test2.json

{"licenses": [{"name": "", "id": 0, "url": ""}], "info": {"contributor": "Jiang Guo", "date_created": "Feb. 01", "description": "A dataset for chemical visual diagram analysis", "url": "", "version": "v1", "year": "2022"}, "categories": [{"id": 1, "name": "structure"}, {"id": 2, "name": "text"}, {"id": 3, "name": "identifier"}, {"id": 4, "name": "supplement"}], "images": [{"id": 788, "width": 1352, "height": 2216, "file_name": "jo501910q-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [478.0, 1558.0, 373.1, 129.1], "category_id": 3}, {"id": 1, "bbox": [918.0, 1138.0, 326.1, 525.2], "category_id": 1}, {"id": 2, "bbox": [157.8, 526.9, 213.2, 158.2], "category_id": 3}, {"id": 3, "bbox": [132.0, 1461.0, 258.0, 206.0], "category_id": 3}, {"id": 4, "bbox": [870.9, 594.9, 340.2, 105.2], "category_id": 3}, {"id": 5, "bbox": [237.0, 948.0, 222.0, 198.0], "category_id": 3}, {"id": 6, "bbox": [696.0, 1043.4, 330.8, 104.1], "category_id": 3}, {"id": 7, "bbox": [490.9, 603.9, 325.2, 104.2], "category_id": 3}, {"id": 8, "bbox": [884.9, 2104.9, 192.2, 68.3], "category_id": 3}, {"id": 9, "bbox": [622.86, 2116.9, 202.3, 64.3], "category_id": 3}, {"id": 10, "bbox": [197.0, 2014.0, 116.0, 157.1], "category_id": 3}, {"id": 11, "bbox": [1061.9, 1670.0, 187.2, 66.1], "category_id": 3}, {"id": 12, "bbox": [134.9, 32.7, 198.9, 63.0], "category_id": 2}, {"id": 13, "bbox": [131.6, 296.6, 315.4, 220.5], "category_id": 1}, {"id": 14, "bbox": [477.12, 0.0, 433.7, 53.53], "category_id": 2}, {"id": 15, "bbox": [256.5, 788.9, 321.6, 186.2], "category_id": 1}, {"id": 16, "bbox": [840.1, 162.9, 351.0, 427.2], "category_id": 1}, {"id": 17, "bbox": [436.9, 1259.9, 417.1, 308.3], "category_id": 1}, {"id": 18, "bbox": [35.9, 1318.9, 436.2, 170.3], "category_id": 1}, {"id": 19, "bbox": [1050.43, 38.67, 160.41, 47.53], "category_id": 2}, {"id": 20, "bbox": [172.8, 1844.9, 313.2, 225.3], "category_id": 1}, {"id": 21, "bbox": [467.8, 264.7, 290.4, 331.4], "category_id": 1}, {"id": 22, "bbox": [349.39, 71.3, 668.36, 62.43], "category_id": 2}, {"id": 23, "bbox": [530.8, 1777.9, 295.5, 338.4], "category_id": 1}, {"id": 24, "bbox": [904.8, 1738.9, 351.5, 426.4], "category_id": 1}, {"id": 25, "bbox": [680.0, 706.0, 466.0, 399.0], "category_id": 1}], "reactions": [{"reactants": [12], "conditions": [14, 22], "products": [19]}], "corefs": [[13, 2], [21, 7], [16, 4], [15, 5], [25, 6], [18, 3], [17, 0], [1, 11], [20, 10], [23, 9], [24, 8]], "caption": "Table 3. Regioselective Synthesis of N-Sulfonyl 6,7-Dihydro- 5H-dibenzo[c,e]azepines ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 417, 125], "ImageBB": [82, 131, 420, 685]}, "diagram_type": "single"}, {"id": 353, "width": 1344, "height": 1304, "file_name": "ol200849k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [394.0, 205.0, 27.0, 37.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 317.0, 1339.0, 987.0], "category_id": 4}, {"id": 2, "bbox": [66.0, 15.0, 200.0, 168.0], "category_id": 1}, {"id": 3, "bbox": [302.0, 80.0, 231.0, 54.0], "category_id": 1}, {"id": 4, "bbox": [1103.0, 207.0, 24.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [143.0, 205.0, 22.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [574.0, 128.0, 267.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [571.0, 184.0, 381.0, 43.0], "category_id": 2}, {"id": 8, "bbox": [567.0, 50.0, 260.0, 42.0], "category_id": 2}, {"id": 9, "bbox": [567.0, 6.0, 336.0, 41.0], "category_id": 2}, {"id": 10, "bbox": [996.7, 14.0, 283.3, 228.8], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [9, 8, 6, 7], "products": [10]}], "corefs": [[2, 5], [3, 0], [10, 4]], "caption": "Table 3. CDC between Various Nitrones 1 and Alkynes 2 Using Oxidant 3 (15 mol %) and Dioxygen As Oxidants ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 405, 114], "ImageBB": [71, 126, 407, 452]}, "diagram_type": "single"}, {"id": 774, "width": 1348, "height": 1708, "file_name": "jo951899j-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 5.0, 299.0, 113.0], "category_id": 2}, {"id": 1, "bbox": [191.0, 140.0, 113.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [144.0, 865.0, 168.0, 98.0], "category_id": 3}, {"id": 3, "bbox": [402.0, 498.0, 176.0, 57.0], "category_id": 2}, {"id": 4, "bbox": [380.0, 696.0, 309.0, 134.0], "category_id": 2}, {"id": 5, "bbox": [407.0, 890.0, 166.0, 60.0], "category_id": 2}, {"id": 6, "bbox": [410.0, 840.0, 181.0, 42.0], "category_id": 2}, {"id": 7, "bbox": [0.0, 1091.0, 1348.0, 617.0], "category_id": 4}, {"id": 8, "bbox": [980.0, 193.0, 117.2, 56.1], "category_id": 3}, {"id": 9, "bbox": [385.0, 382.0, 319.0, 116.0], "category_id": 2}, {"id": 10, "bbox": [161.0, 524.6, 136.0, 62.2], "category_id": 3}, {"id": 11, "bbox": [747.7, 378.4, 442.9, 230.2], "category_id": 1}, {"id": 12, "bbox": [708.0, 108.0, 234.0, 192.7], "category_id": 1}, {"id": 13, "bbox": [382.0, 178.0, 161.0, 50.0], "category_id": 2}, {"id": 14, "bbox": [410.0, 563.0, 161.0, 53.0], "category_id": 2}, {"id": 15, "bbox": [741.6, 713.6, 446.5, 243.7], "category_id": 1}, {"id": 16, "bbox": [892.42, 974.13, 221.0, 60.0], "category_id": 3}, {"id": 17, "bbox": [367.0, 125.0, 184.0, 41.0], "category_id": 2}, {"id": 18, "bbox": [905.0, 633.0, 118.0, 48.0], "category_id": 3}, {"id": 19, "bbox": [784.0, 60.0, 369.0, 70.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [0, 17, 13], "products": [19, 12]}, {"reactants": [10], "conditions": [9, 3, 14], "products": [11]}, {"reactants": [2], "conditions": [4, 6, 5], "products": [15]}], "corefs": [[12, 8], [11, 18], [15, 16]], "caption": "Table 7. Removal of the Saccharide Protecting Groups", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [68, 402, 393, 414], "ImageBB": [63, 423, 400, 850]}, "diagram_type": "multiple"}, {"id": 824, "width": 2820, "height": 2776, "file_name": "jo400755q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [964.1, 944.0, 408.3, 412.7], "category_id": 1}, {"id": 1, "bbox": [1417.28, 408.0, 398.6, 418.0], "category_id": 1}, {"id": 2, "bbox": [481.0, 937.0, 491.0, 469.0], "category_id": 1}, {"id": 3, "bbox": [1378.7, 947.0, 437.3, 422.0], "category_id": 1}, {"id": 4, "bbox": [1805.6, 940.0, 474.4, 419.0], "category_id": 1}, {"id": 5, "bbox": [529.0, 1525.2, 415.6, 446.6], "category_id": 1}, {"id": 6, "bbox": [983.44, 1532.6, 415.0, 419.0], "category_id": 1}, {"id": 7, "bbox": [1421.28, 1528.2, 398.0, 423.8], "category_id": 1}, {"id": 8, "bbox": [1880.7, 1532.2, 414.9, 416.8], "category_id": 1}, {"id": 9, "bbox": [502.0, 2101.0, 316.0, 432.0], "category_id": 1}, {"id": 10, "bbox": [947.3, 2109.2, 307.1, 428.2], "category_id": 1}, {"id": 11, "bbox": [1368.2, 2105.9, 334.0, 440.1], "category_id": 1}, {"id": 12, "bbox": [1829.0, 2101.4, 465.4, 323.9], "category_id": 1}, {"id": 13, "bbox": [520.0, 408.0, 427.6, 394.0], "category_id": 1}, {"id": 14, "bbox": [726.0, 0.0, 338.9, 318.3], "category_id": 1}, {"id": 15, "bbox": [1391.0, 3.0, 334.3, 313.0], "category_id": 1}, {"id": 16, "bbox": [1053.0, 34.6, 320.2, 94.8], "category_id": 2}, {"id": 17, "bbox": [1751.98, 121.9, 343.1, 62.7], "category_id": 2}, {"id": 18, "bbox": [1377.0, 2562.28, 247.0, 54.0], "category_id": 3}, {"id": 19, "bbox": [1825.56, 2549.72, 243.0, 71.0], "category_id": 3}, {"id": 20, "bbox": [824.2, 286.0, 112.2, 43.6], "category_id": 3}, {"id": 21, "bbox": [1485.5, 279.0, 98.3, 50.3], "category_id": 3}, {"id": 22, "bbox": [1063.0, 1420.0, 250.0, 57.0], "category_id": 3}, {"id": 23, "bbox": [976.0, 401.0, 411.0, 402.0], "category_id": 1}, {"id": 24, "bbox": [1854.0, 394.0, 391.0, 422.0], "category_id": 1}, {"id": 25, "bbox": [1053.0, 155.0, 321.0, 94.0], "category_id": 2}, {"id": 26, "bbox": [3.0, 2674.0, 2357.0, 85.0], "category_id": 4}, {"id": 27, "bbox": [773.0, 826.0, 81.0, 71.0], "category_id": 3}, {"id": 28, "bbox": [891.0, 826.0, 287.0, 61.0], "category_id": 3}, {"id": 29, "bbox": [1209.0, 826.0, 74.0, 64.0], "category_id": 3}, {"id": 30, "bbox": [1553.0, 836.0, 247.0, 67.0], "category_id": 3}, {"id": 31, "bbox": [1958.0, 836.0, 260.0, 64.0], "category_id": 3}, {"id": 32, "bbox": [604.0, 1416.0, 270.0, 68.0], "category_id": 3}, {"id": 33, "bbox": [1654.0, 1413.0, 81.0, 67.0], "category_id": 3}, {"id": 34, "bbox": [1776.0, 1430.0, 253.0, 50.0], "category_id": 3}, {"id": 35, "bbox": [2093.0, 1420.0, 71.0, 60.0], "category_id": 3}, {"id": 36, "bbox": [607.0, 2017.0, 260.0, 54.0], "category_id": 3}, {"id": 37, "bbox": [1239.0, 2010.0, 67.0, 57.0], "category_id": 3}, {"id": 38, "bbox": [1337.0, 2017.0, 287.0, 54.0], "category_id": 3}, {"id": 39, "bbox": [1648.0, 2010.0, 70.0, 54.0], "category_id": 3}, {"id": 40, "bbox": [1968.0, 2017.0, 230.0, 60.0], "category_id": 3}, {"id": 41, "bbox": [496.0, 2553.0, 243.0, 74.0], "category_id": 3}, {"id": 42, "bbox": [945.0, 2563.0, 243.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [14], "conditions": [16, 25], "products": [15]}], "corefs": [[14, 20], [15, 21], [13, 27], [23, 29], [1, 30], [24, 31], [2, 32], [0, 22], [3, 33], [4, 35], [5, 36], [6, 37], [7, 39], [8, 40], [9, 41], [10, 42], [11, 18], [12, 19]], "caption": "Table 2. Ortho-Bromination of N-Aryl Ring of N,1-Diaryl-1H-tetrazol-5-aminea", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 529, 111], "ImageBB": [82, 116, 787, 810]}, "diagram_type": "single"}, {"id": 1270, "width": 1356, "height": 1004, "file_name": "op060118l-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [496.54, 0.0, 212.32, 192.64], "category_id": 1}, {"id": 1, "bbox": [22.39, 560.97, 347.3, 166.19], "category_id": 2}, {"id": 2, "bbox": [704.79, 128.88, 37.99, 44.77], "category_id": 3}, {"id": 3, "bbox": [111.93, 389.36, 100.39, 55.62], "category_id": 3}, {"id": 4, "bbox": [432.78, 300.5, 303.9, 53.58], "category_id": 2}, {"id": 5, "bbox": [463.98, 577.25, 393.44, 343.23], "category_id": 1}, {"id": 6, "bbox": [432.78, 77.33, 42.06, 47.48], "category_id": 2}, {"id": 7, "bbox": [482.3, 152.62, 295.08, 91.57], "category_id": 2}, {"id": 8, "bbox": [24.42, 166.19, 291.69, 248.94], "category_id": 1}, {"id": 9, "bbox": [625.43, 956.43, 60.37, 47.48], "category_id": 3}, {"id": 10, "bbox": [934.75, 602.35, 260.48, 136.34], "category_id": 2}, {"id": 11, "bbox": [1042.61, 428.02, 50.19, 50.87], "category_id": 3}, {"id": 12, "bbox": [1242.04, 727.16, 113.96, 56.98], "category_id": 2}, {"id": 13, "bbox": [880.48, 120.06, 448.39, 339.16], "category_id": 1}], "caption": "Scheme 2. Eli Lilly\u2019s assemblage of 2\u201aHCl from (S)-6", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 460, 375, 474], "ImageBB": [73, 479, 412, 730]}, "reactions": [{"reactants": [8], "conditions": [0, 7, 4], "products": [13]}, {"reactants": [13], "conditions": [1], "products": [5]}, {"reactants": [5], "conditions": [10], "products": [12]}], "diagram_type": "multiple"}, {"id": 1225, "width": 1304, "height": 1944, "file_name": "op0100706-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [15.56, 289.8, 301.52, 318.0], "category_id": 1}, {"id": 1, "bbox": [259.7, 983.18, 448.39, 235.35], "category_id": 1}, {"id": 2, "bbox": [18.48, 1126.14, 229.55, 55.43], "category_id": 2}, {"id": 3, "bbox": [727.54, 1108.63, 178.97, 52.52], "category_id": 2}, {"id": 4, "bbox": [1028.09, 465.82, 91.43, 136.15], "category_id": 1}, {"id": 5, "bbox": [935.69, 339.4, 141.04, 58.35], "category_id": 2}, {"id": 6, "bbox": [41.82, 1039.59, 153.68, 46.68], "category_id": 2}, {"id": 7, "bbox": [1079.16, 310.43, 74.68, 130.69], "category_id": 1}, {"id": 8, "bbox": [1016.15, 910.2, 28.0, 37.34], "category_id": 3}, {"id": 9, "bbox": [337.51, 467.77, 189.67, 56.4], "category_id": 2}, {"id": 10, "bbox": [259.7, 50.57, 251.91, 52.51], "category_id": 2}, {"id": 11, "bbox": [532.04, 797.44, 162.43, 90.44], "category_id": 2}, {"id": 12, "bbox": [931.8, 1007.5, 323.89, 213.94], "category_id": 1}, {"id": 13, "bbox": [0.0, 1249.64, 483.41, 192.56], "category_id": 1}, {"id": 14, "bbox": [532.04, 1856.48, 34.04, 39.87], "category_id": 3}, {"id": 15, "bbox": [412.4, 1319.66, 550.53, 284.94], "category_id": 1}, {"id": 16, "bbox": [337.51, 344.26, 220.79, 91.41], "category_id": 2}, {"id": 17, "bbox": [1027.12, 55.43, 146.87, 55.43], "category_id": 2}, {"id": 18, "bbox": [557.33, 3.89, 454.23, 262.41], "category_id": 1}, {"id": 19, "bbox": [534.96, 689.49, 172.16, 88.5], "category_id": 2}, {"id": 20, "bbox": [384.2, 1891.49, 327.78, 49.59], "category_id": 2}, {"id": 21, "bbox": [984.32, 1470.4, 299.58, 87.52], "category_id": 2}, {"id": 22, "bbox": [23.34, 96.28, 178.0, 47.65], "category_id": 2}, {"id": 23, "bbox": [259.7, 138.09, 211.06, 50.57], "category_id": 2}, {"id": 24, "bbox": [132.28, 1475.26, 188.7, 51.54], "category_id": 2}, {"id": 25, "bbox": [78.78, 645.73, 343.35, 284.94], "category_id": 1}, {"id": 26, "bbox": [1028.09, 1192.27, 41.83, 41.82], "category_id": 3}, {"id": 27, "bbox": [984.32, 148.79, 227.6, 48.62], "category_id": 2}, {"id": 28, "bbox": [964.87, 492.08, 52.52, 50.57], "category_id": 2}, {"id": 29, "bbox": [1028.09, 464.85, 91.43, 137.12], "category_id": 1}, {"id": 30, "bbox": [781.04, 706.03, 448.39, 235.34], "category_id": 1}, {"id": 31, "bbox": [622.5, 304.39, 312.22, 315.08], "category_id": 1}, {"id": 32, "bbox": [726.57, 1018.19, 179.94, 58.35], "category_id": 2}, {"id": 33, "bbox": [984.32, 1326.47, 245.11, 88.5], "category_id": 2}, {"id": 34, "bbox": [251.92, 1612.38, 596.23, 283.97], "category_id": 1}], "caption": "Scheme 1. Shionogi synthesis of Ceftibuten", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 299, 686, 313], "ImageBB": [446, 318, 772, 804]}, "reactions": [{"reactants": [22], "conditions": [10, 23], "products": [18]}, {"reactants": [18], "conditions": [17, 27], "products": [0]}, {"reactants": [0], "conditions": [16, 9], "products": [31]}, {"reactants": [31, 7, 29], "conditions": [5], "products": [25]}, {"reactants": [25], "conditions": [19, 11], "products": [30]}, {"reactants": [30], "conditions": [6, 2], "products": [1]}, {"reactants": [1], "conditions": [32, 3], "products": [12]}, {"reactants": [12, 13], "conditions": [24], "products": [15]}, {"reactants": [15], "conditions": [33, 21], "products": [34]}], "diagram_type": "multiple"}, {"id": 632, "width": 1152, "height": 3156, "file_name": "ol5012407-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [29.7, 26.7, 352.4, 219.3], "category_id": 1}, {"id": 1, "bbox": [341.0, 314.7, 556.0, 45.3], "category_id": 2}, {"id": 2, "bbox": [340.6, 265.0, 441.4, 45.0], "category_id": 2}, {"id": 3, "bbox": [757.3, 28.8, 370.1, 204.7], "category_id": 1}, {"id": 4, "bbox": [184.0, 248.0, 27.0, 36.0], "category_id": 3}, {"id": 5, "bbox": [346.0, 0.0, 406.0, 161.0], "category_id": 2}, {"id": 6, "bbox": [4.0, 383.0, 1148.0, 2747.0], "category_id": 4}, {"id": 7, "bbox": [925.0, 249.0, 29.0, 37.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [5, 2, 1], "products": [3]}], "corefs": [[0, 4], [3, 7]], "caption": "Table 2. Rhodium-Catalyzed Intramolecular C\u2212H Acylation of Biarylcarboxylic Acidsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 125], "ImageBB": [473, 131, 761, 920]}, "diagram_type": "single"}, {"id": 1240, "width": 1168, "height": 1744, "file_name": "op025538z-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [709.59, 917.07, 66.99, 52.34], "category_id": 3}, {"id": 1, "bbox": [525.35, 508.81, 48.15, 43.96], "category_id": 2}, {"id": 2, "bbox": [4.03, 429.25, 316.14, 54.43], "category_id": 2}, {"id": 3, "bbox": [550.47, 106.83, 52.34, 46.06], "category_id": 2}, {"id": 4, "bbox": [749.37, 1342.07, 77.46, 52.35], "category_id": 3}, {"id": 5, "bbox": [18.69, 1683.34, 77.46, 43.96], "category_id": 3}, {"id": 6, "bbox": [288.77, 1245.77, 108.86, 58.62], "category_id": 2}, {"id": 7, "bbox": [45.9, 1350.45, 67.0, 50.25], "category_id": 3}, {"id": 8, "bbox": [332.73, 906.6, 58.62, 54.43], "category_id": 3}, {"id": 9, "bbox": [106.62, 912.88, 79.56, 52.34], "category_id": 3}, {"id": 10, "bbox": [749.37, 649.08, 81.65, 56.53], "category_id": 3}, {"id": 11, "bbox": [85.68, 661.64, 60.72, 54.44], "category_id": 3}, {"id": 12, "bbox": [705.4, 502.53, 138.18, 129.8], "category_id": 1}, {"id": 13, "bbox": [364.14, 127.76, 117.24, 60.72], "category_id": 2}, {"id": 14, "bbox": [541.63, 1240.6, 61.92, 43.63], "category_id": 2}, {"id": 15, "bbox": [705.6, 225.96, 189.26, 68.05], "category_id": 2}, {"id": 16, "bbox": [304.39, 1509.31, 183.16, 164.02], "category_id": 1}, {"id": 17, "bbox": [11.34, 1471.8, 190.13, 232.4], "category_id": 1}, {"id": 18, "bbox": [730.7, 730.23, 180.73, 232.77], "category_id": 1}, {"id": 19, "bbox": [52.7, 531.31, 151.2, 111.29], "category_id": 1}, {"id": 20, "bbox": [67.3, 784.32, 155.3, 120.58], "category_id": 1}, {"id": 21, "bbox": [541.63, 8.72, 74.47, 45.38], "category_id": 2}, {"id": 22, "bbox": [315.7, 766.0, 161.0, 147.4], "category_id": 1}, {"id": 23, "bbox": [40.12, 1149.0, 186.65, 225.1], "category_id": 1}, {"id": 24, "bbox": [684.67, 20.94, 146.52, 63.69], "category_id": 2}, {"id": 25, "bbox": [960.28, 835.8, 94.19, 59.0], "category_id": 2}, {"id": 26, "bbox": [325.33, 229.45, 163.97, 61.94], "category_id": 2}, {"id": 27, "bbox": [304.39, 20.94, 165.72, 67.18], "category_id": 2}, {"id": 28, "bbox": [745.4, 1130.68, 188.71, 233.62], "category_id": 1}, {"id": 29, "bbox": [11.34, 1061.75, 257.29, 56.71], "category_id": 2}, {"id": 30, "bbox": [1003.89, 1260.67, 82.85, 61.07], "category_id": 2}, {"id": 31, "bbox": [704.73, 120.4, 150.88, 63.68], "category_id": 2}, {"id": 32, "bbox": [305.26, 531.31, 108.16, 54.97], "category_id": 2}, {"id": 33, "bbox": [914.05, 125.63, 95.94, 60.2], "category_id": 2}, {"id": 34, "bbox": [578.26, 1544.21, 75.88, 55.84], "category_id": 2}, {"id": 35, "bbox": [960.28, 531.31, 74.13, 59.33], "category_id": 2}, {"id": 36, "bbox": [328.81, 1689.04, 73.27, 54.96], "category_id": 3}, {"id": 37, "bbox": [741.36, 1454.35, 258.16, 236.43], "category_id": 1}, {"id": 38, "bbox": [871.31, 1684.67, 75.01, 54.1], "category_id": 3}, {"id": 39, "bbox": [537.27, 220.73, 100.3, 41.87], "category_id": 2}, {"id": 40, "bbox": [11.34, 335.02, 645.42, 52.34], "category_id": 2}, {"id": 41, "bbox": [1072.79, 1569.51, 90.71, 69.8], "category_id": 2}, {"id": 42, "bbox": [166.59, 127.38, 141.29, 60.19], "category_id": 2}, {"id": 43, "bbox": [552.09, 793.92, 81.99, 56.71], "category_id": 2}], "caption": "Scheme 3. Mechanism of solid-liquid phase transfer catalysed C-alkylation of p-chlorophenyl acetonitrile with isopropyl bromide ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 459, 387, 501], "ImageBB": [97, 505, 389, 941]}, "reactions": [{"reactants": [27], "conditions": [21], "products": [24]}, {"reactants": [24], "conditions": [], "products": [27]}, {"reactants": [42, 13], "conditions": [3], "products": [31, 33]}, {"reactants": [31, 33], "conditions": [], "products": [42, 13]}, {"reactants": [26], "conditions": [39], "products": [15]}, {"reactants": [15], "conditions": [], "products": [26]}, {"reactants": [19, 32], "conditions": [1], "products": [12, 35]}, {"reactants": [12, 35], "conditions": [], "products": [19, 32]}, {"reactants": [20, 22], "conditions": [43], "products": [18, 25]}, {"reactants": [23, 6], "conditions": [14], "products": [28, 30]}, {"reactants": [28, 30], "conditions": [], "products": [23, 6]}, {"reactants": [17, 16], "conditions": [34], "products": [37, 41]}], "diagram_type": "multiple"}, {"id": 227, "width": 1228, "height": 1168, "file_name": "op0102013-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [705.0, 341.0, 198.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [708.0, 297.0, 121.0, 35.0], "category_id": 3}, {"id": 2, "bbox": [553.0, 372.0, 489.0, 323.0], "category_id": 1}, {"id": 3, "bbox": [132.0, 288.0, 73.0, 58.0], "category_id": 3}, {"id": 4, "bbox": [140.09, 1082.0, 48.9, 46.5], "category_id": 3}, {"id": 5, "bbox": [563.0, 0.0, 492.0, 323.9], "category_id": 1}, {"id": 6, "bbox": [21.5, 3.0, 446.5, 305.0], "category_id": 1}, {"id": 7, "bbox": [172.0, 682.1, 39.0, 47.4], "category_id": 3}, {"id": 8, "bbox": [780.0, 777.0, 445.0, 320.0], "category_id": 1}, {"id": 9, "bbox": [383.0, 777.0, 451.0, 318.4], "category_id": 1}, {"id": 10, "bbox": [0.0, 773.0, 446.0, 314.0], "category_id": 1}, {"id": 11, "bbox": [16.56, 366.5, 495.44, 326.5], "category_id": 1}, {"id": 12, "bbox": [996.0, 490.0, 163.5, 70.0], "category_id": 2}, {"id": 13, "bbox": [1000.0, 575.5, 96.5, 37.0], "category_id": 2}, {"id": 14, "bbox": [475.0, 83.0, 129.0, 84.5], "category_id": 2}, {"id": 15, "bbox": [485.0, 197.5, 85.0, 47.0], "category_id": 2}, {"id": 16, "bbox": [1159.0, 534.0, 60.0, 75.0], "category_id": 3}, {"id": 17, "bbox": [459.5, 487.1, 153.0, 71.4], "category_id": 2}, {"id": 18, "bbox": [1030.0, 193.5, 97.0, 51.5], "category_id": 2}, {"id": 19, "bbox": [1013.0, 93.0, 130.9, 80.0], "category_id": 2}, {"id": 20, "bbox": [686.5, 675.0, 45.5, 47.0], "category_id": 3}, {"id": 21, "bbox": [541.0, 1087.4, 172.4, 77.6], "category_id": 3}, {"id": 22, "bbox": [917.02, 1090.9, 197.38, 68.07], "category_id": 3}], "reactions": [{"reactants": [6], "conditions": [14, 15], "products": [5]}, {"reactants": [5], "conditions": [19, 18], "products": [11]}, {"reactants": [11], "conditions": [17], "products": [2]}, {"reactants": [2], "conditions": [12, 13], "products": [16]}], "corefs": [[6, 3], [5, 1], [5, 0], [11, 7], [2, 20], [10, 4], [9, 21], [8, 22]], "caption": "Figure 2.", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 715, 495, 729], "ImageBB": [455, 419, 762, 711]}, "diagram_type": "single"}, {"id": 302, "width": 1344, "height": 1628, "file_name": "ol303154k-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [330.0, 69.0, 109.2, 203.0], "category_id": 1}, {"id": 1, "bbox": [365.0, 308.0, 32.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [512.0, 313.0, 31.0, 31.0], "category_id": 3}, {"id": 3, "bbox": [1106.0, 351.0, 48.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 404.0, 1344.0, 1222.0], "category_id": 4}, {"id": 5, "bbox": [669.0, 250.0, 224.0, 35.0], "category_id": 2}, {"id": 6, "bbox": [644.0, 165.0, 283.0, 55.0], "category_id": 2}, {"id": 7, "bbox": [27.9, 71.0, 267.6, 200.6], "category_id": 1}, {"id": 8, "bbox": [104.0, 284.0, 163.0, 70.0], "category_id": 3}, {"id": 9, "bbox": [471.0, 62.0, 199.0, 230.0], "category_id": 1}, {"id": 10, "bbox": [951.0, 2.0, 369.0, 347.8], "category_id": 1}], "reactions": [{"reactants": [7, 0, 9], "conditions": [6, 5], "products": [10]}], "corefs": [[7, 8], [0, 1], [9, 2], [10, 3]], "caption": "Table 3. Substrate Scope of Anilines and R-Alkyl o-Hydroxystyrenesa ", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 333, 115], "ImageBB": [71, 126, 407, 533]}, "diagram_type": "single"}, {"id": 821, "width": 2820, "height": 1424, "file_name": "jo401195c-Table-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1257.0, 428.0, 139.0, 103.7], "category_id": 2}, {"id": 1, "bbox": [552.0, 306.0, 89.0, 41.1], "category_id": 3}, {"id": 2, "bbox": [779.0, 530.5, 206.0, 149.5], "category_id": 1}, {"id": 3, "bbox": [552.9, 347.24, 136.1, 44.66], "category_id": 2}, {"id": 4, "bbox": [461.0, 583.0, 263.0, 72.0], "category_id": 1}, {"id": 5, "bbox": [833.0, 751.0, 143.0, 53.0], "category_id": 2}, {"id": 6, "bbox": [1987.0, 67.0, 318.0, 215.0], "category_id": 1}, {"id": 7, "bbox": [2119.0, 720.0, 52.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [1771.0, 718.0, 57.0, 50.0], "category_id": 3}, {"id": 9, "bbox": [1770.0, 876.0, 419.0, 47.0], "category_id": 2}, {"id": 10, "bbox": [846.0, 305.0, 63.0, 44.0], "category_id": 3}, {"id": 11, "bbox": [1743.0, 313.0, 39.0, 41.0], "category_id": 3}, {"id": 12, "bbox": [2122.0, 312.0, 52.0, 41.0], "category_id": 3}, {"id": 13, "bbox": [1655.0, 33.0, 254.0, 262.0], "category_id": 1}, {"id": 14, "bbox": [2012.0, 537.0, 270.0, 152.0], "category_id": 1}, {"id": 15, "bbox": [1636.0, 518.0, 325.0, 139.0], "category_id": 1}, {"id": 16, "bbox": [1112.0, 289.0, 449.0, 111.0], "category_id": 2}, {"id": 17, "bbox": [854.0, 713.0, 53.0, 42.0], "category_id": 3}, {"id": 18, "bbox": [566.0, 712.0, 61.0, 46.0], "category_id": 3}, {"id": 19, "bbox": [0.0, 932.0, 2820.0, 492.0], "category_id": 4}, {"id": 20, "bbox": [487.0, 135.0, 218.0, 163.0], "category_id": 1}, {"id": 21, "bbox": [748.0, 132.0, 255.0, 150.0], "category_id": 1}, {"id": 22, "bbox": [551.0, 748.0, 145.0, 55.0], "category_id": 2}, {"id": 23, "bbox": [834.0, 341.0, 138.0, 59.0], "category_id": 2}, {"id": 24, "bbox": [2014.0, 347.0, 244.0, 90.0], "category_id": 2}, {"id": 25, "bbox": [1657.0, 353.0, 247.0, 83.0], "category_id": 2}], "reactions": [{"reactants": [20, 21, 4, 2], "conditions": [16, 0], "products": [13, 6, 15, 14]}], "corefs": [[20, 1], [21, 10], [13, 11], [6, 12], [4, 18], [2, 17], [15, 8], [14, 7]], "caption": "Table 6. Concurrent and Competitive Acetylation of trans-Diol (\u00b1)-1 and meso-Diol 28 with Catalyst 12b and DMAP", "pdf": {"Page": 8, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 474, 746, 494], "ImageBB": [82, 116, 787, 472]}, "diagram_type": "single"}, {"id": 17, "width": 1168, "height": 824, "file_name": "ja960062i-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [51.41, 500.95, 333.73, 110.45], "category_id": 1}, {"id": 1, "bbox": [421.42, 220.25, 159.35, 34.96], "category_id": 2}, {"id": 2, "bbox": [451.19, 429.71, 655.88, 385.82], "category_id": 1}, {"id": 3, "bbox": [653.2, 5.48, 507.03, 351.8], "category_id": 1}, {"id": 4, "bbox": [5.7, 15.05, 334.78, 341.17], "category_id": 1}, {"id": 5, "bbox": [364.0, 119.25, 266.75, 36.02], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [5, 1], "products": [3]}, {"reactants": [3], "conditions": [0], "products": [2]}], "corefs": [], "caption": "Figure 4. Scheme of synthesis of oligonucleotide-CHEVP conjugate by the diamine method. 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Base and solvent e\ufb00ects in cyclopropanation", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 263, 734, 278], "ImageBB": [436, 288, 775, 564]}, "diagram_type": "single"}, {"id": 503, "width": 1356, "height": 840, "file_name": "ol051920v-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [473.0, 112.0, 230.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [459.0, 49.0, 269.0, 58.0], "category_id": 2}, {"id": 2, "bbox": [0.0, 11.0, 206.0, 157.0], "category_id": 1}, {"id": 3, "bbox": [231.0, 43.0, 215.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [736.0, 1.0, 316.0, 179.0], "category_id": 1}, {"id": 5, "bbox": [1044.0, 3.0, 310.0, 227.0], "category_id": 1}, {"id": 6, "bbox": [1136.0, 224.0, 201.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [879.0, 192.0, 43.0, 53.0], "category_id": 3}, {"id": 8, "bbox": [272.0, 200.0, 58.0, 48.0], "category_id": 3}, {"id": 9, "bbox": [73.0, 167.0, 35.0, 44.0], "category_id": 3}, {"id": 10, "bbox": [5.0, 291.0, 1336.0, 549.0], "category_id": 4}], "reactions": [{"reactants": [2, 3], "conditions": [1, 0], "products": [4, 5]}], "corefs": [[2, 9], [3, 8], [4, 7], [5, 6]], "caption": "Table 4. Reactions of Salicylic Aldehydes 1 (0.5 mmol) with Ethyl 2-Methylbuta-2,3-dienoate 2c (1.0 mmol) in the Presence of DBU (10 mol %) in DMSO at 80 \u00b0C ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 712, 400, 757], "ImageBB": [73, 760, 412, 970]}, "diagram_type": "single"}, {"id": 1169, "width": 1352, "height": 616, "file_name": "ol071386m-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [752.76, 138.73, 119.72, 62.93], "category_id": 3}, {"id": 1, "bbox": [561.36, 353.25, 179.23, 37.89], "category_id": 3}, {"id": 2, "bbox": [725.71, 341.74, 265.8, 215.76], "category_id": 1}, {"id": 3, "bbox": [6.76, 181.36, 117.69, 98.8], "category_id": 1}, {"id": 4, "bbox": [754.12, 451.37, 43.28, 33.84], "category_id": 3}, {"id": 5, "bbox": [1233.64, 451.37, 110.24, 37.9], "category_id": 3}, {"id": 6, "bbox": [869.09, 525.14, 27.73, 29.77], "category_id": 3}, {"id": 7, "bbox": [561.36, 137.37, 129.18, 60.23], "category_id": 3}, {"id": 8, "bbox": [1086.88, 305.2, 246.18, 219.26], "category_id": 1}, {"id": 9, "bbox": [134.59, 228.05, 93.34, 144.15], "category_id": 1}, {"id": 10, "bbox": [353.72, 190.16, 214.4, 120.45], "category_id": 1}, {"id": 11, "bbox": [723.68, 2.71, 206.96, 119.78], "category_id": 1}], "caption": "Scheme 6. Proposed Reaction Pathways for 6a and 10", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [461, 162, 754, 175], "ImageBB": [439, 180, 777, 334]}, "reactions": [{"reactants": [3, 9], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [], "products": [11]}, {"reactants": [10], "conditions": [1], "products": [2]}, {"reactants": [2], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 247, "width": 1352, "height": 2060, "file_name": "ol9005079-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1084.0, 192.0, 67.0, 64.0], "category_id": 3}, {"id": 1, "bbox": [293.3, 15.9, 308.7, 230.5], "category_id": 1}, {"id": 2, "bbox": [651.0, 121.0, 173.0, 119.0], "category_id": 2}, {"id": 3, "bbox": [20.0, 295.6, 1314.0, 1764.4], "category_id": 4}, {"id": 4, "bbox": [900.7, 15.9, 424.3, 205.6], "category_id": 1}, {"id": 5, "bbox": [27.6, 35.6, 202.8, 167.8], "category_id": 1}, {"id": 6, "bbox": [59.0, 192.0, 80.0, 61.0], "category_id": 3}, {"id": 7, "bbox": [469.0, 193.0, 67.0, 58.0], "category_id": 3}, {"id": 8, "bbox": [623.0, 0.0, 214.0, 102.0], "category_id": 2}], "reactions": [{"reactants": [5, 1], "conditions": [8, 2], "products": [4]}], "corefs": [[5, 6], [1, 7], [4, 0]], "caption": "Table 2. Scope of Fluoromethylaryl Ketones 2 in the tBuTMG-Catalyzed Alkylation of 1a ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 162, 334, 189], "ImageBB": [58, 198, 396, 713]}, "diagram_type": "single"}, {"id": 1060, "width": 2808, "height": 908, "file_name": "jo201478d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1501.63, 594.25, 139.06, 63.21], "category_id": 2}, {"id": 1, "bbox": [155.92, 26.69, 349.77, 53.39], "category_id": 2}, {"id": 2, "bbox": [2122.51, 529.62, 106.75, 64.63], "category_id": 2}, {"id": 3, "bbox": [2312.14, 63.0, 316.76, 285.4], "category_id": 1}, {"id": 4, "bbox": [2288.26, 531.8, 228.94, 240.86], "category_id": 1}, {"id": 5, "bbox": [581.55, 524.0, 255.65, 273.95], "category_id": 1}, {"id": 6, "bbox": [1087.24, 4.21, 334.32, 344.19], "category_id": 1}, {"id": 7, "bbox": [1854.21, 56.19, 320.27, 332.95], "category_id": 1}, {"id": 8, "bbox": [418.6, 615.32, 150.3, 61.81], "category_id": 2}, {"id": 9, "bbox": [1816.28, 512.77, 287.96, 338.56], "category_id": 1}, {"id": 10, "bbox": [1035.27, 469.22, 359.6, 344.18], "category_id": 1}, {"id": 11, "bbox": [2184.31, 80.08, 101.14, 57.59], "category_id": 2}, {"id": 12, "bbox": [1501.63, 49.17, 122.21, 51.98], "category_id": 2}, {"id": 13, "bbox": [160.14, 469.22, 358.2, 53.38], "category_id": 2}, {"id": 14, "bbox": [851.25, 606.89, 147.49, 67.43], "category_id": 2}, {"id": 15, "bbox": [1338.68, 626.56, 108.16, 54.79], "category_id": 2}, {"id": 16, "bbox": [928.51, 144.7, 144.68, 63.22], "category_id": 2}, {"id": 17, "bbox": [578.74, 43.55, 404.55, 307.66], "category_id": 1}, {"id": 18, "bbox": [160.14, 120.82, 303.41, 193.86], "category_id": 1}, {"id": 19, "bbox": [421.41, 165.77, 144.69, 56.19], "category_id": 2}, {"id": 20, "bbox": [198.06, 604.08, 198.07, 129.24], "category_id": 1}, {"id": 21, "bbox": [1566.24, 151.72, 126.43, 56.2], "category_id": 2}, {"id": 22, "bbox": [1446.84, 507.15, 119.4, 57.59], "category_id": 1}, {"id": 23, "bbox": [1406.11, 172.79, 108.16, 54.79], "category_id": 2}], "caption": "Scheme 3. In Situ Generation of Ionic Tri\ufb02ates by Interaction of Substrates and Bi(OTf)3", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 570, 108], "ImageBB": [71, 117, 773, 344]}, "reactions": [{"reactants": [18], "conditions": [19], "products": [17]}, {"reactants": [17], "conditions": [], "products": [18]}, {"reactants": [17], "conditions": [16], "products": [6, 23]}, {"reactants": [6, 23], "conditions": [], "products": [17]}, {"reactants": [6, 23], "conditions": [21], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6, 23]}, {"reactants": [7], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [7]}, {"reactants": [20], "conditions": [8], "products": [5]}, {"reactants": [5], "conditions": [], "products": [20]}, {"reactants": [5], "conditions": [14], "products": [10, 15]}, {"reactants": [10, 15], "conditions": [], "products": [5]}, {"reactants": [10, 15], "conditions": [0], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10, 15]}, {"reactants": [9], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [9]}], "diagram_type": "multiple"}, {"id": 987, "width": 2280, "height": 1976, "file_name": "ja2031294-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1509.95, 1302.38, 85.4, 68.8], "category_id": 2}, {"id": 1, "bbox": [558.88, 1300.55, 126.6, 102.68], "category_id": 2}, {"id": 2, "bbox": [1088.1, 1538.98, 193.9, 225.89], "category_id": 1}, {"id": 3, "bbox": [2098.65, 805.43, 181.35, 261.25], "category_id": 1}, {"id": 4, "bbox": [891.93, 233.87, 296.54, 199.65], "category_id": 1}, {"id": 5, "bbox": [1035.64, 902.4, 167.66, 95.83], "category_id": 2}, {"id": 6, "bbox": [441.4, 962.86, 188.19, 84.43], "category_id": 2}, {"id": 7, "bbox": [1503.27, 563.57, 111.78, 91.27], "category_id": 2}, {"id": 8, "bbox": [0.0, 726.71, 380.95, 420.97], "category_id": 1}, {"id": 9, "bbox": [589.67, 595.52, 95.81, 82.14], "category_id": 2}, {"id": 10, "bbox": [1089.24, 28.52, 185.92, 222.46], "category_id": 1}, {"id": 11, "bbox": [1552.32, 836.23, 385.51, 341.11], "category_id": 1}, {"id": 12, "bbox": [891.93, 1746.62, 302.25, 201.92], "category_id": 1}], "caption": "Scheme 3. Three General Nucleophilic Substitution Mechanisms Considered for TcUP-Catalyzed Arsenolysis of Uridinea", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 419, 743, 440], "ImageBB": [137, 449, 707, 943]}, "reactions": [{"reactants": [10, 4], "conditions": [7], "products": [11, 3]}, {"reactants": [11, 3], "conditions": [], "products": [10, 4]}, {"reactants": [10, 4], "conditions": [], "products": [8, 6]}, {"reactants": [8, 6], "conditions": [9], "products": [10, 4]}, {"reactants": [8, 6], "conditions": [5], "products": [11, 3]}, {"reactants": [11, 3], "conditions": [], "products": [8, 6]}, {"reactants": [8, 6], "conditions": [], "products": [12, 2]}, {"reactants": [12, 2], "conditions": [1], "products": [8, 6]}, {"reactants": [12, 2], "conditions": [], "products": [11, 3]}, {"reactants": [11, 3], "conditions": [0], "products": [12, 2]}], "diagram_type": "graph"}, {"id": 1187, "width": 1344, "height": 668, "file_name": "ol402871f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1061.62, 234.48, 165.39, 143.11], "category_id": 1}, {"id": 1, "bbox": [1176.59, 172.0, 131.1, 40.98], "category_id": 2}, {"id": 2, "bbox": [432.98, 121.61, 69.26, 46.36], "category_id": 2}, {"id": 3, "bbox": [841.09, 38.3, 50.43, 43.67], "category_id": 2}, {"id": 4, "bbox": [342.89, 4.03, 81.35, 38.97], "category_id": 2}, {"id": 5, "bbox": [103.54, 32.25, 230.61, 99.44], "category_id": 1}, {"id": 6, "bbox": [434.33, 491.13, 76.65, 38.97], "category_id": 2}, {"id": 7, "bbox": [482.74, 262.03, 149.26, 98.09], "category_id": 1}, {"id": 8, "bbox": [36.3, 517.3, 266.92, 95.44], "category_id": 1}, {"id": 9, "bbox": [767.81, 260.01, 163.38, 116.23], "category_id": 1}, {"id": 10, "bbox": [666.96, 272.1, 55.13, 37.63], "category_id": 2}, {"id": 11, "bbox": [371.97, 406.43, 41.56, 39.53], "category_id": 2}, {"id": 12, "bbox": [998.42, 28.89, 258.85, 96.08], "category_id": 1}, {"id": 13, "bbox": [556.69, 32.25, 182.21, 101.45], "category_id": 1}, {"id": 14, "bbox": [909.0, 449.48, 264.23, 166.62], "category_id": 1}, {"id": 15, "bbox": [485.43, 474.33, 270.95, 141.77], "category_id": 1}, {"id": 16, "bbox": [317.34, 491.8, 71.94, 38.3], "category_id": 2}], "caption": "Scheme 4. Plausible Reaction Mechanism", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 89, 659, 102], "ImageBB": [437, 113, 773, 280]}, "reactions": [{"reactants": [5, 4], "conditions": [], "products": [2, 13]}, {"reactants": [13, 3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [1, 0]}, {"reactants": [7], "conditions": [10], "products": [9]}, {"reactants": [9, 0], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [], "products": [15]}, {"reactants": [15, 6], "conditions": [], "products": [16, 8]}, {"reactants": [8], "conditions": [11], "products": [15]}], "diagram_type": "graph"}, {"id": 87, "width": 1344, "height": 1024, "file_name": "ja0547477-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [542.14, 92.33, 179.49, 34.27], "category_id": 2}, {"id": 1, "bbox": [715.91, 30.26, 493.52, 316.03], "category_id": 1}, {"id": 2, "bbox": [131.3, 6.68, 476.14, 363.19], "category_id": 1}, {"id": 3, "bbox": [964.91, 305.33, 65.79, 34.75], "category_id": 3}, {"id": 4, "bbox": [328.17, 320.23, 62.06, 34.75], "category_id": 3}, {"id": 5, "bbox": [3.45, 400.15, 1336.31, 613.91], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [0], "products": [1]}], "corefs": [[2, 4], [1, 3]], "caption": "Table 2. Optimization of Ring I Cyclization", "pdf": {"Page": 12, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 290, 76], "ImageBB": [74, 80, 410, 336]}, "diagram_type": "single"}, {"id": 196, "width": 1344, "height": 976, "file_name": "op0501242-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [415.2, 0.0, 212.8, 259.1], "category_id": 1}, {"id": 1, "bbox": [103.2, 3.0, 253.8, 190.0], "category_id": 1}, {"id": 2, "bbox": [599.9, 79.2, 211.1, 53.0], "category_id": 2}, {"id": 3, "bbox": [598.68, 141.29, 164.84, 57.57], "category_id": 2}, {"id": 4, "bbox": [854.0, 3.0, 392.0, 257.0], "category_id": 1}, {"id": 5, "bbox": [190.0, 298.0, 30.