"id": 4, "bbox": [370.0, 245.0, 238.0, 94.0], "category_id": 1}, {"id": 5, "bbox": [622.0, 187.0, 345.0, 289.0], "category_id": 1}, {"id": 6, "bbox": [1040.0, 231.0, 233.0, 92.0], "category_id": 1}, {"id": 7, "bbox": [1142.0, 286.0, 61.0, 60.0], "category_id": 3}, {"id": 8, "bbox": [1043.0, 792.0, 57.0, 59.0], "category_id": 3}, {"id": 9, "bbox": [125.0, 860.0, 52.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [476.0, 304.0, 65.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [806.0, 458.0, 52.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [260.0, 458.0, 56.0, 53.0], "category_id": 3}, {"id": 13, "bbox": [829.0, 0.0, 48.0, 44.0], "category_id": 3}, {"id": 14, "bbox": [878.48, 132.03, 59.0, 46.37], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [14], "products": [13]}, {"reactants": [5], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [0]}], "corefs": [[3, 12], [4, 10], [5, 11], [6, 7], [2, 9], [0, 8]], "caption": "Table 1. E\ufb00ect of acid on the formation of imidazoles 14 and 20a ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 401, 405, 431], "ImageBB": [71, 133, 407, 375]}, "diagram_type": "tree"}, {"id": 1115, "width": 2448, "height": 792, "file_name": "jo9816515-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1911.62, 176.45, 227.78, 58.82], "category_id": 2}, {"id": 1, "bbox": [608.63, 188.71, 153.08, 52.69], "category_id": 2}, {"id": 2, "bbox": [1009.08, 357.81, 58.78, 62.49], "category_id": 3}, {"id": 3, "bbox": [852.33, 19.61, 401.67, 284.28], "category_id": 1}, {"id": 4, "bbox": [121.24, 366.38, 133.48, 62.5], "category_id": 3}, {"id": 5, "bbox": [2187.16, 19.61, 260.84, 267.13], "category_id": 1}, {"id": 6, "bbox": [420.04, 69.85, 169.0, 186.25], "category_id": 1}, {"id": 7, "bbox": [612.31, 112.73, 145.73, 61.27], "category_id": 2}, {"id": 8, "bbox": [1418.1, 3.68, 437.19, 286.73], "category_id": 1}, {"id": 9, "bbox": [0.0, 85.78, 377.18, 151.94], "category_id": 1}, {"id": 10, "bbox": [1592.0, 355.36, 67.35, 64.94], "category_id": 3}, {"id": 11, "bbox": [1939.79, 105.38, 154.3, 55.14], "category_id": 2}, {"id": 12, "bbox": [2204.3, 354.13, 243.7, 73.52], "category_id": 3}, {"id": 13, "bbox": [467.8, 355.36, 89.4, 68.62], "category_id": 3}, {"id": 14, "bbox": [0.0, 442.36, 1225.4, 349.64], "category_id": 4}], "caption": "Scheme 7", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 701, 453, 715], "ImageBB": [119, 720, 731, 918]}, "reactions": [{"reactants": [9, 6], "conditions": [7, 1], "products": [3]}, {"reactants": [3], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [11, 0], "products": [5]}], "diagram_type": "single"}, {"id": 729, "width": 2816, "height": 1212, "file_name": "ol016466j-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [401.42, 394.63, 42.48, 46.72], "category_id": 3}, {"id": 1, "bbox": [852.0, 342.0, 239.0, 56.0], "category_id": 2}, {"id": 2, "bbox": [361.07, 687.69, 197.5, 53.1], "category_id": 3}, {"id": 3, "bbox": [363.2, 747.16, 178.39, 44.6], "category_id": 3}, {"id": 4, "bbox": [126.0, 777.0, 1044.0, 429.0], "category_id": 1}, {"id": 5, "bbox": [672.0, 873.0, 470.0, 56.0], "category_id": 2}, {"id": 6, "bbox": [807.0, 207.0, 312.0, 54.0], "category_id": 2}, {"id": 7, "bbox": [140.0, 449.0, 869.0, 258.0], "category_id": 1}, {"id": 8, "bbox": [1513.0, 140.0, 1218.0, 1039.0], "category_id": 4}, {"id": 9, "bbox": [669.0, 772.0, 484.0, 47.0], "category_id": 2}, {"id": 10, "bbox": [391.0, 831.0, 241.0, 61.0], "category_id": 2}, {"id": 11, "bbox": [933.0, 261.0, 45.0, 47.0], "category_id": 3}, {"id": 12, "bbox": [666.0, 814.0, 585.0, 64.0], "category_id": 2}, {"id": 13, "bbox": [141.75, 694.26, 174.25, 67.84], "category_id": 2}, {"id": 14, "bbox": [109.0, 174.0, 692.0, 257.1], "category_id": 1}], "reactions": [{"reactants": [14], "conditions": [6, 1], "products": [7]}, {"reactants": [2], "conditions": [13], "products": [3]}, {"reactants": [7], "conditions": [9, 12, 5], "products": [4]}], "corefs": [[14, 2], [6, 11], [7, 2], [7, 3]], "caption": "Figure 1. Partial one-dimensional transient NOE spectra of 2 mM polymer-bound trisaccharide 5 and 5 with Verotoxin-1 (200/1) in D2O: (a) 1H NMR spectra of 5 in D2O; (b) 1D NOESY spectra of 5 and VT-1 in D2O; (c) 1D NOESY spectra of 5 in D2O. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 354, 775, 410], "ImageBB": [73, 52, 777, 355]}, "diagram_type": "tree"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}