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [509.0, 298.0, 29.0, 39.0], "category_id": 3}, {"id": 7, "bbox": [1038.0, 299.0, 98.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [3.0, 386.0, 1341.0, 588.0], "category_id": 4}], "reactions": [{"reactants": [1, 0], "conditions": [2, 3], "products": [4]}], "corefs": [[1, 5], [0, 6], [4, 7]], "caption": "Table 2. Coupling reactions of primary anilines with 2-fluorobenzoic acids in THF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 444, 364, 472], "ImageBB": [74, 476, 410, 720]}, "diagram_type": "single"}, {"id": 530, "width": 1348, "height": 2176, "file_name": "jo000745n-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [459.0, 51.0, 208.0, 57.0], "category_id": 2}, {"id": 1, "bbox": [799.0, 24.0, 269.0, 220.0], "category_id": 1}, {"id": 2, "bbox": [446.0, 148.0, 247.0, 110.0], "category_id": 2}, {"id": 3, "bbox": [843.0, 248.0, 118.0, 48.0], "category_id": 3}, {"id": 4, "bbox": [47.0, 311.0, 1262.0, 1796.0], "category_id": 4}, {"id": 5, "bbox": [99.0, 2121.0, 800.0, 51.0], "category_id": 2}, {"id": 6, "bbox": [289.0, 63.0, 111.0, 145.9], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [0, 2], "products": [1]}], "corefs": [[1, 3]], "caption": "         Table 5. Preparation of Protected  2-Iminoimidazolidines 48-66 by the DMC-Induced Cyclization of Thiourea Derivatives 28-41 and 43-47 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [452, 64, 762, 101], "ImageBB": [439, 103, 776, 647]}, "diagram_type": "single"}, {"id": 10, "width": 1352, "height": 1112, "file_name": "jacs.5b05415-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [193.4, 728.31, 53.65, 40.74], "category_id": 3}, {"id": 1, "bbox": [1134.65, 887.57, 191.4, 80.92], "category_id": 2}, {"id": 2, "bbox": [1146.13, 645.08, 172.75, 82.36], "category_id": 2}, {"id": 3, "bbox": [435.89, 907.66, 333.44, 85.22], "category_id": 2}, {"id": 4, "bbox": [420.1, 805.79, 369.32, 92.39], "category_id": 2}, {"id": 5, "bbox": [408.62, 670.91, 373.63, 47.92], "category_id": 2}, {"id": 6, "bbox": [401.45, 557.56, 369.32, 92.4], "category_id": 2}, {"id": 7, "bbox": [260.84, 158.67, 359.27, 79.49], "category_id": 2}, {"id": 8, "bbox": [260.84, 82.63, 370.75, 47.91], "category_id": 2}, {"id": 9, "bbox": [85.79, 587.69, 234.44, 128.27], "category_id": 1}, {"id": 10, "bbox": [1090.17, 45.32, 234.45, 171.31], "category_id": 1}, {"id": 11, "bbox": [863.47, 46.76, 171.31, 158.4], "category_id": 1}, {"id": 12, "bbox": [641.07, 61.11, 187.09, 149.78], "category_id": 1}, {"id": 13, "bbox": [22.65, 82.63, 234.45, 128.26], "category_id": 1}, {"id": 14, "bbox": [18.35, 287.8, 1317.74, 255.98], "category_id": 4}, {"id": 15, "bbox": [981.12, 998.06, 55.09, 42.14], "category_id": 3}, {"id": 16, "bbox": [174.75, 980.84, 53.65, 42.17], "category_id": 3}, {"id": 17, "bbox": [1174.83, 223.24, 53.65, 42.18], "category_id": 3}, {"id": 18, "bbox": [950.99, 223.24, 56.53, 42.18], "category_id": 3}, {"id": 19, "bbox": [744.38, 227.55, 52.22, 42.17], "category_id": 3}, {"id": 20, "bbox": [131.7, 213.2, 50.78, 40.74], "category_id": 3}, {"id": 21, "bbox": [877.82, 824.44, 233.01, 172.75], "category_id": 1}, {"id": 22, "bbox": [68.57, 844.53, 231.57, 129.7], "category_id": 1}, {"id": 23, "bbox": [877.82, 563.3, 255.96, 179.92], "category_id": 1}, {"id": 24, "bbox": [981.12, 738.35, 55.09, 40.74], "category_id": 3}], "reactions": [{"reactants": [13], "conditions": [8, 7], "products": [12, 11, 10]}, {"reactants": [9], "conditions": [6, 5], "products": [23]}, {"reactants": [22], "conditions": [4, 3], "products": [21]}], "corefs": [[13, 20], [12, 19], [11, 18], [10, 17], [9, 0], [23, 24], [22, 16], [21, 15]], "caption": "Figure 2. Fe/O2 as compatible conditions with gold catalysis.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 570, 375, 585], "ImageBB": [82, 283, 420, 561]}, "diagram_type": "multiple"}, {"id": 1311, "width": 1356, "height": 472, "file_name": "op3001788-Scheme-c18.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.69, 29.17, 81.4, 66.47], "category_id": 2}, {"id": 1, "bbox": [484.33, 228.6, 316.79, 177.72], "category_id": 1}, {"id": 2, "bbox": [1079.24, 2.03, 248.27, 159.41], "category_id": 1}, {"id": 3, "bbox": [569.8, 16.28, 250.31, 160.09], "category_id": 1}, {"id": 4, "bbox": [297.79, 87.5, 41.38, 52.91], "category_id": 3}, {"id": 5, "bbox": [29.17, 168.23, 312.03, 229.27], "category_id": 1}, {"id": 6, "bbox": [632.21, 379.19, 64.44, 48.84], "category_id": 3}, {"id": 7, "bbox": [166.19, 379.19, 62.41, 48.84], "category_id": 3}, {"id": 8, "bbox": [909.65, 226.56, 303.9, 164.16], "category_id": 1}], "caption": "Scheme 18. Proposed Origin of Chlorinated Byproducts in CPMA (1) ", "pdf": {"Page": 11, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 141, 782, 171], "ImageBB": [448, 178, 787, 296]}, "reactions": [{"reactants": [2], "conditions": [0], "products": [3]}, {"reactants": [3], "conditions": [], "products": [4]}, {"reactants": [2], "conditions": [0], "products": [8]}, {"reactants": [1], "conditions": [], "products": [5]}], "diagram_type": "tree"}, {"id": 283, "width": 1348, "height": 1192, "file_name": "ol8001706-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [641.0, 231.0, 59.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [221.0, 31.0, 316.0, 187.0], "category_id": 1}, {"id": 2, "bbox": [885.0, 0.0, 253.0, 220.0], "category_id": 1}, {"id": 3, "bbox": [588.0, 85.0, 159.0, 66.0], "category_id": 2}, {"id": 4, "bbox": [346.0, 236.0, 40.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [968.0, 234.0, 53.0, 61.0], "category_id": 3}, {"id": 6, "bbox": [0.0, 316.0, 1348.0, 876.0], "category_id": 4}], "reactions": [{"reactants": [1, 3], "conditions": [], "products": [2]}], "corefs": [[1, 4], [3, 0], [2, 5]], "caption": "Table 1. HDA Reaction between Diene 1 and Benzaldehyde Catalyzed by Ti/L4 under Various Conditionsa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 620, 760, 648], "ImageBB": [439, 658, 776, 956]}, "diagram_type": "single"}, {"id": 287, "width": 1352, "height": 3792, "file_name": "ol7028367-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [998.33, 35.8, 243.07, 211.6], "category_id": 1}, {"id": 1, "bbox": [51.7, 0.0, 214.3, 236.3], "category_id": 1}, {"id": 2, "bbox": [387.0, 103.0, 233.8, 66.3], "category_id": 1}, {"id": 3, "bbox": [668.0, 71.0, 210.0, 63.0], "category_id": 2}, {"id": 4, "bbox": [436.0, 224.0, 87.0, 47.0], "category_id": 3}, {"id": 5, "bbox": [0.0, 273.0, 1352.0, 3408.0], "category_id": 4}, {"id": 6, "bbox": [151.0, 214.0, 77.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [660.0, 158.0, 285.0, 60.0], "category_id": 2}, {"id": 8, "bbox": [977.0, 226.0, 91.0, 53.0], "category_id": 3}], "reactions": [{"reactants": [1, 2], "conditions": [3, 7], "products": [0]}], "corefs": [[1, 6], [2, 4], [0, 8]], "caption": "Table 1. Results of the Reaction of R,\u03b2-Unsaturated Ketoximes with Alkynesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 73, 717, 105], "ImageBB": [439, 105, 777, 1053]}, "diagram_type": "single"}, {"id": 349, "width": 1348, "height": 808, "file_name": "ol2017998-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [135.0, 250.0, 216.0, 59.0], "category_id": 2}, {"id": 1, "bbox": [396.0, 216.0, 394.0, 109.0], "category_id": 2}, {"id": 2, "bbox": [810.0, 207.0, 204.0, 47.0], "category_id": 2}, {"id": 3, "bbox": [1073.0, 207.0, 198.0, 44.0], "category_id": 2}, {"id": 4, "bbox": [8.0, 403.0, 1339.0, 405.0], "category_id": 4}, {"id": 5, "bbox": [1141.0, 258.0, 65.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [879.0, 256.0, 66.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [219.0, 201.0, 43.0, 45.0], "category_id": 3}, {"id": 8, "bbox": [747.1, 52.9, 309.0, 155.8], "category_id": 1}, {"id": 9, "bbox": [1073.3, 2.2, 217.7, 183.3], "category_id": 1}, {"id": 10, "bbox": [461.9, 4.0, 266.5, 157.0], "category_id": 2}, {"id": 11, "bbox": [60.1, 29.8, 396.1, 189.6], "category_id": 1}], "reactions": [{"reactants": [11], "conditions": [10, 1], "products": [8, 9]}], "corefs": [[11, 7], [8, 6], [9, 5]], "caption": "Table 1. Effect of Silanolate Nontransferable Group and Olefin Geometrya ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 154, 771, 181], "ImageBB": [436, 192, 773, 394]}, "diagram_type": "single"}, {"id": 265, "width": 1288, "height": 2192, "file_name": "ol8013717-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 0.0, 341.0, 243.0], "category_id": 1}, {"id": 1, "bbox": [514.0, 2135.0, 200.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [402.0, 93.0, 191.0, 61.0], "category_id": 2}, {"id": 3, "bbox": [779.73, 1411.0, 167.17, 65.5], "category_id": 3}, {"id": 4, "bbox": [766.0, 672.8, 199.7, 60.2], "category_id": 3}, {"id": 5, "bbox": [225.6, 1043.7, 180.6, 66.3], "category_id": 3}, {"id": 6, "bbox": [775.0, 1043.8, 187.1, 63.2], "category_id": 3}, {"id": 7, "bbox": [232.9, 1409.8, 175.5, 67.5], "category_id": 3}, {"id": 8, "bbox": [775.81, 1781.89, 185.39, 67.21], "category_id": 3}, {"id": 9, "bbox": [230.88, 1786.69, 178.12, 61.31], "category_id": 3}, {"id": 10, "bbox": [598.0, 14.0, 279.0, 97.2], "category_id": 2}, {"id": 11, "bbox": [612.0, 135.0, 247.0, 147.3], "category_id": 2}, {"id": 12, "bbox": [96.8, 1148.7, 433.7, 253.6], "category_id": 1}, {"id": 13, "bbox": [99.9, 1523.8, 501.1, 252.2], "category_id": 1}, {"id": 14, "bbox": [649.0, 1521.92, 502.3, 252.38], "category_id": 1}, {"id": 15, "bbox": [348.77, 1870.08, 516.63, 249.22], "category_id": 1}, {"id": 16, "bbox": [85.1, 246.5, 218.9, 52.5], "category_id": 3}, {"id": 17, "bbox": [1097.8, 248.6, 69.1, 47.6], "category_id": 3}, {"id": 18, "bbox": [226.5, 671.7, 183.0, 63.3], "category_id": 3}, {"id": 19, "bbox": [946.7, 0.0, 336.3, 243.0], "category_id": 1}, {"id": 20, "bbox": [393.0, 172.8, 196.3, 56.2], "category_id": 3}, {"id": 21, "bbox": [99.0, 415.0, 424.3, 248.0], "category_id": 1}, {"id": 22, "bbox": [94.0, 780.8, 487.2, 251.4], "category_id": 1}, {"id": 23, "bbox": [640.0, 406.0, 546.3, 257.0], "category_id": 1}, {"id": 24, "bbox": [646.7, 1149.5, 446.6, 251.7], "category_id": 1}, {"id": 25, "bbox": [649.0, 779.7, 484.4, 252.5], "category_id": 1}], "reactions": [{"reactants": [0, 2], "conditions": [10, 11], "products": [19]}], "corefs": [[0, 16], [2, 20], [19, 17], [21, 18], [23, 4], [22, 5], [25, 6], [12, 7], [24, 3], [13, 9], [14, 8], [15, 1]], "caption": "Table 2. Cross-Coupling of 1 and Arylboronic Acids (2)a", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 73, 357, 88], "ImageBB": [66, 94, 388, 642]}, "diagram_type": "single"}, {"id": 364, "width": 1348, "height": 388, "file_name": "ol102784c-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1077.0, 222.0, 44.0, 33.0], "category_id": 3}, {"id": 1, "bbox": [78.0, 162.0, 41.0, 33.0], "category_id": 3}, {"id": 2, "bbox": [263.0, 161.0, 44.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [764.0, 136.0, 45.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [1077.0, 74.0, 38.0, 43.0], "category_id": 3}, {"id": 5, "bbox": [2.0, 283.0, 1346.0, 104.0], "category_id": 4}, {"id": 6, "bbox": [920.2, 145.0, 363.6, 105.9], "category_id": 1}, {"id": 7, "bbox": [673.1, 52.0, 285.8, 106.8], "category_id": 1}, {"id": 8, "bbox": [171.1, 48.3, 185.9, 106.7], "category_id": 1}, {"id": 9, "bbox": [352.1, 31.0, 293.6, 76.0], "category_id": 2}, {"id": 10, "bbox": [372.0, 112.0, 254.0, 38.0], "category_id": 2}, {"id": 11, "bbox": [992.1, 3.0, 209.9, 95.0], "category_id": 1}, {"id": 12, "bbox": [59.3, 45.4, 117.7, 102.6], "category_id": 1}], "reactions": [{"reactants": [12, 8], "conditions": [9, 10], "products": [7, 11, 6]}], "corefs": [[12, 1], [8, 2], [7, 3], [11, 4], [6, 0]], "caption": "Table 4. Cross-Coupling of Aryl Iodides Catalyzed by Cua", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 731, 88], "ImageBB": [425, 97, 762, 194]}, "diagram_type": "single"}, {"id": 1229, "width": 1232, "height": 1512, "file_name": "op010097p-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [995.53, 342.64, 177.77, 133.12], "category_id": 2}, {"id": 1, "bbox": [0.0, 565.77, 326.04, 312.39], "category_id": 1}, {"id": 2, "bbox": [857.85, 309.36, 43.88, 52.95], "category_id": 3}, {"id": 3, "bbox": [34.8, 1126.25, 271.57, 312.38], "category_id": 1}, {"id": 4, "bbox": [54.47, 856.22, 45.39, 49.16], "category_id": 3}, {"id": 5, "bbox": [680.83, 30.26, 283.68, 254.89], "category_id": 1}, {"id": 6, "bbox": [362.35, 638.38, 490.96, 59.76], "category_id": 2}, {"id": 7, "bbox": [133.9, 313.9, 45.39, 49.92], "category_id": 3}, {"id": 8, "bbox": [991.75, 846.39, 98.34, 63.53], "category_id": 3}, {"id": 9, "bbox": [925.93, 572.58, 221.65, 235.99], "category_id": 1}, {"id": 10, "bbox": [105.15, 1462.08, 38.58, 49.92], "category_id": 3}, {"id": 11, "bbox": [363.87, 742.01, 476.58, 103.62], "category_id": 2}, {"id": 12, "bbox": [991.75, 4.54, 236.02, 134.63], "category_id": 1}, {"id": 13, "bbox": [37.07, 37.06, 229.97, 235.24], "category_id": 1}, {"id": 14, "bbox": [351.76, 187.58, 254.18, 130.1], "category_id": 2}, {"id": 15, "bbox": [193.66, 947.74, 274.6, 123.29], "category_id": 2}, {"id": 16, "bbox": [400.18, 89.25, 111.96, 64.29], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [455, 74, 763, 452]}, "reactions": [{"reactants": [13], "conditions": [16, 14], "products": [5]}, {"reactants": [5], "conditions": [0], "products": [9]}, {"reactants": [9], "conditions": [6, 11], "products": [1]}, {"reactants": [1], "conditions": [15], "products": [3]}], "diagram_type": "tree"}, {"id": 706, "width": 1352, "height": 1436, "file_name": "ol035127i-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [77.0, 431.0, 1206.0, 842.0], "category_id": 4}, {"id": 1, "bbox": [149.0, 123.0, 308.0, 61.0], "category_id": 2}, {"id": 2, "bbox": [864.0, 0.0, 419.0, 428.0], "category_id": 1}, {"id": 3, "bbox": [454.0, 24.0, 434.0, 289.0], "category_id": 1}, {"id": 4, "bbox": [140.0, 190.0, 323.0, 102.0], "category_id": 2}, {"id": 5, "bbox": [83.0, 165.0, 39.0, 55.0], "category_id": 3}, {"id": 6, "bbox": [668.0, 319.0, 36.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [1102.0, 322.0, 39.0, 46.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 4], "products": [3, 2]}], "corefs": [[3, 6], [2, 7]], "caption": "Table 3. Tandem Cyclization of (Z,Z)-Diaryldienynes", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 676, 358, 689], "ImageBB": [73, 694, 411, 1053]}, "diagram_type": "single"}, {"id": 964, "width": 1260, "height": 500, "file_name": "ja0171299-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [446.26, 325.85, 289.95, 135.51], "category_id": 1}, {"id": 1, "bbox": [0.0, 0.0, 257.8, 272.28], "category_id": 1}, {"id": 2, "bbox": [598.17, 268.5, 38.45, 48.53], "category_id": 3}, {"id": 3, "bbox": [842.73, 311.36, 91.4, 50.42], "category_id": 2}, {"id": 4, "bbox": [429.87, 0.0, 262.85, 269.13], "category_id": 1}, {"id": 5, "bbox": [1123.85, 453.17, 38.45, 45.38], "category_id": 3}, {"id": 6, "bbox": [861.01, 237.61, 44.12, 44.75], "category_id": 2}, {"id": 7, "bbox": [947.99, 110.3, 308.23, 339.72], "category_id": 1}, {"id": 8, "bbox": [68.07, 325.85, 172.71, 135.51], "category_id": 1}, {"id": 9, "bbox": [325.87, 343.5, 39.08, 46.64], "category_id": 2}, {"id": 10, "bbox": [300.66, 156.31, 97.07, 51.68], "category_id": 2}, {"id": 11, "bbox": [598.17, 457.58, 48.53, 42.42], "category_id": 3}, {"id": 12, "bbox": [329.65, 78.15, 35.3, 46.01], "category_id": 2}, {"id": 13, "bbox": [298.77, 412.2, 98.96, 49.16], "category_id": 2}], "caption": "Scheme 6. Formation of Ethyl 3-(S-tert-butylsulfanyl)benzoate 9a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 382, 767, 395], "ImageBB": [451, 395, 766, 520]}, "reactions": [{"reactants": [1], "conditions": [12, 10], "products": [4]}, {"reactants": [8], "conditions": [9, 13], "products": [0]}, {"reactants": [4, 0], "conditions": [6, 3], "products": [7]}], "diagram_type": "tree"}, {"id": 333, "width": 2808, "height": 968, "file_name": "ol300387f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 314.0, 2808.0, 654.0], "category_id": 4}, {"id": 1, "bbox": [548.0, 226.0, 54.0, 56.0], "category_id": 3}, {"id": 2, "bbox": [1417.21, 229.59, 161.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [1130.6, 17.0, 205.4, 213.6], "category_id": 1}, {"id": 4, "bbox": [1192.6, 238.0, 117.4, 44.0], "category_id": 3}, {"id": 5, "bbox": [1727.38, 235.17, 54.0, 44.0], "category_id": 3}, {"id": 6, "bbox": [1967.79, 231.38, 117.0, 56.0], "category_id": 3}, {"id": 7, "bbox": [2156.4, 90.8, 193.3, 93.6], "category_id": 4}, {"id": 8, "bbox": [1373.0, 26.0, 202.1, 202.8], "category_id": 1}, {"id": 9, "bbox": [671.8, 160.0, 388.4, 59.0], "category_id": 2}, {"id": 10, "bbox": [460.9, 17.0, 177.8, 211.7], "category_id": 1}, {"id": 11, "bbox": [1912.4, 15.2, 178.2, 212.0], "category_id": 1}, {"id": 12, "bbox": [673.2, 0.0, 442.0, 130.6], "category_id": 2}, {"id": 13, "bbox": [1638.1, 13.2, 228.8, 215.3], "category_id": 1}], "reactions": [{"reactants": [10], "conditions": [12, 9], "products": [3, 8, 13, 11]}], "corefs": [[10, 1], [3, 4], [8, 2], [13, 5], [11, 6]], "caption": "Table 2. Rhodium-Catalyzed Addition of AlMe3 to 5-Substituted Cyclohex-2-enones", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 522, 102], "ImageBB": [71, 112, 773, 354]}, "diagram_type": "single"}, {"id": 798, "width": 1348, "height": 288, "file_name": "jo501006u-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 215.0, 1342.0, 73.0], "category_id": 4}, {"id": 1, "bbox": [347.68, 138.37, 194.17, 50.83], "category_id": 2}, {"id": 2, "bbox": [643.51, 49.92, 160.62, 56.93], "category_id": 1}, {"id": 3, "bbox": [817.35, 57.04, 159.6, 53.88], "category_id": 2}, {"id": 4, "bbox": [1121.0, 95.0, 144.0, 53.0], "category_id": 1}, {"id": 5, "bbox": [665.0, 134.1, 290.9, 49.8], "category_id": 2}, {"id": 6, "bbox": [636.0, 0.0, 224.0, 48.9], "category_id": 2}, {"id": 7, "bbox": [329.0, 83.0, 221.0, 60.1], "category_id": 1}, {"id": 8, "bbox": [82.0, 83.0, 97.0, 60.0], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [6, 2, 3, 5], "products": [4]}], "corefs": [], "caption": "Table 2. Coupling Reaction of Alkyl (Pseudo)halides with n- BuMgCl Using 1,3-Butadiene as an Additivea ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 473, 784, 507], "ImageBB": [449, 514, 786, 586]}, "diagram_type": "single"}, {"id": 701, "width": 1352, "height": 2060, "file_name": "ol0362663-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [684.0, 155.0, 406.0, 83.0], "category_id": 2}, {"id": 1, "bbox": [1131.9, 50.9, 197.2, 169.2], "category_id": 1}, {"id": 2, "bbox": [10.0, 280.0, 1342.0, 1780.0], "category_id": 4}, {"id": 3, "bbox": [26.0, 84.0, 194.0, 86.0], "category_id": 1}, {"id": 4, "bbox": [509.0, 62.0, 183.0, 158.0], "category_id": 1}, {"id": 5, "bbox": [743.0, 9.0, 280.0, 127.0], "category_id": 2}, {"id": 6, "bbox": [222.0, 162.0, 266.0, 71.0], "category_id": 2}, {"id": 7, "bbox": [221.0, 41.0, 284.0, 92.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [7, 6], "products": [4]}, {"reactants": [4], "conditions": [5, 0], "products": [1]}], "corefs": [], "caption": "Table 2. Preparation of Enantiopure R-Hydroxyketones", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 73, 367, 90], "ImageBB": [73, 95, 411, 610]}, "diagram_type": "single"}, {"id": 1110, "width": 1200, "height": 1196, "file_name": "jo981397g-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [178.89, 670.31, 563.08, 436.27], "category_id": 1}, {"id": 1, "bbox": [452.08, 588.62, 35.89, 48.81], "category_id": 2}, {"id": 2, "bbox": [386.03, 588.62, 43.07, 50.25], "category_id": 2}, {"id": 3, "bbox": [588.47, 176.55, 35.9, 50.25], "category_id": 2}, {"id": 4, "bbox": [268.3, 182.29, 38.76, 43.08], "category_id": 2}, {"id": 5, "bbox": [249.63, 246.9, 84.71, 56.0], "category_id": 2}, {"id": 6, "bbox": [1050.53, 489.68, 70.83, 56.41], "category_id": 3}, {"id": 7, "bbox": [789.99, 909.15, 139.27, 55.81], "category_id": 2}, {"id": 8, "bbox": [105.05, 484.88, 51.03, 60.01], "category_id": 3}, {"id": 9, "bbox": [958.08, 672.71, 241.92, 438.68], "category_id": 1}, {"id": 10, "bbox": [421.41, 484.88, 70.84, 58.81], "category_id": 3}, {"id": 11, "bbox": [941.27, 54.61, 255.13, 359.46], "category_id": 1}, {"id": 12, "bbox": [842.22, 834.14, 45.02, 48.01], "category_id": 2}, {"id": 13, "bbox": [1048.12, 1136.59, 75.04, 55.81], "category_id": 3}, {"id": 14, "bbox": [729.36, 484.88, 75.64, 63.01], "category_id": 3}, {"id": 15, "bbox": [662.13, 2.4, 205.3, 463.28], "category_id": 1}, {"id": 16, "bbox": [425.01, 1136.59, 74.44, 55.81], "category_id": 3}, {"id": 17, "bbox": [344.57, 14.4, 229.92, 437.48], "category_id": 1}, {"id": 18, "bbox": [0.0, 15.0, 230.52, 437.48], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [91, 84, 391, 383]}, "reactions": [{"reactants": [18], "conditions": [4, 5], "products": [17]}, {"reactants": [17], "conditions": [3], "products": [15, 11]}, {"reactants": [0], "conditions": [2, 1], "products": [17]}, {"reactants": [9], "conditions": [12, 7], "products": [0]}], "diagram_type": "tree"}, {"id": 670, "width": 1348, "height": 1636, "file_name": "ol401881n-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [834.3, 0.0, 367.9, 239.1], "category_id": 1}, {"id": 1, "bbox": [548.78, 162.0, 252.0, 62.0], "category_id": 2}, {"id": 2, "bbox": [147.5, 40.3, 389.9, 207.9], "category_id": 1}, {"id": 3, "bbox": [954.3, 237.0, 44.7, 52.6], "category_id": 3}, {"id": 4, "bbox": [599.9, 75.0, 153.2, 55.0], "category_id": 2}, {"id": 5, "bbox": [10.0, 344.0, 1338.0, 1292.0], "category_id": 4}, {"id": 6, "bbox": [291.0, 247.0, 46.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 1], "products": [0]}], "corefs": [[2, 6], [0, 3]], "caption": "Table 2. DABCO-Catalyzed Anion Relay Leading to Functionalized 2,3-Dihydrofuransa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 354, 114], "ImageBB": [71, 126, 408, 535]}, "diagram_type": "single"}, {"id": 1058, "width": 1356, "height": 536, "file_name": "jo200877k-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [752.28, 88.85, 186.54, 148.53], "category_id": 1}, {"id": 1, "bbox": [408.36, 321.48, 69.19, 50.19], "category_id": 3}, {"id": 2, "bbox": [361.55, 61.72, 183.16, 155.99], "category_id": 1}, {"id": 3, "bbox": [0.0, 73.93, 136.35, 160.73], "category_id": 1}, {"id": 4, "bbox": [790.27, 321.48, 61.72, 48.15], "category_id": 3}, {"id": 5, "bbox": [21.03, 432.03, 388.69, 58.32], "category_id": 2}, {"id": 6, "bbox": [1024.29, 61.72, 139.06, 78.67], "category_id": 1}, {"id": 7, "bbox": [58.34, 320.8, 37.31, 48.15], "category_id": 3}, {"id": 8, "bbox": [1191.84, 198.04, 164.16, 185.83], "category_id": 1}, {"id": 9, "bbox": [607.11, 100.38, 61.73, 51.54], "category_id": 2}, {"id": 10, "bbox": [1204.73, 319.44, 38.67, 50.19], "category_id": 3}, {"id": 11, "bbox": [1191.84, 2.71, 153.98, 126.15], "category_id": 1}, {"id": 12, "bbox": [179.76, 181.09, 131.6, 44.08], "category_id": 2}, {"id": 13, "bbox": [217.07, 100.38, 52.91, 40.01], "category_id": 2}], "caption": "Scheme 2. Photolysis of 4", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 233, 219, 248], "ImageBB": [71, 258, 410, 392]}, "reactions": [{"reactants": [3], "conditions": [13, 12], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [0]}, {"reactants": [0], "conditions": [6], "products": [11, 8]}], "diagram_type": "single"}, {"id": 1328, "width": 2820, "height": 716, "file_name": "op400242j-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [655.98, 241.55, 49.37, 48.03], "category_id": 3}, {"id": 1, "bbox": [465.53, 5.65, 355.5, 220.36], "category_id": 1}, {"id": 2, "bbox": [1201.92, 4.24, 335.75, 221.77], "category_id": 1}, {"id": 3, "bbox": [1254.12, 387.05, 299.07, 214.71], "category_id": 1}, {"id": 4, "bbox": [1922.79, 0.0, 304.71, 224.6], "category_id": 1}, {"id": 5, "bbox": [904.26, 50.85, 239.82, 98.88], "category_id": 2}, {"id": 6, "bbox": [492.34, 532.54, 132.6, 96.06], "category_id": 2}, {"id": 7, "bbox": [1627.95, 67.8, 224.31, 53.68], "category_id": 2}, {"id": 8, "bbox": [701.12, 374.33, 296.25, 224.6], "category_id": 1}, {"id": 9, "bbox": [1048.15, 457.68, 125.56, 56.5], "category_id": 2}, {"id": 10, "bbox": [740.62, 615.89, 259.57, 55.09], "category_id": 2}, {"id": 11, "bbox": [907.08, 149.73, 191.86, 94.65], "category_id": 2}, {"id": 12, "bbox": [1630.78, 161.03, 189.03, 55.1], "category_id": 2}, {"id": 13, "bbox": [492.34, 442.14, 143.89, 55.09], "category_id": 2}, {"id": 14, "bbox": [1596.92, 476.04, 181.98, 49.44], "category_id": 2}, {"id": 15, "bbox": [1811.35, 310.77, 537.47, 363.03], "category_id": 1}], "caption": "Scheme 3. Discovery Chemistry\u2019s preparation of coupled intermediate analogues to 5", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 563, 110], "ImageBB": [82, 116, 787, 295]}, "reactions": [{"reactants": [1], "conditions": [5, 11], "products": [2]}, {"reactants": [2], "conditions": [7, 12], "products": [4]}, {"reactants": [4], "conditions": [13, 6], "products": [8]}, {"reactants": [8], "conditions": [9], "products": [3]}, {"reactants": [3], "conditions": [14], "products": [15]}], "diagram_type": "multiple"}, {"id": 796, "width": 2820, "height": 3068, "file_name": "jo501180a-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1275.0, 1231.0, 275.0, 76.0], "category_id": 2}, {"id": 1, "bbox": [1272.0, 482.0, 280.0, 55.0], "category_id": 2}, {"id": 2, "bbox": [1272.0, 421.0, 288.0, 55.0], "category_id": 2}, {"id": 3, "bbox": [1238.0, 1067.0, 333.0, 135.0], "category_id": 1}, {"id": 4, "bbox": [1000.0, 1682.0, 668.0, 510.0], "category_id": 1}, {"id": 5, "bbox": [1021.0, 2240.0, 592.0, 552.0], "category_id": 1}, {"id": 6, "bbox": [1586.0, 804.0, 844.0, 810.0], "category_id": 1}, {"id": 7, "bbox": [1896.0, 1396.0, 65.0, 58.0], "category_id": 3}, {"id": 8, "bbox": [388.0, 225.0, 841.0, 353.0], "category_id": 1}, {"id": 9, "bbox": [1251.0, 1297.0, 314.0, 57.0], "category_id": 2}, {"id": 10, "bbox": [1594.0, 2.0, 828.0, 802.0], "category_id": 1}, {"id": 11, "bbox": [1248.0, 2043.0, 71.0, 57.0], "category_id": 3}, {"id": 12, "bbox": [1261.0, 2614.0, 63.0, 63.0], "category_id": 3}, {"id": 13, "bbox": [1301.0, 529.0, 209.0, 65.0], "category_id": 2}, {"id": 14, "bbox": [1911.0, 568.0, 50.0, 63.0], "category_id": 3}, {"id": 15, "bbox": [1251.0, 246.0, 322.0, 133.0], "category_id": 1}, {"id": 16, "bbox": [786.0, 1402.0, 41.0, 57.0], "category_id": 3}, {"id": 17, "bbox": [386.0, 1033.0, 836.0, 350.0], "category_id": 1}, {"id": 18, "bbox": [793.0, 599.0, 45.0, 55.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [15, 2, 1, 13], "products": [10]}, {"reactants": [17], "conditions": [3, 0, 9], "products": [6]}], "corefs": [[8, 18], [10, 14], [17, 16], [6, 7], [4, 11], [5, 12]], "caption": "Figure 3. 1H NMR spectra (aliphatic region) of compounds 10 and 9 in CDCl3.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 890, 476, 907], "ImageBB": [82, 116, 787, 883]}, "diagram_type": "multiple"}, {"id": 462, "width": 1344, "height": 548, "file_name": "op200011x-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [16.0, 446.0, 1328.0, 102.0], "category_id": 4}, {"id": 1, "bbox": [49.3, 82.2, 223.6, 175.8], "category_id": 1}, {"id": 2, "bbox": [742.9, 254.95, 40.9, 44.05], "category_id": 3}, {"id": 3, "bbox": [315.1, 100.0, 38.9, 50.0], "category_id": 3}, {"id": 4, "bbox": [84.95, 248.08, 43.0, 55.0], "category_id": 3}, {"id": 5, "bbox": [1114.0, 253.0, 38.1, 46.0], "category_id": 3}, {"id": 6, "bbox": [1069.1, 77.0, 233.3, 237.7], "category_id": 1}, {"id": 7, "bbox": [702.3, 80.1, 257.3, 205.6], "category_id": 1}, {"id": 8, "bbox": [375.1, 5.0, 241.9, 134.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [8], "products": [7, 6]}], "corefs": [[1, 4], [8, 3], [7, 2], [6, 5]], "caption": "Table 1", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 481, 115, 496], "ImageBB": [71, 521, 407, 658]}, "diagram_type": "single"}, {"id": 1310, "width": 2820, "height": 944, "file_name": "op300171m-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1934.08, 501.05, 386.53, 210.3], "category_id": 1}, {"id": 1, "bbox": [1166.65, 172.19, 224.31, 56.46], "category_id": 2}, {"id": 2, "bbox": [533.76, 850.63, 176.51, 48.92], "category_id": 3}, {"id": 3, "bbox": [1426.22, 46.58, 382.3, 224.41], "category_id": 1}, {"id": 4, "bbox": [529.2, 801.68, 164.7, 47.02], "category_id": 3}, {"id": 5, "bbox": [2120.29, 374.02, 179.16, 101.63], "category_id": 2}, {"id": 6, "bbox": [839.37, 656.31, 380.89, 97.39], "category_id": 2}, {"id": 7, "bbox": [839.37, 567.39, 361.14, 59.28], "category_id": 2}, {"id": 8, "bbox": [490.93, 64.93, 283.55, 169.36], "category_id": 1}, {"id": 9, "bbox": [490.93, 262.52, 410.51, 611.15], "category_id": 1}, {"id": 10, "bbox": [1613.85, 285.11, 69.12, 50.81], "category_id": 3}, {"id": 11, "bbox": [1433.28, 396.61, 486.69, 153.84], "category_id": 1}, {"id": 12, "bbox": [1589.86, 588.56, 229.95, 57.87], "category_id": 2}, {"id": 13, "bbox": [1166.65, 67.75, 234.18, 60.69], "category_id": 2}, {"id": 14, "bbox": [1897.4, 4.23, 387.94, 245.59], "category_id": 1}, {"id": 15, "bbox": [1268.22, 832.73, 63.49, 55.05], "category_id": 3}, {"id": 16, "bbox": [1098.94, 280.87, 462.71, 612.56], "category_id": 1}, {"id": 17, "bbox": [2090.67, 275.23, 55.01, 50.81], "category_id": 3}, {"id": 18, "bbox": [836.55, 60.69, 303.3, 125.62], "category_id": 1}, {"id": 19, "bbox": [2120.29, 731.11, 60.66, 50.81], "category_id": 3}, {"id": 20, "bbox": [1778.9, 539.16, 46.55, 49.4], "category_id": 3}, {"id": 21, "bbox": [1589.86, 669.01, 228.54, 55.05], "category_id": 2}], "caption": "Scheme 2. Over-Reduction of Indole to Indoline under the Acidic Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 358, 521, 373], "ImageBB": [82, 116, 787, 352]}, "reactions": [{"reactants": [8, 18], "conditions": [13, 1], "products": [3, 14]}, {"reactants": [14], "conditions": [5], "products": [0]}, {"reactants": [0, 11], "conditions": [12, 21], "products": [16]}, {"reactants": [16], "conditions": [7, 6], "products": [9]}], "diagram_type": "tree"}, {"id": 1332, "width": 1352, "height": 1020, "file_name": "op400269b-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [37.2, 4.06, 128.5, 254.22], "category_id": 1}, {"id": 1, "bbox": [100.77, 932.36, 46.67, 43.95], "category_id": 3}, {"id": 2, "bbox": [1106.49, 294.79, 73.04, 50.03], "category_id": 3}, {"id": 3, "bbox": [359.14, 294.79, 80.48, 50.03], "category_id": 3}, {"id": 4, "bbox": [669.57, 436.77, 349.67, 117.64], "category_id": 1}, {"id": 5, "bbox": [591.12, 2.7, 298.26, 248.81], "category_id": 1}, {"id": 6, "bbox": [407.16, 425.95, 250.24, 54.77], "category_id": 2}, {"id": 7, "bbox": [359.14, 709.92, 153.52, 62.2], "category_id": 2}, {"id": 8, "bbox": [710.83, 297.49, 71.02, 46.65], "category_id": 3}, {"id": 9, "bbox": [1065.91, 4.06, 200.2, 250.83], "category_id": 1}, {"id": 10, "bbox": [194.79, 532.78, 60.19, 44.62], "category_id": 3}, {"id": 11, "bbox": [162.32, 66.94, 106.19, 50.7], "category_id": 2}, {"id": 12, "bbox": [1103.11, 932.36, 56.81, 47.33], "category_id": 3}, {"id": 13, "bbox": [906.97, 803.9, 84.54, 50.71], "category_id": 2}, {"id": 14, "bbox": [884.65, 690.31, 134.59, 84.52], "category_id": 2}, {"id": 15, "bbox": [827.84, 530.75, 60.19, 50.03], "category_id": 3}, {"id": 16, "bbox": [343.58, 4.06, 200.2, 250.83], "category_id": 1}, {"id": 17, "bbox": [63.58, 292.08, 58.84, 52.74], "category_id": 3}, {"id": 18, "bbox": [906.97, 140.63, 98.07, 52.74], "category_id": 2}, {"id": 19, "bbox": [620.2, 931.68, 52.76, 45.98], "category_id": 3}, {"id": 20, "bbox": [478.85, 495.59, 98.74, 50.71], "category_id": 2}, {"id": 21, "bbox": [544.45, 605.12, 291.5, 312.37], "category_id": 1}, {"id": 22, "bbox": [399.04, 803.22, 81.84, 47.33], "category_id": 2}, {"id": 23, "bbox": [884.65, 62.88, 153.53, 57.47], "category_id": 2}, {"id": 24, "bbox": [1065.91, 636.22, 252.95, 277.89], "category_id": 1}, {"id": 25, "bbox": [173.14, 139.96, 81.84, 50.03], "category_id": 2}, {"id": 26, "bbox": [516.05, 290.05, 118.36, 47.33], "category_id": 2}, {"id": 27, "bbox": [65.6, 430.01, 332.09, 116.29], "category_id": 1}, {"id": 28, "bbox": [1132.87, 413.78, 198.84, 140.63], "category_id": 2}, {"id": 29, "bbox": [16.23, 607.15, 292.86, 310.34], "category_id": 1}], "caption": "Scheme 4. Discovery Chemistry synthesis of 4 (Z = benzyloxycarbonyl) ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 374, 125], "ImageBB": [82, 131, 420, 386]}, "reactions": [{"reactants": [0], "conditions": [11, 25], "products": [16, 5]}, {"reactants": [16], "conditions": [23, 18], "products": [9]}, {"reactants": [27], "conditions": [6, 20], "products": [4]}, {"reactants": [4, 9], "conditions": [28], "products": [24]}, {"reactants": [24], "conditions": [14, 13], "products": [21]}, {"reactants": [21], "conditions": [7, 22], "products": [29]}], "diagram_type": "tree"}, {"id": 252, "width": 1352, "height": 1960, "file_name": "ol802556f-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [390.0, 120.0, 49.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [1126.0, 123.0, 49.0, 29.0], "category_id": 3}, {"id": 2, "bbox": [151.0, 113.0, 56.0, 29.0], "category_id": 3}, {"id": 3, "bbox": [72.0, 16.0, 212.0, 86.4], "category_id": 1}, {"id": 4, "bbox": [577.0, 68.6, 369.0, 55.4], "category_id": 2}, {"id": 5, "bbox": [1042.0, 4.0, 240.2, 96.3], "category_id": 1}, {"id": 6, "bbox": [585.0, 1.9, 342.0, 41.1], "category_id": 2}, {"id": 7, "bbox": [64.0, 195.0, 1255.0, 1707.0], "category_id": 4}, {"id": 8, "bbox": [321.6, 5.0, 183.6, 113.0], "category_id": 1}], "reactions": [{"reactants": [3, 8], "conditions": [6, 4], "products": [5]}], "corefs": [[3, 2], [8, 0], [5, 1]], "caption": "Table 2. Scope of Heterocyclic Boronates", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 276, 88], "ImageBB": [58, 97, 396, 587]}, "diagram_type": "single"}, {"id": 1028, "width": 1024, "height": 944, "file_name": "jo000585f-Scheme-c6.png", "license": 0, "bboxes": [{"id": 0, "bbox": [761.21, 536.27, 67.11, 53.27], "category_id": 3}, {"id": 1, "bbox": [683.86, 641.78, 340.14, 205.91], "category_id": 1}, {"id": 2, "bbox": [762.75, 229.46, 70.69, 49.69], "category_id": 3}, {"id": 3, "bbox": [0.0, 94.24, 60.45, 55.32], "category_id": 3}, {"id": 4, "bbox": [771.97, 880.47, 130.63, 57.36], "category_id": 3}, {"id": 5, "bbox": [205.93, 880.47, 130.11, 56.85], "category_id": 3}, {"id": 6, "bbox": [496.89, 804.66, 109.11, 56.34], "category_id": 2}, {"id": 7, "bbox": [106.55, 648.44, 343.21, 209.49], "category_id": 1}, {"id": 8, "bbox": [58.4, 473.78, 235.64, 53.78], "category_id": 2}, {"id": 9, "bbox": [462.06, 713.49, 175.19, 54.81], "category_id": 2}, {"id": 10, "bbox": [104.5, 135.73, 418.51, 122.93], "category_id": 2}, {"id": 11, "bbox": [639.81, 0.0, 336.55, 212.05], "category_id": 1}, {"id": 12, "bbox": [16.9, 405.15, 539.41, 60.95], "category_id": 2}, {"id": 13, "bbox": [639.81, 342.66, 341.16, 149.56], "category_id": 1}, {"id": 14, "bbox": [104.5, 61.98, 367.8, 56.34], "category_id": 2}], "caption": "Scheme 6", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 182, 270, 196], "ImageBB": [114, 200, 370, 436]}, "reactions": [{"reactants": [3], "conditions": [14, 10], "products": [11]}, {"reactants": [11], "conditions": [12, 8], "products": [13]}, {"reactants": [13], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [9], "products": [1]}], "diagram_type": "multiple"}, {"id": 275, "width": 1348, "height": 1260, "file_name": "ol8006106-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.37, 3.25, 503.13, 364.85], "category_id": 1}, {"id": 1, "bbox": [335.0, 314.0, 54.9, 52.9], "category_id": 3}, {"id": 2, "bbox": [12.0, 415.9, 1336.0, 844.1], "category_id": 4}, {"id": 3, "bbox": [1046.13, 316.0, 47.8, 48.0], "category_id": 3}, {"id": 4, "bbox": [767.87, 2.38, 511.93, 363.82], "category_id": 1}, {"id": 5, "bbox": [539.0, 327.0, 241.0, 73.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [], "products": [4]}], "corefs": [[0, 1], [4, 3]], "caption": "Table 2. Conditions Tested for the Oxidative Cyclization of 8 as Well as the Yields of 9 in These Reactions ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 746, 102], "ImageBB": [425, 111, 762, 426]}, "diagram_type": "single"}, {"id": 1261, "width": 2032, "height": 2812, "file_name": "op050151s-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [367.24, 938.27, 73.17, 59.08], "category_id": 3}, {"id": 1, "bbox": [160.41, 1291.35, 769.66, 409.35], "category_id": 1}, {"id": 2, "bbox": [0.0, 1339.18, 122.41, 66.12], "category_id": 2}, {"id": 3, "bbox": [748.56, 2088.95, 97.09, 59.09], "category_id": 3}, {"id": 4, "bbox": [1317.01, 1745.72, 671.18, 399.5], "category_id": 1}, {"id": 5, "bbox": [1526.67, 2730.41, 56.28, 52.05], "category_id": 3}, {"id": 6, "bbox": [1526.67, 2200.08, 36.58, 52.05], "category_id": 2}, {"id": 7, "bbox": [1317.01, 631.61, 593.79, 413.57], "category_id": 1}, {"id": 8, "bbox": [98.49, 1789.33, 43.62, 60.48], "category_id": 2}, {"id": 9, "bbox": [1246.66, 1453.12, 54.88, 64.71], "category_id": 2}, {"id": 10, "bbox": [1249.48, 1847.0, 59.09, 61.9], "category_id": 2}, {"id": 11, "bbox": [318.0, 1145.06, 50.65, 46.42], "category_id": 2}, {"id": 12, "bbox": [1317.01, 469.84, 60.51, 56.27], "category_id": 2}, {"id": 13, "bbox": [318.0, 2193.05, 35.17, 49.24], "category_id": 2}, {"id": 14, "bbox": [614.89, 419.2, 80.2, 54.86], "category_id": 3}, {"id": 15, "bbox": [975.1, 198.35, 46.43, 56.26], "category_id": 3}, {"id": 16, "bbox": [98.49, 2384.36, 765.45, 406.54], "category_id": 1}, {"id": 17, "bbox": [443.23, 270.09, 461.51, 163.17], "category_id": 1}, {"id": 18, "bbox": [747.15, 1676.79, 98.5, 61.9], "category_id": 3}, {"id": 19, "bbox": [1550.59, 1014.23, 64.72, 57.68], "category_id": 3}, {"id": 20, "bbox": [160.41, 1685.23, 757.0, 405.13], "category_id": 1}, {"id": 21, "bbox": [1934.72, 2081.92, 97.28, 63.3], "category_id": 3}, {"id": 22, "bbox": [98.49, 606.29, 711.98, 403.72], "category_id": 1}, {"id": 23, "bbox": [554.38, 547.21, 52.07, 47.83], "category_id": 2}, {"id": 24, "bbox": [1186.16, 1344.81, 129.45, 66.11], "category_id": 2}, {"id": 25, "bbox": [367.24, 2720.56, 73.17, 61.9], "category_id": 3}, {"id": 26, "bbox": [1380.63, 1309.74, 638.02, 391.59], "category_id": 1}, {"id": 27, "bbox": [1556.17, 1178.08, 40.51, 40.51], "category_id": 2}, {"id": 28, "bbox": [50.65, 1448.9, 53.47, 63.31], "category_id": 2}, {"id": 29, "bbox": [1934.72, 1645.84, 97.28, 66.12], "category_id": 3}, {"id": 30, "bbox": [1317.01, 2408.28, 658.51, 403.72], "category_id": 1}, {"id": 31, "bbox": [1246.66, 244.77, 189.96, 151.92], "category_id": 1}, {"id": 32, "bbox": [811.88, 0.0, 358.8, 272.9], "category_id": 1}, {"id": 33, "bbox": [1317.01, 402.32, 70.36, 50.64], "category_id": 3}], "caption": "Scheme 3. Efficient three-step prodrug synthesis using n-Bu3GeH as a highly stereoselective debromination reagenta", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 717, 68], "ImageBB": [171, 71, 679, 774]}, "reactions": [{"reactants": [32, 31], "conditions": [12], "products": [7]}, {"reactants": [7], "conditions": [27], "products": [26, 4]}, {"reactants": [4], "conditions": [6], "products": [30]}, {"reactants": [32, 17], "conditions": [23], "products": [22]}, {"reactants": [22], "conditions": [11], "products": [1, 20]}, {"reactants": [20], "conditions": [13], "products": [16]}], "diagram_type": "tree"}, {"id": 804, "width": 1352, "height": 352, "file_name": "jo500412w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1187.0, 214.0, 74.0, 39.0], "category_id": 3}, {"id": 1, "bbox": [17.0, 259.0, 1335.0, 93.0], "category_id": 4}, {"id": 2, "bbox": [449.2, 37.1, 237.9, 83.9], "category_id": 2}, {"id": 3, "bbox": [137.1, 212.1, 56.0, 35.0], "category_id": 3}, {"id": 4, "bbox": [1043.3, 6.1, 308.7, 196.7], "category_id": 1}, {"id": 5, "bbox": [706.1, 4.1, 303.9, 199.7], "category_id": 1}, {"id": 6, "bbox": [6.0, 15.3, 297.0, 195.7], "category_id": 1}, {"id": 7, "bbox": [852.1, 211.2, 62.5, 34.7], "category_id": 3}, {"id": 8, "bbox": [344.0, 101.0, 94.9, 47.9], "category_id": 2}, {"id": 9, "bbox": [453.0, 132.0, 188.7, 88.9], "category_id": 2}], "reactions": [{"reactants": [6, 8], "conditions": [2, 9], "products": [5, 4]}], "corefs": [[6, 3], [5, 7], [4, 0]], "caption": "Table 1. Condition Optimizations for Amidation Reactiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 303, 417, 324], "ImageBB": [82, 330, 420, 418]}, "diagram_type": "single"}, {"id": 496, "width": 1352, "height": 960, "file_name": "ol053021c-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 0.0, 319.0, 110.0], "category_id": 2}, {"id": 1, "bbox": [459.0, 130.0, 396.0, 105.4], "category_id": 2}, {"id": 2, "bbox": [10.0, 251.0, 1342.0, 709.0], "category_id": 4}, {"id": 3, "bbox": [259.9, 94.0, 118.1, 56.7], "category_id": 1}, {"id": 4, "bbox": [929.0, 94.0, 135.0, 58.1], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [4]}], "corefs": [], "caption": "Table 4. Direct Comparison of Azoles Arylation Conditionsa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 75, 762, 89], "ImageBB": [439, 98, 777, 338]}, "diagram_type": "single"}, {"id": 710, "width": 2816, "height": 1016, "file_name": "ol0348957-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [4.0, 257.0, 2809.0, 759.0], "category_id": 4}, {"id": 1, "bbox": [1747.0, 66.9, 217.0, 161.7], "category_id": 1}, {"id": 2, "bbox": [850.5, 65.0, 208.3, 156.0], "category_id": 1}, {"id": 3, "bbox": [1519.4, 7.0, 193.0, 130.6], "category_id": 1}, {"id": 4, "bbox": [1068.0, 76.1, 144.8, 67.9], "category_id": 2}, {"id": 5, "bbox": [1239.6, 38.7, 226.9, 183.6], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [3], "products": [1]}], "corefs": [], "caption": "Table 4. Key Experiments from CNRS Group Using 1 Equiv of Synthetic Aliphatic Fluoroketones", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 777, 591, 790], "ImageBB": [73, 799, 777, 1053]}, "diagram_type": "single"}, {"id": 277, "width": 1348, "height": 552, "file_name": "ol800527p-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [117.11, 216.62, 138.59, 121.37], "category_id": 2}, {"id": 1, "bbox": [36.0, 448.0, 1306.0, 102.0], "category_id": 4}, {"id": 2, "bbox": [919.33, 317.91, 52.17, 46.37], "category_id": 3}, {"id": 3, "bbox": [231.28, 154.7, 51.6, 42.7], "category_id": 3}, {"id": 4, "bbox": [99.5, 1.4, 180.0, 194.2], "category_id": 1}, {"id": 5, "bbox": [307.4, 18.8, 582.2, 397.1], "category_id": 1}, {"id": 6, "bbox": [943.4, 84.5, 379.6, 328.5], "category_id": 1}, {"id": 7, "bbox": [456.28, 329.42, 68.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [26.0, 185.0, 50.0, 51.0], "category_id": 3}], "reactions": [{"reactants": [8], "conditions": [4, 0], "products": [5, 6]}], "corefs": [[4, 3], [5, 7], [6, 2]], "caption": "Table 2. Optimization of the Pictet-Spengler Reaction", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 713, 711, 726], "ImageBB": [425, 736, 762, 874]}, "diagram_type": "single"}, {"id": 1081, "width": 2820, "height": 1108, "file_name": "jo501180a-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1743.63, 179.07, 263.8, 50.76], "category_id": 2}, {"id": 1, "bbox": [2192.24, 446.98, 259.57, 126.9], "category_id": 2}, {"id": 2, "bbox": [653.16, 43.71, 234.17, 101.52], "category_id": 2}, {"id": 3, "bbox": [620.71, 179.07, 299.07, 50.76], "category_id": 2}, {"id": 4, "bbox": [129.78, 4.23, 465.54, 311.61], "category_id": 1}, {"id": 5, "bbox": [93.11, 445.57, 259.57, 131.13], "category_id": 2}, {"id": 6, "bbox": [1747.86, 43.71, 232.77, 101.52], "category_id": 2}, {"id": 7, "bbox": [898.62, 0.0, 789.99, 313.02], "category_id": 1}, {"id": 8, "bbox": [2375.63, 1002.53, 142.48, 65.57], "category_id": 3}, {"id": 9, "bbox": [2076.56, 0.0, 619.3, 315.84], "category_id": 1}, {"id": 10, "bbox": [1747.86, 709.24, 238.41, 105.75], "category_id": 2}, {"id": 11, "bbox": [0.0, 655.66, 739.21, 317.26], "category_id": 1}, {"id": 12, "bbox": [342.35, 327.47, 40.41, 53.13], "category_id": 3}, {"id": 13, "bbox": [2437.15, 325.34, 44.66, 53.17], "category_id": 3}, {"id": 14, "bbox": [1067.9, 664.12, 605.2, 317.26], "category_id": 1}, {"id": 15, "bbox": [1724.71, 835.75, 306.24, 59.54], "category_id": 2}, {"id": 16, "bbox": [2471.56, 452.62, 255.33, 118.44], "category_id": 2}, {"id": 17, "bbox": [300.48, 988.43, 135.43, 63.45], "category_id": 3}, {"id": 18, "bbox": [2075.15, 668.35, 744.85, 314.44], "category_id": 1}, {"id": 19, "bbox": [1278.1, 1002.53, 45.14, 49.35], "category_id": 3}, {"id": 20, "bbox": [375.25, 452.62, 256.75, 102.93], "category_id": 2}, {"id": 21, "bbox": [898.62, 796.66, 69.12, 57.81], "category_id": 3}, {"id": 22, "bbox": [1241.42, 327.13, 139.66, 62.04], "category_id": 3}], "caption": "Scheme 2. Synthesis of Regioisomerically Pure 1,7-Dibromo-Substituted Compounds 4\u22128 from 3", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 583, 630, 598], "ImageBB": [82, 605, 787, 882]}, "reactions": [{"reactants": [4], "conditions": [5, 20], "products": [11]}, {"reactants": [7], "conditions": [2, 3], "products": [4]}, {"reactants": [7], "conditions": [6, 0], "products": [9]}, {"reactants": [9], "conditions": [1, 16], "products": [18]}, {"reactants": [18], "conditions": [10, 15], "products": [14]}, {"reactants": [14], "conditions": [], "products": [21]}], "diagram_type": "tree"}, {"id": 786, "width": 1356, "height": 1120, "file_name": "jo502408z-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [513.0, 15.0, 236.0, 231.5], "category_id": 1}, {"id": 1, "bbox": [798.0, 161.0, 310.0, 68.5], "category_id": 1}, {"id": 2, "bbox": [249.0, 149.0, 210.0, 136.0], "category_id": 2}, {"id": 3, "bbox": [1093.5, 1.0, 258.5, 315.0], "category_id": 1}, {"id": 4, "bbox": [828.0, 229.0, 219.0, 91.0], "category_id": 2}, {"id": 5, "bbox": [460.5, 835.0, 400.5, 285.0], "category_id": 2}, {"id": 6, "bbox": [839.5, 367.5, 366.5, 297.4], "category_id": 1}, {"id": 7, "bbox": [3.0, 29.0, 247.0, 211.5], "category_id": 1}, {"id": 8, "bbox": [164.0, 379.0, 566.0, 369.0], "category_id": 4}, {"id": 9, "bbox": [274.0, 66.0, 157.0, 62.0], "category_id": 2}, {"id": 10, "bbox": [807.0, 0.0, 270.0, 148.0], "category_id": 2}, {"id": 11, "bbox": [593.0, 280.0, 75.0, 54.0], "category_id": 3}, {"id": 12, "bbox": [69.0, 282.0, 71.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [939.0, 677.0, 68.0, 56.0], "category_id": 3}, {"id": 14, "bbox": [1164.0, 278.0, 68.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [9, 2], "products": [0]}, {"reactants": [0], "conditions": [10, 1, 4], "products": [3]}], "corefs": [[7, 12], [0, 11], [3, 14], [6, 13]], "caption": "Figure 1. Grotjahn\u2019s catalyst.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 850, 588, 864], "ImageBB": [448, 561, 787, 841]}, "diagram_type": "single"}, {"id": 1106, "width": 1344, "height": 2604, "file_name": "jo980181b-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [371.77, 1441.19, 275.09, 125.04], "category_id": 1}, {"id": 1, "bbox": [937.58, 884.75, 359.5, 262.59], "category_id": 1}, {"id": 2, "bbox": [497.61, 177.16, 149.81, 50.8], "category_id": 2}, {"id": 3, "bbox": [591.4, 986.11, 148.51, 54.71], "category_id": 2}, {"id": 4, "bbox": [497.61, 2396.88, 177.16, 119.84], "category_id": 2}, {"id": 5, "bbox": [732.09, 2231.44, 424.66, 298.31], "category_id": 1}, {"id": 6, "bbox": [612.8, 1789.84, 335.53, 333.48], "category_id": 1}, {"id": 7, "bbox": [780.29, 2128.53, 110.72, 57.32], "category_id": 2}, {"id": 8, "bbox": [0.0, 2207.99, 429.87, 325.67], "category_id": 1}, {"id": 9, "bbox": [0.0, 1905.78, 578.38, 56.01], "category_id": 2}, {"id": 10, "bbox": [0.0, 1959.19, 583.59, 61.22], "category_id": 2}, {"id": 11, "bbox": [0.0, 48.2, 381.68, 184.97], "category_id": 1}, {"id": 12, "bbox": [1081.2, 1163.27, 190.19, 143.29], "category_id": 3}, {"id": 13, "bbox": [594.01, 446.81, 338.69, 300.91], "category_id": 1}, {"id": 14, "bbox": [0.0, 1905.78, 573.17, 56.01], "category_id": 2}, {"id": 15, "bbox": [1081.2, 580.98, 65.13, 46.9], "category_id": 3}, {"id": 16, "bbox": [18.8, 876.68, 420.19, 304.82], "category_id": 1}, {"id": 17, "bbox": [1006.95, 647.42, 270.95, 58.62], "category_id": 2}, {"id": 18, "bbox": [1081.2, 1914.9, 36.47, 48.2], "category_id": 3}, {"id": 19, "bbox": [1003.04, 1973.52, 281.37, 54.71], "category_id": 2}, {"id": 20, "bbox": [907.95, 0.0, 363.44, 291.79], "category_id": 1}, {"id": 21, "bbox": [728.18, 745.12, 201.91, 145.89], "category_id": 3}, {"id": 22, "bbox": [1006.95, 293.1, 207.12, 145.89], "category_id": 3}, {"id": 23, "bbox": [969.4, 1822.2, 215.5, 92.4], "category_id": 1}, {"id": 24, "bbox": [396.01, 24.75, 277.46, 134.17], "category_id": 1}, {"id": 25, "bbox": [161.53, 1177.6, 388.19, 158.92], "category_id": 3}, {"id": 26, "bbox": [1207.56, 1839.34, 126.35, 80.77], "category_id": 2}, {"id": 27, "bbox": [960.05, 2557.1, 74.26, 46.9], "category_id": 3}, {"id": 28, "bbox": [591.4, 1052.54, 141.99, 46.9], "category_id": 2}, {"id": 29, "bbox": [0.0, 1408.17, 359.8, 218.84], "category_id": 1}, {"id": 30, "bbox": [30.2, 626.58, 537.76, 59.42], "category_id": 2}, {"id": 31, "bbox": [960.05, 478.07, 234.48, 105.52], "category_id": 1}, {"id": 32, "bbox": [160.23, 2540.17, 337.38, 63.83], "category_id": 3}, {"id": 33, "bbox": [537.99, 1584.02, 153.72, 48.2], "category_id": 2}, {"id": 34, "bbox": [492.4, 2334.35, 199.31, 53.41], "category_id": 2}, {"id": 35, "bbox": [122.45, 235.78, 230.57, 140.69], "category_id": 3}, {"id": 36, "bbox": [1220.1, 504.13, 106.0, 62.77], "category_id": 2}, {"id": 37, "bbox": [907.95, 1396.44, 349.65, 329.56], "category_id": 1}, {"id": 38, "bbox": [34.15, 572.15, 456.41, 56.27], "category_id": 2}, {"id": 39, "bbox": [665.62, 109.49, 250.08, 53.15], "category_id": 2}, {"id": 40, "bbox": [1087.63, 1728.79, 96.91, 50.01], "category_id": 2}, {"id": 41, "bbox": [665.62, 1516.22, 212.57, 53.14], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [75, 84, 411, 735]}, "reactions": [{"reactants": [11, 24], "conditions": [39, 2], "products": [20]}, {"reactants": [20], "conditions": [38, 30], "products": [13]}, {"reactants": [13, 31], "conditions": [36, 17], "products": [16]}, {"reactants": [16], "conditions": [3, 28], "products": [1]}, {"reactants": [29, 0], "conditions": [41, 33], "products": [37]}, {"reactants": [37], "conditions": [14, 10], "products": [6]}, {"reactants": [6, 23], "conditions": [26, 19], "products": [8]}, {"reactants": [8], "conditions": [34, 4], "products": [5]}], "diagram_type": "multiple"}, {"id": 652, "width": 1348, "height": 324, "file_name": "ol5000692-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [283.4, 5.3, 221.6, 190.7], "category_id": 1}, {"id": 1, "bbox": [311.0, 178.6, 45.0, 50.4], "category_id": 3}, {"id": 2, "bbox": [5.0, 250.1, 1343.0, 73.9], "category_id": 4}, {"id": 3, "bbox": [794.8, 5.6, 272.2, 173.0], "category_id": 1}, {"id": 4, "bbox": [870.0, 183.0, 56.0, 48.0], "category_id": 3}, {"id": 5, "bbox": [547.0, 101.0, 225.0, 87.0], "category_id": 2}, {"id": 6, "bbox": [555.0, 27.0, 154.0, 56.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [6, 5], "products": [3]}], "corefs": [[0, 1], [3, 4]], "caption": "Table 1. Optimization Study for 1-Catalyzed Cyclization of 2a to 3aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 415, 125], "ImageBB": [82, 131, 419, 212]}, "diagram_type": "single"}, {"id": 471, "width": 1356, "height": 780, "file_name": "op100202j-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.3, 358.1, 450.3, 80.8], "category_id": 1}, {"id": 1, "bbox": [685.1, 28.0, 662.6, 239.0], "category_id": 1}, {"id": 2, "bbox": [825.8, 234.6, 253.2, 234.9], "category_id": 1}, {"id": 3, "bbox": [93.5, 3.0, 255.8, 236.2], "category_id": 1}, {"id": 4, "bbox": [481.0, 425.5, 875.0, 354.5], "category_id": 1}, {"id": 5, "bbox": [435.23, 30.23, 114.2, 56.5], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [5], "products": [1]}, {"reactants": [1], "conditions": [2], "products": [4]}], "corefs": [], "caption": "Table 3. Some typical values of absorption bands in the IR spectra of 6-isopropylisocytosine and 6-phenylisocytosine ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 286, 751, 313], "ImageBB": [424, 79, 763, 274]}, "diagram_type": "tree"}, {"id": 371, "width": 1348, "height": 992, "file_name": "ol1022036-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1152.0, 282.0, 71.0, 45.0], "category_id": 2}, {"id": 1, "bbox": [458.0, 15.0, 196.0, 82.0], "category_id": 2}, {"id": 2, "bbox": [1.0, 353.0, 1343.0, 639.0], "category_id": 4}, {"id": 3, "bbox": [216.0, 161.0, 178.8, 52.0], "category_id": 1}, {"id": 4, "bbox": [30.0, 89.6, 146.0, 121.1], "category_id": 1}, {"id": 5, "bbox": [1061.6, 108.6, 257.4, 150.4], "category_id": 1}, {"id": 6, "bbox": [471.0, 226.0, 158.3, 48.0], "category_id": 2}, {"id": 7, "bbox": [46.0, 282.0, 76.7, 37.0], "category_id": 2}, {"id": 8, "bbox": [764.0, 211.0, 209.7, 79.4], "category_id": 2}, {"id": 9, "bbox": [818.0, 2.0, 118.0, 41.7], "category_id": 1}, {"id": 10, "bbox": [758.0, 50.3, 222.0, 54.7], "category_id": 2}], "reactions": [{"reactants": [4, 3, 1, 9, 10], "conditions": [6, 8], "products": [5]}], "corefs": [[4, 7], [5, 0]], "caption": "Table 3. One-Pot, Three-Step Synthesis of 1-Substituted 4-Acyl-1H-1,2,3-triazoles 7a-e ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 75, 717, 102], "ImageBB": [425, 111, 762, 359]}, "diagram_type": "tree"}, {"id": 444, "width": 1344, "height": 1116, "file_name": "op200174k-Table-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 343.0, 1343.0, 773.0], "category_id": 4}, {"id": 1, "bbox": [644.0, 133.0, 260.0, 136.0], "category_id": 2}, {"id": 2, "bbox": [660.0, 11.0, 239.0, 100.1], "category_id": 2}, {"id": 3, "bbox": [356.5, 56.5, 265.0, 171.5], "category_id": 1}, {"id": 4, "bbox": [1062.5, 249.88, 71.81, 55.35], "category_id": 3}, {"id": 5, "bbox": [953.0, 44.5, 366.0, 203.0], "category_id": 1}, {"id": 6, "bbox": [25.4, 2.0, 284.6, 196.5], "category_id": 1}], "reactions": [{"reactants": [6, 3], "conditions": [2, 1], "products": [5]}], "corefs": [[5, 4]], "caption": "Table 8. E\ufb00ect of Added Tertiary Amine Base on Model Reaction Performancea ", "pdf": {"Page": 7, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 750, 122], "ImageBB": [437, 133, 773, 412]}, "diagram_type": "single"}, {"id": 108, "width": 1348, "height": 1100, "file_name": "ja001164i-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [546.61, 269.48, 331.84, 44.61], "category_id": 2}, {"id": 1, "bbox": [1032.69, 422.56, 169.29, 43.04], "category_id": 3}, {"id": 2, "bbox": [614.47, 5.92, 200.85, 189.8], "category_id": 1}, {"id": 3, "bbox": [1026.38, 204.77, 181.91, 188.23], "category_id": 1}, {"id": 4, "bbox": [6.26, 541.64, 1337.61, 555.55], "category_id": 4}, {"id": 5, "bbox": [248.3, 420.98, 46.22, 36.72], "category_id": 3}, {"id": 6, "bbox": [710.27, 219.45, 25.67, 31.98], "category_id": 3}, {"id": 7, "bbox": [140.67, 456.0, 260.0, 52.0], "category_id": 2}, {"id": 8, "bbox": [177.31, 204.77, 185.07, 188.23], "category_id": 1}, {"id": 9, "bbox": [570.28, 351.54, 270.29, 115.63], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [2, 0, 9], "products": [3]}], "corefs": [[8, 5], [2, 6], [3, 1]], "caption": "Table 5. Chiral LBA-catalyzed Enantioselective Protonation of 3aa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 64, 774, 78], "ImageBB": [439, 86, 776, 362]}, "diagram_type": "single"}, {"id": 1297, "width": 2820, "height": 780, "file_name": "op200313v-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [613.5, 166.33, 100.32, 59.2], "category_id": 2}, {"id": 1, "bbox": [1919.97, 625.85, 224.3, 63.43], "category_id": 2}, {"id": 2, "bbox": [435.91, 291.78, 56.43, 53.56], "category_id": 3}, {"id": 3, "bbox": [873.23, 297.42, 52.19, 50.74], "category_id": 3}, {"id": 4, "bbox": [1122.92, 356.62, 292.02, 60.61], "category_id": 2}, {"id": 5, "bbox": [1127.15, 0.0, 239.82, 215.66], "category_id": 2}, {"id": 6, "bbox": [634.82, 467.98, 572.74, 243.85], "category_id": 1}, {"id": 7, "bbox": [399.23, 427.1, 273.68, 121.22], "category_id": 2}, {"id": 8, "bbox": [808.33, 46.52, 266.63, 238.21], "category_id": 1}, {"id": 9, "bbox": [922.6, 683.64, 57.84, 57.79], "category_id": 3}, {"id": 10, "bbox": [434.5, 583.56, 136.84, 73.3], "category_id": 2}, {"id": 11, "bbox": [605.19, 12.69, 125.56, 98.67], "category_id": 2}, {"id": 12, "bbox": [1783.13, 138.14, 150.95, 129.68], "category_id": 2}, {"id": 13, "bbox": [397.82, 14.1, 181.98, 239.62], "category_id": 1}, {"id": 14, "bbox": [1783.13, 649.81, 53.61, 59.2], "category_id": 3}, {"id": 15, "bbox": [1283.74, 459.52, 126.97, 114.17], "category_id": 2}, {"id": 16, "bbox": [1413.53, 46.52, 348.44, 245.26], "category_id": 1}, {"id": 17, "bbox": [1125.74, 249.49, 197.5, 100.08], "category_id": 2}, {"id": 18, "bbox": [1502.4, 427.1, 582.62, 243.85], "category_id": 1}, {"id": 19, "bbox": [2223.27, 291.78, 55.02, 52.15], "category_id": 3}, {"id": 20, "bbox": [1783.13, 33.83, 131.2, 64.84], "category_id": 2}, {"id": 21, "bbox": [1623.72, 259.36, 46.56, 53.56], "category_id": 3}, {"id": 22, "bbox": [1972.17, 67.66, 452.83, 245.26], "category_id": 1}, {"id": 23, "bbox": [1303.49, 600.48, 152.36, 128.27], "category_id": 2}], "caption": "Scheme 1. Medicinal chemistry route to A-ring fragment of CEP-28122", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 485, 110], "ImageBB": [82, 116, 787, 311]}, "reactions": [{"reactants": [13], "conditions": [11, 0], "products": [8]}, {"reactants": [8], "conditions": [5, 17, 4], "products": [16]}, {"reactants": [16], "conditions": [20, 12], "products": [22]}, {"reactants": [22], "conditions": [7, 10], "products": [6]}, {"reactants": [6], "conditions": [15, 23], "products": [18]}], "diagram_type": "multiple"}, {"id": 723, "width": 1296, "height": 1008, "file_name": "ol0171867-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [361.0, 76.0, 306.0, 113.0], "category_id": 2}, {"id": 1, "bbox": [29.0, 170.0, 122.0, 58.0], "category_id": 1}, {"id": 2, "bbox": [9.0, 349.0, 1287.0, 659.0], "category_id": 4}, {"id": 3, "bbox": [367.0, 210.0, 276.0, 114.0], "category_id": 2}, {"id": 4, "bbox": [938.0, 9.0, 294.0, 196.0], "category_id": 1}, {"id": 5, "bbox": [215.0, 106.0, 125.0, 173.0], "category_id": 1}, {"id": 6, "bbox": [724.0, 105.0, 170.0, 166.0], "category_id": 1}, {"id": 7, "bbox": [947.0, 205.0, 304.0, 88.0], "category_id": 3}], "reactions": [{"reactants": [1, 5], "conditions": [0, 3], "products": [6]}], "corefs": [[4, 7]], "caption": "Table 4. Copper-Catalyzed Amination of Aryl Bromides", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 740, 89], "ImageBB": [446, 91, 770, 343]}, "diagram_type": "single"}, {"id": 12, "width": 1344, "height": 800, "file_name": "ja9810742-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [612.17, 106.36, 169.22, 43.29], "category_id": 2}, {"id": 1, "bbox": [619.39, 27.91, 155.81, 45.35], "category_id": 2}, {"id": 2, "bbox": [806.23, 2.1, 277.62, 183.68], "category_id": 1}, {"id": 3, "bbox": [364.43, 10.36, 235.29, 171.29], "category_id": 1}, {"id": 4, "bbox": [935.26, 184.81, 37.1, 37.1], "category_id": 3}, {"id": 5, "bbox": [467.65, 185.84, 37.1, 40.2], "category_id": 3}, {"id": 6, "bbox": [244.68, 75.39, 52.58, 41.23], "category_id": 3}, {"id": 7, "bbox": [2.1, 310.75, 1337.75, 483.03], "category_id": 4}, {"id": 8, "bbox": [811.39, 232.3, 281.74, 44.32], "category_id": 2}], "reactions": [{"reactants": [6, 3], "conditions": [1, 0], "products": [2]}], "corefs": [[3, 5], [2, 4]], "caption": "Table 3. Allylation of 3-Phenylpropanal 1a with Homoallylic Alcohols 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 544, 385, 569], "ImageBB": [74, 570, 410, 770]}, "diagram_type": "single"}, {"id": 350, "width": 1204, "height": 1048, "file_name": "ol2017438-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [468.0, 145.0, 241.0, 86.1], "category_id": 2}, {"id": 1, "bbox": [3.0, 400.0, 1201.0, 648.0], "category_id": 4}, {"id": 2, "bbox": [14.0, 3.0, 395.0, 249.0], "category_id": 1}, {"id": 3, "bbox": [993.0, 19.0, 211.0, 224.0], "category_id": 1}, {"id": 4, "bbox": [418.0, 29.9, 331.0, 81.1], "category_id": 2}, {"id": 5, "bbox": [767.1, 19.0, 208.9, 221.2], "category_id": 1}, {"id": 6, "bbox": [116.0, 254.0, 48.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [820.0, 250.0, 106.0, 46.0], "category_id": 3}, {"id": 8, "bbox": [1029.0, 250.0, 126.0, 43.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [4, 0], "products": [5, 3]}], "corefs": [[2, 6], [5, 7], [3, 8]], "caption": "Table 3. Amplified Diastereoselective Aza-[3 \u00fe 3] Annulationa", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 769, 103], "ImageBB": [454, 112, 755, 374]}, "diagram_type": "single"}, {"id": 519, "width": 1332, "height": 1096, "file_name": "jo011082s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [192.0, 559.0, 283.0, 129.9], "category_id": 1}, {"id": 1, "bbox": [392.0, 193.0, 177.0, 128.0], "category_id": 1}, {"id": 2, "bbox": [635.0, 81.0, 283.0, 212.5], "category_id": 1}, {"id": 3, "bbox": [0.0, 95.5, 358.0, 205.5], "category_id": 1}, {"id": 4, "bbox": [141.0, 571.0, 51.0, 59.0], "category_id": 2}, {"id": 5, "bbox": [144.5, 485.0, 373.5, 62.0], "category_id": 2}, {"id": 6, "bbox": [364.0, 78.0, 273.0, 99.6], "category_id": 2}, {"id": 7, "bbox": [25.0, 288.8, 312.0, 183.2], "category_id": 3}, {"id": 8, "bbox": [363.8, 203.62, 52.5, 54.08], "category_id": 2}, {"id": 9, "bbox": [944.0, 127.0, 121.0, 55.0], "category_id": 2}, {"id": 10, "bbox": [172.0, 981.0, 49.0, 50.0], "category_id": 3}, {"id": 11, "bbox": [318.0, 685.0, 45.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [412.0, 789.0, 112.0, 63.0], "category_id": 2}, {"id": 13, "bbox": [557.0, 1032.0, 675.0, 64.0], "category_id": 2}, {"id": 14, "bbox": [1151.0, 281.0, 48.0, 46.0], "category_id": 3}, {"id": 15, "bbox": [762.0, 295.0, 46.0, 60.0], "category_id": 3}, {"id": 16, "bbox": [611.0, 971.0, 104.0, 60.0], "category_id": 3}, {"id": 17, "bbox": [1049.0, 968.0, 171.0, 61.0], "category_id": 3}, {"id": 18, "bbox": [1077.0, 97.0, 252.0, 195.0], "category_id": 1}, {"id": 19, "bbox": [975.0, 724.0, 279.0, 240.0], "category_id": 1}, {"id": 20, "bbox": [526.0, 724.0, 275.0, 233.0], "category_id": 1}, {"id": 21, "bbox": [42.0, 738.0, 302.0, 243.0], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [6, 8, 1], "products": [2]}, {"reactants": [2], "conditions": [9], "products": [18]}, {"reactants": [3], "conditions": [5, 4, 0], "products": [21]}, {"reactants": [21], "conditions": [12], "products": [20, 19]}], "corefs": [[3, 7], [2, 15], [18, 14], [0, 4], [21, 10], [20, 16], [19, 17]], "caption": "Table 1. 3,4,6-Trisubstituted 3,4-Dihydropyran-2-ones 6                          and 7 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [78, 348, 403, 373], "ImageBB": [76, 63, 409, 337]}, "diagram_type": "tree"}, {"id": 870, "width": 1344, "height": 936, "file_name": "jo0524728-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [922.0, 837.0, 232.0, 99.0], "category_id": 3}, {"id": 1, "bbox": [875.5, 477.1, 312.4, 329.7], "category_id": 1}, {"id": 2, "bbox": [32.3, 460.8, 307.8, 369.7], "category_id": 1}, {"id": 3, "bbox": [0.0, 0.0, 310.0, 378.0], "category_id": 1}, {"id": 4, "bbox": [447.2, 477.9, 307.7, 326.7], "category_id": 1}, {"id": 5, "bbox": [358.5, 217.0, 248.7, 135.0], "category_id": 2}, {"id": 6, "bbox": [126.0, 384.0, 74.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [157.0, 843.0, 78.0, 55.0], "category_id": 3}, {"id": 8, "bbox": [507.0, 833.0, 232.0, 103.0], "category_id": 3}, {"id": 9, "bbox": [437.7, 146.9, 81.2, 51.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [9, 5], "products": [2, 4, 1]}], "corefs": [[3, 6], [2, 7], [4, 8], [1, 0]], "caption": "Table 1 it can be seen that the highest yields of products were obtained upon photolysis at 350 nm, while irradiation at 300 and 254 nm resulted mostly in recovery of the starting material. This observation can be rationalized by absorption of light (at 300 and 254 nm) by photoproducts which revert to the starting material by a photochemical reaction. After prolonged irradia- tion, a photostationary state is reached, determined by the ratio of absorption coefficients, and rates of interconversions, of products and the starting material. Thus, after irradiation of 8 at 350 nm where the products are formed with maximal efficiency, subsequent irradiation (of the same solution) at 300 or 254 nm gives back the starting material and hence a lower observed yield of photoproducts (Table 1). ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 347, 775, 544], "ImageBB": [440, 555, 776, 789]}, "diagram_type": "multiple"}, {"id": 380, "width": 1344, "height": 1188, "file_name": "ol071386m-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.4, 0.0, 258.6, 139.0], "category_id": 1}, {"id": 1, "bbox": [450.9, 223.0, 239.1, 195.0], "category_id": 1}, {"id": 2, "bbox": [745.0, 289.0, 181.0, 76.8], "category_id": 3}, {"id": 3, "bbox": [620.0, 49.0, 195.0, 45.0], "category_id": 2}, {"id": 4, "bbox": [398.0, 82.0, 148.0, 49.0], "category_id": 1}, {"id": 5, "bbox": [218.0, 155.0, 47.0, 39.0], "category_id": 3}, {"id": 6, "bbox": [464.0, 155.0, 45.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [975.0, 151.0, 52.0, 41.0], "category_id": 3}, {"id": 8, "bbox": [175.0, 36.0, 133.0, 107.0], "category_id": 1}, {"id": 9, "bbox": [10.0, 484.0, 1331.0, 704.0], "category_id": 4}], "reactions": [{"reactants": [8, 4], "conditions": [3], "products": [0]}], "corefs": [[8, 5], [4, 6], [0, 7], [1, 2]], "caption": "Table 1. Pt/SPOs-Catalyzed [2 + 1] Cycloaddition of 4a with 5a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 141, 376, 173], "ImageBB": [74, 181, 410, 478]}, "diagram_type": "single"}, {"id": 682, "width": 1348, "height": 2212, "file_name": "ol401443a-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [841.0, 2.0, 198.0, 282.6], "category_id": 1}, {"id": 1, "bbox": [27.0, 331.0, 1321.0, 1878.0], "category_id": 4}, {"id": 2, "bbox": [1028.0, 187.0, 74.0, 79.0], "category_id": 3}, {"id": 3, "bbox": [304.45, 219.85, 65.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [435.6, 8.6, 396.4, 195.4], "category_id": 2}, {"id": 5, "bbox": [569.4, 214.0, 124.6, 79.3], "category_id": 2}, {"id": 6, "bbox": [256.3, 65.6, 173.1, 173.5], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [4, 5], "products": [0]}], "corefs": [[6, 3], [0, 2]], "caption": "Table 2. Synthesis of R-Azido-peroxides from Aldehydesa", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 85, 377, 103], "ImageBB": [71, 112, 408, 665]}, "diagram_type": "single"}, {"id": 546, "width": 1352, "height": 1000, "file_name": "acs.orglett.5b03589-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [851.0, 27.0, 174.0, 155.0], "category_id": 1}, {"id": 1, "bbox": [437.0, 839.0, 62.0, 52.0], "category_id": 3}, {"id": 2, "bbox": [914.0, 839.0, 64.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [1.0, 901.0, 886.0, 71.0], "category_id": 2}, {"id": 4, "bbox": [921.0, 655.0, 62.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [442.0, 660.0, 66.0, 46.0], "category_id": 3}, {"id": 6, "bbox": [354.0, 741.0, 285.0, 124.0], "category_id": 1}, {"id": 7, "bbox": [720.0, 520.0, 206.0, 159.0], "category_id": 1}, {"id": 8, "bbox": [968.0, 205.0, 42.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [554.0, 331.0, 255.0, 72.0], "category_id": 2}, {"id": 10, "bbox": [598.0, 134.0, 228.0, 126.0], "category_id": 1}, {"id": 11, "bbox": [202.0, 436.0, 943.0, 459.8], "category_id": 4}, {"id": 12, "bbox": [549.5, 0.0, 273.5, 113.0], "category_id": 2}, {"id": 13, "bbox": [597.0, 252.7, 204.0, 71.3], "category_id": 2}, {"id": 14, "bbox": [330.0, 201.0, 197.2, 42.0], "category_id": 3}, {"id": 15, "bbox": [550.05, 136.78, 44.24, 44.24], "category_id": 2}, {"id": 16, "bbox": [352.0, 529.0, 195.0, 107.7], "category_id": 1}, {"id": 17, "bbox": [727.6, 713.0, 292.4, 153.1], "category_id": 1}, {"id": 18, "bbox": [343.0, 62.4, 140.0, 112.6], "category_id": 1}, {"id": 19, "bbox": [716.27, 167.61, 30.83, 40.22], "category_id": 3}], "reactions": [{"reactants": [18], "conditions": [12, 15, 10, 13, 9], "products": [0]}], "corefs": [[18, 14], [10, 19], [0, 8], [16, 5], [7, 4], [6, 1], [17, 2]], "caption": "Table 3. Scope of the Tandem Coupling/Cyclization Reactions with Alkyl Substituted Carboxylic Acids ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 141, 373, 171], "ImageBB": [82, 178, 420, 428]}, "diagram_type": "single"}, {"id": 356, "width": 2808, "height": 888, "file_name": "ol200288w-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1391.0, 108.0, 266.0, 54.0], "category_id": 2}, {"id": 1, "bbox": [4.0, 210.0, 2804.0, 566.0], "category_id": 4}, {"id": 2, "bbox": [1706.0, 2.0, 389.0, 166.0], "category_id": 1}, {"id": 3, "bbox": [71.0, 769.0, 1935.0, 82.0], "category_id": 2}, {"id": 4, "bbox": [722.19, 64.87, 97.41, 65.65], "category_id": 2}, {"id": 5, "bbox": [1408.0, 29.0, 216.0, 67.0], "category_id": 2}, {"id": 6, "bbox": [1175.0, 61.0, 186.0, 75.6], "category_id": 1}, {"id": 7, "bbox": [809.9, 6.4, 215.7, 178.1], "category_id": 1}], "reactions": [{"reactants": [7, 6], "conditions": [5, 0], "products": [2]}], "corefs": [], "caption": "Table 1. Subset of Selected Products that are Synthesized by NRPS325", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 87, 447, 100], "ImageBB": [71, 112, 773, 334]}, "diagram_type": "single"}, {"id": 1008, "width": 1208, "height": 980, "file_name": "ja9612413-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [30.59, 164.3, 237.41, 249.97], "category_id": 1}, {"id": 1, "bbox": [766.86, 677.68, 301.55, 46.72], "category_id": 1}, {"id": 2, "bbox": [619.0, 102.6, 151.1, 41.9], "category_id": 1}, {"id": 3, "bbox": [638.12, 178.82, 188.23, 45.89], "category_id": 2}, {"id": 4, "bbox": [0.0, 527.15, 161.95, 50.78], "category_id": 1}, {"id": 5, "bbox": [461.08, 0.0, 288.25, 48.97], "category_id": 2}, {"id": 6, "bbox": [79.29, 558.82, 310.59, 251.77], "category_id": 1}, {"id": 7, "bbox": [418.78, 324.03, 295.12, 53.87], "category_id": 1}, {"id": 8, "bbox": [860.47, 761.18, 150.59, 34.11], "category_id": 1}, {"id": 9, "bbox": [928.71, 476.47, 154.11, 31.77], "category_id": 1}, {"id": 10, "bbox": [836.94, 329.41, 47.06, 37.65], "category_id": 2}, {"id": 11, "bbox": [886.35, 329.41, 315.3, 40.0], "category_id": 1}], "caption": "Scheme 3. A Plausible Pathway for the Organolanthanide- Catalyzed Coupling Reactions of Terminal Alkynes ", "pdf": {"Page": 11, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [73, 50, 396, 78], "ImageBB": [91, 84, 393, 329]}, "reactions": [{"reactants": [5, 2], "conditions": [], "products": [3, 7]}, {"reactants": [7], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [7]}, {"reactants": [7, 9], "conditions": [], "products": [1]}, {"reactants": [8], "conditions": [], "products": [1]}, {"reactants": [8], "conditions": [], "products": [6]}, {"reactants": [6, 4], "conditions": [], "products": [0, 7]}], "diagram_type": "graph"}, {"id": 580, "width": 1352, "height": 2384, "file_name": "acs.orglett.5b00312-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [22.0, 42.0, 160.0, 120.0], "category_id": 1}, {"id": 1, "bbox": [3.0, 239.0, 1349.0, 2145.0], "category_id": 4}, {"id": 2, "bbox": [1048.0, 10.0, 272.0, 175.0], "category_id": 1}, {"id": 3, "bbox": [1153.0, 184.0, 65.0, 31.0], "category_id": 3}, {"id": 4, "bbox": [578.0, 184.0, 26.0, 37.0], "category_id": 3}, {"id": 5, "bbox": [547.0, 29.0, 92.0, 145.0], "category_id": 1}, {"id": 6, "bbox": [259.0, 22.0, 193.0, 142.0], "category_id": 1}, {"id": 7, "bbox": [704.0, 2.0, 293.0, 82.0], "category_id": 2}, {"id": 8, "bbox": [784.0, 109.0, 140.0, 53.0], "category_id": 2}, {"id": 9, "bbox": [69.0, 178.0, 69.0, 45.0], "category_id": 3}, {"id": 10, "bbox": [339.0, 182.0, 48.0, 37.0], "category_id": 3}], "reactions": [{"reactants": [0, 6, 5], "conditions": [7, 8], "products": [2]}], "corefs": [[0, 9], [6, 10], [5, 4], [2, 3]], "caption": "Table 2. Addition of Alcohols to Phenylacetylene", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 727, 111], "ImageBB": [448, 116, 786, 712]}, "diagram_type": "single"}, {"id": 123, "width": 1348, "height": 904, "file_name": "op970105v-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [63.0, 469.7, 1224.0, 412.3], "category_id": 4}, {"id": 1, "bbox": [267.0, 0.0, 438.0, 389.0], "category_id": 1}, {"id": 2, "bbox": [834.0, 1.0, 489.0, 430.0], "category_id": 1}, {"id": 3, "bbox": [119.0, 104.0, 164.0, 107.2], "category_id": 2}, {"id": 4, "bbox": [34.0, 188.0, 57.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [882.0, 198.0, 40.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [716.0, 132.0, 119.0, 69.0], "category_id": 2}, {"id": 7, "bbox": [430.0, 381.0, 61.0, 59.0], "category_id": 3}, {"id": 8, "bbox": [1043.0, 387.0, 67.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [6], "products": [5, 2]}], "corefs": [[1, 7], [2, 8]], "caption": "Table 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [439, 50, 485, 64], "ImageBB": [438, 65, 775, 291]}, "diagram_type": "single"}, {"id": 1074, "width": 1148, "height": 1120, "file_name": "jo402749d-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [558.78, 459.03, 85.57, 55.72], "category_id": 2}, {"id": 1, "bbox": [701.2, 175.8, 43.65, 44.81], "category_id": 2}, {"id": 2, "bbox": [321.03, 689.98, 111.98, 51.13], "category_id": 2}, {"id": 3, "bbox": [0.0, 783.62, 693.16, 222.91], "category_id": 1}, {"id": 4, "bbox": [771.27, 705.9, 376.73, 355.78], "category_id": 1}, {"id": 5, "bbox": [859.71, 0.0, 288.29, 461.9], "category_id": 1}, {"id": 6, "bbox": [163.1, 997.34, 236.03, 109.15], "category_id": 2}, {"id": 7, "bbox": [694.89, 805.45, 33.88, 47.11], "category_id": 2}, {"id": 8, "bbox": [103.95, 334.36, 493.31, 329.77], "category_id": 1}], "caption": "Scheme 2. GB Reaction of Mixed Propargyl Systems", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 261, 379, 276], "ImageBB": [149, 282, 436, 562]}, "reactions": [{"reactants": [3], "conditions": [2], "products": [8]}, {"reactants": [8], "conditions": [0, 1], "products": [5]}, {"reactants": [8], "conditions": [0, 7], "products": [4]}], "diagram_type": "tree"}, {"id": 853, "width": 1344, "height": 468, "file_name": "jo2008675-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [681.1, 128.96, 280.9, 46.0], "category_id": 2}, {"id": 1, "bbox": [980.0, 3.0, 361.0, 259.0], "category_id": 1}, {"id": 2, "bbox": [681.2, 182.0, 262.8, 49.0], "category_id": 2}, {"id": 3, "bbox": [514.0, 258.0, 29.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [6.0, 374.0, 1338.0, 93.0], "category_id": 4}, {"id": 5, "bbox": [1140.04, 260.0, 38.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [386.1, 87.3, 311.9, 127.6], "category_id": 1}, {"id": 7, "bbox": [128.0, 257.0, 34.0, 39.0], "category_id": 3}, {"id": 8, "bbox": [9.1, 35.0, 339.5, 222.0], "category_id": 1}], "reactions": [{"reactants": [8, 6], "conditions": [0, 2], "products": [1]}], "corefs": [[8, 7], [6, 3], [1, 5]], "caption": "Table 2. Reaction Scopes of 2-Hydroxyaryl-r,\u03b2-unsaturated Ketones in the Domino Reactiona ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 403, 122], "ImageBB": [71, 133, 407, 250]}, "diagram_type": "single"}, {"id": 1037, "width": 1328, "height": 2092, "file_name": "jo001700p-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [362.18, 0.0, 720.16, 389.31], "category_id": 1}, {"id": 1, "bbox": [217.73, 1298.74, 59.66, 58.6], "category_id": 3}, {"id": 2, "bbox": [0.0, 1598.04, 1328.0, 423.84], "category_id": 1}, {"id": 3, "bbox": [601.88, 858.15, 705.52, 389.31], "category_id": 1}, {"id": 4, "bbox": [460.57, 632.1, 88.98, 55.47], "category_id": 2}, {"id": 5, "bbox": [578.86, 399.77, 253.31, 63.84], "category_id": 3}, {"id": 6, "bbox": [647.94, 2038.63, 164.34, 53.37], "category_id": 3}, {"id": 7, "bbox": [809.14, 1258.97, 368.46, 60.7], "category_id": 3}, {"id": 8, "bbox": [875.09, 623.73, 90.02, 60.7], "category_id": 2}, {"id": 9, "bbox": [34.54, 898.96, 430.22, 420.71], "category_id": 1}], "caption": "Scheme 2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [76, 84, 408, 607]}, "reactions": [{"reactants": [0], "conditions": [8], "products": [3]}, {"reactants": [0], "conditions": [4, 9, 3], "products": [2]}], "diagram_type": "tree"}, {"id": 249, "width": 1352, "height": 2396, "file_name": "ol802674r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 821.0, 37.0, 36.0], "category_id": 3}, {"id": 1, "bbox": [863.0, 520.0, 32.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [355.0, 482.0, 64.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [6.0, 1873.0, 1346.0, 386.0], "category_id": 4}, {"id": 4, "bbox": [98.0, 100.0, 1145.0, 136.0], "category_id": 4}, {"id": 5, "bbox": [228.0, 258.0, 268.0, 214.0], "category_id": 1}, {"id": 6, "bbox": [640.0, 264.0, 477.0, 282.0], "category_id": 1}, {"id": 7, "bbox": [574.0, 336.0, 41.0, 40.0], "category_id": 2}, {"id": 8, "bbox": [516.0, 425.0, 206.0, 47.0], "category_id": 2}, {"id": 9, "bbox": [509.0, 732.0, 204.0, 40.0], "category_id": 2}, {"id": 10, "bbox": [578.0, 648.0, 43.0, 39.0], "category_id": 2}, {"id": 11, "bbox": [661.0, 566.0, 463.0, 294.0], "category_id": 1}, {"id": 12, "bbox": [221.0, 589.0, 298.0, 224.0], "category_id": 1}, {"id": 13, "bbox": [498.0, 1024.0, 220.0, 41.0], "category_id": 2}, {"id": 14, "bbox": [574.0, 928.0, 48.0, 46.0], "category_id": 2}, {"id": 15, "bbox": [637.0, 862.0, 469.0, 267.0], "category_id": 1}, {"id": 16, "bbox": [201.0, 894.0, 311.0, 157.0], "category_id": 1}, {"id": 17, "bbox": [478.0, 1332.0, 208.0, 53.0], "category_id": 2}, {"id": 18, "bbox": [533.0, 1254.0, 56.0, 46.0], "category_id": 2}, {"id": 19, "bbox": [619.0, 1197.0, 494.0, 242.0], "category_id": 1}, {"id": 20, "bbox": [201.0, 1184.0, 308.0, 228.0], "category_id": 1}, {"id": 21, "bbox": [466.0, 1699.0, 191.0, 48.0], "category_id": 2}, {"id": 22, "bbox": [535.0, 1606.0, 51.0, 52.0], "category_id": 2}, {"id": 23, "bbox": [592.0, 1460.0, 536.0, 307.0], "category_id": 1}, {"id": 24, "bbox": [210.0, 1507.0, 311.0, 254.0], "category_id": 1}, {"id": 25, "bbox": [830.0, 1765.0, 54.0, 38.0], "category_id": 3}, {"id": 26, "bbox": [339.0, 1773.0, 35.0, 47.0], "category_id": 3}, {"id": 27, "bbox": [846.0, 1452.0, 48.0, 43.0], "category_id": 3}, {"id": 28, "bbox": [345.0, 1418.0, 36.0, 39.0], "category_id": 3}, {"id": 29, "bbox": [885.0, 1124.0, 53.0, 44.0], "category_id": 3}, {"id": 30, "bbox": [353.0, 1061.0, 39.0, 38.0], "category_id": 3}, {"id": 31, "bbox": [876.0, 828.0, 34.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [7, 8], "products": [6]}, {"reactants": [12], "conditions": [10, 9], "products": [11]}, {"reactants": [16], "conditions": [14, 13], "products": [15]}, {"reactants": [20], "conditions": [18, 17], "products": [19]}, {"reactants": [24], "conditions": [22, 21], "products": [23]}], "corefs": [[5, 2], [6, 1], [12, 0], [11, 31], [16, 30], [15, 29], [20, 28], [19, 27], [24, 26], [23, 25]], "caption": "Table 1. Compounds Obtained by Variation of the Carbonyl Component ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 653, 738, 680], "ImageBB": [425, 46, 763, 645]}, "diagram_type": "multiple"}, {"id": 688, "width": 1344, "height": 2056, "file_name": "ol401179k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [655.0, 0.0, 277.0, 81.0], "category_id": 2}, {"id": 1, "bbox": [642.0, 122.0, 303.0, 91.0], "category_id": 2}, {"id": 2, "bbox": [10.0, 301.0, 1330.0, 1755.0], "category_id": 4}, {"id": 3, "bbox": [950.0, 15.0, 277.0, 185.0], "category_id": 1}, {"id": 4, "bbox": [112.0, 8.0, 306.0, 196.0], "category_id": 1}, {"id": 5, "bbox": [426.0, 94.0, 205.0, 67.0], "category_id": 1}], "reactions": [{"reactants": [4, 5], "conditions": [0, 1], "products": [3]}], "corefs": [], "caption": "Table 1. Suzuki Miyaura Cross-Coupling Reactions of 12- Chloro-19,20-dihydroakuammicine 2a with Aryl and Hetero- aryl Boronic Acids 3d i ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 196, 763, 237], "ImageBB": [437, 248, 773, 762]}, "diagram_type": "single"}, {"id": 77, "width": 2428, "height": 636, "file_name": "ja106807u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [871.49, 167.62, 58.76, 42.29], "category_id": 2}, {"id": 1, "bbox": [1843.79, 4.66, 578.78, 467.09], "category_id": 1}, {"id": 2, "bbox": [1034.45, 110.86, 580.62, 263.84], "category_id": 1}, {"id": 3, "bbox": [287.38, 110.86, 516.53, 267.51], "category_id": 1}, {"id": 4, "bbox": [1668.0, 167.62, 55.1, 42.28], "category_id": 2}, {"id": 5, "bbox": [5.39, 579.61, 2408.03, 49.59], "category_id": 2}, {"id": 6, "bbox": [324.0, 440.45, 186.94, 99.05], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [1]}], "corefs": [[3, 6]], "caption": "Table 1. Absorption and Emission Properties of B, G, and R in Solution and in Organogels (Deoxygenated): Lowest Energy Absorption Wavelength, \u03bbabs, Extinction Coefficient, \u03b5, Emission Wavelength, \u03bbem, and Quantum Yield, \u03a6em, Decay Time, \u03c4, and Radiative Constant, kr ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 249, 748, 274], "ImageBB": [71, 73, 678, 232]}, "diagram_type": "single"}, {"id": 941, "width": 1352, "height": 728, "file_name": "acs.orglett.5b01872-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1053.73, 273.83, 200.88, 48.0], "category_id": 3}, {"id": 1, "bbox": [263.1, 294.11, 110.24, 41.92], "category_id": 3}, {"id": 2, "bbox": [680.4, 278.56, 277.29, 76.4], "category_id": 3}, {"id": 3, "bbox": [878.5, 491.3, 257.3, 132.7], "category_id": 1}, {"id": 4, "bbox": [68.99, 3.2, 442.32, 324.04], "category_id": 1}, {"id": 5, "bbox": [72.0, 376.5, 586.3, 286.77], "category_id": 1}, {"id": 6, "bbox": [1132.87, 576.73, 92.65, 47.33], "category_id": 2}, {"id": 7, "bbox": [1028.03, 75.73, 252.95, 163.62], "category_id": 1}, {"id": 8, "bbox": [980.69, 641.64, 34.49, 41.92], "category_id": 3}, {"id": 9, "bbox": [273.92, 641.64, 36.52, 42.59], "category_id": 3}, {"id": 10, "bbox": [595.18, 22.31, 397.01, 256.25], "category_id": 1}, {"id": 11, "bbox": [784.08, 579.65, 66.27, 34.66], "category_id": 2}, {"id": 12, "bbox": [767.76, 421.61, 120.32, 46.9], "category_id": 1}], "caption": "Scheme 1. Retrosynthesis of v-Coelenterazine", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 339, 111], "ImageBB": [82, 116, 420, 298]}, "reactions": [{"reactants": [4], "conditions": [], "products": [10, 7]}, {"reactants": [10], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [3, 6, 11, 12]}], "diagram_type": "tree"}, {"id": 407, "width": 1352, "height": 868, "file_name": "op400278d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [922.16, 98.78, 322.84, 153.32], "category_id": 1}, {"id": 1, "bbox": [242.8, 363.33, 257.4, 272.87], "category_id": 1}, {"id": 2, "bbox": [519.8, 365.69, 266.9, 270.11], "category_id": 1}, {"id": 3, "bbox": [750.0, 334.0, 296.0, 337.2], "category_id": 1}, {"id": 4, "bbox": [525.1, 5.0, 366.9, 169.9], "category_id": 2}, {"id": 5, "bbox": [258.0, 700.0, 227.0, 133.0], "category_id": 3}, {"id": 6, "bbox": [9.0, 700.0, 197.1, 131.5], "category_id": 3}, {"id": 7, "bbox": [1065.0, 357.0, 261.0, 289.0], "category_id": 1}, {"id": 8, "bbox": [36.0, 245.0, 198.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [299.0, 239.0, 189.0, 60.0], "category_id": 2}, {"id": 10, "bbox": [523.0, 197.0, 351.0, 93.0], "category_id": 2}, {"id": 11, "bbox": [315.49, 139.51, 164.0, 47.0], "category_id": 2}, {"id": 12, "bbox": [13.35, 372.3, 243.85, 254.52], "category_id": 1}, {"id": 13, "bbox": [60.7, 31.2, 171.3, 198.8], "category_id": 1}, {"id": 14, "bbox": [528.0, 700.5, 227.5, 131.2], "category_id": 3}, {"id": 15, "bbox": [802.1, 698.1, 224.2, 132.9], "category_id": 3}, {"id": 16, "bbox": [1087.1, 695.1, 225.9, 135.8], "category_id": 3}], "reactions": [{"reactants": [13, 11], "conditions": [4, 10], "products": [0]}], "corefs": [[12, 6], [1, 5], [2, 14], [3, 15], [7, 16]], "caption": "Table 4. Comparative study of Pd-PEPPSI-IPr (2) and Pd- PEPPSI-IPent (1) in aryl aminations with dialkylamines ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 555, 413, 586], "ImageBB": [82, 591, 420, 808]}, "diagram_type": "single"}, {"id": 385, "width": 1356, "height": 1756, "file_name": "op500224x-Table-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [530.0, 748.0, 175.0, 95.0], "category_id": 3}, {"id": 1, "bbox": [254.0, 1618.0, 172.0, 100.0], "category_id": 3}, {"id": 2, "bbox": [757.0, 1621.0, 174.0, 94.0], "category_id": 3}, {"id": 3, "bbox": [981.0, 740.0, 172.0, 103.0], "category_id": 3}, {"id": 4, "bbox": [126.0, 748.0, 177.0, 97.0], "category_id": 3}, {"id": 5, "bbox": [775.0, 1186.0, 173.0, 104.0], "category_id": 3}, {"id": 6, "bbox": [858.0, 120.5, 89.2, 51.5], "category_id": 2}, {"id": 7, "bbox": [269.0, 1186.0, 175.0, 109.0], "category_id": 3}, {"id": 8, "bbox": [326.0, 123.0, 60.0, 47.0], "category_id": 2}, {"id": 9, "bbox": [618.0, 337.0, 45.0, 54.0], "category_id": 3}, {"id": 10, "bbox": [848.0, 415.0, 415.0, 339.0], "category_id": 1}, {"id": 11, "bbox": [613.0, 843.0, 498.0, 353.0], "category_id": 1}, {"id": 12, "bbox": [165.0, 852.0, 376.0, 355.0], "category_id": 1}, {"id": 13, "bbox": [160.0, 1293.0, 370.0, 305.0], "category_id": 1}, {"id": 14, "bbox": [621.0, 1291.0, 483.0, 331.0], "category_id": 1}, {"id": 15, "bbox": [1033.0, 16.0, 315.0, 315.0], "category_id": 1}, {"id": 16, "bbox": [502.0, 8.0, 286.0, 313.0], "category_id": 1}, {"id": 17, "bbox": [48.0, 441.0, 318.0, 295.0], "category_id": 1}, {"id": 18, "bbox": [1190.0, 331.0, 46.0, 61.0], "category_id": 3}, {"id": 19, "bbox": [809.0, 189.0, 225.0, 47.0], "category_id": 2}, {"id": 20, "bbox": [0.0, 3.0, 290.0, 318.0], "category_id": 1}, {"id": 21, "bbox": [452.0, 438.0, 331.0, 292.0], "category_id": 1}, {"id": 22, "bbox": [295.0, 183.0, 143.0, 91.0], "category_id": 2}, {"id": 23, "bbox": [115.0, 331.0, 44.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [20], "conditions": [8, 22], "products": [16]}, {"reactants": [16], "conditions": [6, 19], "products": [15]}], "corefs": [[20, 23], [16, 9], [15, 18], [17, 4], [21, 0], [10, 3], [12, 7], [11, 5], [13, 1], [14, 2]], "caption": "Table 5. Addition of carbon electrophiles and carbon nucleophiles under kinetic control ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 750, 125], "ImageBB": [448, 131, 787, 570]}, "diagram_type": "single"}, {"id": 718, "width": 1352, "height": 948, "file_name": "ol027494k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [356.0, 0.0, 304.0, 98.0], "category_id": 2}, {"id": 1, "bbox": [54.0, 6.4, 198.5, 135.6], "category_id": 1}, {"id": 2, "bbox": [360.0, 120.0, 260.0, 100.0], "category_id": 2}, {"id": 3, "bbox": [0.0, 378.0, 1352.0, 570.0], "category_id": 4}, {"id": 4, "bbox": [112.0, 186.0, 61.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [880.0, 300.0, 60.0, 49.0], "category_id": 3}, {"id": 6, "bbox": [772.0, 0.0, 365.0, 280.0], "category_id": 1}, {"id": 7, "bbox": [1171.0, 91.0, 129.0, 61.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [0, 2], "products": [6, 7]}], "corefs": [[1, 4], [6, 5]], "caption": "Table 1. Alkenylation Reaction of Enolate with Alkenylselenonium Salt 1a ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 328, 104], "ImageBB": [73, 108, 411, 345]}, "diagram_type": "single"}, {"id": 320, "width": 1348, "height": 1108, "file_name": "ol3023177-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [281.0, 145.0, 60.1, 53.6], "category_id": 3}, {"id": 1, "bbox": [4.0, 233.0, 1344.0, 872.0], "category_id": 4}, {"id": 2, "bbox": [1012.3, 153.9, 60.4, 45.7], "category_id": 3}, {"id": 3, "bbox": [584.4, 147.3, 69.0, 44.8], "category_id": 3}, {"id": 4, "bbox": [878.4, 4.0, 279.3, 146.1], "category_id": 1}, {"id": 5, "bbox": [529.4, 44.9, 182.6, 99.0], "category_id": 1}, {"id": 6, "bbox": [194.0, 28.9, 239.1, 103.2], "category_id": 1}], "reactions": [{"reactants": [6, 5], "conditions": [], "products": [4]}], "corefs": [[6, 0], [5, 3], [4, 2]], "caption": "Table 1. Optimization of Reaction of 1a with 2aa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 387, 698, 403], "ImageBB": [436, 414, 773, 691]}, "diagram_type": "single"}, {"id": 26, "width": 1348, "height": 1132, "file_name": "ja9039289-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [949.48, 205.43, 374.46, 47.28], "category_id": 2}, {"id": 1, "bbox": [1110.15, 253.63, 39.98, 41.47], "category_id": 3}, {"id": 2, "bbox": [1110.15, 148.46, 38.52, 42.9], "category_id": 3}, {"id": 3, "bbox": [743.53, 253.63, 35.59, 42.9], "category_id": 3}, {"id": 4, "bbox": [281.96, 222.95, 301.44, 45.82], "category_id": 2}, {"id": 5, "bbox": [636.9, 142.62, 254.69, 108.63], "category_id": 1}, {"id": 6, "bbox": [1050.26, 95.88, 155.37, 48.74], "category_id": 2}, {"id": 7, "bbox": [21.97, 139.7, 206.49, 107.16], "category_id": 1}, {"id": 8, "bbox": [2.98, 303.29, 1341.41, 827.21], "category_id": 4}, {"id": 9, "bbox": [298.03, 3.86, 269.3, 180.2], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [9, 4], "products": [5, 6, 0]}], "corefs": [[5, 3], [6, 2], [0, 1]], "caption": "Table 3. Fluoride Effect on Ni- and Co-Catalyzed Biaryl Cross-Coupling in the Presence of Phosphine Ligands ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 57, 703, 81], "ImageBB": [425, 89, 762, 372]}, "diagram_type": "single"}, {"id": 1316, "width": 1268, "height": 772, "file_name": "op300209p-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1108.79, 720.84, 60.89, 49.45], "category_id": 3}, {"id": 1, "bbox": [1012.37, 84.32, 43.13, 40.57], "category_id": 2}, {"id": 2, "bbox": [407.23, 299.87, 40.6, 43.75], "category_id": 3}, {"id": 3, "bbox": [544.88, 562.98, 45.03, 50.72], "category_id": 2}, {"id": 4, "bbox": [460.51, 344.89, 272.76, 174.98], "category_id": 1}, {"id": 5, "bbox": [111.01, 719.57, 57.08, 52.43], "category_id": 3}, {"id": 6, "bbox": [39.96, 294.8, 41.23, 45.02], "category_id": 3}, {"id": 7, "bbox": [1009.2, 339.18, 258.8, 334.11], "category_id": 1}, {"id": 8, "bbox": [19.66, 388.0, 422.46, 285.29], "category_id": 1}, {"id": 9, "bbox": [521.41, 476.12, 58.36, 46.92], "category_id": 3}, {"id": 10, "bbox": [346.97, 2.54, 271.49, 278.95], "category_id": 1}, {"id": 11, "bbox": [823.34, 722.74, 37.43, 45.02], "category_id": 3}, {"id": 12, "bbox": [230.26, 97.0, 40.59, 39.31], "category_id": 2}, {"id": 13, "bbox": [733.27, 367.08, 260.07, 306.21], "category_id": 1}, {"id": 14, "bbox": [713.61, 8.24, 281.0, 278.95], "category_id": 1}, {"id": 15, "bbox": [641.93, 83.69, 42.5, 48.18], "category_id": 2}, {"id": 16, "bbox": [756.11, 303.68, 38.69, 42.48], "category_id": 3}, {"id": 17, "bbox": [0.0, 0.0, 227.09, 281.49], "category_id": 1}], "caption": "Scheme 2. Original Synthesis of N-Aryl Pyrazole 6", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 91, 367, 111], "ImageBB": [92, 116, 409, 309]}, "reactions": [{"reactants": [17], "conditions": [12], "products": [10]}, {"reactants": [10], "conditions": [15], "products": [14]}, {"reactants": [14], "conditions": [1], "products": [8]}, {"reactants": [8, 4], "conditions": [3], "products": [13, 7]}], "diagram_type": "multiple"}, {"id": 1004, "width": 1352, "height": 296, "file_name": "ja905415r-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 119.65, 32.46, 47.99], "category_id": 3}, {"id": 1, "bbox": [874.51, 39.88, 477.49, 59.49], "category_id": 2}, {"id": 2, "bbox": [276.62, 251.46, 42.61, 44.54], "category_id": 3}, {"id": 3, "bbox": [48.7, 95.99, 79.8, 46.64], "category_id": 2}, {"id": 4, "bbox": [615.47, 250.11, 43.96, 45.89], "category_id": 3}, {"id": 5, "bbox": [156.91, 12.17, 252.95, 227.12], "category_id": 1}, {"id": 6, "bbox": [468.03, 6.08, 259.03, 253.49], "category_id": 1}, {"id": 7, "bbox": [873.83, 122.35, 453.15, 53.4], "category_id": 2}, {"id": 8, "bbox": [873.83, 202.11, 438.94, 53.41], "category_id": 2}], "caption": "Scheme 1. Hypothetical Stepwise Mechanism Involving Carbocationic Intermediate II ", "pdf": {"Page": 7, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 444, 334, 468], "ImageBB": [58, 479, 396, 553]}, "reactions": [{"reactants": [0], "conditions": [3], "products": [5]}, {"reactants": [5], "conditions": [], "products": [6]}, {"reactants": [5], "conditions": [], "products": [0]}, {"reactants": [6], "conditions": [], "products": [5]}, {"reactants": [6], "conditions": [], "products": [1]}, {"reactants": [6], "conditions": [], "products": [7]}, {"reactants": [6], "conditions": [], "products": [8]}], "diagram_type": "single"}, {"id": 1047, "width": 1048, "height": 1648, "file_name": "jo010904i-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [632.86, 1109.85, 57.37, 47.48], "category_id": 2}, {"id": 1, "bbox": [361.78, 277.83, 37.09, 41.22], "category_id": 3}, {"id": 2, "bbox": [561.22, 1003.31, 101.36, 39.57], "category_id": 3}, {"id": 3, "bbox": [229.1, 1241.56, 696.37, 193.74], "category_id": 1}, {"id": 4, "bbox": [184.6, 3.3, 426.89, 258.04], "category_id": 1}, {"id": 5, "bbox": [633.74, 1046.18, 111.25, 46.99], "category_id": 2}, {"id": 6, "bbox": [689.78, 1046.18, 267.83, 150.87], "category_id": 1}, {"id": 7, "bbox": [633.74, 666.13, 196.96, 89.86], "category_id": 2}, {"id": 8, "bbox": [824.93, 275.35, 50.27, 45.35], "category_id": 3}, {"id": 9, "bbox": [668.35, 66.78, 379.65, 179.72], "category_id": 1}, {"id": 10, "bbox": [365.08, 401.49, 558.74, 184.67], "category_id": 1}, {"id": 11, "bbox": [361.78, 793.08, 565.34, 198.69], "category_id": 1}, {"id": 12, "bbox": [561.22, 596.05, 101.36, 40.4], "category_id": 3}, {"id": 13, "bbox": [561.22, 1452.61, 228.27, 89.04], "category_id": 3}, {"id": 14, "bbox": [688.62, 1195.4, 236.52, 46.99], "category_id": 2}, {"id": 15, "bbox": [0.0, 1588.64, 528.25, 59.36], "category_id": 2}], "caption": "Scheme 1a", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [573, 451, 641, 465], "ImageBB": [453, 471, 715, 883]}, "reactions": [{"reactants": [4, 9], "conditions": [], "products": [10]}, {"reactants": [10], "conditions": [7], "products": [11]}, {"reactants": [11], "conditions": [5, 6, 0, 14], "products": [3]}], "diagram_type": "tree"}, {"id": 1085, "width": 1044, "height": 1260, "file_name": "jo951899j-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [785.14, 382.64, 180.0, 235.97], "category_id": 2}, {"id": 1, "bbox": [801.48, 661.83, 97.11, 49.17], "category_id": 2}, {"id": 2, "bbox": [672.84, 277.34, 100.9, 50.42], "category_id": 2}, {"id": 3, "bbox": [40.36, 1104.94, 146.93, 52.95], "category_id": 2}, {"id": 4, "bbox": [8.2, 216.2, 466.64, 56.1], "category_id": 1}, {"id": 5, "bbox": [376.46, 27.1, 321.61, 53.58], "category_id": 1}, {"id": 6, "bbox": [0.0, 25.21, 305.21, 51.69], "category_id": 1}, {"id": 7, "bbox": [9.46, 758.9, 664.01, 250.86], "category_id": 1}, {"id": 8, "bbox": [285.66, 1099.27, 588.34, 138.04], "category_id": 1}, {"id": 9, "bbox": [423.76, 290.58, 55.49, 50.42], "category_id": 3}, {"id": 10, "bbox": [375.2, 560.98, 48.56, 48.53], "category_id": 3}, {"id": 11, "bbox": [622.39, 857.86, 47.3, 46.01], "category_id": 3}, {"id": 12, "bbox": [590.23, 160.73, 378.99, 94.55], "category_id": 2}, {"id": 13, "bbox": [850.67, 0.0, 114.14, 46.64], "category_id": 2}, {"id": 14, "bbox": [945.89, 1138.98, 91.43, 65.55], "category_id": 2}, {"id": 15, "bbox": [11.98, 442.48, 706.9, 253.39], "category_id": 1}, {"id": 16, "bbox": [856.34, 66.81, 99.01, 52.95], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [197, 55, 260, 69], "ImageBB": [101, 75, 362, 390]}, "reactions": [{"reactants": [6, 5], "conditions": [13, 16], "products": [4]}, {"reactants": [4], "conditions": [12, 2], "products": [15]}, {"reactants": [15], "conditions": [0, 1], "products": [7]}], "diagram_type": "multiple"}, {"id": 1072, "width": 1356, "height": 1564, "file_name": "jo4027148-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [800.98, 50.07, 534.24, 416.24], "category_id": 1}, {"id": 1, "bbox": [800.98, 1105.52, 531.89, 353.64], "category_id": 1}, {"id": 2, "bbox": [321.49, 995.2, 150.96, 53.2], "category_id": 2}, {"id": 3, "bbox": [263.6, 1474.03, 62.58, 51.63], "category_id": 3}, {"id": 4, "bbox": [31.29, 1125.86, 531.11, 351.29], "category_id": 1}, {"id": 5, "bbox": [31.29, 548.46, 531.11, 347.38], "category_id": 1}, {"id": 6, "bbox": [1035.64, 422.49, 61.01, 47.73], "category_id": 3}, {"id": 7, "bbox": [267.51, 891.93, 57.89, 42.25], "category_id": 3}, {"id": 8, "bbox": [31.29, 50.07, 531.11, 352.08], "category_id": 1}, {"id": 9, "bbox": [263.6, 422.49, 66.49, 50.07], "category_id": 3}, {"id": 10, "bbox": [1034.85, 1474.03, 63.36, 50.07], "category_id": 3}, {"id": 11, "bbox": [1089.61, 1003.03, 122.02, 56.33], "category_id": 2}, {"id": 12, "bbox": [4.69, 516.38, 50.06, 53.2], "category_id": 3}, {"id": 13, "bbox": [578.05, 263.67, 219.01, 129.87], "category_id": 2}, {"id": 14, "bbox": [604.64, 1219.75, 155.66, 62.59], "category_id": 2}, {"id": 15, "bbox": [554.58, 28.95, 252.65, 143.18], "category_id": 1}, {"id": 16, "bbox": [578.83, 614.18, 208.07, 93.1], "category_id": 2}, {"id": 17, "bbox": [649.23, 175.26, 63.36, 48.5], "category_id": 3}, {"id": 18, "bbox": [605.42, 729.19, 154.88, 96.23], "category_id": 2}, {"id": 19, "bbox": [1034.85, 891.14, 63.36, 43.04], "category_id": 3}, {"id": 20, "bbox": [4.69, 0.0, 53.19, 47.73], "category_id": 3}, {"id": 21, "bbox": [800.98, 544.54, 531.89, 351.3], "category_id": 1}], "caption": "Scheme 10. Controlled C-3 Epimerization of 82", "pdf": {"Page": 12, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 720, 110], "ImageBB": [448, 116, 787, 507]}, "reactions": [{"reactants": [8], "conditions": [15, 13], "products": [0]}, {"reactants": [5], "conditions": [16, 18], "products": [21]}, {"reactants": [5], "conditions": [2], "products": [4]}, {"reactants": [4], "conditions": [14], "products": [1]}], "diagram_type": "graph"}, {"id": 843, "width": 3396, "height": 1140, "file_name": "jo201975b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1644.0, 22.0, 163.0, 87.0], "category_id": 2}, {"id": 1, "bbox": [289.0, 300.0, 2803.0, 495.0], "category_id": 4}, {"id": 2, "bbox": [1920.0, 236.0, 150.0, 36.0], "category_id": 3}, {"id": 3, "bbox": [1864.0, 0.0, 251.0, 236.0], "category_id": 1}, {"id": 4, "bbox": [1643.0, 135.0, 153.0, 131.0], "category_id": 2}, {"id": 5, "bbox": [1351.0, 231.0, 154.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [1257.0, 22.0, 326.0, 198.0], "category_id": 1}, {"id": 7, "bbox": [289.43, 800.62, 2363.88, 74.28], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [0, 4], "products": [3]}], "corefs": [[6, 5], [3, 2]], "caption": "Table 1. Stereoselective Synthesis of cis-2,6-Disubstituted Morpholines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 820, 479, 836], "ImageBB": [10, 842, 859, 1127]}, "diagram_type": "single"}, {"id": 904, "width": 1352, "height": 1388, "file_name": "acs.joc.5b02057-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 10.0, 302.0, 170.6], "category_id": 1}, {"id": 1, "bbox": [629.0, 294.0, 332.0, 42.0], "category_id": 2}, {"id": 2, "bbox": [703.0, 142.0, 205.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [1019.0, 0.0, 333.0, 203.0], "category_id": 1}, {"id": 4, "bbox": [587.0, 35.0, 430.0, 89.0], "category_id": 2}, {"id": 5, "bbox": [1.0, 356.0, 1349.0, 1032.0], "category_id": 4}, {"id": 6, "bbox": [1132.0, 194.0, 56.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [447.0, 191.0, 57.0, 42.0], "category_id": 3}, {"id": 8, "bbox": [120.0, 190.0, 56.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [383.0, 70.6, 212.4, 127.4], "category_id": 1}], "reactions": [{"reactants": [0, 9], "conditions": [4, 2], "products": [3]}], "corefs": [[0, 8], [9, 7], [3, 6]], "caption": "Table 1. E\ufb00ect of Reaction Parameters on the Gold- Catalyzed Reaction of 1b and 2ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 433, 745, 463], "ImageBB": [448, 470, 786, 817]}, "diagram_type": "single"}, {"id": 171, "width": 1352, "height": 1248, "file_name": "op500234a-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [147.0, 1150.0, 290.0, 98.0], "category_id": 1}, {"id": 1, "bbox": [134.0, 997.0, 300.0, 102.0], "category_id": 1}, {"id": 2, "bbox": [968.1, 992.0, 281.9, 256.0], "category_id": 1}, {"id": 3, "bbox": [555.0, 1036.0, 290.0, 73.0], "category_id": 1}], "reactions": [{"reactants": [1, 0], "conditions": [3], "products": [2]}], "corefs": [], "caption": "Figure 4. Real-time in situ Raman analysis of the addition cyclization involving group 7 (C\ue0c8C). ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 513, 417, 541], "ImageBB": [82, 192, 420, 504]}, "diagram_type": "single"}, {"id": 378, "width": 2816, "height": 2140, "file_name": "ol100073y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [659.18, 126.2, 218.02, 63.1], "category_id": 2}, {"id": 1, "bbox": [514.0, 306.0, 32.0, 45.0], "category_id": 3}, {"id": 2, "bbox": [14.0, 421.0, 2802.0, 1719.0], "category_id": 4}, {"id": 3, "bbox": [1080.0, 0.0, 438.0, 304.0], "category_id": 1}, {"id": 4, "bbox": [1989.0, 1.0, 444.0, 300.0], "category_id": 1}, {"id": 5, "bbox": [665.0, 48.0, 143.0, 50.0], "category_id": 2}, {"id": 6, "bbox": [382.0, 15.0, 232.0, 215.0], "category_id": 1}, {"id": 7, "bbox": [1536.0, 1.3, 440.0, 297.7], "category_id": 1}, {"id": 8, "bbox": [1610.0, 309.0, 323.0, 55.0], "category_id": 3}, {"id": 9, "bbox": [879.1, 269.9, 222.9, 139.1], "category_id": 3}, {"id": 10, "bbox": [1154.0, 308.0, 321.0, 61.0], "category_id": 3}, {"id": 11, "bbox": [2084.0, 309.0, 318.0, 56.0], "category_id": 3}, {"id": 12, "bbox": [675.5, 115.0, 330.5, 246.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 0, 12], "products": [3, 7, 4]}], "corefs": [[6, 1], [12, 9], [3, 10], [7, 8], [4, 11]], "caption": "Table 1. Optimization of the Addition Reaction of N-Sulfinyl Imidate 1 across Aldimines 2", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 531, 88], "ImageBB": [58, 97, 762, 632]}, "diagram_type": "single"}, {"id": 1203, "width": 1356, "height": 684, "file_name": "ol503708v-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [434.82, 471.73, 80.72, 45.47], "category_id": 2}, {"id": 1, "bbox": [340.53, 21.04, 212.99, 100.45], "category_id": 2}, {"id": 2, "bbox": [122.6, 0.0, 174.51, 232.81], "category_id": 1}, {"id": 3, "bbox": [950.35, 461.54, 78.69, 46.16], "category_id": 2}, {"id": 4, "bbox": [127.53, 301.36, 327.64, 275.57], "category_id": 1}, {"id": 5, "bbox": [319.5, 147.97, 273.37, 97.73], "category_id": 2}, {"id": 6, "bbox": [548.1, 377.38, 376.48, 208.37], "category_id": 1}, {"id": 7, "bbox": [759.06, 590.5, 34.6, 37.34], "category_id": 3}, {"id": 8, "bbox": [1064.31, 374.67, 207.58, 266.74], "category_id": 1}, {"id": 9, "bbox": [674.27, 245.7, 118.03, 41.41], "category_id": 3}, {"id": 10, "bbox": [976.81, 25.11, 206.89, 266.75], "category_id": 1}, {"id": 11, "bbox": [601.01, 6.11, 263.87, 245.02], "category_id": 1}, {"id": 12, "bbox": [295.08, 579.64, 35.27, 39.37], "category_id": 3}, {"id": 13, "bbox": [86.83, 476.48, 86.82, 71.94], "category_id": 2}, {"id": 14, "bbox": [1103.2, 250.46, 113.06, 39.36], "category_id": 3}, {"id": 15, "bbox": [1189.7, 598.65, 29.28, 38.01], "category_id": 3}, {"id": 16, "bbox": [86.83, 126.25, 85.47, 71.94], "category_id": 2}], "caption": "Scheme 4. (A) Enzymatic Dioxygenation of Benzyl Thiocyanate; (B) Mechanistic Proposal ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 156, 736, 186], "ImageBB": [448, 193, 787, 364]}, "reactions": [{"reactants": [2], "conditions": [1, 5], "products": [11, 10]}, {"reactants": [4], "conditions": [0], "products": [6]}, {"reactants": [6], "conditions": [3], "products": [8]}], "diagram_type": "multiple"}, {"id": 840, "width": 2820, "height": 1940, "file_name": "jo2020856-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1068.0, 264.0, 136.0, 86.0], "category_id": 3}, {"id": 1, "bbox": [1505.68, 98.69, 154.86, 45.05], "category_id": 2}, {"id": 2, "bbox": [3.0, 365.0, 2817.0, 1572.0], "category_id": 4}, {"id": 3, "bbox": [1061.0, 146.0, 172.0, 97.0], "category_id": 2}, {"id": 4, "bbox": [829.0, 264.0, 67.2, 61.6], "category_id": 3}, {"id": 5, "bbox": [1695.0, 50.0, 389.0, 244.0], "category_id": 1}, {"id": 6, "bbox": [743.8, 66.6, 258.6, 205.6], "category_id": 1}, {"id": 7, "bbox": [1316.2, 0.4, 352.6, 197.6], "category_id": 1}, {"id": 8, "bbox": [1751.0, 261.0, 132.6, 55.4], "category_id": 3}, {"id": 9, "bbox": [1369.0, 211.0, 187.8, 95.0], "category_id": 2}], "reactions": [{"reactants": [6, 3], "conditions": [7, 1, 9], "products": [5]}], "corefs": [[6, 4], [3, 0], [5, 8]], "caption": "Table 3. Scope of the Reaction with Different Aromatic and Heteroaromatic Aldehydes", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 574, 110], "ImageBB": [82, 116, 787, 601]}, "diagram_type": "single"}, {"id": 1146, "width": 1352, "height": 1004, "file_name": "ol036111v-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [69.66, 107.53, 266.48, 304.99], "category_id": 1}, {"id": 1, "bbox": [598.56, 6.09, 716.24, 518.01], "category_id": 1}, {"id": 2, "bbox": [610.06, 742.54, 87.24, 37.19], "category_id": 2}, {"id": 3, "bbox": [980.69, 901.46, 35.85, 42.6], "category_id": 3}, {"id": 4, "bbox": [346.96, 197.47, 204.93, 45.98], "category_id": 2}, {"id": 5, "bbox": [708.13, 576.85, 589.09, 342.19], "category_id": 1}, {"id": 6, "bbox": [347.64, 795.96, 198.84, 37.87], "category_id": 2}, {"id": 7, "bbox": [347.64, 728.34, 200.87, 42.6], "category_id": 2}, {"id": 8, "bbox": [347.64, 264.42, 198.84, 40.57], "category_id": 2}, {"id": 9, "bbox": [35.95, 755.74, 38.57, 49.42], "category_id": 2}, {"id": 10, "bbox": [392.95, 408.46, 318.35, 125.11], "category_id": 3}, {"id": 11, "bbox": [75.9, 630.28, 266.33, 281.32], "category_id": 1}, {"id": 12, "bbox": [762.73, 454.42, 79.55, 47.01], "category_id": 2}, {"id": 13, "bbox": [509.96, 849.39, 66.96, 38.54], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 674, 265, 687], "ImageBB": [73, 691, 411, 942]}, "reactions": [{"reactants": [0], "conditions": [4, 8], "products": [1]}, {"reactants": [11], "conditions": [7, 6, 2, 13], "products": [5]}], "diagram_type": "multiple"}, {"id": 1113, "width": 2080, "height": 648, "file_name": "jo9816515-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [310.08, 240.52, 204.98, 44.78], "category_id": 2}, {"id": 1, "bbox": [0.0, 4.16, 288.22, 352.98], "category_id": 1}, {"id": 2, "bbox": [1464.01, 233.23, 206.03, 45.82], "category_id": 2}, {"id": 3, "bbox": [559.8, 79.13, 390.19, 305.08], "category_id": 1}, {"id": 4, "bbox": [1801.14, 394.62, 139.43, 55.19], "category_id": 3}, {"id": 5, "bbox": [74.92, 399.83, 126.94, 58.31], "category_id": 3}, {"id": 6, "bbox": [7.28, 471.67, 1619.62, 176.33], "category_id": 4}, {"id": 7, "bbox": [1204.92, 397.75, 129.03, 57.26], "category_id": 3}, {"id": 8, "bbox": [316.32, 172.84, 198.74, 60.39], "category_id": 2}, {"id": 9, "bbox": [675.3, 394.62, 135.27, 54.15], "category_id": 3}, {"id": 10, "bbox": [1697.09, 78.09, 382.91, 306.12], "category_id": 1}, {"id": 11, "bbox": [1056.13, 57.27, 388.11, 296.75], "category_id": 1}, {"id": 12, "bbox": [1466.09, 169.72, 196.66, 54.14], "category_id": 2}], "caption": "Scheme 10", "pdf": {"Page": 8, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [387, 531, 458, 545], "ImageBB": [165, 551, 685, 713]}, "reactions": [{"reactants": [1], "conditions": [8, 0], "products": [3]}, {"reactants": [3], "conditions": [], "products": [11]}, {"reactants": [10], "conditions": [12, 2], "products": [11]}], "diagram_type": "single"}, {"id": 1102, "width": 1316, "height": 672, "file_name": "jo9717245-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [545.1, 136.87, 195.52, 152.66], "category_id": 1}, {"id": 1, "bbox": [0.0, 271.1, 311.39, 144.11], "category_id": 1}, {"id": 2, "bbox": [955.89, 0.0, 360.11, 138.84], "category_id": 1}, {"id": 3, "bbox": [450.3, 523.78, 312.05, 144.11], "category_id": 1}, {"id": 4, "bbox": [616.2, 338.88, 97.43, 106.6], "category_id": 1}, {"id": 5, "bbox": [49.37, 0.0, 273.21, 152.0], "category_id": 1}, {"id": 6, "bbox": [955.24, 266.5, 273.2, 147.39], "category_id": 1}, {"id": 7, "bbox": [339.7, 282.95, 183.01, 51.98], "category_id": 1}, {"id": 8, "bbox": [358.13, 21.71, 142.2, 48.04], "category_id": 1}, {"id": 9, "bbox": [748.1, 270.45, 190.02, 65.35], "category_id": 1}, {"id": 10, "bbox": [743.25, 0.0, 188.94, 69.75], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [78, 84, 407, 252]}, "reactions": [{"reactants": [0, 8], "conditions": [], "products": [5]}, {"reactants": [0, 10], "conditions": [], "products": [2]}, {"reactants": [0, 7], "conditions": [], "products": [1]}, {"reactants": [0, 9], "conditions": [], "products": [6]}, {"reactants": [0, 4], "conditions": [], "products": [3]}], "diagram_type": "tree"}, {"id": 1160, "width": 1352, "height": 960, "file_name": "ol060123+-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1036.83, 35.15, 58.84, 41.91], "category_id": 3}, {"id": 1, "bbox": [77.78, 781.44, 213.72, 73.01], "category_id": 1}, {"id": 2, "bbox": [1092.29, 251.47, 122.41, 54.75], "category_id": 2}, {"id": 3, "bbox": [519.43, 751.02, 75.75, 52.05], "category_id": 2}, {"id": 4, "bbox": [505.22, 32.45, 129.19, 50.02], "category_id": 2}, {"id": 5, "bbox": [698.66, 526.59, 55.46, 46.65], "category_id": 3}, {"id": 6, "bbox": [742.62, 351.51, 115.65, 56.79], "category_id": 2}, {"id": 7, "bbox": [315.85, 32.45, 75.75, 47.32], "category_id": 2}, {"id": 8, "bbox": [1100.4, 583.38, 113.63, 60.16], "category_id": 2}, {"id": 9, "bbox": [259.71, 297.43, 113.63, 57.46], "category_id": 2}, {"id": 10, "bbox": [867.07, 246.74, 113.62, 58.13], "category_id": 2}, {"id": 11, "bbox": [641.17, 194.01, 129.86, 55.43], "category_id": 2}, {"id": 12, "bbox": [906.97, 761.84, 263.77, 127.08], "category_id": 1}, {"id": 13, "bbox": [906.97, 371.79, 370.63, 127.76], "category_id": 1}, {"id": 14, "bbox": [80.2, 395.28, 153.27, 86.43], "category_id": 1}, {"id": 15, "bbox": [724.36, 4.06, 127.15, 45.96], "category_id": 2}, {"id": 16, "bbox": [135.94, 34.48, 61.55, 45.29], "category_id": 3}, {"id": 17, "bbox": [197.49, 175.76, 194.11, 56.1], "category_id": 2}, {"id": 18, "bbox": [411.89, 360.98, 280.68, 138.57], "category_id": 1}], "caption": "Scheme 2. Possible Reaction Mechanism", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [497, 575, 717, 588], "ImageBB": [439, 593, 777, 833]}, "reactions": [{"reactants": [16, 7, 4], "conditions": [15], "products": [0]}, {"reactants": [16], "conditions": [17], "products": [14, 9]}, {"reactants": [14], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [14]}, {"reactants": [1, 3], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [1]}, {"reactants": [18], "conditions": [11], "products": [0]}, {"reactants": [18], "conditions": [6], "products": [13]}, {"reactants": [13], "conditions": [2], "products": [0, 10]}, {"reactants": [18], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [5], "products": [18]}, {"reactants": [12], "conditions": [8], "products": [13]}], "diagram_type": "graph"}, {"id": 129, "width": 1352, "height": 1216, "file_name": "op900102a-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [908.8, 4.0, 443.2, 176.2], "category_id": 1}, {"id": 1, "bbox": [3.4, 49.3, 448.6, 79.0], "category_id": 1}, {"id": 2, "bbox": [500.8, 4.0, 330.9, 76.5], "category_id": 2}, {"id": 3, "bbox": [500.42, 100.36, 289.9, 50.15], "category_id": 2}, {"id": 4, "bbox": [3.0, 200.0, 1345.0, 984.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [2, 3], "products": [0]}], "corefs": [], "caption": "Table 4. Nucleophilic epoxide opening and silanation of (3-glycidoxypropyl)trimethoxysilane to S4x ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 365, 73], "ImageBB": [58, 85, 396, 389]}, "diagram_type": "single"}, {"id": 752, "width": 1348, "height": 604, "file_name": "jo990938e-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [707.56, 148.53, 95.56, 40.67], "category_id": 3}, {"id": 1, "bbox": [985.09, 148.53, 96.57, 42.7], "category_id": 3}, {"id": 2, "bbox": [228.0, 148.0, 187.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [628.0, 1.0, 257.0, 193.0], "category_id": 1}, {"id": 4, "bbox": [184.0, 21.0, 273.0, 125.0], "category_id": 1}, {"id": 5, "bbox": [62.0, 545.0, 1228.0, 54.0], "category_id": 2}, {"id": 6, "bbox": [13.0, 229.0, 1335.0, 299.0], "category_id": 4}, {"id": 7, "bbox": [439.0, 147.0, 165.0, 46.0], "category_id": 2}, {"id": 8, "bbox": [496.0, 112.0, 50.0, 40.0], "category_id": 2}, {"id": 9, "bbox": [464.0, 39.0, 140.0, 44.0], "category_id": 2}, {"id": 10, "bbox": [905.0, 4.0, 260.0, 192.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [9, 8, 7], "products": [3, 10]}], "corefs": [[4, 2], [3, 0], [10, 1]], "caption": "Table 4. Additions of Allenylmetal Reagents Prepared          from Allenyl Iodide 6 to Aldehyde 3a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [447, 64, 767, 89], "ImageBB": [439, 98, 776, 249]}, "diagram_type": "single"}, {"id": 735, "width": 1344, "height": 968, "file_name": "ol015948s-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [595.0, 85.0, 363.0, 134.0], "category_id": 2}, {"id": 1, "bbox": [23.0, 444.0, 1258.0, 517.0], "category_id": 4}, {"id": 2, "bbox": [660.0, 231.0, 250.0, 67.0], "category_id": 2}, {"id": 3, "bbox": [117.1, 39.4, 147.6, 311.8], "category_id": 1}, {"id": 4, "bbox": [1007.1, 6.0, 220.9, 379.2], "category_id": 1}, {"id": 5, "bbox": [381.1, 109.2, 139.9, 169.7], "category_id": 1}], "reactions": [{"reactants": [3, 5], "conditions": [0, 2], "products": [4]}], "corefs": [], "caption": "Table 3. Direct Reductive Amination Using Alkylaminesa", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 195, 381, 209], "ImageBB": [74, 220, 410, 462]}, "diagram_type": "single"}, {"id": 637, "width": 1352, "height": 1632, "file_name": "ol501085y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [10.0, 291.0, 1341.0, 997.0], "category_id": 4}, {"id": 1, "bbox": [269.0, 1548.0, 340.0, 80.0], "category_id": 3}, {"id": 2, "bbox": [708.0, 1542.0, 371.0, 90.0], "category_id": 3}, {"id": 3, "bbox": [511.94, 119.93, 452.17, 96.74], "category_id": 2}, {"id": 4, "bbox": [1046.9, 3.0, 303.0, 227.5], "category_id": 1}, {"id": 5, "bbox": [664.72, 1312.21, 465.48, 219.79], "category_id": 1}, {"id": 6, "bbox": [222.9, 1295.59, 402.6, 249.31], "category_id": 1}, {"id": 7, "bbox": [25.49, 216.41, 212.61, 55.59], "category_id": 3}, {"id": 8, "bbox": [327.0, 215.9, 167.0, 60.0], "category_id": 2}, {"id": 9, "bbox": [326.69, 79.31, 151.0, 71.4], "category_id": 2}, {"id": 10, "bbox": [542.4, 9.0, 362.0, 95.1], "category_id": 2}, {"id": 11, "bbox": [0.0, 0.0, 257.1, 230.0], "category_id": 1}], "reactions": [{"reactants": [11, 9], "conditions": [10, 3], "products": [4]}], "corefs": [[11, 7], [6, 1], [5, 2]], "caption": "Table 1. Exploration of E\ufb03cient Asymmetric Nitro-Mannich Catalysis for Isatin-Derived N-Boc Ketimine (1a) ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 365, 417, 397], "ImageBB": [82, 402, 420, 810]}, "diagram_type": "single"}, {"id": 1152, "width": 1280, "height": 1232, "file_name": "ol049640n-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [71.72, 247.81, 228.59, 100.53], "category_id": 3}, {"id": 1, "bbox": [1049.48, 1133.38, 133.83, 49.94], "category_id": 3}, {"id": 2, "bbox": [71.08, 79.4, 238.83, 147.28], "category_id": 1}, {"id": 3, "bbox": [71.08, 876.61, 42.26, 51.22], "category_id": 2}, {"id": 4, "bbox": [1142.97, 302.87, 37.78, 48.03], "category_id": 2}, {"id": 5, "bbox": [978.41, 427.1, 301.59, 237.56], "category_id": 1}, {"id": 6, "bbox": [900.29, 521.23, 46.1, 42.26], "category_id": 2}, {"id": 7, "bbox": [834.98, 838.19, 435.42, 312.48], "category_id": 1}, {"id": 8, "bbox": [483.44, 502.66, 39.06, 54.42], "category_id": 2}, {"id": 9, "bbox": [311.84, 837.55, 429.65, 313.12], "category_id": 1}, {"id": 10, "bbox": [859.95, 84.52, 45.46, 40.34], "category_id": 2}, {"id": 11, "bbox": [980.33, 0.0, 299.67, 230.52], "category_id": 1}, {"id": 12, "bbox": [566.68, 83.24, 223.48, 147.28], "category_id": 1}, {"id": 13, "bbox": [219.63, 699.24, 136.39, 53.78], "category_id": 3}, {"id": 14, "bbox": [394.44, 78.12, 72.99, 50.59], "category_id": 2}, {"id": 15, "bbox": [522.5, 1135.94, 135.75, 49.3], "category_id": 3}, {"id": 16, "bbox": [1024.51, 1187.81, 181.85, 43.54], "category_id": 2}, {"id": 17, "bbox": [487.92, 1187.81, 192.1, 44.19], "category_id": 2}, {"id": 18, "bbox": [567.96, 423.9, 309.92, 234.36], "category_id": 1}, {"id": 19, "bbox": [0.0, 409.81, 432.22, 316.96], "category_id": 1}], "caption": "Scheme 1. Synthesis of Four New Chiral Nonracemic                   1-Azadienesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [98, 389, 384, 416], "ImageBB": [82, 420, 402, 728]}, "reactions": [{"reactants": [2], "conditions": [14], "products": [12]}, {"reactants": [12], "conditions": [10], "products": [11]}, {"reactants": [11], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [6], "products": [18]}, {"reactants": [18], "conditions": [8], "products": [19]}, {"reactants": [19], "conditions": [3], "products": [9, 7]}], "diagram_type": "tree"}, {"id": 948, "width": 1352, "height": 676, "file_name": "acs.orglett.5b02680-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.51, 175.98, 280.68, 44.67], "category_id": 2}, {"id": 1, "bbox": [549.86, 54.82, 225.22, 102.21], "category_id": 2}, {"id": 2, "bbox": [624.26, 578.7, 89.28, 42.64], "category_id": 3}, {"id": 3, "bbox": [89.28, 36.55, 437.59, 223.36], "category_id": 1}, {"id": 4, "bbox": [858.27, 4.06, 400.4, 257.88], "category_id": 1}, {"id": 5, "bbox": [196.14, 303.23, 222.51, 96.79], "category_id": 2}, {"id": 6, "bbox": [479.52, 329.62, 405.13, 258.56], "category_id": 1}, {"id": 7, "bbox": [938.08, 230.13, 94.69, 43.99], "category_id": 3}, {"id": 8, "bbox": [272.56, 228.1, 85.22, 46.02], "category_id": 3}, {"id": 9, "bbox": [938.08, 304.58, 177.88, 92.05], "category_id": 2}], "caption": "Scheme 2. Reduction of Isoxazoles 3a\u2212d to Quinolinones 4a\u2212 d Followed by Condensation with Acetone Delivers DBNs 5a\u2212 d ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 493, 417, 538], "ImageBB": [82, 544, 420, 713]}, "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [4]}, {"reactants": [3], "conditions": [5], "products": [6]}, {"reactants": [6], "conditions": [9], "products": [4]}], "diagram_type": "graph"}, {"id": 758, "width": 1348, "height": 976, "file_name": "jo9902998-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [8.0, 337.1, 1340.0, 638.9], "category_id": 4}, {"id": 1, "bbox": [578.3, 0.0, 306.7, 110.0], "category_id": 2}, {"id": 2, "bbox": [459.5, 94.0, 92.7, 56.4], "category_id": 2}, {"id": 3, "bbox": [899.2, 58.9, 297.2, 137.6], "category_id": 1}, {"id": 4, "bbox": [537.5, 240.0, 370.2, 68.8], "category_id": 2}, {"id": 5, "bbox": [159.1, 55.7, 293.2, 135.0], "category_id": 1}, {"id": 6, "bbox": [1054.23, 203.96, 65.9, 56.5], "category_id": 3}, {"id": 7, "bbox": [288.0, 205.0, 78.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [673.01, 137.07, 127.1, 43.0], "category_id": 2}], "reactions": [{"reactants": [5, 2], "conditions": [1, 8], "products": [3]}], "corefs": [[5, 7], [3, 6]], "caption": "Table 1. Pd-Catalyzed Allylic Alkylation of 5a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [472, 63, 741, 76], "ImageBB": [439, 82, 776, 326]}, "diagram_type": "single"}, {"id": 31, "width": 1352, "height": 972, "file_name": "ja806060a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [717.89, 6.77, 255.35, 188.87], "category_id": 1}, {"id": 1, "bbox": [476.75, 46.53, 214.91, 42.66], "category_id": 2}, {"id": 2, "bbox": [38.12, 13.04, 144.98, 168.8], "category_id": 1}, {"id": 3, "bbox": [222.49, 13.04, 227.75, 111.11], "category_id": 1}, {"id": 4, "bbox": [1000.05, 8.22, 306.93, 181.75], "category_id": 1}, {"id": 5, "bbox": [468.19, 111.79, 229.89, 72.62], "category_id": 2}, {"id": 6, "bbox": [89.43, 211.3, 29.82, 38.38], "category_id": 3}, {"id": 7, "bbox": [321.61, 211.3, 79.03, 35.17], "category_id": 3}, {"id": 8, "bbox": [782.75, 211.3, 76.89, 35.17], "category_id": 3}, {"id": 9, "bbox": [1157.22, 211.3, 26.61, 35.17], "category_id": 3}, {"id": 10, "bbox": [4.91, 260.51, 1339.41, 707.79], "category_id": 4}], "reactions": [{"reactants": [2, 3], "conditions": [1, 5], "products": [0, 4]}], "corefs": [[2, 6], [3, 7], [0, 8], [4, 9]], "caption": "Table 1. [3 + 2] Annulation Reactions of Ethyl 2,3-Butadienoate 6 with the Unsaturated Esters 7a,b and Enones 7c-k Promoted by Phosphine 5c ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 54, 389, 92], "ImageBB": [58, 101, 396, 344]}, "diagram_type": "single"}, {"id": 41, "width": 1340, "height": 1444, "file_name": "ja5017206-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [703.82, 49.61, 118.82, 41.68], "category_id": 2}, {"id": 1, "bbox": [1214.5, 71.32, 118.06, 42.44], "category_id": 3}, {"id": 2, "bbox": [882.33, 5.49, 275.89, 175.28], "category_id": 1}, {"id": 3, "bbox": [58.78, 262.62, 1224.28, 1172.1], "category_id": 4}, {"id": 4, "bbox": [6.61, 5.49, 242.36, 175.28], "category_id": 1}, {"id": 5, "bbox": [885.78, 197.12, 259.58, 41.68], "category_id": 3}, {"id": 6, "bbox": [77.09, 194.87, 103.09, 43.19], "category_id": 3}, {"id": 7, "bbox": [709.81, 129.73, 107.58, 31.95], "category_id": 2}, {"id": 8, "bbox": [358.63, 129.73, 237.12, 40.94], "category_id": 2}, {"id": 9, "bbox": [340.66, 46.61, 273.81, 43.19], "category_id": 2}], "reactions": [{"reactants": [4], "conditions": [9, 8, 0, 7], "products": [2, 1]}], "corefs": [[4, 6], [2, 5]], "caption": "Table 2. APF Rearrangement of Enantiomerically Pure and Racemic (Z)-1a Catalyzed by (R)-3aa ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 416, 125], "ImageBB": [83, 131, 418, 492]}, "diagram_type": "single"}, {"id": 70, "width": 1412, "height": 3028, "file_name": "ja208286b-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [188.6, 2073.83, 90.24, 43.48], "category_id": 3}, {"id": 1, "bbox": [529.23, 1965.29, 292.34, 182.9], "category_id": 2}, {"id": 2, "bbox": [718.96, 1854.09, 44.36, 33.77], "category_id": 3}, {"id": 3, "bbox": [780.74, 1495.81, 27.59, 32.89], "category_id": 3}, {"id": 4, "bbox": [844.28, 1495.81, 163.49, 40.83], "category_id": 2}, {"id": 5, "bbox": [540.71, 1184.29, 218.2, 38.19], "category_id": 2}, {"id": 6, "bbox": [531.0, 1052.8, 242.91, 39.95], "category_id": 2}, {"id": 7, "bbox": [1156.67, 1165.76, 73.48, 35.54], "category_id": 2}, {"id": 8, "bbox": [1062.25, 1164.0, 47.89, 35.53], "category_id": 3}, {"id": 9, "bbox": [1273.16, 2057.95, 74.34, 33.76], "category_id": 2}, {"id": 10, "bbox": [99.7, 449.9, 375.6, 370.53], "category_id": 1}, {"id": 11, "bbox": [513.96, 307.59, 300.63, 192.61], "category_id": 1}, {"id": 12, "bbox": [909.17, 336.81, 267.59, 495.09], "category_id": 1}, {"id": 13, "bbox": [136.54, 1001.42, 252.34, 273.95], "category_id": 1}, {"id": 14, "bbox": [489.81, 837.5, 300.63, 193.88], "category_id": 1}, {"id": 15, "bbox": [900.27, 881.97, 266.32, 493.79], "category_id": 1}, {"id": 16, "bbox": [483.46, 1277.18, 374.33, 370.52], "category_id": 1}, {"id": 17, "bbox": [80.63, 1768.97, 305.71, 272.67], "category_id": 1}, {"id": 18, "bbox": [508.88, 1701.62, 301.9, 192.61], "category_id": 1}, {"id": 19, "bbox": [906.62, 1762.61, 304.45, 495.06], "category_id": 1}, {"id": 20, "bbox": [529.45, 527.7, 248.95, 45.11], "category_id": 2}, {"id": 21, "bbox": [547.76, 620.39, 218.21, 39.95], "category_id": 2}, {"id": 22, "bbox": [1163.73, 696.29, 107.02, 39.06], "category_id": 2}, {"id": 23, "bbox": [416.28, 698.05, 27.62, 33.77], "category_id": 3}, {"id": 24, "bbox": [1094.02, 695.4, 47.0, 36.42], "category_id": 3}, {"id": 25, "bbox": [812.51, 406.83, 44.36, 33.77], "category_id": 3}, {"id": 26, "bbox": [339.5, 1183.41, 23.18, 34.65], "category_id": 3}, {"id": 27, "bbox": [1301.4, 1941.46, 90.25, 40.83], "category_id": 3}, {"id": 28, "bbox": [788.68, 931.91, 46.12, 34.65], "category_id": 3}, {"id": 29, "bbox": [1131.08, 2055.3, 111.43, 40.83], "category_id": 3}], "reactions": [{"reactants": [10], "conditions": [11, 20, 21], "products": [12]}, {"reactants": [13], "conditions": [14, 6, 5, 16], "products": [15]}, {"reactants": [17], "conditions": [18, 1], "products": [19, 27]}], "corefs": [[10, 23], [11, 25], [12, 24], [13, 26], [14, 28], [15, 8], [16, 3], [17, 0], [18, 2], [19, 29]], "caption": "Figure 1. Single-crystal X-ray structure of the novel meta product 3a. Ellipsoids are represented at 30% probability. 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Construction of Naphthopyrazine by RCM", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 500, 753, 515], "ImageBB": [448, 521, 787, 796]}, "reactions": [{"reactants": [16], "conditions": [4, 0], "products": [6]}, {"reactants": [16], "conditions": [7, 9], "products": [3]}, {"reactants": [3], "conditions": [11, 12], "products": [1]}], "diagram_type": "tree"}, {"id": 53, "width": 1252, "height": 1948, "file_name": "ja407179c-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [946.39, 6.34, 270.72, 186.03], "category_id": 1}, {"id": 1, "bbox": [390.02, 201.73, 27.55, 32.75], "category_id": 3}, {"id": 2, "bbox": [602.45, 45.13, 272.14, 86.21], "category_id": 2}, {"id": 3, "bbox": [682.87, 157.73, 120.28, 36.53], "category_id": 2}, {"id": 4, "bbox": [99.54, 201.25, 22.34, 33.23], "category_id": 3}, {"id": 5, "bbox": [251.88, 57.9, 301.47, 131.63], "category_id": 1}, {"id": 6, "bbox": [34.72, 57.9, 186.04, 131.63], "category_id": 1}, {"id": 7, "bbox": [1.58, 256.67, 1246.96, 1688.81], "category_id": 4}, {"id": 8, "bbox": [1059.46, 201.25, 91.42, 34.65], "category_id": 3}], "reactions": [{"reactants": [6, 5], "conditions": [2, 3], "products": [0]}], "corefs": [[6, 4], [5, 1], [0, 8]], "caption": "Table 1. Au(I)-Catalyzed Vinylogous [3 + 2] Reaction of Enol Ethers and Various Vinyl Diazoacetates ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 187, 404, 217], "ImageBB": [94, 223, 407, 710]}, "diagram_type": "single"}, {"id": 1293, "width": 1356, "height": 444, "file_name": "op200112g-Scheme-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [765.84, 6.79, 158.74, 110.69], "category_id": 1}, {"id": 1, "bbox": [1135.54, 48.21, 220.46, 52.29], "category_id": 2}, {"id": 2, "bbox": [0.0, 48.21, 303.9, 93.04], "category_id": 1}, {"id": 3, "bbox": [822.15, 315.77, 227.92, 81.49], "category_id": 1}, {"id": 4, "bbox": [632.21, 32.6, 90.22, 50.25], "category_id": 1}, {"id": 5, "bbox": [433.46, 6.79, 171.62, 150.07], "category_id": 1}, {"id": 6, "bbox": [1036.5, 18.33, 48.84, 78.78], "category_id": 1}], "caption": "Scheme 8. Proposed mechanism for in situ generation of MOM-Cl ", "pdf": {"Page": 8, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 625, 389, 655], "ImageBB": [71, 665, 410, 776]}, "reactions": [{"reactants": [2, 5], "conditions": [4], "products": [0, 6, 1]}, {"reactants": [0, 6], "conditions": [], "products": [3]}], "diagram_type": "tree"}, {"id": 1359, "width": 956, "height": 1768, "file_name": "op900188v-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [641.03, 1332.85, 286.47, 360.86], "category_id": 1}, {"id": 1, "bbox": [458.89, 120.28, 46.86, 39.8], "category_id": 2}, {"id": 2, "bbox": [684.35, 33.61, 209.55, 285.67], "category_id": 1}, {"id": 3, "bbox": [651.64, 631.49, 269.67, 359.97], "category_id": 1}, {"id": 4, "bbox": [616.27, 1024.18, 337.76, 103.48], "category_id": 3}, {"id": 5, "bbox": [682.59, 1720.24, 201.59, 47.76], "category_id": 3}, {"id": 6, "bbox": [24.76, 631.49, 293.54, 361.74], "category_id": 1}, {"id": 7, "bbox": [807.26, 1183.38, 98.14, 53.95], "category_id": 2}, {"id": 8, "bbox": [100.8, 23.88, 210.43, 289.21], "category_id": 1}, {"id": 9, "bbox": [469.5, 1441.64, 50.4, 39.8], "category_id": 2}, {"id": 10, "bbox": [458.89, 1522.13, 95.49, 54.83], "category_id": 2}, {"id": 11, "bbox": [159.15, 377.66, 53.94, 46.87], "category_id": 3}, {"id": 12, "bbox": [469.5, 738.51, 46.86, 41.57], "category_id": 2}, {"id": 13, "bbox": [24.76, 1332.85, 308.58, 360.86], "category_id": 1}, {"id": 14, "bbox": [0.0, 1022.42, 343.95, 108.78], "category_id": 3}, {"id": 15, "bbox": [75.16, 1720.24, 201.59, 47.76], "category_id": 3}, {"id": 16, "bbox": [755.97, 378.54, 51.29, 45.11], "category_id": 3}, {"id": 17, "bbox": [719.5, 1191.58, 34.18, 38.73], "category_id": 2}, {"id": 18, "bbox": [717.95, 494.4, 38.02, 46.88], "category_id": 2}], "caption": "Scheme 3. Preparation of aryl-propargyl ether substratesa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 46, 750, 60], "ImageBB": [474, 70, 713, 512]}, "reactions": [{"reactants": [8], "conditions": [1], "products": [2]}, {"reactants": [2], "conditions": [18], "products": [3]}, {"reactants": [3], "conditions": [12], "products": [6]}, {"reactants": [3], "conditions": [17, 7], "products": [0]}, {"reactants": [0], "conditions": [9, 10], "products": [13]}], "diagram_type": "tree"}, {"id": 950, "width": 1704, "height": 1680, "file_name": "acs.orglett.5b02743-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [886.52, 431.4, 312.84, 62.24], "category_id": 2}, {"id": 1, "bbox": [601.81, 1058.89, 475.66, 71.62], "category_id": 2}, {"id": 2, "bbox": [1196.81, 682.91, 381.88, 243.84], "category_id": 1}, {"id": 3, "bbox": [1280.34, 493.64, 239.54, 66.5], "category_id": 2}, {"id": 4, "bbox": [366.54, 1064.01, 197.77, 186.71], "category_id": 1}, {"id": 5, "bbox": [1309.33, 307.78, 311.98, 215.7], "category_id": 1}, {"id": 6, "bbox": [1277.79, 1040.99, 211.4, 150.05], "category_id": 1}, {"id": 7, "bbox": [307.46, 280.24, 56.47, 62.72], "category_id": 2}, {"id": 8, "bbox": [307.46, 665.45, 56.47, 58.48], "category_id": 2}, {"id": 9, "bbox": [366.54, 728.1, 206.29, 150.05], "category_id": 1}, {"id": 10, "bbox": [640.17, 1207.24, 154.29, 85.26], "category_id": 1}, {"id": 11, "bbox": [886.52, 329.95, 308.58, 78.43], "category_id": 2}, {"id": 12, "bbox": [601.81, 1161.2, 59.67, 61.39], "category_id": 2}, {"id": 13, "bbox": [366.54, 18.76, 177.31, 146.64], "category_id": 1}, {"id": 14, "bbox": [788.49, 812.5, 181.57, 70.77], "category_id": 2}, {"id": 15, "bbox": [722.86, 122.77, 243.79, 62.24], "category_id": 2}, {"id": 16, "bbox": [1225.79, 1220.03, 393.82, 64.8], "category_id": 2}, {"id": 17, "bbox": [790.2, 1191.04, 183.27, 121.07], "category_id": 1}, {"id": 18, "bbox": [732.23, 0.0, 234.42, 78.44], "category_id": 2}, {"id": 19, "bbox": [1195.95, 17.9, 190.95, 145.79], "category_id": 1}, {"id": 20, "bbox": [306.87, 992.39, 261.7, 63.09], "category_id": 2}, {"id": 21, "bbox": [976.03, 1173.14, 191.79, 157.73], "category_id": 1}, {"id": 22, "bbox": [741.61, 598.51, 287.27, 187.56], "category_id": 1}, {"id": 23, "bbox": [0.0, 0.0, 0.85, 0.85], "category_id": 3}, {"id": 24, "bbox": [366.54, 301.81, 441.56, 225.93], "category_id": 1}, {"id": 25, "bbox": [304.32, 0.0, 63.08, 63.09], "category_id": 2}], "caption": "Scheme 1. Recent New Protocols for Synthetizing Compounds Containing a Sul\ufb01nyl Group ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 671, 364, 701], "ImageBB": [10, 707, 436, 1127]}, "reactions": [{"reactants": [13], "conditions": [18, 15], "products": [19]}, {"reactants": [24], "conditions": [11, 0], "products": [5]}, {"reactants": [9], "conditions": [22, 14], "products": [2]}, {"reactants": [4], "conditions": [1, 12, 10, 17, 21], "products": [6]}], "diagram_type": "multiple"}, {"id": 83, "width": 1344, "height": 868, "file_name": "ja074044k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [810.11, 386.85, 46.08, 34.77], "category_id": 3}, {"id": 1, "bbox": [821.41, 174.37, 25.69, 34.78], "category_id": 3}, {"id": 2, "bbox": [134.25, 26.2, 264.2, 118.52], "category_id": 1}, {"id": 3, "bbox": [718.56, 4.84, 328.63, 145.42], "category_id": 1}, {"id": 4, "bbox": [744.56, 239.81, 299.24, 135.48], "category_id": 1}, {"id": 5, "bbox": [248.4, 170.98, 24.6, 33.53], "category_id": 3}, {"id": 6, "bbox": [161.37, 245.57, 234.82, 107.0], "category_id": 1}, {"id": 7, "bbox": [245.01, 387.98, 24.6, 33.53], "category_id": 3}, {"id": 8, "bbox": [3.14, 447.88, 1336.78, 413.39], "category_id": 4}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [6], "conditions": [], "products": [4]}], "corefs": [[2, 5], [3, 1], [6, 7], [4, 0]], "caption": "Table 1. Yields and Enantioselectivities in Allylic Alkylationsa Using Pd Catalysts Containing Ligands 1-6 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 63, 380, 88], "ImageBB": [74, 95, 410, 312]}, "diagram_type": "multiple"}, {"id": 259, "width": 1348, "height": 668, "file_name": "ol8019605-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [472.0, 8.0, 353.0, 94.0], "category_id": 2}, {"id": 1, "bbox": [462.0, 224.0, 283.0, 218.0], "category_id": 1}, {"id": 2, "bbox": [523.0, 126.0, 257.0, 50.0], "category_id": 2}, {"id": 3, "bbox": [805.0, 227.0, 128.0, 267.0], "category_id": 1}, {"id": 4, "bbox": [883.0, 0.0, 211.0, 191.0], "category_id": 1}, {"id": 5, "bbox": [247.0, 1.0, 219.0, 193.0], "category_id": 1}, {"id": 6, "bbox": [853.0, 511.0, 36.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [583.0, 508.0, 34.0, 44.0], "category_id": 3}, {"id": 8, "bbox": [375.0, 272.0, 68.0, 46.0], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [0, 2], "products": [4]}], "corefs": [[1, 7], [3, 6]], "caption": "Table 1. Borylation of Sterically Hindered m-Terphenylsa", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 367, 724, 382], "ImageBB": [425, 392, 762, 559]}, "diagram_type": "single"}, {"id": 1044, "width": 1328, "height": 1512, "file_name": "jo010404p-Scheme-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [182.25, 0.0, 387.95, 396.34], "category_id": 1}, {"id": 1, "bbox": [890.85, 929.59, 65.79, 49.16], "category_id": 3}, {"id": 2, "bbox": [622.38, 648.97, 84.7, 58.24], "category_id": 2}, {"id": 3, "bbox": [735.06, 1133.05, 368.29, 270.03], "category_id": 1}, {"id": 4, "bbox": [717.67, 574.85, 378.88, 340.37], "category_id": 1}, {"id": 5, "bbox": [366.78, 412.98, 68.81, 55.22], "category_id": 3}, {"id": 6, "bbox": [889.34, 1457.54, 61.25, 49.92], "category_id": 3}, {"id": 7, "bbox": [348.63, 1459.05, 67.3, 49.92], "category_id": 3}, {"id": 8, "bbox": [0.0, 156.57, 69.57, 62.02], "category_id": 3}, {"id": 9, "bbox": [717.67, 30.26, 385.68, 357.76], "category_id": 1}, {"id": 10, "bbox": [348.63, 906.9, 75.62, 51.43], "category_id": 3}, {"id": 11, "bbox": [200.4, 1131.54, 356.19, 313.9], "category_id": 1}, {"id": 12, "bbox": [84.7, 130.85, 83.18, 53.71], "category_id": 2}, {"id": 13, "bbox": [1262.92, 1237.43, 64.28, 56.73], "category_id": 3}, {"id": 14, "bbox": [899.17, 412.23, 68.06, 50.67], "category_id": 3}, {"id": 15, "bbox": [204.18, 568.04, 364.51, 322.97], "category_id": 1}], "caption": "Scheme 7", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 283, 270, 297], "ImageBB": [76, 303, 408, 681]}, "reactions": [{"reactants": [8], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [4]}, {"reactants": [4], "conditions": [], "products": [9]}, {"reactants": [4], "conditions": [2], "products": [15]}, {"reactants": [15], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [], "products": [15]}, {"reactants": [15], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [15]}, {"reactants": [11], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [11]}, {"reactants": [3], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [3]}], "diagram_type": "graph"}, {"id": 285, "width": 1356, "height": 2204, "file_name": "ol800086s-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [325.0, 59.0, 470.0, 56.0], "category_id": 2}, {"id": 1, "bbox": [378.0, 123.0, 358.0, 88.0], "category_id": 2}, {"id": 2, "bbox": [905.0, 1959.0, 302.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [461.0, 1965.0, 297.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [258.0, 1787.0, 310.0, 190.0], "category_id": 1}, {"id": 5, "bbox": [691.0, 1787.0, 317.0, 189.0], "category_id": 1}, {"id": 6, "bbox": [3.0, 2042.0, 1353.0, 125.0], "category_id": 2}, {"id": 7, "bbox": [11.0, 302.0, 1345.0, 1482.0], "category_id": 4}, {"id": 8, "bbox": [3.0, 51.0, 43.0, 141.0], "category_id": 1}, {"id": 9, "bbox": [70.0, 3.0, 222.0, 234.0], "category_id": 1}, {"id": 10, "bbox": [806.0, 0.0, 257.0, 232.0], "category_id": 1}, {"id": 11, "bbox": [1095.0, 0.0, 257.0, 231.0], "category_id": 1}, {"id": 12, "bbox": [1174.0, 245.0, 96.0, 46.0], "category_id": 3}, {"id": 13, "bbox": [896.0, 245.0, 104.0, 51.0], "category_id": 3}, {"id": 14, "bbox": [211.0, 245.0, 61.0, 43.0], "category_id": 3}, {"id": 15, "bbox": [6.0, 242.0, 194.0, 54.0], "category_id": 3}], "reactions": [{"reactants": [8, 9], "conditions": [0, 1], "products": [10, 11]}], "corefs": [[8, 15], [9, 14], [10, 13], [11, 12], [4, 3], [5, 2]], "caption": "Table 2. Aliphatic Alkyne Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 331, 253, 344], "ImageBB": [73, 345, 412, 896]}, "diagram_type": "single"}, {"id": 1073, "width": 2820, "height": 1232, "file_name": "jo4027148-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1627.95, 436.18, 74.77, 56.46], "category_id": 3}, {"id": 1, "bbox": [132.61, 149.63, 342.8, 231.5], "category_id": 1}, {"id": 2, "bbox": [1702.72, 571.69, 892.98, 602.74], "category_id": 1}, {"id": 3, "bbox": [708.17, 801.78, 64.9, 46.58], "category_id": 3}, {"id": 4, "bbox": [1296.44, 200.44, 66.3, 50.82], "category_id": 3}, {"id": 5, "bbox": [2092.08, 1130.67, 156.58, 60.7], "category_id": 3}, {"id": 6, "bbox": [1193.46, 297.84, 272.26, 138.34], "category_id": 2}, {"id": 7, "bbox": [2382.68, 431.94, 73.36, 62.11], "category_id": 3}, {"id": 8, "bbox": [179.16, 678.97, 362.55, 381.13], "category_id": 1}, {"id": 9, "bbox": [1987.68, 145.39, 228.54, 107.28], "category_id": 2}, {"id": 10, "bbox": [949.4, 604.16, 469.77, 529.34], "category_id": 1}, {"id": 11, "bbox": [1093.3, 1033.28, 77.59, 70.57], "category_id": 3}, {"id": 12, "bbox": [632.0, 606.98, 213.01, 217.38], "category_id": 1}, {"id": 13, "bbox": [293.43, 391.01, 77.59, 62.11], "category_id": 3}, {"id": 14, "bbox": [787.17, 77.64, 386.54, 378.3], "category_id": 1}, {"id": 15, "bbox": [497.98, 276.67, 266.62, 151.04], "category_id": 1}, {"id": 16, "bbox": [293.43, 1043.16, 73.35, 56.46], "category_id": 3}, {"id": 17, "bbox": [2238.79, 43.76, 450.01, 440.41], "category_id": 1}, {"id": 18, "bbox": [1485.47, 4.23, 472.59, 520.88], "category_id": 1}, {"id": 19, "bbox": [1959.47, 283.73, 273.68, 97.4], "category_id": 2}, {"id": 20, "bbox": [608.01, 894.94, 273.68, 138.34], "category_id": 2}, {"id": 21, "bbox": [924.01, 436.18, 79.0, 56.46], "category_id": 3}, {"id": 22, "bbox": [1224.49, 12.7, 205.97, 213.15], "category_id": 1}, {"id": 23, "bbox": [459.89, 60.7, 369.6, 189.15], "category_id": 2}], "caption": "Scheme 5. Successful Deprotection of the Picolinimide Directing Group", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 267, 489, 282], "ImageBB": [82, 288, 787, 596]}, "reactions": [{"reactants": [1], "conditions": [23, 15], "products": [14]}, {"reactants": [14], "conditions": [22, 16], "products": [18]}, {"reactants": [18], "conditions": [9, 19], "products": [17]}], "diagram_type": "multiple"}, {"id": 346, "width": 1348, "height": 1180, "file_name": "ol202027k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [103.0, 71.0, 114.0, 141.0], "category_id": 1}, {"id": 1, "bbox": [1019.9, 0.0, 239.1, 309.0], "category_id": 1}, {"id": 2, "bbox": [1016.0, 321.1, 227.0, 92.9], "category_id": 3}, {"id": 3, "bbox": [11.0, 533.0, 1337.0, 647.0], "category_id": 4}, {"id": 4, "bbox": [551.1, 62.0, 319.9, 200.0], "category_id": 1}, {"id": 5, "bbox": [296.0, 160.0, 180.0, 38.0], "category_id": 2}, {"id": 6, "bbox": [289.0, 53.0, 162.0, 49.0], "category_id": 2}, {"id": 7, "bbox": [652.0, 302.0, 224.0, 100.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [6, 5], "products": [4, 1]}], "corefs": [[4, 7], [1, 2]], "caption": "Table 1. Screening of Metal Salts As Promoter of the Perkin  Acyl-Mannich Additiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 767, 114], "ImageBB": [436, 126, 773, 421]}, "diagram_type": "single"}, {"id": 1095, "width": 1276, "height": 864, "file_name": "jo961323+-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [505.55, 0.0, 296.18, 356.66], "category_id": 1}, {"id": 1, "bbox": [1046.21, 350.92, 52.34, 51.68], "category_id": 3}, {"id": 2, "bbox": [637.68, 354.75, 40.21, 47.85], "category_id": 3}, {"id": 3, "bbox": [575.13, 482.99, 280.86, 316.47], "category_id": 1}, {"id": 4, "bbox": [128.3, 815.41, 68.94, 48.59], "category_id": 3}, {"id": 5, "bbox": [0.0, 493.2, 284.69, 299.24], "category_id": 1}, {"id": 6, "bbox": [273.2, 128.24, 162.13, 58.07], "category_id": 2}, {"id": 7, "bbox": [19.7, 174.3, 57.3, 48.6], "category_id": 3}, {"id": 8, "bbox": [129.9, 176.6, 57.3, 41.8], "category_id": 3}, {"id": 9, "bbox": [250.22, 512.98, 265.54, 57.42], "category_id": 2}, {"id": 10, "bbox": [270.01, 216.93, 183.83, 56.79], "category_id": 2}, {"id": 11, "bbox": [979.82, 482.99, 296.18, 321.57], "category_id": 1}, {"id": 12, "bbox": [901.31, 0.0, 298.09, 354.75], "category_id": 1}, {"id": 13, "bbox": [1117.06, 812.85, 69.58, 48.49], "category_id": 3}, {"id": 14, "bbox": [695.77, 812.85, 45.32, 48.49], "category_id": 3}, {"id": 15, "bbox": [330.01, 632.93, 144.26, 55.51], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [572, 340, 635, 354], "ImageBB": [448, 360, 767, 576]}, "reactions": [{"reactants": [7, 8], "conditions": [6, 10], "products": [0, 12]}, {"reactants": [5], "conditions": [9, 15], "products": [3]}, {"reactants": [3], "conditions": [], "products": [11]}], "diagram_type": "multiple"}, {"id": 466, "width": 1344, "height": 416, "file_name": "op100335q-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [52.2, 61.2, 352.8, 291.8], "category_id": 1}, {"id": 1, "bbox": [863.0, 102.2, 176.0, 270.8], "category_id": 1}, {"id": 2, "bbox": [517.0, 103.3, 336.0, 261.7], "category_id": 1}, {"id": 3, "bbox": [1142.0, 360.0, 31.0, 43.0], "category_id": 3}, {"id": 4, "bbox": [1055.0, 81.0, 215.0, 279.0], "category_id": 1}, {"id": 5, "bbox": [657.0, 362.0, 55.0, 47.0], "category_id": 3}, {"id": 6, "bbox": [238.0, 333.0, 54.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [918.0, 361.0, 66.0, 48.0], "category_id": 3}], "reactions": [{"reactants": [0], "conditions": [], "products": [2, 1, 4]}], "corefs": [[0, 6], [2, 5], [1, 7], [4, 3]], "caption": "Figure 3. 1H NMR spectra acquired with a \ufb02ow probe for the reaction of 18 with compound 12 to give intermediate 13. A reaction mixture consisting of compound 18, propargylamine (12) and acetonitrile is cycled through the probe. The addition of acetic acid leads to the formation of intermediate 13. This is evident by the disappearance of the N,N-dimethyl peak as intermediate 13 is formed. 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Aromatic ring hydrogenation of phenyl lactic acid: catalyst screening", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 244, 506, 258], "ImageBB": [74, 263, 776, 615]}, "diagram_type": "single"}, {"id": 336, "width": 1348, "height": 1124, "file_name": "ol203001w-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1032.3, 78.1, 237.7, 174.5], "category_id": 1}, {"id": 1, "bbox": [31.9, 2.9, 242.8, 327.1], "category_id": 1}, {"id": 2, "bbox": [663.8, 14.2, 286.2, 276.0], "category_id": 1}, {"id": 3, "bbox": [304.66, 38.55, 321.0, 113.0], "category_id": 2}, {"id": 4, "bbox": [339.1, 194.1, 248.0, 45.0], "category_id": 2}, {"id": 5, "bbox": [123.0, 313.0, 102.0, 59.0], "category_id": 3}, {"id": 6, "bbox": [1144.0, 320.0, 47.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [832.0, 315.0, 38.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 487.0, 1348.0, 637.0], "category_id": 4}], "reactions": [{"reactants": [1], "conditions": [3, 4], "products": [2]}], "corefs": [[1, 5], [2, 7], [0, 6]], "caption": "Table 3. Copper-Catalyzed Reaction of (E)-1g na", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 704, 101], "ImageBB": [436, 112, 773, 393]}, "diagram_type": "single"}, {"id": 1084, "width": 1704, "height": 1256, "file_name": "jo502578x-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [397.23, 0.0, 291.53, 158.48], "category_id": 1}, {"id": 1, "bbox": [904.42, 568.3, 292.39, 147.4], "category_id": 1}, {"id": 2, "bbox": [797.87, 11.08, 139.8, 138.02], "category_id": 1}, {"id": 3, "bbox": [395.53, 823.06, 293.23, 159.33], "category_id": 1}, {"id": 4, "bbox": [1035.7, 69.01, 43.47, 48.57], "category_id": 3}, {"id": 5, "bbox": [667.45, 562.34, 138.09, 135.47], "category_id": 1}, {"id": 6, "bbox": [1035.7, 886.11, 46.03, 57.08], "category_id": 3}, {"id": 7, "bbox": [277.04, 547.0, 291.53, 132.92], "category_id": 1}, {"id": 8, "bbox": [667.45, 301.62, 138.95, 109.06], "category_id": 1}, {"id": 9, "bbox": [904.42, 284.58, 292.39, 143.99], "category_id": 1}, {"id": 10, "bbox": [278.74, 263.28, 288.12, 157.62], "category_id": 1}, {"id": 11, "bbox": [797.87, 832.43, 139.8, 140.59], "category_id": 1}], "caption": "Scheme 2. Postulated Mechanism of the NHC-Catalyzed H/ D Exchange Reaction ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 766, 784, 796], "ImageBB": [433, 813, 859, 1127]}, "reactions": [{"reactants": [0, 2, 4], "conditions": [], "products": [10, 8, 9]}, {"reactants": [10, 8, 9], "conditions": [], "products": [0, 2, 4]}, {"reactants": [10, 8, 9], "conditions": [], "products": [7, 5, 1]}, {"reactants": [7, 5, 1], "conditions": [], "products": [10, 8, 9]}, {"reactants": [7, 5, 1], "conditions": [], "products": [3, 11, 6]}, {"reactants": [3, 11, 6], "conditions": [], "products": [7, 5, 1]}], "diagram_type": "tree"}, {"id": 267, "width": 1480, "height": 1496, "file_name": "ol801163v-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [298.0, 97.0, 984.2, 93.0], "category_id": 2}, {"id": 1, "bbox": [506.0, 426.0, 249.0, 59.0], "category_id": 2}, {"id": 2, "bbox": [1176.0, 468.0, 62.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [760.0, 197.0, 395.0, 610.4], "category_id": 1}, {"id": 4, "bbox": [393.0, 1076.7, 367.2, 56.3], "category_id": 2}, {"id": 5, "bbox": [504.5, 506.0, 253.5, 113.0], "category_id": 2}, {"id": 6, "bbox": [698.5, 823.07, 546.8, 622.0], "category_id": 1}, {"id": 7, "bbox": [396.0, 460.0, 61.2, 65.4], "category_id": 3}, {"id": 8, "bbox": [268.5, 1104.6, 119.5, 69.4], "category_id": 3}, {"id": 9, "bbox": [419.7, 1141.8, 250.2, 50.5], "category_id": 2}, {"id": 10, "bbox": [1014.78, 1267.0, 334.7, 101.4], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [1, 5], "products": [3]}, {"reactants": [8], "conditions": [4, 9], "products": [6]}], "corefs": [[3, 2], [6, 10]], "caption": "Figure 1. 1H NMR spectra of dicarbonyl compound 6a and cyclophane 7a in CDCl3 at the aromatic range. ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 185, 393, 214], "ImageBB": [392, 46, 762, 420]}, "diagram_type": "multiple"}, {"id": 1250, "width": 1184, "height": 848, "file_name": "op049899l-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [781.83, 2.37, 274.23, 293.69], "category_id": 1}, {"id": 1, "bbox": [111.35, 331.0, 28.43, 37.3], "category_id": 3}, {"id": 2, "bbox": [1027.04, 754.95, 53.9, 40.86], "category_id": 3}, {"id": 3, "bbox": [88.25, 529.36, 195.46, 101.25], "category_id": 2}, {"id": 4, "bbox": [5.33, 21.32, 270.68, 271.78], "category_id": 1}, {"id": 5, "bbox": [358.93, 114.87, 336.43, 42.04], "category_id": 2}, {"id": 6, "bbox": [27.25, 675.02, 317.47, 97.1], "category_id": 2}, {"id": 7, "bbox": [959.52, 442.91, 224.48, 308.49], "category_id": 1}, {"id": 8, "bbox": [455.48, 459.49, 280.15, 317.96], "category_id": 1}, {"id": 9, "bbox": [888.44, 349.35, 49.16, 37.9], "category_id": 3}, {"id": 10, "bbox": [542.54, 785.15, 49.16, 42.04], "category_id": 3}, {"id": 11, "bbox": [399.8, 197.77, 258.24, 87.04], "category_id": 2}], "caption": "Scheme 3", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 253, 135, 267], "ImageBB": [94, 272, 390, 484]}, "reactions": [{"reactants": [4], "conditions": [5, 11], "products": [0]}, {"reactants": [0], "conditions": [3, 6], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}], "diagram_type": "multiple"}, {"id": 1259, "width": 520, "height": 2132, "file_name": "op050087e-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 894.82, 105.63, 58.66], "category_id": 2}, {"id": 1, "bbox": [128.03, 1546.47, 389.43, 60.8], "category_id": 2}, {"id": 2, "bbox": [10.67, 502.34, 228.32, 301.83], "category_id": 1}, {"id": 3, "bbox": [0.0, 1702.19, 254.2, 429.81], "category_id": 1}, {"id": 4, "bbox": [20.5, 0.0, 220.9, 187.3], "category_id": 1}, {"id": 5, "bbox": [339.24, 1883.85, 38.39, 48.63], "category_id": 3}, {"id": 6, "bbox": [339.24, 616.94, 38.36, 51.16], "category_id": 3}, {"id": 7, "bbox": [10.67, 309.29, 94.96, 56.53], "category_id": 2}, {"id": 8, "bbox": [10.67, 1068.67, 228.32, 299.69], "category_id": 1}, {"id": 9, "bbox": [337.15, 75.72, 46.95, 52.26], "category_id": 3}, {"id": 10, "bbox": [333.95, 1177.45, 44.81, 50.13], "category_id": 3}, {"id": 11, "bbox": [128.03, 852.16, 367.03, 141.85], "category_id": 2}, {"id": 12, "bbox": [131.23, 1441.95, 322.22, 104.52], "category_id": 2}, {"id": 13, "bbox": [0.0, 1495.28, 105.63, 59.73], "category_id": 2}, {"id": 14, "bbox": [128.03, 239.97, 224.06, 191.98], "category_id": 2}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 501, 67], "ImageBB": [543, 71, 673, 604]}, "reactions": [{"reactants": [4], "conditions": [7, 14], "products": [2]}, {"reactants": [2], "conditions": [0, 11], "products": [8]}, {"reactants": [8], "conditions": [13, 12, 1], "products": [3]}], "diagram_type": "tree"}, {"id": 473, "width": 2556, "height": 1176, "file_name": "op100108j-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1074.0, 204.0, 142.0, 69.6], "category_id": 2}, {"id": 1, "bbox": [0.0, 312.0, 546.0, 390.6], "category_id": 1}, {"id": 2, "bbox": [927.0, 776.6, 615.9, 382.1], "category_id": 1}, {"id": 3, "bbox": [1595.0, 314.0, 52.0, 56.0], "category_id": 3}, {"id": 4, "bbox": [1926.0, 1110.0, 52.0, 63.0], "category_id": 3}, {"id": 5, "bbox": [1239.0, 1123.0, 58.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [1065.0, 674.0, 60.0, 54.0], "category_id": 3}, {"id": 7, "bbox": [231.0, 699.0, 60.0, 54.0], "category_id": 3}, {"id": 8, "bbox": [2051.0, 208.0, 126.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [692.9, 337.6, 563.4, 373.7], "category_id": 1}, {"id": 10, "bbox": [1330.22, 0.0, 619.0, 355.0], "category_id": 1}, {"id": 11, "bbox": [1933.0, 275.0, 623.0, 376.0], "category_id": 1}, {"id": 12, "bbox": [2245.0, 645.0, 311.0, 121.7], "category_id": 3}, {"id": 13, "bbox": [1618.0, 786.0, 619.0, 374.0], "category_id": 1}, {"id": 14, "bbox": [1524.71, 561.1, 63.61, 53.97], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [0], "products": [10]}, {"reactants": [9], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [14], "products": [10]}, {"reactants": [10], "conditions": [8], "products": [11]}, {"reactants": [2], "conditions": [], "products": [13]}, {"reactants": [13], "conditions": [], "products": [2]}, {"reactants": [13], "conditions": [], "products": [11]}], "corefs": [[1, 7], [9, 6], [2, 5], [10, 3], [11, 12], [13, 4]], "caption": "Figure 3. Proposed pathways for the formation of B-ring fission lactones from 1.", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 1009, 502, 1023], "ImageBB": [90, 711, 729, 1005]}, "diagram_type": "graph"}, {"id": 1174, "width": 1356, "height": 1104, "file_name": "ol202027k-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 124.85, 105.14, 54.96], "category_id": 3}, {"id": 1, "bbox": [69.87, 666.98, 204.86, 73.95], "category_id": 3}, {"id": 2, "bbox": [299.83, 0.0, 177.72, 228.66], "category_id": 1}, {"id": 3, "bbox": [894.73, 236.8, 50.87, 40.03], "category_id": 3}, {"id": 4, "bbox": [720.4, 670.37, 47.48, 41.39], "category_id": 3}, {"id": 5, "bbox": [230.64, 792.5, 259.8, 238.84], "category_id": 1}, {"id": 6, "bbox": [0.0, 531.27, 97.68, 45.46], "category_id": 3}, {"id": 7, "bbox": [545.38, 151.99, 182.48, 117.38], "category_id": 2}, {"id": 8, "bbox": [489.76, 863.07, 255.06, 56.31], "category_id": 2}, {"id": 9, "bbox": [933.39, 504.13, 137.71, 46.82], "category_id": 2}, {"id": 10, "bbox": [272.69, 1007.59, 48.16, 40.03], "category_id": 3}, {"id": 11, "bbox": [89.54, 400.32, 182.47, 251.73], "category_id": 1}, {"id": 12, "bbox": [520.96, 929.56, 169.59, 127.56], "category_id": 2}, {"id": 13, "bbox": [823.5, 22.39, 257.77, 206.27], "category_id": 1}, {"id": 14, "bbox": [570.48, 89.56, 137.03, 46.82], "category_id": 2}, {"id": 15, "bbox": [1102.3, 662.23, 201.47, 71.24], "category_id": 3}, {"id": 16, "bbox": [655.28, 381.32, 253.69, 268.01], "category_id": 1}, {"id": 17, "bbox": [776.7, 845.42, 447.02, 162.85], "category_id": 1}, {"id": 18, "bbox": [300.5, 471.56, 330.36, 54.96], "category_id": 2}, {"id": 19, "bbox": [356.81, 202.87, 50.87, 35.97], "category_id": 3}, {"id": 20, "bbox": [319.5, 545.4, 309.32, 67.97], "category_id": 2}, {"id": 21, "bbox": [934.75, 997.41, 34.6, 37.32], "category_id": 3}, {"id": 22, "bbox": [1102.3, 445.78, 249.63, 206.27], "category_id": 1}, {"id": 23, "bbox": [0.0, 899.71, 100.39, 51.56], "category_id": 3}], "caption": "Scheme 3. Simple Elaborations of Inverse Adducts", "pdf": {"Page": 4, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 341, 102], "ImageBB": [71, 113, 410, 389]}, "reactions": [{"reactants": [2], "conditions": [14, 7], "products": [13]}, {"reactants": [11], "conditions": [18, 20], "products": [16]}, {"reactants": [16], "conditions": [9], "products": [22]}, {"reactants": [5], "conditions": [8, 12], "products": [17]}], "diagram_type": "multiple"}, {"id": 1166, "width": 1352, "height": 940, "file_name": "ol0616236-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [706.77, 609.92, 438.27, 267.09], "category_id": 1}, {"id": 1, "bbox": [783.2, 401.65, 38.55, 45.98], "category_id": 2}, {"id": 2, "bbox": [543.1, 778.29, 75.75, 37.87], "category_id": 2}, {"id": 3, "bbox": [1044.27, 398.95, 279.32, 50.71], "category_id": 2}, {"id": 4, "bbox": [343.58, 4.06, 173.82, 242.07], "category_id": 1}, {"id": 5, "bbox": [499.14, 668.07, 167.73, 77.76], "category_id": 2}, {"id": 6, "bbox": [783.88, 530.13, 376.04, 47.33], "category_id": 2}, {"id": 7, "bbox": [213.72, 841.17, 54.79, 43.28], "category_id": 3}, {"id": 8, "bbox": [31.11, 607.21, 442.33, 265.07], "category_id": 1}, {"id": 9, "bbox": [83.19, 202.18, 173.14, 109.54], "category_id": 1}, {"id": 10, "bbox": [827.84, 332.68, 221.16, 159.58], "category_id": 1}, {"id": 11, "bbox": [314.5, 288.73, 290.15, 84.52], "category_id": 2}, {"id": 12, "bbox": [918.47, 843.2, 45.31, 39.22], "category_id": 3}, {"id": 13, "bbox": [629.67, 69.65, 283.39, 241.4], "category_id": 1}], "caption": "Scheme 3. Synthesis and Fluorination of 1c", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [122, 157, 360, 170], "ImageBB": [73, 174, 411, 409]}, "reactions": [{"reactants": [9, 4], "conditions": [11], "products": [13]}, {"reactants": [13, 10], "conditions": [3, 6], "products": [0]}, {"reactants": [0], "conditions": [5, 2], "products": [8]}], "diagram_type": "tree"}, {"id": 659, "width": 1348, "height": 1100, "file_name": "ol402871f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1003.0, 140.0, 61.0, 29.0], "category_id": 3}, {"id": 1, "bbox": [546.0, 137.0, 50.0, 34.0], "category_id": 3}, {"id": 2, "bbox": [295.0, 140.0, 42.0, 28.0], "category_id": 3}, {"id": 3, "bbox": [480.0, 20.0, 166.0, 111.0], "category_id": 1}, {"id": 4, "bbox": [662.0, 93.0, 156.0, 73.0], "category_id": 2}, {"id": 5, "bbox": [662.0, 27.0, 165.0, 32.0], "category_id": 2}, {"id": 6, "bbox": [195.3, 0.0, 250.8, 151.0], "category_id": 1}, {"id": 7, "bbox": [1.0, 226.8, 1346.0, 871.2], "category_id": 4}, {"id": 8, "bbox": [856.0, 29.0, 299.7, 106.2], "category_id": 1}], "reactions": [{"reactants": [6, 3], "conditions": [5, 4], "products": [8]}], "corefs": [[6, 2], [3, 1], [8, 0]], "caption": "Table 1. Investigation of the Reaction Parametersa", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 707, 101], "ImageBB": [436, 112, 773, 387]}, "diagram_type": "single"}, {"id": 85, "width": 1348, "height": 736, "file_name": "ja063878k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.28, 145.42, 21.31, 30.46], "category_id": 3}, {"id": 1, "bbox": [630.33, 103.74, 154.49, 88.41], "category_id": 2}, {"id": 2, "bbox": [650.66, 38.67, 101.63, 31.48], "category_id": 2}, {"id": 3, "bbox": [302.99, 10.21, 229.71, 165.67], "category_id": 1}, {"id": 4, "bbox": [70.19, 4.11, 143.3, 169.74], "category_id": 1}, {"id": 5, "bbox": [8.18, 208.44, 1335.72, 517.46], "category_id": 4}, {"id": 6, "bbox": [853.98, 15.29, 320.19, 168.72], "category_id": 1}, {"id": 7, "bbox": [142.37, 146.43, 81.29, 36.57], "category_id": 3}], "reactions": [{"reactants": [4, 3], "conditions": [2, 1], "products": [6]}], "corefs": [[4, 7], [3, 0]], "caption": "Table 2. Alkenylation with 2-Substituted Vinylsilanes", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 514, 705, 526], "ImageBB": [439, 528, 776, 712]}, "diagram_type": "single"}, {"id": 1341, "width": 1256, "height": 1380, "file_name": "op7000172-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [325.9, 630.98, 55.24, 55.91], "category_id": 2}, {"id": 1, "bbox": [0.0, 623.38, 285.86, 479.1], "category_id": 1}, {"id": 2, "bbox": [26.7, 198.13, 87.23, 56.61], "category_id": 2}, {"id": 3, "bbox": [829.95, 354.84, 260.31, 100.79], "category_id": 2}, {"id": 4, "bbox": [613.83, 8.97, 283.09, 477.03], "category_id": 1}, {"id": 5, "bbox": [390.81, 608.88, 183.66, 214.01], "category_id": 1}, {"id": 6, "bbox": [325.9, 0.0, 214.05, 329.29], "category_id": 1}, {"id": 7, "bbox": [414.97, 825.65, 214.05, 56.61], "category_id": 2}, {"id": 8, "bbox": [868.61, 1144.59, 77.34, 55.23], "category_id": 3}, {"id": 9, "bbox": [828.57, 552.97, 292.76, 576.43], "category_id": 1}, {"id": 10, "bbox": [667.69, 493.6, 68.35, 52.46], "category_id": 3}, {"id": 11, "bbox": [325.9, 902.97, 434.31, 221.6], "category_id": 2}, {"id": 12, "bbox": [779.54, 185.01, 309.33, 142.9], "category_id": 1}, {"id": 13, "bbox": [296.9, 361.74, 290.0, 59.37], "category_id": 2}, {"id": 14, "bbox": [698.07, 1216.39, 541.33, 149.11], "category_id": 2}, {"id": 15, "bbox": [107.71, 479.79, 71.81, 55.92], "category_id": 3}, {"id": 16, "bbox": [85.62, 1103.17, 73.88, 55.23], "category_id": 3}, {"id": 17, "bbox": [15.19, 207.1, 285.86, 222.29], "category_id": 1}], "caption": "Scheme 4. Synthesis of Valsartan precursor 21 using a Suzuki coupling ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 53, 746, 81], "ImageBB": [451, 85, 765, 430]}, "reactions": [{"reactants": [17, 6], "conditions": [13], "products": [4]}, {"reactants": [4, 12], "conditions": [3], "products": [1]}, {"reactants": [1, 5], "conditions": [7, 11], "products": [9]}], "diagram_type": "multiple"}, {"id": 679, "width": 1344, "height": 1568, "file_name": "ol401571r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1.0, 311.0, 1343.0, 1234.0], "category_id": 4}, {"id": 1, "bbox": [178.0, 250.0, 56.0, 47.0], "category_id": 3}, {"id": 2, "bbox": [76.0, 0.0, 300.0, 224.0], "category_id": 1}, {"id": 3, "bbox": [970.0, 3.0, 300.0, 247.0], "category_id": 1}, {"id": 4, "bbox": [609.0, 13.0, 313.0, 113.0], "category_id": 2}, {"id": 5, "bbox": [1073.0, 248.0, 62.0, 50.0], "category_id": 3}, {"id": 6, "bbox": [405.0, 107.0, 167.0, 105.9], "category_id": 2}, {"id": 7, "bbox": [585.0, 145.1, 353.0, 59.9], "category_id": 2}], "reactions": [{"reactants": [2, 6], "conditions": [4, 7], "products": [3]}], "corefs": [[2, 1], [3, 5]], "caption": "Table 1. Examination of Metal Salts and Condition Optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 343, 405, 356], "ImageBB": [71, 367, 407, 759]}, "diagram_type": "single"}, {"id": 1045, "width": 2140, "height": 1636, "file_name": "jo0108865-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [254.79, 103.85, 178.78, 66.38], "category_id": 2}, {"id": 1, "bbox": [1873.44, 20.34, 266.56, 314.76], "category_id": 1}, {"id": 2, "bbox": [41.75, 865.04, 343.64, 64.24], "category_id": 2}, {"id": 3, "bbox": [974.19, 1573.78, 276.2, 55.67], "category_id": 3}, {"id": 4, "bbox": [1475.38, 77.44, 398.23, 55.67], "category_id": 2}, {"id": 5, "bbox": [1471.4, 504.25, 266.08, 207.7], "category_id": 1}, {"id": 6, "bbox": [1495.54, 730.15, 156.3, 56.74], "category_id": 3}, {"id": 7, "bbox": [1477.34, 1130.55, 267.63, 107.06], "category_id": 3}, {"id": 8, "bbox": [1470.92, 174.51, 129.53, 58.88], "category_id": 2}, {"id": 9, "bbox": [0.0, 510.68, 232.31, 208.76], "category_id": 1}, {"id": 10, "bbox": [1154.04, 312.61, 491.37, 105.99], "category_id": 3}, {"id": 11, "bbox": [571.67, 41.75, 200.19, 245.17], "category_id": 1}, {"id": 12, "bbox": [41.75, 321.18, 165.93, 103.85], "category_id": 3}, {"id": 13, "bbox": [41.75, 964.61, 165.93, 101.71], "category_id": 2}, {"id": 14, "bbox": [0.0, 61.02, 185.2, 240.89], "category_id": 1}, {"id": 15, "bbox": [969.9, 981.74, 285.84, 103.85], "category_id": 2}, {"id": 16, "bbox": [571.67, 314.76, 285.83, 107.06], "category_id": 3}, {"id": 17, "bbox": [377.9, 1581.27, 324.37, 54.6], "category_id": 3}, {"id": 18, "bbox": [377.9, 520.31, 140.24, 64.24], "category_id": 2}, {"id": 19, "bbox": [969.9, 885.38, 291.19, 62.1], "category_id": 2}, {"id": 20, "bbox": [1265.37, 6.42, 189.49, 296.56], "category_id": 1}, {"id": 21, "bbox": [499.94, 844.7, 385.39, 207.7], "category_id": 1}, {"id": 22, "bbox": [681.93, 735.5, 475.32, 58.88], "category_id": 3}, {"id": 23, "bbox": [807.18, 192.71, 279.41, 62.09], "category_id": 2}, {"id": 24, "bbox": [896.04, 1282.58, 328.65, 230.18], "category_id": 1}, {"id": 25, "bbox": [527.77, 1096.29, 337.22, 63.17], "category_id": 3}, {"id": 26, "bbox": [278.34, 183.07, 143.45, 56.74], "category_id": 2}, {"id": 27, "bbox": [1837.04, 350.09, 302.96, 64.23], "category_id": 3}, {"id": 28, "bbox": [113.48, 1339.32, 50.31, 51.39], "category_id": 3}, {"id": 29, "bbox": [41.75, 741.92, 73.87, 53.53], "category_id": 3}, {"id": 30, "bbox": [762.22, 499.97, 271.92, 211.98], "category_id": 1}, {"id": 31, "bbox": [348.99, 1286.86, 326.52, 243.02], "category_id": 1}, {"id": 32, "bbox": [1410.97, 867.18, 371.47, 237.68], "category_id": 1}, {"id": 33, "bbox": [965.62, 1086.66, 264.43, 133.82], "category_id": 1}, {"id": 34, "bbox": [807.18, 92.07, 313.67, 66.38], "category_id": 2}, {"id": 35, "bbox": [1150.83, 518.17, 195.9, 72.8], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [390, 64, 453, 78], "ImageBB": [158, 85, 693, 494]}, "reactions": [{"reactants": [14], "conditions": [0, 26], "products": [11]}, {"reactants": [11], "conditions": [34, 23], "products": [20]}, {"reactants": [20], "conditions": [4, 8], "products": [1]}, {"reactants": [9], "conditions": [18], "products": [30]}, {"reactants": [30], "conditions": [35], "products": [5]}, {"reactants": [5], "conditions": [2, 13], "products": [21]}, {"reactants": [21], "conditions": [19, 15, 33], "products": [32]}, {"reactants": [32], "conditions": [28], "products": [31]}], "diagram_type": "multiple"}, {"id": 607, "width": 1356, "height": 300, "file_name": "acs.oprd.5b00371-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [518.0, 35.0, 191.0, 46.0], "category_id": 2}, {"id": 1, "bbox": [905.0, 6.0, 338.0, 223.0], "category_id": 1}, {"id": 2, "bbox": [112.0, 39.0, 272.0, 139.0], "category_id": 1}, {"id": 3, "bbox": [1101.0, 216.0, 25.0, 33.0], "category_id": 3}, {"id": 4, "bbox": [208.0, 214.0, 26.0, 39.0], "category_id": 3}, {"id": 5, "bbox": [470.0, 116.0, 280.0, 99.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0, 5], "products": [1]}], "corefs": [[2, 4], [1, 3]], "caption": "Table 3. Comparison of the Amount of BF3OEt2 for the Formation of 3a ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 701, 767, 731], "ImageBB": [448, 621, 787, 696]}, "diagram_type": "single"}, {"id": 404, "width": 1352, "height": 1772, "file_name": "op400278d-Table-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [34.14, 840.0, 388.0, 111.0], "category_id": 3}, {"id": 1, "bbox": [544.0, 844.0, 364.0, 105.0], "category_id": 3}, {"id": 2, "bbox": [548.0, 134.8, 241.2, 65.2], "category_id": 2}, {"id": 3, "bbox": [150.8, 1123.0, 427.3, 383.1], "category_id": 1}, {"id": 4, "bbox": [1045.5, 530.8, 306.5, 320.2], "category_id": 1}, {"id": 5, "bbox": [534.4, 438.5, 406.6, 385.7], "category_id": 1}, {"id": 6, "bbox": [12.0, 984.0, 1158.0, 115.0], "category_id": 2}, {"id": 7, "bbox": [5.0, 316.0, 1132.0, 105.0], "category_id": 2}, {"id": 8, "bbox": [7.0, 425.5, 435.7, 394.0], "category_id": 1}, {"id": 9, "bbox": [866.0, 0.0, 450.0, 305.0], "category_id": 1}, {"id": 10, "bbox": [50.4, 51.4, 171.3, 198.6], "category_id": 1}, {"id": 11, "bbox": [143.0, 1529.0, 417.9, 109.9], "category_id": 3}, {"id": 12, "bbox": [1102.0, 874.2, 177.0, 43.8], "category_id": 3}, {"id": 13, "bbox": [812.75, 1532.37, 468.0, 207.0], "category_id": 3}, {"id": 14, "bbox": [824.6, 1121.4, 443.4, 427.6], "category_id": 1}, {"id": 15, "bbox": [274.66, 244.73, 190.03, 57.01], "category_id": 2}, {"id": 16, "bbox": [307.91, 47.58, 171.03, 201.9], "category_id": 1}, {"id": 17, "bbox": [34.75, 244.73, 192.4, 56.97], "category_id": 2}], "reactions": [{"reactants": [10, 16], "conditions": [2], "products": [9]}], "corefs": [[8, 0], [5, 1], [4, 12], [3, 11], [14, 13]], "caption": "Table 7. Formation of symmetric triarylamines with Pd- PEPPSI-IPentCl (84) in the presence of excess aryl chloride and aniline derivatives ", "pdf": {"Page": 7, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 94, 416, 139], "ImageBB": [82, 146, 420, 589]}, "diagram_type": "single"}, {"id": 27, "width": 1352, "height": 1396, "file_name": "ja9039289-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [283.2, 176.39, 302.82, 48.83], "category_id": 2}, {"id": 1, "bbox": [239.97, 3.46, 387.48, 137.1], "category_id": 2}, {"id": 2, "bbox": [951.48, 165.58, 374.82, 50.63], "category_id": 2}, {"id": 3, "bbox": [1052.35, 53.9, 153.31, 50.6], "category_id": 2}, {"id": 4, "bbox": [647.06, 100.73, 254.18, 111.88], "category_id": 1}, {"id": 5, "bbox": [23.82, 98.93, 201.98, 110.08], "category_id": 1}, {"id": 6, "bbox": [2.2, 264.65, 1345.76, 1129.61], "category_id": 4}, {"id": 7, "bbox": [1109.99, 106.13, 39.83, 45.24], "category_id": 3}, {"id": 8, "bbox": [1111.79, 214.21, 39.83, 41.63], "category_id": 3}, {"id": 9, "bbox": [749.74, 216.01, 39.82, 39.83], "category_id": 3}, {"id": 10, "bbox": [95.87, 214.21, 34.42, 41.63], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [1, 0], "products": [4, 3, 2]}], "corefs": [[5, 10], [4, 9], [3, 7], [2, 8]], "caption": "Table 2. Screening of Cobalt and Nickel Salts in the Presence of Various NHC Ligands ", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 384, 81], "ImageBB": [58, 89, 396, 438]}, "diagram_type": "single"}, {"id": 1241, "width": 916, "height": 1456, "file_name": "op0255736-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [13.1, 426.09, 211.86, 190.83], "category_id": 1}, {"id": 1, "bbox": [112.85, 622.02, 45.86, 44.43], "category_id": 3}, {"id": 2, "bbox": [481.96, 6.56, 247.53, 258.56], "category_id": 1}, {"id": 3, "bbox": [625.38, 1416.67, 37.86, 34.96], "category_id": 3}, {"id": 4, "bbox": [102.65, 252.01, 35.68, 42.98], "category_id": 3}, {"id": 5, "bbox": [671.25, 1000.04, 186.37, 179.91], "category_id": 2}, {"id": 6, "bbox": [753.51, 574.68, 157.26, 135.48], "category_id": 2}, {"id": 7, "bbox": [619.56, 929.39, 48.77, 48.8], "category_id": 3}, {"id": 8, "bbox": [288.3, 914.83, 133.23, 123.09], "category_id": 2}, {"id": 9, "bbox": [11.65, 11.65, 235.88, 223.61], "category_id": 1}, {"id": 10, "bbox": [240.25, 581.96, 192.2, 83.76], "category_id": 2}, {"id": 11, "bbox": [756.43, 180.63, 152.88, 130.38], "category_id": 2}, {"id": 12, "bbox": [395.11, 451.05, 47.2, 38.45], "category_id": 2}, {"id": 13, "bbox": [263.55, 186.46, 179.09, 158.78], "category_id": 2}, {"id": 14, "bbox": [472.49, 771.34, 342.18, 186.46], "category_id": 1}, {"id": 15, "bbox": [481.96, 1189.42, 321.79, 218.51], "category_id": 1}, {"id": 16, "bbox": [472.49, 394.77, 326.89, 219.97], "category_id": 1}, {"id": 17, "bbox": [602.08, 1368.6, 188.56, 50.25], "category_id": 2}, {"id": 18, "bbox": [240.25, 378.75, 260.64, 162.42], "category_id": 1}, {"id": 19, "bbox": [32.76, 729.82, 325.43, 225.79], "category_id": 1}, {"id": 20, "bbox": [288.3, 31.32, 158.71, 107.07], "category_id": 1}], "caption": "Scheme 1. First-generation synthesis", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 306, 651, 320], "ImageBB": [494, 325, 723, 689]}, "reactions": [{"reactants": [9, 20], "conditions": [13], "products": [2]}, {"reactants": [2], "conditions": [11], "products": [0]}, {"reactants": [0, 18], "conditions": [10], "products": [16]}, {"reactants": [16], "conditions": [6], "products": [19]}, {"reactants": [19], "conditions": [8], "products": [14]}, {"reactants": [14], "conditions": [5], "products": [15, 17]}], "diagram_type": "tree"}, {"id": 638, "width": 1312, "height": 1336, "file_name": "ol501019y-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [211.0, 215.0, 193.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [7.0, 273.0, 1305.0, 1063.0], "category_id": 4}, {"id": 2, "bbox": [945.0, 175.0, 26.0, 34.0], "category_id": 3}, {"id": 3, "bbox": [289.0, 185.0, 29.0, 32.0], "category_id": 3}, {"id": 4, "bbox": [245.0, 13.0, 145.0, 168.0], "category_id": 1}, {"id": 5, "bbox": [407.0, 50.0, 361.0, 59.0], "category_id": 2}, {"id": 6, "bbox": [855.0, 206.0, 196.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [449.0, 114.0, 283.0, 87.9], "category_id": 2}, {"id": 8, "bbox": [796.0, 2.0, 308.0, 172.1], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [5, 7], "products": [8]}], "corefs": [[4, 3], [8, 2]], "caption": "Table 4. Palladium-Catalyzed Homocoupling of 3- Substituted Furans and Thiophenesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 733, 125], "ImageBB": [453, 131, 781, 465]}, "diagram_type": "single"}, {"id": 863, "width": 1356, "height": 992, "file_name": "jo2003264-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [306.0, 102.0, 135.0, 47.0], "category_id": 1}, {"id": 1, "bbox": [354.0, 166.0, 31.0, 43.0], "category_id": 3}, {"id": 2, "bbox": [86.0, 163.0, 45.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [2.0, 102.0, 213.0, 47.0], "category_id": 1}, {"id": 4, "bbox": [517.0, 127.0, 281.0, 78.0], "category_id": 2}, {"id": 5, "bbox": [707.0, 327.0, 53.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [1111.0, 329.0, 53.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [554.28, 198.83, 294.0, 128.0], "category_id": 1}, {"id": 8, "bbox": [941.0, 198.83, 415.0, 127.0], "category_id": 1}, {"id": 9, "bbox": [9.2, 444.2, 1331.8, 547.8], "category_id": 4}, {"id": 10, "bbox": [469.11, 8.0, 762.0, 100.0], "category_id": 2}], "reactions": [{"reactants": [3, 0], "conditions": [10, 4], "products": [7, 8]}], "corefs": [[3, 2], [0, 1], [7, 5], [8, 6]], "caption": "Table 2. E\ufb00ects of Additives in the Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of 1a with 2a ", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 92, 759, 122], "ImageBB": [436, 133, 775, 381]}, "diagram_type": "multiple"}, {"id": 479, "width": 1356, "height": 1940, "file_name": "ol0703579-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [41.0, 1014.0, 1219.0, 70.0], "category_id": 2}, {"id": 1, "bbox": [0.0, 1146.0, 1356.0, 671.0], "category_id": 2}, {"id": 2, "bbox": [573.0, 76.0, 304.0, 64.0], "category_id": 2}, {"id": 3, "bbox": [8.0, 300.0, 1348.0, 714.0], "category_id": 4}, {"id": 4, "bbox": [1001.0, 220.0, 60.0, 55.0], "category_id": 3}, {"id": 5, "bbox": [416.0, 214.0, 45.0, 51.0], "category_id": 3}, {"id": 6, "bbox": [148.0, 223.0, 48.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [596.0, 146.0, 245.0, 106.0], "category_id": 2}, {"id": 8, "bbox": [879.0, 6.0, 360.2, 266.8], "category_id": 1}, {"id": 9, "bbox": [348.2, 85.6, 201.8, 184.2], "category_id": 1}, {"id": 10, "bbox": [43.0, 2.6, 293.0, 208.8], "category_id": 1}], "reactions": [{"reactants": [10, 9], "conditions": [2, 7], "products": [8]}], "corefs": [[10, 6], [9, 5], [8, 4]], "caption": "Table 1. Optimized Catalytic Asymmetric Conditions", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 724, 89], "ImageBB": [439, 93, 777, 578]}, "diagram_type": "single"}, {"id": 169, "width": 1352, "height": 704, "file_name": "op5002462-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [93.0, 38.8, 352.0, 288.2], "category_id": 1}, {"id": 1, "bbox": [484.0, 87.0, 330.0, 101.0], "category_id": 2}, {"id": 2, "bbox": [894.0, 101.0, 365.0, 236.0], "category_id": 1}, {"id": 3, "bbox": [831.6, 450.0, 350.4, 235.0], "category_id": 1}, {"id": 4, "bbox": [362.2, 449.0, 333.8, 194.0], "category_id": 1}, {"id": 5, "bbox": [414.0, 642.0, 157.0, 52.0], "category_id": 3}, {"id": 6, "bbox": [894.0, 651.0, 157.0, 49.0], "category_id": 3}, {"id": 7, "bbox": [959.0, 303.0, 161.0, 57.0], "category_id": 3}, {"id": 8, "bbox": [230.0, 313.0, 35.0, 38.0], "category_id": 3}, {"id": 9, "bbox": [478.0, 229.0, 360.0, 90.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 9], "products": [2, 4, 3]}], "corefs": [[0, 8], [2, 7], [4, 5], [3, 6]], "caption": "Figure 2. Allylic oxidation of valencene with SeO2 and TBHP.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 688, 379, 703], "ImageBB": [82, 502, 420, 678]}, "diagram_type": "multiple"}, {"id": 415, "width": 2820, "height": 2056, "file_name": "op400242j-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1477.0, 281.0, 45.0, 34.0], "category_id": 3}, {"id": 1, "bbox": [476.0, 789.0, 646.0, 395.0], "category_id": 1}, {"id": 2, "bbox": [699.0, 1170.0, 276.0, 43.0], "category_id": 3}, {"id": 3, "bbox": [1340.0, 651.0, 254.0, 45.0], "category_id": 3}, {"id": 4, "bbox": [439.0, 651.0, 28.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [536.0, 269.0, 26.0, 37.0], "category_id": 3}, {"id": 6, "bbox": [2274.0, 524.0, 25.0, 33.0], "category_id": 3}, {"id": 7, "bbox": [1211.0, 893.0, 582.0, 49.0], "category_id": 2}, {"id": 8, "bbox": [1211.0, 947.0, 354.0, 42.0], "category_id": 2}, {"id": 9, "bbox": [804.0, 574.0, 193.0, 40.0], "category_id": 2}, {"id": 10, "bbox": [1251.0, 34.0, 406.0, 263.0], "category_id": 1}, {"id": 11, "bbox": [1885.0, 139.0, 644.0, 395.0], "category_id": 1}, {"id": 12, "bbox": [1307.0, 422.0, 353.0, 235.0], "category_id": 1}, {"id": 13, "bbox": [1213.0, 1001.0, 420.0, 43.0], "category_id": 2}, {"id": 14, "bbox": [1211.0, 1054.0, 579.0, 99.0], "category_id": 2}, {"id": 15, "bbox": [756.0, 65.0, 455.0, 50.0], "category_id": 2}, {"id": 16, "bbox": [818.0, 176.0, 301.0, 99.0], "category_id": 2}, {"id": 17, "bbox": [285.0, 408.0, 349.0, 237.0], "category_id": 1}, {"id": 18, "bbox": [288.0, 38.0, 408.0, 261.0], "category_id": 1}, {"id": 19, "bbox": [806.0, 467.0, 280.0, 46.0], "category_id": 2}, {"id": 20, "bbox": [805.0, 523.0, 207.0, 37.0], "category_id": 2}, {"id": 21, "bbox": [754.0, 120.0, 347.0, 50.0], "category_id": 2}], "reactions": [{"reactants": [18], "conditions": [15, 21, 16], "products": [10]}, {"reactants": [17], "conditions": [19, 20, 9], "products": [12]}, {"reactants": [10, 12], "conditions": [], "products": [11]}, {"reactants": [11], "conditions": [7, 8, 13, 14], "products": [1]}], "corefs": [[18, 5], [10, 0], [11, 6], [17, 4], [12, 3], [1, 2]], "caption": "Figure 4. FTIR spectroscopy of DIPEA-catalyzed and DIPEA-free chlorinations.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 640, 471, 654], "ImageBB": [82, 116, 787, 630]}, "diagram_type": "tree"}, {"id": 923, "width": 1352, "height": 780, "file_name": "acs.joc.5b02382-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 294.9, 214.4, 100.78], "category_id": 1}, {"id": 1, "bbox": [726.39, 248.23, 121.06, 138.77], "category_id": 1}, {"id": 2, "bbox": [645.9, 293.55, 50.73, 41.25], "category_id": 2}, {"id": 3, "bbox": [461.94, 588.44, 319.91, 106.19], "category_id": 1}, {"id": 4, "bbox": [401.74, 449.79, 201.55, 96.72], "category_id": 1}, {"id": 5, "bbox": [1170.74, 251.61, 181.26, 131.22], "category_id": 1}, {"id": 6, "bbox": [627.64, 492.4, 257.01, 45.32], "category_id": 2}, {"id": 7, "bbox": [276.62, 286.11, 50.73, 33.81], "category_id": 2}, {"id": 8, "bbox": [802.14, 627.0, 161.64, 41.26], "category_id": 2}, {"id": 9, "bbox": [498.46, 537.72, 43.29, 33.14], "category_id": 3}, {"id": 10, "bbox": [925.91, 339.54, 121.06, 41.26], "category_id": 2}, {"id": 11, "bbox": [897.5, 278.67, 248.89, 40.58], "category_id": 2}, {"id": 12, "bbox": [256.33, 357.8, 104.83, 35.85], "category_id": 2}, {"id": 13, "bbox": [516.05, 399.06, 27.73, 32.47], "category_id": 3}, {"id": 14, "bbox": [771.03, 389.59, 42.6, 37.2], "category_id": 3}, {"id": 15, "bbox": [597.88, 703.43, 25.03, 31.11], "category_id": 3}, {"id": 16, "bbox": [522.81, 4.06, 169.08, 94.69], "category_id": 1}, {"id": 17, "bbox": [624.94, 140.01, 240.1, 81.16], "category_id": 2}, {"id": 18, "bbox": [417.98, 286.11, 186.67, 109.57], "category_id": 1}], "caption": "Scheme 1. Transition-Metal-Catalyzed Cyclization/ Functionalization of Propargylic Amides To Synthesize Oxazoles ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 743, 393, 788], "ImageBB": [82, 795, 420, 990]}, "reactions": [{"reactants": [18], "conditions": [2], "products": [1]}, {"reactants": [18], "conditions": [17], "products": [16]}, {"reactants": [18], "conditions": [7, 12], "products": [0]}, {"reactants": [18], "conditions": [11, 10], "products": [5]}, {"reactants": [18], "conditions": [4, 6], "products": [3]}], "diagram_type": "tree"}, {"id": 685, "width": 1344, "height": 1004, "file_name": "ol4013926-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [434.2, 877.3, 547.8, 106.0], "category_id": 2}, {"id": 1, "bbox": [22.6, 367.5, 432.4, 377.0], "category_id": 1}, {"id": 2, "bbox": [478.9, 368.2, 437.8, 378.9], "category_id": 1}, {"id": 3, "bbox": [972.3, 366.0, 335.0, 415.2], "category_id": 1}, {"id": 4, "bbox": [291.9, 186.8, 457.9, 96.7], "category_id": 2}, {"id": 5, "bbox": [474.0, 745.0, 312.0, 99.0], "category_id": 3}, {"id": 6, "bbox": [188.0, 747.0, 103.0, 61.0], "category_id": 3}], "reactions": [], "corefs": [[1, 6], [2, 5]], "caption": "Figure 1. Bifunctional quaternary phophonium salts and a possible working model. ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 581, 405, 608], "ImageBB": [71, 317, 407, 568]}, "diagram_type": "tree"}, {"id": 345, "width": 1356, "height": 1192, "file_name": "ol202027k-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [653.0, 220.0, 24.0, 31.0], "category_id": 3}, {"id": 1, "bbox": [1195.0, 184.0, 20.0, 26.0], "category_id": 3}, {"id": 2, "bbox": [451.0, 84.0, 95.0, 29.0], "category_id": 2}, {"id": 3, "bbox": [1.0, 72.0, 258.0, 146.0], "category_id": 1}, {"id": 4, "bbox": [329.0, 55.0, 105.0, 30.0], "category_id": 1}, {"id": 5, "bbox": [311.0, 183.0, 123.0, 35.0], "category_id": 1}, {"id": 6, "bbox": [1057.6, 20.8, 285.6, 197.6], "category_id": 1}, {"id": 7, "bbox": [595.0, 4.0, 152.0, 212.0], "category_id": 1}, {"id": 8, "bbox": [814.0, 14.0, 176.0, 184.0], "category_id": 1}, {"id": 9, "bbox": [6.0, 382.0, 1342.0, 807.0], "category_id": 4}, {"id": 10, "bbox": [192.0, 223.0, 40.0, 32.0], "category_id": 3}, {"id": 11, "bbox": [881.0, 225.0, 22.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 4], "conditions": [2], "products": [7, 8]}, {"reactants": [3, 5], "conditions": [2], "products": [7, 8]}], "corefs": [[3, 10], [7, 0], [8, 11], [6, 1]], "caption": "Table 2. Regioselectivity of the Nitroso Diels Alder Reaction of 1,2-Dihydropyridine 1b ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [436, 126, 775, 424]}, "diagram_type": "single"}, {"id": 722, "width": 1348, "height": 1352, "file_name": "ol0173127-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1002.6, 17.9, 309.2, 144.5], "category_id": 1}, {"id": 1, "bbox": [319.9, 0.0, 229.1, 160.0], "category_id": 1}, {"id": 2, "bbox": [282.47, 157.6, 197.55, 52.56], "category_id": 2}, {"id": 3, "bbox": [3.0, 272.9, 1345.0, 1077.1], "category_id": 4}, {"id": 4, "bbox": [22.0, 51.0, 150.6, 52.7], "category_id": 2}, {"id": 5, "bbox": [349.0, 209.0, 48.6, 47.7], "category_id": 3}, {"id": 6, "bbox": [82.0, 204.0, 62.8, 51.0], "category_id": 3}, {"id": 7, "bbox": [586.0, 2.0, 362.0, 65.0], "category_id": 2}, {"id": 8, "bbox": [597.0, 95.0, 358.0, 155.0], "category_id": 2}], "reactions": [{"reactants": [4, 1], "conditions": [7, 8], "products": [0]}], "corefs": [[4, 6], [1, 5]], "caption": "Table 1. Effect of Additives and Catalysts", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 311, 301, 324], "ImageBB": [74, 329, 411, 667]}, "diagram_type": "single"}, {"id": 29, "width": 1352, "height": 1604, "file_name": "ja9039289-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1051.85, 47.37, 152.05, 46.83], "category_id": 2}, {"id": 1, "bbox": [646.54, 106.01, 253.81, 105.48], "category_id": 1}, {"id": 2, "bbox": [99.8, 216.39, 27.87, 36.5], "category_id": 3}, {"id": 3, "bbox": [27.36, 100.84, 198.62, 105.48], "category_id": 1}, {"id": 4, "bbox": [1.32, 265.0, 1343.15, 1334.87], "category_id": 4}, {"id": 5, "bbox": [1113.94, 216.39, 33.05, 38.22], "category_id": 3}, {"id": 6, "bbox": [1113.94, 99.11, 31.32, 39.95], "category_id": 3}, {"id": 7, "bbox": [750.03, 216.39, 33.04, 38.22], "category_id": 3}, {"id": 8, "bbox": [286.07, 178.45, 296.93, 45.12], "category_id": 2}, {"id": 9, "bbox": [244.68, 4.25, 379.71, 134.81], "category_id": 2}, {"id": 10, "bbox": [951.82, 168.1, 371.09, 45.12], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [9, 8], "products": [1, 0, 10]}], "corefs": [[3, 2], [1, 7], [0, 6], [10, 5]], "caption": "Table 1. Effect of Iron Salts and Additives on the Cross-Coupling of Chlorobenzene with p-TolMgBr ", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 57, 385, 81], "ImageBB": [58, 89, 396, 490]}, "diagram_type": "single"}, {"id": 1162, "width": 1352, "height": 1228, "file_name": "ol060531d-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [471.41, 400.31, 289.47, 288.06], "category_id": 1}, {"id": 1, "bbox": [140.0, 537.57, 272.57, 99.41], "category_id": 2}, {"id": 2, "bbox": [988.81, 314.43, 46.66, 52.07], "category_id": 3}, {"id": 3, "bbox": [668.22, 831.04, 281.36, 104.14], "category_id": 2}, {"id": 4, "bbox": [928.61, 0.0, 299.62, 293.47], "category_id": 1}, {"id": 5, "bbox": [971.22, 810.08, 257.01, 294.15], "category_id": 1}, {"id": 6, "bbox": [703.39, 160.93, 154.88, 58.16], "category_id": 2}, {"id": 7, "bbox": [1033.44, 1123.84, 54.11, 51.39], "category_id": 3}, {"id": 8, "bbox": [431.5, 314.43, 44.64, 51.39], "category_id": 3}, {"id": 9, "bbox": [542.42, 688.37, 48.7, 48.68], "category_id": 3}, {"id": 10, "bbox": [470.73, 1117.07, 49.37, 49.37], "category_id": 3}, {"id": 11, "bbox": [144.06, 449.67, 332.08, 64.24], "category_id": 2}, {"id": 12, "bbox": [176.52, 806.02, 157.59, 154.85], "category_id": 2}, {"id": 13, "bbox": [1005.04, 686.34, 47.34, 50.71], "category_id": 3}, {"id": 14, "bbox": [938.08, 398.95, 290.15, 291.44], "category_id": 1}, {"id": 15, "bbox": [761.56, 540.28, 175.84, 89.93], "category_id": 2}, {"id": 16, "bbox": [704.07, 81.14, 169.76, 66.27], "category_id": 2}, {"id": 17, "bbox": [367.93, 810.08, 291.5, 292.12], "category_id": 1}, {"id": 18, "bbox": [669.57, 957.49, 267.83, 106.84], "category_id": 2}, {"id": 19, "bbox": [131.21, 0.0, 509.96, 352.97], "category_id": 1}, {"id": 20, "bbox": [761.56, 454.4, 170.43, 59.51], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 153, 631, 166], "ImageBB": [439, 171, 777, 478]}, "reactions": [{"reactants": [19], "conditions": [16, 6], "products": [4]}, {"reactants": [4], "conditions": [11, 1], "products": [0]}, {"reactants": [0], "conditions": [20, 15], "products": [14]}, {"reactants": [14], "conditions": [12], "products": [17]}, {"reactants": [17], "conditions": [3, 18], "products": [5]}], "diagram_type": "multiple"}, {"id": 895, "width": 1348, "height": 328, "file_name": "acs.joc.6b01262-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.0, 253.0, 1342.0, 75.0], "category_id": 4}, {"id": 1, "bbox": [496.0, 21.0, 376.0, 107.0], "category_id": 2}, {"id": 2, "bbox": [550.0, 143.0, 248.0, 75.0], "category_id": 2}, {"id": 3, "bbox": [263.0, 182.0, 26.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1057.0, 178.0, 36.0, 50.0], "category_id": 3}, {"id": 5, "bbox": [118.1, 41.4, 317.8, 158.2], "category_id": 1}, {"id": 6, "bbox": [905.0, 6.0, 327.0, 185.7], "category_id": 1}], "reactions": [{"reactants": [5], "conditions": [1, 2], "products": [6]}], "corefs": [[5, 3], [6, 4]], "caption": "Table 2. E\ufb00ect of Alkyl in the Alkoxy Group in the Benzylimidatesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 372, 125], "ImageBB": [82, 131, 419, 213]}, "diagram_type": "single"}, {"id": 280, "width": 1184, "height": 2508, "file_name": "ol800288b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [100.65, 145.57, 255.32, 58.18], "category_id": 2}, {"id": 1, "bbox": [559.58, 152.04, 80.8, 48.47], "category_id": 2}, {"id": 2, "bbox": [282.0, 6.0, 279.2, 302.7], "category_id": 1}, {"id": 3, "bbox": [19.0, 489.39, 1150.0, 2018.61], "category_id": 4}, {"id": 4, "bbox": [3.0, 338.0, 140.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [175.0, 317.0, 570.0, 161.3], "category_id": 2}, {"id": 6, "bbox": [805.2, 232.9, 348.8, 105.7], "category_id": 1}, {"id": 7, "bbox": [1.0, 252.5, 128.0, 67.6], "category_id": 1}], "reactions": [{"reactants": [7], "conditions": [0, 2, 1, 5], "products": [6]}], "corefs": [], "caption": "Table 3. Aziridination of Olefins Catalyzed by 10% IPrCu(DBM)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 76, 717, 104], "ImageBB": [460, 105, 756, 732]}, "diagram_type": "single"}, {"id": 808, "width": 3396, "height": 1324, "file_name": "jo4027148-Figure-c7.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1696.0, 810.0, 331.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [2121.0, 971.4, 313.0, 285.8], "category_id": 1}, {"id": 2, "bbox": [2505.0, 752.0, 363.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [1934.0, 1030.0, 59.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [507.0, 753.0, 361.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [770.0, 1274.0, 319.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [1650.0, 1275.0, 48.0, 38.0], "category_id": 3}, {"id": 7, "bbox": [2259.0, 1273.0, 51.0, 40.0], "category_id": 3}, {"id": 8, "bbox": [2599.0, 1278.0, 378.0, 39.0], "category_id": 3}, {"id": 9, "bbox": [1653.0, 702.0, 47.0, 37.0], "category_id": 3}, {"id": 10, "bbox": [412.0, 288.0, 555.0, 439.0], "category_id": 1}, {"id": 11, "bbox": [1098.0, 380.0, 254.0, 91.0], "category_id": 2}, {"id": 12, "bbox": [1435.0, 318.0, 476.0, 375.0], "category_id": 1}, {"id": 13, "bbox": [1982.0, 383.0, 312.0, 87.0], "category_id": 2}, {"id": 14, "bbox": [1504.0, 965.0, 345.0, 277.0], "category_id": 1}, {"id": 15, "bbox": [794.0, 1053.0, 276.0, 118.0], "category_id": 1}, {"id": 16, "bbox": [1234.0, 1003.0, 131.0, 80.0], "category_id": 2}, {"id": 17, "bbox": [2405.0, 289.0, 554.0, 440.0], "category_id": 1}, {"id": 18, "bbox": [2726.0, 953.0, 177.0, 285.0], "category_id": 1}, {"id": 19, "bbox": [2556.0, 1030.0, 55.0, 36.0], "category_id": 2}], "reactions": [{"reactants": [10], "conditions": [11], "products": [12]}, {"reactants": [17], "conditions": [13], "products": [12]}, {"reactants": [12], "conditions": [0], "products": [14]}, {"reactants": [15], "conditions": [16], "products": [14]}, {"reactants": [14], "conditions": [3], "products": [1]}, {"reactants": [1], "conditions": [19], "products": [18]}], "corefs": [[10, 4], [12, 9], [17, 2], [15, 5], [14, 6], [1, 7], [18, 8]], "caption": "Figure 7. Retrosynthesis of the piperarborenines from methyl coumalate (78).", "pdf": {"Page": 9, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 362, 463, 376], "ImageBB": [10, 22, 859, 353]}, "diagram_type": "tree"}, {"id": 500, "width": 1352, "height": 1272, "file_name": "ol053021c-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.7, 138.3, 386.3, 118.7], "category_id": 2}, {"id": 1, "bbox": [476.9, 293.2, 310.7, 117.6], "category_id": 2}, {"id": 2, "bbox": [922.6, 167.2, 346.8, 233.0], "category_id": 1}, {"id": 3, "bbox": [81.7, 141.5, 313.6, 237.6], "category_id": 1}, {"id": 4, "bbox": [143.0, 323.0, 84.0, 84.0], "category_id": 3}, {"id": 5, "bbox": [41.0, 429.0, 1242.0, 842.0], "category_id": 4}, {"id": 6, "bbox": [977.0, 341.0, 74.0, 60.0], "category_id": 3}], "reactions": [{"reactants": [3], "conditions": [0, 1], "products": [2]}], "corefs": [[3, 4], [2, 6]], "caption": "Figure 3. Direct comparison of catalysts 1a-d, conversion established by HPLC or GC analysis with benzoic acid and dodecane, respectively, as internal standards (average of 2-3 runs). ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 692, 775, 733], "ImageBB": [439, 362, 777, 680]}, "diagram_type": "single"}, {"id": 226, "width": 1396, "height": 1296, "file_name": "op010232y-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 10.0, 405.3, 221.6], "category_id": 1}, {"id": 1, "bbox": [448.0, 78.0, 146.0, 51.0], "category_id": 2}, {"id": 2, "bbox": [243.0, 269.0, 54.0, 62.0], "category_id": 3}, {"id": 3, "bbox": [807.0, 320.0, 229.0, 65.0], "category_id": 2}, {"id": 4, "bbox": [936.0, 229.0, 49.0, 61.0], "category_id": 3}, {"id": 5, "bbox": [64.0, 641.0, 1332.0, 655.0], "category_id": 4}, {"id": 6, "bbox": [629.0, 0.0, 472.6, 235.0], "category_id": 1}, {"id": 7, "bbox": [456.0, 156.0, 135.0, 56.0], "category_id": 2}, {"id": 8, "bbox": [186.0, 336.0, 154.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [0], "conditions": [1, 7], "products": [6]}], "corefs": [[0, 2], [6, 4]], "caption": "Figure 2. Effect of pH on reaction rate.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 401, 664, 415], "ImageBB": [424, 73, 773, 397]}, "diagram_type": "multiple"}, {"id": 618, "width": 3396, "height": 1556, "file_name": "acs.oprd.5b00170-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1844.0, 1414.0, 186.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [773.0, 287.0, 254.0, 120.0], "category_id": 1}, {"id": 2, "bbox": [1338.0, 522.0, 181.0, 48.0], "category_id": 2}, {"id": 3, "bbox": [815.0, 1510.0, 55.0, 42.0], "category_id": 3}, {"id": 4, "bbox": [1501.0, 1510.0, 59.0, 46.0], "category_id": 3}, {"id": 5, "bbox": [2344.0, 1510.0, 34.0, 41.0], "category_id": 3}, {"id": 6, "bbox": [1518.0, 1096.0, 27.0, 37.0], "category_id": 3}, {"id": 7, "bbox": [2344.0, 1090.0, 34.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [2340.0, 755.0, 38.0, 45.0], "category_id": 3}, {"id": 9, "bbox": [1513.0, 759.0, 40.0, 42.0], "category_id": 3}, {"id": 10, "bbox": [1505.0, 423.0, 56.0, 44.0], "category_id": 3}, {"id": 11, "bbox": [808.0, 423.0, 66.0, 44.0], "category_id": 3}, {"id": 12, "bbox": [2170.0, 1191.0, 179.0, 44.0], "category_id": 2}, {"id": 13, "bbox": [2170.0, 863.0, 177.0, 40.0], "category_id": 2}, {"id": 14, "bbox": [1401.0, 289.0, 318.0, 122.0], "category_id": 1}, {"id": 15, "bbox": [1074.0, 1411.0, 296.0, 61.0], "category_id": 2}, {"id": 16, "bbox": [1333.0, 1184.0, 191.0, 58.0], "category_id": 2}, {"id": 17, "bbox": [1074.0, 1032.0, 293.0, 66.0], "category_id": 2}, {"id": 18, "bbox": [849.0, 851.0, 188.0, 61.0], "category_id": 2}, {"id": 19, "bbox": [1338.0, 848.0, 186.0, 64.0], "category_id": 2}, {"id": 20, "bbox": [1805.0, 702.0, 269.0, 66.0], "category_id": 2}, {"id": 21, "bbox": [1071.0, 699.0, 294.0, 64.0], "category_id": 2}, {"id": 22, "bbox": [1069.0, 374.0, 306.0, 56.0], "category_id": 2}, {"id": 23, "bbox": [2099.0, 1298.0, 523.0, 196.0], "category_id": 1}, {"id": 24, "bbox": [1402.0, 1333.0, 315.0, 122.0], "category_id": 1}, {"id": 25, "bbox": [773.0, 1333.0, 253.0, 121.0], "category_id": 1}, {"id": 26, "bbox": [2104.0, 936.0, 517.0, 164.0], "category_id": 1}, {"id": 27, "bbox": [1401.0, 942.0, 327.0, 153.0], "category_id": 1}, {"id": 28, "bbox": [2102.0, 588.0, 519.0, 178.0], "category_id": 1}, {"id": 29, "bbox": [1404.0, 624.0, 298.0, 123.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [18], "products": [25]}, {"reactants": [14], "conditions": [22], "products": [1]}, {"reactants": [14], "conditions": [2], "products": [29]}, {"reactants": [29], "conditions": [19], "products": [27]}, {"reactants": [27], "conditions": [16], "products": [24]}, {"reactants": [24], "conditions": [15], "products": [25]}, {"reactants": [29], "conditions": [21, 18], "products": [25]}, {"reactants": [27], "conditions": [17, 18], "products": [25]}, {"reactants": [29, 27], "conditions": [20], "products": [28]}, {"reactants": [28], "conditions": [13], "products": [26]}, {"reactants": [26], "conditions": [12], "products": [23]}, {"reactants": [23], "conditions": [0], "products": [24]}], "corefs": [[1, 11], [14, 10], [25, 3], [29, 9], [27, 6], [24, 4], [28, 8], [26, 7], [23, 5]], "caption": "Figure 1. Mechanistic pathways for the reduction of 1-iodo-4-nitrobenzene.1e", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 418, 457, 435], "ImageBB": [10, 22, 859, 411]}, "diagram_type": "graph"}, {"id": 560, "width": 1348, "height": 1276, "file_name": "acs.orglett.5b01842-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [859.0, 5.0, 299.0, 146.7], "category_id": 1}, {"id": 1, "bbox": [416.9, 22.0, 228.1, 62.0], "category_id": 1}, {"id": 2, "bbox": [683.4, 1.4, 163.6, 38.6], "category_id": 2}, {"id": 3, "bbox": [191.4, 5.0, 168.3, 126.6], "category_id": 1}, {"id": 4, "bbox": [6.0, 206.0, 1340.0, 1070.0], "category_id": 4}, {"id": 5, "bbox": [494.0, 130.0, 33.0, 31.0], "category_id": 3}, {"id": 6, "bbox": [263.0, 134.0, 28.0, 31.0], "category_id": 3}, {"id": 7, "bbox": [1001.0, 146.0, 32.0, 29.0], "category_id": 3}], "reactions": [{"reactants": [3, 1], "conditions": [2], "products": [0]}], "corefs": [[3, 6], [1, 5], [0, 7]], "caption": "Table 1. Reductive Amination of Phenol: Reaction Condition Optimization ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 523, 417, 553], "ImageBB": [82, 560, 419, 879]}, "diagram_type": "single"}, {"id": 1237, "width": 1336, "height": 556, "file_name": "op0202179-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [509.27, 0.0, 187.13, 54.11], "category_id": 2}, {"id": 1, "bbox": [531.33, 503.7, 154.38, 47.43], "category_id": 2}, {"id": 2, "bbox": [535.34, 425.54, 145.69, 44.76], "category_id": 2}, {"id": 3, "bbox": [0.0, 275.23, 370.26, 62.8], "category_id": 1}, {"id": 4, "bbox": [0.0, 42.09, 243.27, 58.78], "category_id": 1}, {"id": 5, "bbox": [934.33, 10.69, 157.73, 43.42], "category_id": 2}, {"id": 6, "bbox": [0.0, 456.27, 296.74, 61.46], "category_id": 1}, {"id": 7, "bbox": [415.7, 83.5, 366.25, 101.55], "category_id": 2}, {"id": 8, "bbox": [886.88, 247.17, 259.31, 49.44], "category_id": 2}, {"id": 9, "bbox": [932.33, 87.51, 167.08, 46.77], "category_id": 2}, {"id": 10, "bbox": [854.13, 452.93, 475.85, 62.79], "category_id": 1}, {"id": 11, "bbox": [934.33, 330.01, 165.75, 45.43], "category_id": 2}, {"id": 12, "bbox": [534.0, 325.33, 138.34, 58.12], "category_id": 2}, {"id": 13, "bbox": [467.83, 245.17, 270.01, 48.1], "category_id": 2}], "caption": "Scheme 1. Continuous synthesis of short peptides", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 246, 721, 260], "ImageBB": [441, 265, 775, 404]}, "reactions": [{"reactants": [4], "conditions": [0, 7, 5, 9], "products": [3]}, {"reactants": [3], "conditions": [13, 12, 8, 11], "products": [6]}, {"reactants": [6], "conditions": [2, 1], "products": [10]}], "diagram_type": "multiple"}, {"id": 1304, "width": 1356, "height": 656, "file_name": "op300058f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [48.84, 396.07, 248.95, 160.06], "category_id": 1}, {"id": 1, "bbox": [1270.53, 69.86, 85.47, 54.93], "category_id": 2}, {"id": 2, "bbox": [111.93, 194.65, 35.95, 40.01], "category_id": 3}, {"id": 3, "bbox": [300.5, 567.66, 37.99, 40.69], "category_id": 3}, {"id": 4, "bbox": [339.17, 36.62, 239.45, 120.05], "category_id": 1}, {"id": 5, "bbox": [1019.54, 193.29, 37.99, 43.4], "category_id": 3}, {"id": 6, "bbox": [801.12, 2.71, 405.65, 191.26], "category_id": 1}, {"id": 7, "bbox": [449.06, 191.25, 43.41, 43.41], "category_id": 3}, {"id": 8, "bbox": [320.18, 407.6, 240.81, 137.68], "category_id": 1}, {"id": 9, "bbox": [0.0, 31.2, 274.73, 132.93], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 505, 110], "ImageBB": [448, 116, 787, 280]}, "reactions": [{"reactants": [9, 4], "conditions": [], "products": [6, 1]}, {"reactants": [6, 1], "conditions": [], "products": [9, 4]}, {"reactants": [9, 4], "conditions": [], "products": [0, 8]}, {"reactants": [0, 8], "conditions": [], "products": [9, 4]}], "diagram_type": "tree"}, {"id": 400, "width": 1356, "height": 1124, "file_name": "op4003467-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [800.6, 16.6, 316.2, 281.9], "category_id": 1}, {"id": 1, "bbox": [342.49, 274.03, 78.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [321.57, 752.52, 184.0, 204.0], "category_id": 2}, {"id": 3, "bbox": [561.47, 647.0, 75.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [539.47, 877.48, 154.0, 61.0], "category_id": 2}, {"id": 5, "bbox": [374.7, 390.5, 302.3, 274.5], "category_id": 1}, {"id": 6, "bbox": [806.0, 391.5, 315.5, 320.5], "category_id": 1}, {"id": 7, "bbox": [220.1, 70.5, 316.9, 171.5], "category_id": 1}, {"id": 8, "bbox": [559.0, 189.6, 177.5, 91.4], "category_id": 1}, {"id": 9, "bbox": [564.0, 85.0, 144.0, 62.5], "category_id": 2}, {"id": 10, "bbox": [992.0, 276.0, 57.0, 57.0], "category_id": 3}, {"id": 11, "bbox": [230.0, 560.0, 150.0, 62.0], "category_id": 2}, {"id": 12, "bbox": [245.5, 463.6, 111.5, 49.4], "category_id": 2}, {"id": 13, "bbox": [490.0, 1023.0, 59.0, 62.0], "category_id": 3}, {"id": 14, "bbox": [209.0, 647.0, 231.0, 59.0], "category_id": 2}, {"id": 15, "bbox": [952.0, 703.0, 65.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [9, 8], "products": [0]}, {"reactants": [0], "conditions": [12, 11, 14], "products": [5, 6]}, {"reactants": [5], "conditions": [2, 4], "products": [13]}], "corefs": [[7, 1], [0, 10], [5, 3], [6, 15]], "caption": "Table 1. Dechlorination of 18", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 824, 619, 839], "ImageBB": [448, 537, 787, 818]}, "diagram_type": "tree"}, {"id": 306, "width": 1300, "height": 1696, "file_name": "ol302997q-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [403.0, 271.0, 53.0, 46.0], "category_id": 3}, {"id": 1, "bbox": [543.0, 57.2, 376.3, 93.8], "category_id": 2}, {"id": 2, "bbox": [587.0, 163.6, 301.7, 50.8], "category_id": 2}, {"id": 3, "bbox": [278.0, 70.3, 253.8, 180.8], "category_id": 1}, {"id": 4, "bbox": [965.7, 5.0, 334.3, 248.3], "category_id": 1}, {"id": 5, "bbox": [2.2, 74.7, 261.1, 203.2], "category_id": 1}, {"id": 6, "bbox": [1115.37, 271.0, 59.0, 55.0], "category_id": 3}, {"id": 7, "bbox": [74.0, 271.0, 67.0, 52.0], "category_id": 3}, {"id": 8, "bbox": [0.0, 361.0, 1300.0, 1335.0], "category_id": 4}], "reactions": [{"reactants": [5, 3], "conditions": [1, 2], "products": [4]}], "corefs": [[5, 7], [3, 0], [4, 6]], "caption": "Table 2. Diels Alder Reaction of 3,5-Di-tert-butyl 1,2-Benzo- quinone with Arynes ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 768, 114], "ImageBB": [442, 126, 767, 550]}, "diagram_type": "single"}, {"id": 361, "width": 1368, "height": 1372, "file_name": "ol1030487-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [257.0, 318.0, 217.0, 135.0], "category_id": 1}, {"id": 1, "bbox": [338.84, 141.32, 228.5, 71.4], "category_id": 2}, {"id": 2, "bbox": [559.0, 320.2, 105.0, 127.8], "category_id": 1}, {"id": 3, "bbox": [326.0, 455.0, 42.0, 46.2], "category_id": 3}, {"id": 4, "bbox": [1033.0, 0.0, 318.0, 195.0], "category_id": 1}, {"id": 5, "bbox": [353.1, 34.4, 210.9, 65.6], "category_id": 1}, {"id": 6, "bbox": [0.0, 30.0, 295.0, 186.3], "category_id": 1}, {"id": 7, "bbox": [531.36, 77.27, 45.98, 42.3], "category_id": 3}, {"id": 8, "bbox": [1124.0, 214.0, 103.0, 44.0], "category_id": 3}, {"id": 9, "bbox": [0.0, 559.0, 1366.0, 813.0], "category_id": 4}, {"id": 10, "bbox": [593.0, 455.0, 26.0, 37.0], "category_id": 3}, {"id": 11, "bbox": [144.0, 214.0, 95.0, 37.0], "category_id": 3}, {"id": 12, "bbox": [730.0, 217.0, 100.0, 38.0], "category_id": 3}, {"id": 13, "bbox": [649.0, 2.0, 308.0, 201.0], "category_id": 1}, {"id": 14, "bbox": [799.0, 457.0, 46.0, 42.0], "category_id": 3}, {"id": 15, "bbox": [737.0, 328.0, 205.0, 125.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 1], "products": [13, 4]}], "corefs": [[6, 11], [5, 7], [13, 12], [4, 8], [0, 3], [2, 10], [15, 14]], "caption": "Table 1. Screening of Catalyst, Solvent, and Reaction Condi- tions for the Synthesis of Pentasubstituted Cyclopentanecar- baldehydesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 553, 762, 594], "ImageBB": [436, 593, 778, 936]}, "diagram_type": "single"}, {"id": 1234, "width": 1264, "height": 900, "file_name": "op020049k-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [849.83, 267.51, 398.99, 225.13], "category_id": 1}, {"id": 1, "bbox": [545.69, 648.85, 302.25, 60.71], "category_id": 2}, {"id": 2, "bbox": [338.29, 191.62, 34.78, 46.8], "category_id": 3}, {"id": 3, "bbox": [911.8, 566.0, 352.2, 228.3], "category_id": 1}, {"id": 4, "bbox": [545.69, 20.87, 598.17, 104.98], "category_id": 2}, {"id": 5, "bbox": [182.11, 5.69, 326.27, 169.49], "category_id": 1}, {"id": 6, "bbox": [1117.3, 853.74, 33.52, 40.48], "category_id": 3}, {"id": 7, "bbox": [339.55, 496.44, 45.53, 43.63], "category_id": 3}, {"id": 8, "bbox": [364.85, 849.95, 34.14, 42.37], "category_id": 3}, {"id": 9, "bbox": [153.65, 568.53, 356.63, 225.77], "category_id": 1}, {"id": 10, "bbox": [100.54, 267.51, 436.93, 225.76], "category_id": 1}, {"id": 11, "bbox": [604.49, 337.7, 146.7, 65.14], "category_id": 2}, {"id": 12, "bbox": [1117.93, 497.07, 39.21, 45.53], "category_id": 3}, {"id": 13, "bbox": [17.07, 650.74, 86.0, 51.86], "category_id": 2}], "caption": "Scheme 1. Synthesis of 2 using diazomethane", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 332, 67], "ImageBB": [85, 73, 401, 298]}, "reactions": [{"reactants": [5], "conditions": [4], "products": [10]}, {"reactants": [10], "conditions": [11], "products": [0]}, {"reactants": [0], "conditions": [13], "products": [9]}, {"reactants": [9], "conditions": [1], "products": [3]}], "diagram_type": "multiple"}, {"id": 1078, "width": 1356, "height": 436, "file_name": "jo501006u-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [548.1, 197.89, 54.94, 50.83], "category_id": 2}, {"id": 1, "bbox": [664.09, 16.27, 153.31, 151.8], "category_id": 1}, {"id": 2, "bbox": [1007.33, 149.1, 261.16, 98.27], "category_id": 2}, {"id": 3, "bbox": [692.58, 312.43, 127.53, 49.47], "category_id": 2}, {"id": 4, "bbox": [320.85, 346.31, 94.29, 46.76], "category_id": 2}, {"id": 5, "bbox": [281.51, 270.41, 176.37, 54.89], "category_id": 1}, {"id": 6, "bbox": [349.34, 22.36, 276.09, 53.54], "category_id": 2}, {"id": 7, "bbox": [664.09, 185.69, 151.95, 61.0], "category_id": 1}, {"id": 8, "bbox": [187.22, 314.46, 54.95, 52.18], "category_id": 2}, {"id": 9, "bbox": [87.51, 132.15, 191.29, 73.2], "category_id": 1}, {"id": 10, "bbox": [489.76, 305.65, 118.03, 54.22], "category_id": 1}], "caption": "Scheme 1. Possible Pathways in Metal-Catalyzed Alkyl\u2212 Alkyl Cross-Coupling ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 729, 765, 759], "ImageBB": [448, 765, 787, 874]}, "reactions": [{"reactants": [9], "conditions": [6], "products": [1]}, {"reactants": [9], "conditions": [], "products": [0, 7]}, {"reactants": [8], "conditions": [5, 4], "products": [10, 3]}], "diagram_type": "graph"}, {"id": 1143, "width": 1352, "height": 876, "file_name": "ol016693l-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [505.9, 657.16, 341.55, 49.36], "category_id": 2}, {"id": 1, "bbox": [482.23, 304.24, 376.04, 114.26], "category_id": 2}, {"id": 2, "bbox": [311.12, 4.06, 248.21, 183.22], "category_id": 1}, {"id": 3, "bbox": [254.98, 699.08, 206.28, 49.36], "category_id": 2}, {"id": 4, "bbox": [961.08, 533.44, 29.08, 38.54], "category_id": 3}, {"id": 5, "bbox": [566.1, 744.38, 204.93, 49.36], "category_id": 2}, {"id": 6, "bbox": [254.98, 338.05, 192.08, 156.85], "category_id": 1}, {"id": 7, "bbox": [567.45, 452.31, 204.93, 52.06], "category_id": 2}, {"id": 8, "bbox": [895.47, 349.54, 192.76, 172.41], "category_id": 1}, {"id": 9, "bbox": [870.45, 185.93, 34.49, 43.94], "category_id": 3}, {"id": 10, "bbox": [749.38, 0.0, 252.95, 180.52], "category_id": 1}, {"id": 11, "bbox": [885.24, 648.84, 188.24, 137.76], "category_id": 1}, {"id": 12, "bbox": [926.7, 748.44, 34.38, 40.56], "category_id": 3}, {"id": 13, "bbox": [277.97, 526.68, 117.01, 55.92], "category_id": 2}, {"id": 14, "bbox": [894.8, 350.22, 192.08, 171.73], "category_id": 1}, {"id": 15, "bbox": [482.23, 593.61, 372.66, 56.79], "category_id": 2}, {"id": 16, "bbox": [443.68, 186.6, 39.23, 45.3], "category_id": 3}], "caption": "Scheme 3", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [212, 75, 265, 88], "ImageBB": [73, 94, 411, 313]}, "reactions": [{"reactants": [14], "conditions": [1, 7], "products": [6]}], "diagram_type": "multiple"}, {"id": 803, "width": 2820, "height": 996, "file_name": "jo501006u-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1257.0, 28.0, 675.4, 89.3], "category_id": 2}, {"id": 1, "bbox": [1616.24, 115.22, 431.72, 76.56], "category_id": 2}, {"id": 2, "bbox": [605.0, 165.0, 142.0, 65.0], "category_id": 1}, {"id": 3, "bbox": [920.0, 160.0, 298.0, 73.0], "category_id": 1}, {"id": 4, "bbox": [1256.83, 117.35, 359.41, 70.18], "category_id": 1}, {"id": 5, "bbox": [1435.0, 211.0, 283.0, 65.0], "category_id": 2}, {"id": 6, "bbox": [2122.0, 172.0, 197.0, 74.0], "category_id": 1}, {"id": 7, "bbox": [365.0, 298.0, 2087.0, 698.0], "category_id": 4}, {"id": 8, "bbox": [930.0, 235.0, 274.0, 70.0], "category_id": 2}], "reactions": [{"reactants": [2, 3], "conditions": [0, 4, 1, 5], "products": [6]}], "corefs": [], "caption": "Figure 1. Time-course of reaction of RBr and n-BuMgCl (a) with 500 mol ppm of CuCl2 (R = PhCH(Me)CH2: 1m) and (b) 25 mol ppm of CuCl2 (R = n-Non). With alkyne R-n-Bu: \u25cf (solid line), R-H: \u25cb (dashed line), without alkyne R-n-Bu: \u25a0 (solid line), R-H: \u25a1 (dashed line). ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 1032, 784, 1060], "ImageBB": [82, 763, 787, 1012]}, "diagram_type": "single"}, {"id": 20, "width": 1156, "height": 448, "file_name": "ja953272o-Figure-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [6.16, 124.19, 302.44, 241.17], "category_id": 1}, {"id": 1, "bbox": [297.74, 155.93, 304.66, 52.2], "category_id": 2}, {"id": 2, "bbox": [696.56, 392.66, 170.88, 46.2], "category_id": 2}, {"id": 3, "bbox": [98.51, 395.27, 131.64, 46.21], "category_id": 2}, {"id": 4, "bbox": [615.9, 122.71, 348.21, 243.39], "category_id": 1}], "reactions": [{"reactants": [0], "conditions": [1], "products": [4]}, {"reactants": [4], "conditions": [], "products": [0]}], "corefs": [[0, 3], [4, 2]], "caption": "Figure 9. An equilibrium between agostic and anagostic conformers.", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [429, 143, 764, 156], "ImageBB": [476, 27, 765, 139]}, "diagram_type": "single"}, {"id": 785, "width": 1356, "height": 736, "file_name": "jo502578x-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [352.0, 30.0, 293.0, 259.0], "category_id": 1}, {"id": 1, "bbox": [26.0, 36.0, 285.0, 113.2], "category_id": 1}, {"id": 2, "bbox": [1167.0, 252.0, 38.0, 47.0], "category_id": 3}, {"id": 3, "bbox": [816.0, 309.0, 39.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [477.0, 309.0, 42.0, 45.0], "category_id": 3}, {"id": 5, "bbox": [150.0, 310.0, 46.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [121.65, 220.75, 102.27, 48.06], "category_id": 2}, {"id": 7, "bbox": [1043.0, 51.0, 286.0, 164.0], "category_id": 1}, {"id": 8, "bbox": [692.0, 38.0, 289.0, 238.0], "category_id": 1}], "reactions": [{"reactants": [1, 6], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [], "products": [7]}], "corefs": [[7, 4]], "caption": "Figure 3. Detailed mechanism and energy pro\ufb01le of the reaction of SIMes (2) with chloroform in chloroform (blue) and energies of the stationary points A, B, and 4 in n-hexane (green). The energy pro\ufb01le was obtained by DFT calculations at the B3LYP/6-311++G** level of theory (free energies at 25 \u00b0C including ZPE corrections in kcal/mol with the IEFPCM solvation model); see the Supporting Information for details. ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 339, 784, 436], "ImageBB": [448, 146, 787, 330]}, "diagram_type": "single"}, {"id": 599, "width": 2820, "height": 2492, "file_name": "acs.oprd.6b00117-Figure-c8.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1359.0, 159.0, 264.0, 103.0], "category_id": 2}, {"id": 1, "bbox": [1816.0, 11.0, 578.0, 242.0], "category_id": 1}, {"id": 2, "bbox": [1335.0, 506.0, 240.0, 101.0], "category_id": 2}, {"id": 3, "bbox": [1240.0, 365.0, 438.0, 104.0], "category_id": 2}, {"id": 4, "bbox": [504.0, 407.0, 297.0, 161.2], "category_id": 1}, {"id": 5, "bbox": [1260.0, 5.0, 464.0, 101.0], "category_id": 2}, {"id": 6, "bbox": [1787.0, 365.0, 525.0, 234.4], "category_id": 1}, {"id": 7, "bbox": [836.0, 31.0, 328.0, 218.6], "category_id": 1}, {"id": 8, "bbox": [455.5, 651.0, 1894.5, 1044.2], "category_id": 4}, {"id": 9, "bbox": [2023.0, 592.0, 151.0, 48.0], "category_id": 3}, {"id": 10, "bbox": [983.0, 594.0, 60.0, 46.0], "category_id": 3}, {"id": 11, "bbox": [895.0, 398.0, 302.0, 189.0], "category_id": 1}, {"id": 12, "bbox": [632.0, 596.0, 59.0, 48.0], "category_id": 3}, {"id": 13, "bbox": [406.0, 44.0, 334.0, 172.0], "category_id": 1}, {"id": 14, "bbox": [2078.0, 258.0, 169.0, 48.0], "category_id": 3}, {"id": 15, "bbox": [950.0, 260.0, 53.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [424.0, 1780.0, 1977.0, 683.0], "category_id": 4}, {"id": 17, "bbox": [557.0, 255.0, 59.0, 38.0], "category_id": 3}], "reactions": [{"reactants": [13, 7], "conditions": [5, 0], "products": [1]}, {"reactants": [4, 11], "conditions": [3, 2], "products": [6]}], "corefs": [[13, 17], [7, 15], [1, 14], [4, 12], [11, 10], [6, 9]], "caption": "Figure 8. Wavenumbers monitoring and potential intermediate identi\ufb01cation.", "pdf": {"Page": 6, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 988, 451, 1002], "ImageBB": [82, 355, 787, 978]}, "diagram_type": "multiple"}, {"id": 399, "width": 1352, "height": 1232, "file_name": "op500072b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [931.0, 1135.0, 38.0, 45.0], "category_id": 3}, {"id": 1, "bbox": [5.0, 0.0, 1347.0, 330.0], "category_id": 4}, {"id": 2, "bbox": [62.0, 1011.0, 256.0, 54.0], "category_id": 2}, {"id": 3, "bbox": [616.0, 690.0, 52.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [298.0, 822.0, 907.0, 410.0], "category_id": 1}, {"id": 5, "bbox": [0.0, 379.0, 897.0, 423.0], "category_id": 1}, {"id": 6, "bbox": [19.0, 892.1, 331.0, 89.9], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [6, 2], "products": [4]}], "corefs": [[5, 3], [4, 0]], "caption": "Table 3. Selective O-alkylation of triol 14", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 243, 317, 258], "ImageBB": [82, 265, 420, 573]}, "diagram_type": "multiple"}, {"id": 861, "width": 1356, "height": 896, "file_name": "jo2003264-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [84.0, 227.0, 47.0, 41.0], "category_id": 3}, {"id": 1, "bbox": [879.0, 237.0, 51.0, 39.0], "category_id": 3}, {"id": 2, "bbox": [1184.0, 235.0, 53.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [320.0, 5.0, 440.0, 144.0], "category_id": 2}, {"id": 4, "bbox": [333.0, 165.0, 268.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [11.0, 421.0, 1330.0, 475.0], "category_id": 4}, {"id": 6, "bbox": [1050.0, 63.0, 303.0, 154.0], "category_id": 1}, {"id": 7, "bbox": [0.0, 95.0, 200.0, 101.0], "category_id": 1}, {"id": 8, "bbox": [753.0, 63.0, 263.0, 150.0], "category_id": 1}, {"id": 9, "bbox": [253.0, 130.0, 33.0, 39.0], "category_id": 3}], "reactions": [{"reactants": [7, 9], "conditions": [3, 4], "products": [8, 6]}], "corefs": [[7, 0], [8, 1], [6, 2]], "caption": "Table 4. Ir-Catalyzed Oxidative Methyl Esteri\ufb01cation of r,\u03c9- Diols 5a with 2a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 88, 771, 122], "ImageBB": [436, 133, 775, 357]}, "diagram_type": "single"}, {"id": 212, "width": 1128, "height": 468, "file_name": "op0340661-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [383.7, 408.37, 52.74, 51.89], "category_id": 3}, {"id": 1, "bbox": [614.0, 0.0, 358.0, 237.0], "category_id": 1}, {"id": 2, "bbox": [104.67, 179.53, 42.54, 49.34], "category_id": 3}, {"id": 3, "bbox": [706.95, 181.23, 40.84, 47.64], "category_id": 3}, {"id": 4, "bbox": [4.0, 21.0, 307.0, 209.0], "category_id": 1}, {"id": 5, "bbox": [372.0, 142.0, 227.0, 43.0], "category_id": 2}, {"id": 6, "bbox": [355.0, 50.0, 202.0, 50.0], "category_id": 2}, {"id": 7, "bbox": [302.0, 250.0, 443.3, 214.0], "category_id": 1}, {"id": 8, "bbox": [685.0, 232.6, 441.0, 233.4], "category_id": 1}, {"id": 9, "bbox": [769.05, 407.51, 51.9, 46.79], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [6, 5], "products": [1, 7, 8]}], "corefs": [[4, 2], [1, 3], [7, 0], [8, 9]], "caption": "Table 1. Alkylation of 9 with ethylbromoacetate in the presence of K2CO3 in DMF ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 767, 740, 796], "ImageBB": [467, 638, 749, 755]}, "diagram_type": "multiple"}, {"id": 63, "width": 1344, "height": 1220, "file_name": "ja312277g-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1076.65, 32.98, 219.63, 117.92], "category_id": 1}, {"id": 1, "bbox": [155.3, 153.71, 24.24, 33.77], "category_id": 3}, {"id": 2, "bbox": [318.92, 147.36, 162.44, 40.12], "category_id": 2}, {"id": 3, "bbox": [523.84, 115.59, 503.98, 130.67], "category_id": 2}, {"id": 4, "bbox": [581.03, 1.21, 367.36, 87.78], "category_id": 2}, {"id": 5, "bbox": [345.92, 79.05, 102.08, 48.07], "category_id": 1}, {"id": 6, "bbox": [48.87, 42.51, 178.33, 94.14], "category_id": 1}, {"id": 7, "bbox": [7.57, 274.44, 1328.43, 940.83], "category_id": 4}], "reactions": [{"reactants": [6, 5], "conditions": [4, 3], "products": [0]}], "corefs": [[6, 1]], "caption": "Table 2. Evaluation of Alkyl Halides", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 655, 111], "ImageBB": [449, 116, 785, 421]}, "diagram_type": "single"}, {"id": 426, "width": 1348, "height": 592, "file_name": "op300235t-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [438.0, 444.0, 58.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [985.0, 445.0, 51.0, 50.0], "category_id": 3}, {"id": 2, "bbox": [32.0, 246.0, 54.0, 45.0], "category_id": 3}, {"id": 3, "bbox": [34.0, 509.0, 1295.0, 68.0], "category_id": 4}, {"id": 4, "bbox": [799.0, 5.0, 524.6, 440.0], "category_id": 1}, {"id": 5, "bbox": [237.2, 0.0, 504.6, 441.9], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [5, 4]}], "corefs": [[5, 0], [4, 1]], "caption": "Table 2. Investigations into electrophilic halogenationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 393, 110], "ImageBB": [82, 116, 419, 264]}, "diagram_type": "single"}, {"id": 478, "width": 1352, "height": 1816, "file_name": "ol0703579-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [183.0, 244.0, 88.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [632.0, 172.0, 239.0, 86.0], "category_id": 2}, {"id": 2, "bbox": [1005.0, 238.0, 86.0, 50.0], "category_id": 3}, {"id": 3, "bbox": [474.0, 247.0, 56.0, 37.0], "category_id": 3}, {"id": 4, "bbox": [123.0, 18.0, 280.0, 240.0], "category_id": 1}, {"id": 5, "bbox": [399.0, 104.0, 212.0, 162.0], "category_id": 1}, {"id": 6, "bbox": [0.0, 318.0, 1344.0, 1177.0], "category_id": 4}, {"id": 7, "bbox": [901.0, 11.0, 325.0, 276.0], "category_id": 1}, {"id": 8, "bbox": [0.0, 1521.0, 1347.0, 155.0], "category_id": 2}, {"id": 9, "bbox": [804.0, 1746.0, 548.0, 70.0], "category_id": 2}, {"id": 10, "bbox": [616.0, 117.0, 271.0, 40.0], "category_id": 2}], "reactions": [{"reactants": [4, 5], "conditions": [10, 1], "products": [7]}], "corefs": [[4, 0], [5, 3], [7, 2]], "caption": "Table 2. Variation of the Imine Substrate", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 583, 662, 596], "ImageBB": [439, 599, 777, 1053]}, "diagram_type": "single"}, {"id": 556, "width": 1348, "height": 436, "file_name": "acs.orglett.5b02279-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [991.0, 0.0, 350.0, 300.0], "category_id": 1}, {"id": 1, "bbox": [355.0, 7.0, 242.0, 249.0], "category_id": 1}, {"id": 2, "bbox": [27.0, 355.0, 1310.0, 77.0], "category_id": 4}, {"id": 3, "bbox": [6.0, 18.0, 339.0, 237.0], "category_id": 1}, {"id": 4, "bbox": [827.0, 167.0, 128.0, 35.0], "category_id": 2}, {"id": 5, "bbox": [829.0, 28.0, 164.0, 123.0], "category_id": 2}, {"id": 6, "bbox": [1116.0, 276.0, 34.0, 42.0], "category_id": 3}, {"id": 7, "bbox": [600.0, 53.0, 222.0, 134.0], "category_id": 1}, {"id": 8, "bbox": [585.0, 204.0, 420.0, 140.0], "category_id": 3}, {"id": 9, "bbox": [411.07, 248.0, 58.0, 38.0], "category_id": 3}, {"id": 10, "bbox": [195.95, 197.98, 46.0, 49.0], "category_id": 3}], "reactions": [{"reactants": [1, 7], "conditions": [5, 4], "products": [0]}], "corefs": [[3, 10], [1, 9], [7, 8], [0, 6]], "caption": "Table 1. Screening Conditions of [4 + 3] Cycloadditiona", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 196, 405, 217], "ImageBB": [82, 223, 419, 332]}, "diagram_type": "single"}, {"id": 951, "width": 1352, "height": 700, "file_name": "acs.orglett.6b00233-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [954.99, 566.23, 384.16, 85.91], "category_id": 2}, {"id": 1, "bbox": [1117.31, 161.01, 171.79, 87.26], "category_id": 2}, {"id": 2, "bbox": [728.42, 38.56, 344.93, 199.57], "category_id": 1}, {"id": 3, "bbox": [453.15, 417.4, 56.81, 40.59], "category_id": 2}, {"id": 4, "bbox": [766.97, 583.82, 36.52, 40.59], "category_id": 3}, {"id": 5, "bbox": [498.46, 64.94, 60.87, 48.71], "category_id": 2}, {"id": 6, "bbox": [389.57, 147.48, 251.6, 84.56], "category_id": 2}, {"id": 7, "bbox": [585.71, 388.31, 327.35, 186.71], "category_id": 1}, {"id": 8, "bbox": [10.82, 24.35, 329.38, 198.89], "category_id": 1}, {"id": 9, "bbox": [194.11, 251.66, 33.82, 38.56], "category_id": 3}, {"id": 10, "bbox": [183.96, 598.02, 35.85, 41.95], "category_id": 3}, {"id": 11, "bbox": [4.06, 390.34, 330.73, 188.74], "category_id": 1}, {"id": 12, "bbox": [931.99, 263.83, 24.35, 39.24], "category_id": 3}], "caption": "Scheme 2. Strategy for Fused Tetrahydroisoquinolines", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 383, 110], "ImageBB": [82, 116, 420, 291]}, "reactions": [{"reactants": [8], "conditions": [5, 6], "products": [2]}, {"reactants": [2], "conditions": [1], "products": [11]}, {"reactants": [11], "conditions": [3], "products": [7]}], "diagram_type": "multiple"}, {"id": 418, "width": 1356, "height": 936, "file_name": "op400050n-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [899.3, 397.3, 240.7, 198.7], "category_id": 1}, {"id": 1, "bbox": [522.0, 401.7, 192.0, 163.3], "category_id": 1}, {"id": 2, "bbox": [505.1, 44.0, 302.9, 191.0], "category_id": 1}, {"id": 3, "bbox": [705.8, 734.0, 273.2, 195.7], "category_id": 1}, {"id": 4, "bbox": [251.9, 731.3, 325.1, 204.7], "category_id": 1}, {"id": 5, "bbox": [215.3, 391.5, 176.7, 205.5], "category_id": 1}, {"id": 6, "bbox": [733.0, 616.0, 113.0, 62.0], "category_id": 2}, {"id": 7, "bbox": [738.0, 423.0, 82.0, 63.0], "category_id": 2}, {"id": 8, "bbox": [642.0, 283.0, 156.0, 58.0], "category_id": 2}, {"id": 9, "bbox": [295.0, 618.0, 200.0, 54.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [8], "products": [2]}, {"reactants": [1], "conditions": [], "products": [5]}, {"reactants": [1], "conditions": [7], "products": [0]}, {"reactants": [1], "conditions": [9], "products": [4]}, {"reactants": [1], "conditions": [6], "products": [3]}], "corefs": [], "caption": "Figure 2. Possible oxirane ring-opening reactions.", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 741, 691, 755], "ImageBB": [448, 498, 787, 732]}, "diagram_type": "tree"}, {"id": 845, "width": 1356, "height": 1308, "file_name": "jo201478d-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [66.5, 346.0, 427.5, 258.0], "category_id": 1}, {"id": 1, "bbox": [1035.0, 1205.0, 64.0, 60.0], "category_id": 3}, {"id": 2, "bbox": [4.0, 271.0, 613.0, 82.0], "category_id": 2}, {"id": 3, "bbox": [4.0, 0.0, 325.0, 55.0], "category_id": 2}, {"id": 4, "bbox": [903.0, 898.3, 70.5, 65.7], "category_id": 3}, {"id": 5, "bbox": [1156.0, 898.5, 73.0, 61.5], "category_id": 3}, {"id": 6, "bbox": [308.0, 1205.8, 56.0, 61.2], "category_id": 3}, {"id": 7, "bbox": [667.26, 1207.55, 74.5, 59.7], "category_id": 3}, {"id": 8, "bbox": [645.0, 106.8, 267.5, 65.9], "category_id": 2}, {"id": 9, "bbox": [496.0, 415.8, 269.2, 53.7], "category_id": 2}, {"id": 10, "bbox": [10.0, 971.5, 619.0, 53.5], "category_id": 2}, {"id": 11, "bbox": [170.0, 212.0, 71.0, 59.0], "category_id": 3}, {"id": 12, "bbox": [905.0, 1025.0, 317.0, 193.0], "category_id": 1}, {"id": 13, "bbox": [543.0, 1025.2, 376.0, 196.8], "category_id": 1}, {"id": 14, "bbox": [123.0, 1029.0, 435.0, 153.7], "category_id": 1}, {"id": 15, "bbox": [770.0, 750.0, 237.0, 136.0], "category_id": 1}, {"id": 16, "bbox": [801.0, 331.0, 396.5, 249.2], "category_id": 1}, {"id": 17, "bbox": [423.0, 886.0, 71.0, 78.0], "category_id": 3}, {"id": 18, "bbox": [960.0, 59.5, 382.7, 203.0], "category_id": 1}, {"id": 19, "bbox": [450.5, 90.3, 143.3, 133.8], "category_id": 1}, {"id": 20, "bbox": [9.0, 61.0, 399.7, 202.2], "category_id": 1}, {"id": 21, "bbox": [978.0, 560.3, 69.0, 62.7], "category_id": 3}, {"id": 22, "bbox": [243.0, 561.8, 72.7, 59.2], "category_id": 3}, {"id": 23, "bbox": [477.0, 208.8, 71.2, 59.2], "category_id": 3}, {"id": 24, "bbox": [53.0, 734.0, 200.0, 177.0], "category_id": 1}, {"id": 25, "bbox": [288.0, 707.0, 415.0, 204.0], "category_id": 1}, {"id": 26, "bbox": [1052.0, 719.0, 284.0, 190.0], "category_id": 1}, {"id": 27, "bbox": [1146.0, 210.0, 81.0, 65.0], "category_id": 3}, {"id": 28, "bbox": [141.0, 886.0, 65.0, 78.0], "category_id": 3}], "reactions": [{"reactants": [20, 19], "conditions": [8], "products": [18]}, {"reactants": [0], "conditions": [9], "products": [16]}, {"reactants": [16], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [24, 25]}, {"reactants": [24, 25], "conditions": [], "products": [0]}, {"reactants": [16], "conditions": [], "products": [15, 26]}, {"reactants": [15, 26], "conditions": [], "products": [16]}], "corefs": [[20, 11], [19, 23], [18, 27], [0, 22], [16, 21], [24, 28], [25, 17], [15, 4], [26, 5], [14, 6], [13, 7], [12, 1]], "caption": "Table 4. E\ufb00ects of Additives on the Addition/ISMS Reaction Sequence ", "pdf": {"Page": 4, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 482, 771, 512], "ImageBB": [436, 133, 775, 460]}, "diagram_type": "tree"}, {"id": 1324, "width": 1356, "height": 828, "file_name": "op300343q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1033.79, 0.0, 322.21, 377.14], "category_id": 1}, {"id": 1, "bbox": [528.43, 0.0, 286.26, 377.14], "category_id": 1}, {"id": 2, "bbox": [385.3, 665.41, 125.49, 71.23], "category_id": 3}, {"id": 3, "bbox": [531.14, 263.86, 47.48, 54.26], "category_id": 3}, {"id": 4, "bbox": [845.21, 61.73, 142.45, 63.08], "category_id": 2}, {"id": 5, "bbox": [0.0, 6.1, 248.95, 292.35], "category_id": 1}, {"id": 6, "bbox": [982.91, 269.29, 128.89, 56.97], "category_id": 3}, {"id": 7, "bbox": [261.16, 21.03, 211.64, 101.74], "category_id": 2}, {"id": 8, "bbox": [1097.55, 516.87, 44.77, 62.4], "category_id": 3}, {"id": 9, "bbox": [122.1, 369.0, 238.1, 187.21], "category_id": 2}, {"id": 10, "bbox": [433.46, 407.66, 323.57, 376.46], "category_id": 1}], "caption": "Scheme 1. Synthetic route to solifenacin (1)", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 472, 700, 487], "ImageBB": [448, 493, 787, 700]}, "reactions": [{"reactants": [5], "conditions": [7], "products": [1]}, {"reactants": [1], "conditions": [4], "products": [0]}, {"reactants": [0], "conditions": [9], "products": [10]}, {"reactants": [10], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 1048, "width": 1332, "height": 1016, "file_name": "jo011082s-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [974.85, 644.86, 273.86, 234.49], "category_id": 1}, {"id": 1, "bbox": [762.7, 219.84, 50.23, 49.86], "category_id": 3}, {"id": 2, "bbox": [21.99, 212.9, 310.51, 170.3], "category_id": 3}, {"id": 3, "bbox": [0.0, 17.99, 358.49, 197.01], "category_id": 1}, {"id": 4, "bbox": [138.6, 405.04, 377.14, 61.28], "category_id": 2}, {"id": 5, "bbox": [1050.14, 890.01, 168.58, 55.96], "category_id": 3}, {"id": 6, "bbox": [176.58, 904.0, 43.31, 45.3], "category_id": 3}, {"id": 7, "bbox": [391.14, 113.92, 179.24, 128.57], "category_id": 1}, {"id": 8, "bbox": [1148.76, 205.18, 47.31, 50.63], "category_id": 3}, {"id": 9, "bbox": [44.64, 659.52, 300.52, 234.49], "category_id": 1}, {"id": 10, "bbox": [315.84, 604.89, 46.65, 54.63], "category_id": 3}, {"id": 11, "bbox": [522.41, 640.86, 281.85, 235.16], "category_id": 1}, {"id": 12, "bbox": [637.01, 0.0, 284.53, 217.84], "category_id": 1}, {"id": 13, "bbox": [612.36, 892.68, 101.28, 55.29], "category_id": 3}, {"id": 14, "bbox": [194.57, 476.32, 279.19, 134.56], "category_id": 1}, {"id": 15, "bbox": [1078.79, 28.65, 253.21, 181.86], "category_id": 1}, {"id": 16, "bbox": [138.6, 487.64, 53.3, 62.62], "category_id": 2}, {"id": 17, "bbox": [553.72, 953.3, 682.33, 60.62], "category_id": 2}, {"id": 18, "bbox": [362.49, 122.58, 53.97, 55.96], "category_id": 2}, {"id": 19, "bbox": [365.82, 0.0, 271.19, 98.59], "category_id": 2}, {"id": 20, "bbox": [937.53, 46.63, 126.6, 59.29], "category_id": 2}, {"id": 21, "bbox": [408.46, 710.81, 119.94, 63.29], "category_id": 2}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [76, 83, 409, 337]}, "reactions": [{"reactants": [3], "conditions": [19, 18, 7], "products": [12]}, {"reactants": [12], "conditions": [20], "products": [15]}, {"reactants": [3], "conditions": [4, 16, 14], "products": [9]}, {"reactants": [9], "conditions": [21], "products": [11, 0]}], "diagram_type": "tree"}, {"id": 724, "width": 1308, "height": 2828, "file_name": "ol0171867-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [540.34, 0.0, 386.67, 113.86], "category_id": 2}, {"id": 1, "bbox": [278.77, 30.46, 132.68, 166.8], "category_id": 1}, {"id": 2, "bbox": [39.94, 91.12, 106.15, 49.28], "category_id": 1}, {"id": 3, "bbox": [2.03, 265.5, 1300.27, 2558.85], "category_id": 4}, {"id": 4, "bbox": [532.75, 129.03, 276.74, 109.93], "category_id": 2}, {"id": 5, "bbox": [1082.43, 38.04, 166.8, 163.01], "category_id": 1}], "reactions": [{"reactants": [2, 1], "conditions": [0, 4], "products": [5]}], "corefs": [], "caption": "Table 3. Amination of Aryl Iodides with Different Amines", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 386, 89], "ImageBB": [80, 93, 407, 800]}, "diagram_type": "single"}, {"id": 156, "width": 2816, "height": 832, "file_name": "op700160a-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1499.37, 63.54, 78.57, 63.72], "category_id": 2}, {"id": 1, "bbox": [1798.0, 274.0, 61.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [1153.0, 268.0, 172.0, 66.0], "category_id": 3}, {"id": 3, "bbox": [1729.0, 3.0, 211.0, 256.0], "category_id": 1}, {"id": 4, "bbox": [911.0, 274.0, 133.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [6.0, 340.0, 2810.0, 492.0], "category_id": 4}, {"id": 6, "bbox": [878.0, 0.0, 202.0, 265.0], "category_id": 1}, {"id": 7, "bbox": [1140.0, 0.0, 194.0, 259.0], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [0], "products": [3]}], "corefs": [[6, 4], [7, 2], [3, 1]], "caption": "Table 1. Screening of oxidation conditions for conversion of bisfuran alcohol, 1, to ketone, 9", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 564, 60], "ImageBB": [58, 74, 762, 282]}, "diagram_type": "single"}, {"id": 711, "width": 1344, "height": 1300, "file_name": "ol034469l-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [990.0, 209.0, 93.0, 38.0], "category_id": 3}, {"id": 1, "bbox": [206.3, 71.0, 327.7, 136.1], "category_id": 1}, {"id": 2, "bbox": [930.9, 25.3, 204.6, 176.9], "category_id": 1}, {"id": 3, "bbox": [333.0, 202.0, 73.0, 52.0], "category_id": 3}, {"id": 4, "bbox": [2.0, 280.0, 1342.0, 1020.0], "category_id": 4}, {"id": 5, "bbox": [563.0, 159.0, 342.5, 47.0], "category_id": 2}, {"id": 6, "bbox": [610.0, 4.0, 243.0, 133.4], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [6, 5], "products": [2]}], "corefs": [[1, 3], [2, 0]], "caption": "Table 2. Intramolecular Reductive Dimerization Scope", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 76, 364, 89], "ImageBB": [74, 93, 410, 418]}, "diagram_type": "single"}, {"id": 1144, "width": 1352, "height": 1804, "file_name": "ol025887d-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [751.75, 204.86, 172.37, 55.05], "category_id": 2}, {"id": 1, "bbox": [462.96, 580.28, 203.96, 46.92], "category_id": 2}, {"id": 2, "bbox": [309.54, 849.21, 254.5, 174.17], "category_id": 2}, {"id": 3, "bbox": [751.75, 0.0, 247.27, 175.08], "category_id": 2}, {"id": 4, "bbox": [304.13, 147.1, 121.83, 59.56], "category_id": 2}, {"id": 5, "bbox": [82.12, 147.1, 167.88, 61.37], "category_id": 2}, {"id": 6, "bbox": [52.34, 333.0, 497.26, 434.08], "category_id": 1}, {"id": 7, "bbox": [462.96, 425.96, 224.72, 128.15], "category_id": 2}, {"id": 8, "bbox": [95.66, 853.72, 189.52, 96.56], "category_id": 2}, {"id": 9, "bbox": [309.54, 1054.06, 178.69, 55.05], "category_id": 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"op800033c-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [311.02, 336.04, 122.16, 60.73], "category_id": 2}, {"id": 1, "bbox": [1115.3, 228.42, 56.13, 43.58], "category_id": 3}, {"id": 2, "bbox": [704.57, 549.94, 60.09, 42.25], "category_id": 3}, {"id": 3, "bbox": [704.57, 228.42, 60.09, 41.6], "category_id": 3}, {"id": 4, "bbox": [640.52, 344.62, 215.93, 175.61], "category_id": 1}, {"id": 5, "bbox": [0.0, 14.52, 224.51, 176.93], "category_id": 1}, {"id": 6, "bbox": [994.46, 26.41, 293.18, 180.23], "category_id": 1}, {"id": 7, "bbox": [640.52, 21.79, 231.08, 181.55], "category_id": 1}, {"id": 8, "bbox": [283.94, 49.51, 277.34, 50.18], "category_id": 2}, {"id": 9, "bbox": [75.28, 229.75, 35.66, 40.27], "category_id": 3}, {"id": 10, "bbox": [328.18, 129.4, 188.86, 97.04], "category_id": 2}], "caption": "Scheme 4", "pdf": {"Page": 6, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 319, 119, 333], "ImageBB": [62, 338, 392, 487]}, "reactions": [{"reactants": [5], "conditions": [8, 10], "products": [7]}, {"reactants": [5], "conditions": [0], "products": [4]}], "diagram_type": "tree"}, {"id": 82, "width": 1272, "height": 964, "file_name": "ja075824w-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [645.33, 156.18, 197.81, 45.93], "category_id": 2}, {"id": 1, "bbox": [615.21, 4.3, 254.29, 107.43], "category_id": 2}, {"id": 2, "bbox": [7.69, 19.36, 286.93, 221.66], "category_id": 1}, {"id": 3, "bbox": [925.24, 21.87, 339.65, 221.66], "category_id": 1}, {"id": 4, "bbox": [362.91, 107.22, 220.39, 52.21], "category_id": 1}], "reactions": [{"reactants": [2, 4], "conditions": [1, 0], "products": [3]}], "corefs": [], "caption": "Figure 2. Solvent effect in the DMAP-catalyzed isobutyrylation of l-menthol. The reaction of l-menthol (5 mmol) was conducted with (i-PrCO)2O (5 mmol) in the presence of 1 (0.1 mol %) in solvent (5 mL): green circles, no solvent; red squares, heptane; blue triangles, THF; orange squares, CH3CN; black circles, CH2Cl2. 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Substrate Scopea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 487, 229, 508], "ImageBB": [82, 514, 419, 1005]}, "diagram_type": "single"}, {"id": 1255, "width": 1352, "height": 1684, "file_name": "op049954q-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [305.86, 155.01, 181.15, 42.12], "category_id": 2}, {"id": 1, "bbox": [342.09, 58.97, 123.01, 58.13], "category_id": 2}, {"id": 2, "bbox": [821.51, 62.34, 111.22, 47.17], "category_id": 2}, {"id": 3, "bbox": [934.42, 946.04, 343.77, 737.96], "category_id": 1}, {"id": 4, "bbox": [754.11, 1118.74, 167.67, 109.51], "category_id": 2}, {"id": 5, "bbox": [581.38, 635.19, 141.55, 280.52], "category_id": 1}, {"id": 6, "bbox": [750.76, 1592.96, 56.6, 52.56], "category_id": 3}, {"id": 7, "bbox": [0.0, 0.0, 306.7, 288.95], "category_id": 1}, {"id": 8, "bbox": [1157.7, 1533.21, 49.71, 51.38], "category_id": 3}, {"id": 9, "bbox": [488.7, 0.0, 301.64, 281.37], "category_id": 1}, {"id": 10, "bbox": 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KR of trans-Cyclohexane-1,2-diol 1 with Boc2O using Various Reaction Conditions", "pdf": {"Page": 10, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 300, 600, 320], "ImageBB": [82, 131, 787, 297]}, "diagram_type": "single"}, {"id": 1275, "width": 1908, "height": 1052, "file_name": "op100103v-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [858.08, 298.74, 54.4, 40.08], "category_id": 3}, {"id": 1, "bbox": [911.53, 801.72, 51.54, 42.95], "category_id": 3}, {"id": 2, "bbox": [1195.96, 619.43, 222.39, 101.17], "category_id": 2}, {"id": 3, "bbox": [372.25, 166.07, 282.52, 83.99], "category_id": 2}, {"id": 4, "bbox": [505.87, 628.97, 138.4, 36.27], "category_id": 2}, {"id": 5, "bbox": [1646.47, 1008.84, 38.18, 41.99], "category_id": 3}, {"id": 6, "bbox": [708.22, 0.0, 353.16, 327.37], "category_id": 1}, {"id": 7, "bbox": [374.16, 86.85, 172.76, 44.86], "category_id": 2}, {"id": 8, "bbox": [1129.15, 162.25, 323.56, 126.94], "category_id": 2}, {"id": 9, "bbox": [1127.24, 77.31, 305.43, 47.72], "category_id": 2}, {"id": 10, "bbox": [711.09, 459.08, 465.78, 295.88], "category_id": 1}, {"id": 11, "bbox": [21.0, 2.86, 281.57, 271.06], "category_id": 1}, {"id": 12, "bbox": [506.83, 507.76, 129.81, 83.03], "category_id": 2}, {"id": 13, "bbox": [1454.62, 340.73, 453.38, 650.93], "category_id": 1}, {"id": 14, "bbox": [1332.45, 430.45, 36.27, 41.99], "category_id": 3}, {"id": 15, "bbox": [106.9, 271.06, 48.68, 41.04], "category_id": 3}, {"id": 16, "bbox": [1221.73, 335.96, 177.53, 244.34], "category_id": 1}, {"id": 17, "bbox": [188.99, 801.72, 54.4, 42.95], "category_id": 3}, {"id": 18, "bbox": [21.0, 416.13, 455.28, 382.73], "category_id": 1}], "caption": "Scheme 5. Initial conditions for stage two for the synthesis of imidazo[5,1-c][1,4]benzoxazine-3-carboxylate 9", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 461, 657, 475], "ImageBB": [171, 480, 648, 743]}, "reactions": [{"reactants": [11], "conditions": [7, 3], "products": [6]}, {"reactants": [6], "conditions": [9, 8], "products": [18]}, {"reactants": [18], "conditions": [12, 4], "products": [10]}, {"reactants": [10, 16], "conditions": [2], "products": [13]}], "diagram_type": "multiple"}, {"id": 731, "width": 1348, "height": 704, "file_name": "ol016212y-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [923.2, 4.0, 252.8, 240.8], "category_id": 1}, {"id": 1, "bbox": [108.3, 5.0, 252.7, 234.8], "category_id": 1}, {"id": 2, "bbox": [924.0, 275.0, 322.0, 41.0], "category_id": 2}, {"id": 3, "bbox": [437.0, 99.0, 434.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [5.0, 365.0, 1343.0, 339.0], "category_id": 4}, {"id": 5, "bbox": [124.0, 270.0, 549.0, 58.0], "category_id": 2}, {"id": 6, "bbox": [543.0, 165.0, 201.0, 49.0], "category_id": 2}], "reactions": [{"reactants": [1], "conditions": [3, 6], "products": [0]}], "corefs": [], "caption": "Table 3. Comparison of the Fiber-Supported Amino Alcohol P3 with 3 and 5 as Catalysts in the Reduction of PhCOMe with NaBH4/Me3SiCl ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 747, 770, 791], "ImageBB": [439, 792, 776, 968]}, "diagram_type": "single"}, {"id": 79, "width": 2816, "height": 1156, "file_name": "ja1048847-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1568.01, 245.3, 32.09, 37.41], "category_id": 3}, {"id": 1, "bbox": [4.42, 339.8, 2809.48, 816.2], "category_id": 4}, {"id": 2, "bbox": [1457.02, 25.87, 301.43, 178.26], "category_id": 1}, {"id": 3, "bbox": [695.53, 241.77, 203.75, 85.18], "category_id": 3}, {"id": 4, "bbox": [1813.79, 4.63, 322.68, 216.49], "category_id": 1}, {"id": 5, "bbox": [675.5, 2.51, 324.8, 218.61], "category_id": 1}, {"id": 6, "bbox": [1013.17, 159.66, 360.9, 97.56], "category_id": 2}, {"id": 7, "bbox": [1015.29, 21.62, 413.99, 95.44], "category_id": 2}, {"id": 8, "bbox": [1888.33, 231.16, 51.56, 49.78], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[5, 3], [2, 0], [4, 8]], "caption": "Table 1. Synthesis of Cyclobutarenes: Study of C(sp3)-H Arylation Parameters", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 56, 455, 69], "ImageBB": [58, 78, 762, 367]}, "diagram_type": "single"}, {"id": 451, "width": 2808, "height": 928, "file_name": "op2001047-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1958.15, 201.35, 77.5, 64.9], "category_id": 3}, {"id": 1, "bbox": [11.0, 274.0, 2797.0, 654.0], "category_id": 4}, {"id": 2, "bbox": [667.35, 199.35, 56.0, 67.0], "category_id": 3}, {"id": 3, "bbox": [437.3, 4.5, 343.7, 221.6], "category_id": 1}, {"id": 4, "bbox": [1156.5, 25.7, 433.7, 220.7], "category_id": 1}, {"id": 5, "bbox": [1627.9, 24.1, 743.5, 218.9], "category_id": 1}, {"id": 6, "bbox": [1434.53, 204.0, 56.0, 59.0], "category_id": 3}, {"id": 7, "bbox": [897.95, 152.75, 192.71, 57.18], "category_id": 2}, {"id": 8, "bbox": [828.07, 36.28, 326.12, 101.65], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [8, 7], "products": [4, 5]}], "corefs": [[3, 2], [4, 6], [5, 0]], "caption": "Table 4. Reaction Optimization for the Microwave-assisted Aldol Reaction of p-Anisaldehyde (4b) with Acetonea", "pdf": {"Page": 5, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 697, 109], "ImageBB": [71, 117, 773, 349]}, "diagram_type": "single"}, {"id": 282, "width": 1348, "height": 948, "file_name": "ol800288b-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [517.0, 3.0, 250.0, 43.0], "category_id": 2}, {"id": 1, "bbox": [887.0, 10.0, 303.0, 91.0], "category_id": 1}, {"id": 2, "bbox": [161.0, 39.0, 265.0, 64.0], "category_id": 1}, {"id": 3, "bbox": [9.0, 289.0, 1334.0, 659.0], "category_id": 4}, {"id": 4, "bbox": [470.0, 84.0, 325.0, 155.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [0, 4], "products": [1]}], "corefs": [], "caption": "Table 1. Aziridination of 1-Hexene Catalyzed by IPrCuCla", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 475, 752, 489], "ImageBB": [439, 494, 776, 731]}, "diagram_type": "single"}, {"id": 245, "width": 1352, "height": 1056, "file_name": "ol901684h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [114.0, 223.0, 42.0, 55.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 294.0, 1352.0, 762.0], "category_id": 4}, {"id": 2, "bbox": [611.0, 141.0, 212.0, 107.0], "category_id": 2}, {"id": 3, "bbox": [549.0, 0.0, 348.0, 145.0], "category_id": 2}, {"id": 4, "bbox": [369.0, 224.0, 69.0, 59.0], "category_id": 3}, {"id": 5, "bbox": [1115.0, 224.0, 70.0, 57.0], "category_id": 3}, {"id": 6, "bbox": [914.9, 72.8, 407.2, 138.0], "category_id": 1}, {"id": 7, "bbox": [278.0, 111.2, 266.0, 63.5], "category_id": 1}, {"id": 8, "bbox": [25.8, 79.0, 208.2, 135.5], "category_id": 1}], "reactions": [{"reactants": [8, 7], "conditions": [3, 2], "products": [6]}], "corefs": [[8, 0], [7, 4], [6, 5]], "caption": "Table 1. Optimization for Nickel-Catalyzed Direct Alkynylation of Benzoxazole (1) with (Bromoethynyl)benzene (2a)a ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 195, 390, 222], "ImageBB": [58, 231, 396, 495]}, "diagram_type": "single"}, {"id": 642, "width": 1356, "height": 1428, "file_name": "ol5007604-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [818.28, 12.16, 341.92, 540.54], "category_id": 1}, {"id": 1, "bbox": [307.0, 561.0, 46.8, 49.4], "category_id": 3}, {"id": 2, "bbox": [519.0, 188.0, 346.2, 107.0], "category_id": 2}, {"id": 3, "bbox": [619.8, 310.0, 135.2, 49.6], "category_id": 2}, {"id": 4, "bbox": [1003.48, 559.84, 54.0, 54.0], "category_id": 3}, {"id": 5, "bbox": [593.44, 139.83, 200.58, 46.0], "category_id": 1}, {"id": 6, "bbox": [203.0, 5.0, 286.0, 535.0], "category_id": 1}, {"id": 7, "bbox": [14.0, 636.0, 1342.0, 792.0], "category_id": 4}], "reactions": [{"reactants": [6], "conditions": [5, 2, 3], "products": [0]}], "corefs": [[6, 1], [0, 4]], "caption": "Table 1. [2 + 1 + 2 + 1] Cycloaddition on Strained Precursor", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 110], "ImageBB": [448, 116, 787, 473]}, "diagram_type": "single"}, {"id": 497, "width": 1356, "height": 1040, "file_name": "ol053021c-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [14.0, 270.0, 1311.0, 770.0], "category_id": 4}, {"id": 1, "bbox": [795.0, 450.0, 217.0, 204.0], "category_id": 1}, {"id": 2, "bbox": [923.0, 45.0, 291.0, 213.0], "category_id": 1}, {"id": 3, "bbox": [715.0, 648.0, 380.0, 192.0], "category_id": 1}, {"id": 4, "bbox": [234.0, 859.0, 346.0, 122.0], "category_id": 1}, {"id": 5, "bbox": [449.0, 0.0, 359.0, 108.0], "category_id": 2}, {"id": 6, "bbox": [113.18, 45.97, 293.0, 138.0], "category_id": 1}, {"id": 7, "bbox": [463.0, 142.0, 359.0, 103.0], "category_id": 2}, {"id": 8, "bbox": [677.0, 838.0, 455.0, 202.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [5, 7], "products": [2]}], "corefs": [], "caption": "Table 3. Direct Arylation of Imidazo[1,2-a]pyridinesa", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 359, 89], "ImageBB": [73, 98, 412, 358]}, "diagram_type": "single"}, {"id": 534, "width": 1344, "height": 1540, "file_name": "jo000745n-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [320.0, 369.0, 715.0, 1171.0], "category_id": 4}, {"id": 1, "bbox": [439.0, 113.0, 164.0, 111.0], "category_id": 2}, {"id": 2, "bbox": [420.4, 28.0, 183.4, 60.0], "category_id": 2}, {"id": 3, "bbox": [268.0, 73.0, 145.0, 60.0], "category_id": 1}, {"id": 4, "bbox": [650.4, 69.7, 391.0, 58.1], "category_id": 1}, {"id": 5, "bbox": [728.0, 261.0, 205.0, 54.0], "category_id": 1}, {"id": 6, "bbox": [694.0, 150.0, 122.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [788.0, 316.6, 97.0, 38.2], "category_id": 3}, {"id": 8, "bbox": [859.0, 142.0, 199.0, 113.0], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [2, 1], "products": [4]}, {"reactants": [4], "conditions": [6, 8], "products": [5]}], "corefs": [[5, 7]], "caption": "Table 1. Preparation of Isothiocyanates 9-16 from     Primary Amines through Thiocarbamates ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [91, 64, 391, 89], "ImageBB": [74, 90, 410, 475]}, "diagram_type": "tree"}, {"id": 1262, "width": 1048, "height": 312, "file_name": "op0501803-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [644.84, 6.81, 82.84, 51.36], "category_id": 2}, {"id": 1, "bbox": [153.08, 6.81, 100.66, 51.88], "category_id": 2}, {"id": 2, "bbox": [0.0, 5.24, 72.35, 48.74], "category_id": 2}, {"id": 3, "bbox": [644.84, 114.25, 231.73, 194.95], "category_id": 1}, {"id": 4, "bbox": [0.0, 190.76, 85.45, 53.45], "category_id": 2}, {"id": 5, "bbox": [471.31, 4.72, 89.13, 50.83], "category_id": 2}, {"id": 6, "bbox": [968.84, 192.33, 79.16, 48.21], "category_id": 2}, {"id": 7, "bbox": [182.97, 115.29, 225.43, 196.0], "category_id": 1}], "caption": "Scheme 3. Postulated mechanism of the formation of hydrazoic acid in presence of protic components ", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 419, 740, 447], "ImageBB": [477, 451, 739, 529]}, "reactions": [{"reactants": [2, 1], "conditions": [], "products": [5, 0]}, {"reactants": [4, 7], "conditions": [], "products": [3, 6]}, {"reactants": [3, 6], "conditions": [], "products": [4, 7]}], "diagram_type": "multiple"}, {"id": 653, "width": 1324, "height": 1352, "file_name": "ol403122a-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.0, 103.0, 303.0, 61.0], "category_id": 2}, {"id": 1, "bbox": [1108.0, 28.2, 187.1, 121.9], "category_id": 1}, {"id": 2, "bbox": [851.0, 52.7, 118.5, 54.3], "category_id": 2}, {"id": 3, "bbox": [511.0, 23.0, 199.3, 125.6], "category_id": 1}, {"id": 4, "bbox": [277.0, 44.0, 150.0, 52.0], "category_id": 2}, {"id": 5, "bbox": [11.0, 185.0, 1313.0, 1167.0], "category_id": 4}, {"id": 6, "bbox": [229.0, 100.0, 227.0, 57.0], "category_id": 2}, {"id": 7, "bbox": [30.0, 65.0, 180.0, 63.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [4, 6], "products": [3]}, {"reactants": [3], "conditions": [2, 0], "products": [1]}], "corefs": [], "caption": "Table 3. Extending the Substrate Scope for the in Situ Electrophilic Trapping of Metal Sul\ufb01nates with Alternative Alkyl Halidesa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 412, 140], "ImageBB": [85, 146, 416, 484]}, "diagram_type": "single"}, {"id": 254, "width": 1348, "height": 1180, "file_name": "ol802141g-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [678.0, 301.0, 111.0, 55.0], "category_id": 2}, {"id": 1, "bbox": [699.0, 236.0, 72.0, 53.0], "category_id": 2}, {"id": 2, "bbox": [1019.0, 236.2, 221.0, 83.6], "category_id": 1}, {"id": 3, "bbox": [489.4, 145.6, 238.6, 248.3], "category_id": 1}, {"id": 4, "bbox": [820.6, 178.2, 179.4, 221.2], "category_id": 1}], "reactions": [{"reactants": [3], "conditions": [1, 0], "products": [4, 2]}], "corefs": [], "caption": "Figure 2. UV spectra of 9e (solid line, ca. 1 \u00d7 10-4 M in 20% aqueous methanol) and its 300 nm photolysis (dashed lines, every 5 min). ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 856, 761, 886], "ImageBB": [425, 557, 762, 852]}, "diagram_type": "single"}, {"id": 266, "width": 1348, "height": 1020, "file_name": "ol8013717-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [19.72, 0.69, 321.08, 239.0], "category_id": 1}, {"id": 1, "bbox": [1145.0, 247.4, 65.0, 46.9], "category_id": 3}, {"id": 2, "bbox": [989.3, 0.0, 337.9, 240.9], "category_id": 1}, {"id": 3, "bbox": [714.5, 11.2, 186.9, 99.1], "category_id": 2}, {"id": 4, "bbox": [105.5, 245.3, 207.0, 58.7], "category_id": 3}, {"id": 5, "bbox": [449.5, 89.8, 191.5, 64.7], "category_id": 2}, {"id": 6, "bbox": [686.8, 132.9, 234.9, 147.0], "category_id": 2}, {"id": 7, "bbox": [2.0, 323.0, 1344.0, 694.0], "category_id": 4}, {"id": 8, "bbox": [425.8, 167.3, 223.6, 60.5], "category_id": 3}], "reactions": [{"reactants": [0, 5], "conditions": [3, 6], "products": [2]}], "corefs": [[0, 4], [5, 8], [2, 1]], "caption": "Table 1. Cu-Mediated Cross-Coupling of 1 and 2aa", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 693, 88], "ImageBB": [425, 97, 762, 352]}, "diagram_type": "single"}, {"id": 1185, "width": 1344, "height": 580, "file_name": "ol4017244-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [341.55, 61.21, 190.27, 51.79], "category_id": 2}, {"id": 1, "bbox": [26.89, 6.05, 302.55, 186.32], "category_id": 1}, {"id": 2, "bbox": [455.84, 265.02, 166.07, 45.06], "category_id": 2}, {"id": 3, "bbox": [824.96, 61.88, 166.06, 47.09], "category_id": 2}, {"id": 4, "bbox": [855.21, 155.38, 105.56, 51.79], "category_id": 2}, {"id": 5, "bbox": [545.94, 54.48, 270.95, 135.2], "category_id": 1}, {"id": 6, "bbox": [1016.57, 2.69, 270.95, 183.63], "category_id": 1}, {"id": 7, "bbox": [385.25, 164.12, 105.56, 47.09], "category_id": 2}, {"id": 8, "bbox": [658.22, 234.75, 141.19, 91.48], "category_id": 2}, {"id": 9, "bbox": [543.25, 345.73, 303.22, 183.63], "category_id": 1}, {"id": 10, "bbox": [997.07, 212.55, 324.74, 100.22], "category_id": 2}], "caption": "Scheme 1. Palladium-Catalyzed Carbonylative Couplings of Aryl Diazonium Salts ", "pdf": {"Page": 2, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [71, 89, 390, 116], "ImageBB": [71, 127, 407, 272]}, "reactions": [{"reactants": [5], "conditions": [8], "products": [9]}, {"reactants": [5], "conditions": [3, 4], "products": [6]}], "diagram_type": "tree"}, {"id": 810, "width": 3396, "height": 1416, "file_name": "jo4027148-Figure-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2290.5, 434.6, 183.4, 116.0], "category_id": 1}, {"id": 1, "bbox": [1105.0, 381.0, 622.0, 369.6], "category_id": 1}, {"id": 2, "bbox": [1846.2, 388.0, 265.8, 346.0], "category_id": 1}, {"id": 3, "bbox": [751.0, 416.2, 315.0, 117.8], "category_id": 1}, {"id": 4, "bbox": [1019.7, 963.84, 190.1, 113.6], "category_id": 1}, {"id": 5, "bbox": [2611.0, 1293.0, 53.0, 40.0], "category_id": 3}, {"id": 6, "bbox": [2627.0, 388.0, 429.0, 370.0], "category_id": 1}, {"id": 7, "bbox": [412.0, 378.0, 297.0, 384.0], "category_id": 1}, {"id": 8, "bbox": [1421.0, 924.0, 277.0, 338.0], "category_id": 1}, {"id": 9, "bbox": [531.0, 923.0, 280.0, 349.0], "category_id": 1}, {"id": 10, "bbox": [1871.0, 923.0, 409.0, 356.0], "category_id": 1}, {"id": 11, "bbox": [2426.0, 924.0, 422.0, 351.0], "category_id": 1}, {"id": 12, "bbox": [2203.0, 778.0, 338.0, 37.0], "category_id": 2}, {"id": 13, "bbox": [1957.0, 784.0, 50.0, 49.0], "category_id": 3}, {"id": 14, "bbox": [1388.0, 785.0, 56.0, 48.0], "category_id": 3}, {"id": 15, "bbox": [2044.0, 1293.0, 53.0, 37.0], "category_id": 3}, {"id": 16, "bbox": [1529.0, 1293.0, 49.0, 44.0], "category_id": 3}, {"id": 17, "bbox": [934.82, 933.28, 99.88, 61.47], "category_id": 2}, {"id": 18, "bbox": [752.98, 387.77, 94.76, 64.03], "category_id": 2}, {"id": 19, "bbox": [2202.56, 408.26, 99.88, 56.34], "category_id": 2}, {"id": 20, "bbox": [2811.0, 789.0, 49.0, 35.0], "category_id": 3}, {"id": 21, "bbox": [640.0, 1293.0, 61.0, 47.0], "category_id": 3}, {"id": 22, "bbox": [539.0, 789.0, 56.0, 44.0], "category_id": 3}, {"id": 23, "bbox": [2200.0, 598.0, 338.0, 173.0], "category_id": 2}, {"id": 24, "bbox": [754.0, 584.0, 324.0, 179.0], "category_id": 2}, {"id": 25, "bbox": [654.0, 763.0, 527.0, 42.0], "category_id": 2}, {"id": 26, "bbox": [951.0, 1120.0, 332.0, 119.0], "category_id": 2}], "reactions": [{"reactants": [7], "conditions": [18, 3, 24, 25], "products": [1]}, {"reactants": [2], "conditions": [19, 0, 23, 12], "products": [6]}, {"reactants": [9], "conditions": [17, 4, 26], "products": [8, 10, 11]}], "corefs": [[7, 22], [1, 14], [2, 13], [6, 20], [9, 21], [8, 16], [10, 15], [11, 5]], "caption": "Figure 5. (A) Daugulis\u2019 methylene C\u2212H arylation. (B) Statistical arylation of 28 with 1 equiv of iodobenzene.", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 386, 620, 400], "ImageBB": [10, 22, 859, 376]}, "diagram_type": "multiple"}, {"id": 762, "width": 1344, "height": 1672, "file_name": "jo962200s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [512.0, 1082.0, 76.0, 64.8], "category_id": 3}, {"id": 1, "bbox": [106.0, 1144.52, 130.6, 46.1], "category_id": 2}, {"id": 2, "bbox": [707.0, 1274.0, 384.9, 398.0], "category_id": 1}, {"id": 3, "bbox": [237.25, 1010.72, 47.07, 56.03], "category_id": 3}, {"id": 4, "bbox": [421.52, 1430.76, 251.0, 58.0], "category_id": 2}, {"id": 5, "bbox": [1192.04, 1387.26, 47.07, 51.55], "category_id": 3}, {"id": 6, "bbox": [512.0, 1348.0, 76.0, 58.8], "category_id": 3}, {"id": 7, "bbox": [143.3, 721.7, 296.1, 266.0], "category_id": 1}, {"id": 8, "bbox": [777.0, 712.0, 415.0, 422.0], "category_id": 1}, {"id": 9, "bbox": [130.0, 1265.0, 345.0, 275.0], "category_id": 1}, {"id": 10, "bbox": [591.0, 816.0, 147.0, 64.0], "category_id": 2}, {"id": 11, "bbox": [54.0, 534.0, 491.0, 74.0], "category_id": 2}, {"id": 12, "bbox": [5.0, 0.0, 1331.0, 525.0], "category_id": 4}, {"id": 13, "bbox": [380.75, 822.66, 198.99, 315.47], "category_id": 1}, {"id": 14, "bbox": [237.0, 1549.0, 86.0, 68.0], "category_id": 3}], "reactions": [{"reactants": [7, 13], "conditions": [10], "products": [8]}, {"reactants": [7], "conditions": [1], "products": [9]}, {"reactants": [9], "conditions": [], "products": [7]}, {"reactants": [9], "conditions": [6, 4], "products": [2]}, {"reactants": [2], "conditions": [], "products": [5]}], "corefs": [[7, 3], [13, 0], [9, 14]], "caption": "Table 1. Reaction of 6-Amino-1,3-dimethyl-5-    thioformyluracil (1) with Enamines 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [108, 49, 373, 74], "ImageBB": [73, 76, 409, 494]}, "diagram_type": "graph"}, {"id": 162, "width": 1416, "height": 1576, "file_name": "op700039r-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 374.0, 1374.9, 1197.9], "category_id": 1}, {"id": 1, "bbox": [1029.46, 0.0, 386.54, 252.0], "category_id": 1}, {"id": 2, "bbox": [6.34, 0.0, 741.56, 286.2], "category_id": 1}, {"id": 3, "bbox": [862.0, 83.0, 40.0, 45.0], "category_id": 2}, {"id": 4, "bbox": [60.0, 283.0, 1356.0, 76.0], "category_id": 2}, {"id": 5, "bbox": [279.0, 224.0, 55.0, 56.0], "category_id": 3}, {"id": 6, "bbox": [1281.0, 219.0, 57.0, 63.0], "category_id": 3}], "reactions": [{"reactants": [2], "conditions": [3], "products": [1]}], "corefs": [[2, 5], [1, 6]], "caption": "Figure 1. Accelerating rate calorimetry (ARC) of 1.0 vol. 30 wt % H2O2 in 2.5 vol. formic acid (14.6 wt % performic acid assuming 100% conversion); 5 \u00b0C , O-corrected onset temper- ature, 179 \u00b0C adiabatic temperature rise (ATR), 252 \u00b0C/min maximum temperature rate, 1972 psi/min maximum pressure rate. ", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 617, 409, 700], "ImageBB": [73, 220, 427, 614]}, "diagram_type": "single"}, {"id": 457, "width": 2808, "height": 824, "file_name": "op200052z-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2248.0, 541.0, 71.0, 61.0], "category_id": 3}, {"id": 1, "bbox": [673.0, 441.0, 234.1, 112.6], "category_id": 2}, {"id": 2, "bbox": [1449.0, 166.9, 548.6, 481.0], "category_id": 1}, {"id": 3, "bbox": [941.2, 286.5, 448.9, 225.5], "category_id": 1}, {"id": 4, "bbox": [271.9, 304.9, 394.2, 223.8], "category_id": 1}, {"id": 5, "bbox": [675.4, 238.1, 253.1, 180.4], "category_id": 1}, {"id": 6, "bbox": [2027.0, 0.0, 508.0, 652.0], "category_id": 1}, {"id": 7, "bbox": [23.0, 726.0, 2768.0, 94.0], "category_id": 4}, {"id": 8, "bbox": [1707.0, 550.0, 58.0, 56.0], "category_id": 3}, {"id": 9, "bbox": [1126.0, 550.0, 54.0, 56.0], "category_id": 3}, {"id": 10, "bbox": [394.0, 560.0, 61.0, 36.0], "category_id": 3}], "reactions": [{"reactants": [4], "conditions": [5, 1], "products": [3, 2, 6]}], "corefs": [[4, 10], [3, 9], [2, 8], [6, 0]], "caption": "Table 1. Carbonate base screen for the di\ufb02uoromethylation of 5a", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 87, 432, 108], "ImageBB": [71, 117, 773, 323]}, "diagram_type": "single"}, {"id": 851, "width": 1356, "height": 1176, "file_name": "jo2008675-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1162.0, 204.0, 106.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [0.0, 8.0, 226.0, 190.0], "category_id": 1}, {"id": 2, "bbox": [10.0, 415.0, 1346.0, 761.0], "category_id": 4}, {"id": 3, "bbox": [664.0, 77.0, 288.0, 53.0], "category_id": 2}, {"id": 4, "bbox": [667.0, 138.0, 278.0, 39.0], "category_id": 2}, {"id": 5, "bbox": [261.0, 187.0, 446.4, 146.1], "category_id": 3}, {"id": 6, "bbox": [356.3, 29.6, 195.3, 161.0], "category_id": 1}, {"id": 7, "bbox": [1029.6, 23.9, 326.4, 172.1], "category_id": 1}, {"id": 8, "bbox": [68.0, 202.0, 66.8, 48.0], "category_id": 3}], "reactions": [{"reactants": [1, 6], "conditions": [3, 4], "products": [7]}], "corefs": [[1, 8], [6, 5], [7, 0]], "caption": "Table 4. Domino Reaction of 2-Hydroxyaryl-r,\u03b2-unsatu- rated Ketones 2, 2-Hydroxyarylimines 4, 2-Hydroxyarylni- troalkenes 3, and Salicylic Aldehydes 1 to 1,3-Dicarbonyl Compounds (8a and 8b)a ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 519, 758, 580], "ImageBB": [436, 589, 775, 883]}, "diagram_type": "single"}, {"id": 1066, "width": 1356, "height": 1384, "file_name": "jo300771f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1015.3, 1197.9, 147.87, 51.5], "category_id": 2}, {"id": 1, "bbox": [741.52, 15.23, 299.1, 277.63], "category_id": 1}, {"id": 2, "bbox": [9.0, 693.73, 301.18, 273.48], "category_id": 1}, {"id": 3, "bbox": [401.57, 0.0, 294.95, 144.7], "category_id": 2}, {"id": 4, "bbox": [437.57, 1163.83, 221.56, 51.93], "category_id": 2}, {"id": 5, "bbox": [486.04, 168.93, 123.24, 96.93], "category_id": 2}, {"id": 6, "bbox": [824.6, 1293.3, 249.26, 53.31], "category_id": 3}, {"id": 7, "bbox": [123.24, 940.21, 72.01, 60.92], "category_id": 3}, {"id": 8, "bbox": [401.57, 1008.75, 301.18, 148.16], "category_id": 2}, {"id": 9, "bbox": [9.0, 16.62, 292.5, 268.48], "category_id": 1}, {"id": 10, "bbox": [744.29, 693.73, 335.41, 270.02], "category_id": 1}, {"id": 11, "bbox": [413.85, 400.4, 280.79, 98.02], "category_id": 2}, {"id": 12, "bbox": [1164.84, 1143.07, 61.47, 48.18], "category_id": 3}, {"id": 13, "bbox": [918.94, 1026.77, 149.53, 53.16], "category_id": 2}, {"id": 14, "bbox": [1021.95, 863.94, 149.53, 49.85], "category_id": 2}, {"id": 15, "bbox": [923.92, 692.81, 154.52, 49.85], "category_id": 2}, {"id": 16, "bbox": [893.15, 297.02, 75.47, 47.08], "category_id": 3}, {"id": 17, "bbox": [434.11, 830.12, 225.02, 51.93], "category_id": 2}, {"id": 18, "bbox": [796.91, 956.82, 274.87, 52.62], "category_id": 3}, {"id": 19, "bbox": [877.4, 631.34, 122.95, 41.54], "category_id": 3}, {"id": 20, "bbox": [741.52, 360.02, 295.28, 274.28], "category_id": 1}, {"id": 21, "bbox": [741.52, 1027.44, 298.18, 273.48], "category_id": 1}, {"id": 22, "bbox": [434.11, 500.57, 231.25, 54.0], "category_id": 2}, {"id": 23, "bbox": [399.49, 679.88, 301.18, 145.4], "category_id": 2}, {"id": 24, "bbox": [1015.3, 533.31, 151.2, 53.17], "category_id": 2}, {"id": 25, "bbox": [918.94, 367.17, 151.19, 49.84], "category_id": 2}, {"id": 26, "bbox": [1164.84, 127.92, 61.47, 49.84], "category_id": 3}, {"id": 27, "bbox": [280.94, 240.9, 154.51, 54.82], "category_id": 2}, {"id": 28, "bbox": [102.47, 294.94, 116.32, 55.39], "category_id": 3}], "caption": "Scheme 4. Isotopic Labeling Experiments", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 313, 683, 328], "ImageBB": [448, 335, 787, 681]}, "reactions": [{"reactants": [9], "conditions": [3, 5], "products": [1, 26]}, {"reactants": [2], "conditions": [11, 22], "products": [20]}, {"reactants": [2], "conditions": [23, 17], "products": [10]}, {"reactants": [2], "conditions": [8, 4], "products": [21, 12]}], "diagram_type": "tree"}, {"id": 517, "width": 2808, "height": 1160, "file_name": "jo0157425-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [493.0, 407.0, 140.0, 62.0], "category_id": 3}, {"id": 1, "bbox": [117.0, 511.0, 2598.0, 649.0], "category_id": 4}, {"id": 2, "bbox": [1319.0, 446.0, 67.0, 65.0], "category_id": 3}, {"id": 3, "bbox": [1744.0, 448.0, 96.0, 60.0], "category_id": 3}, {"id": 4, "bbox": [2193.0, 446.0, 91.0, 73.0], "category_id": 3}, {"id": 5, "bbox": [387.0, 57.0, 376.0, 308.0], "category_id": 1}, {"id": 6, "bbox": [1147.0, 83.0, 379.0, 295.0], "category_id": 1}, {"id": 7, "bbox": [1591.0, 77.0, 387.0, 312.0], "category_id": 1}, {"id": 8, "bbox": [2040.0, 103.0, 392.0, 307.0], "category_id": 1}, {"id": 9, "bbox": [1029.25, 142.8, 44.47, 52.94], "category_id": 3}, {"id": 10, "bbox": [914.9, 2.0, 117.7, 193.0], "category_id": 1}, {"id": 11, "bbox": [813.0, 282.0, 256.4, 153.4], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [10, 11], "products": [6, 7, 8]}], "corefs": [[5, 0], [10, 9], [6, 2], [7, 3], [8, 4]], "caption": "Table 1. Reaction of Enolates of Mandelic Acid Acetal 7 with 2-Cyclopenten-1-one (5)", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [175, 64, 674, 76], "ImageBB": [74, 87, 776, 377]}, "diagram_type": "single"}, {"id": 889, "width": 1356, "height": 616, "file_name": "acs.oprd.5b00148-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [953.2, 40.1, 297.4, 205.5], "category_id": 1}, {"id": 1, "bbox": [425.0, 55.1, 508.0, 94.5], "category_id": 2}, {"id": 2, "bbox": [102.2, 48.2, 301.6, 209.96], "category_id": 1}, {"id": 3, "bbox": [261.0, 333.0, 877.0, 257.0], "category_id": 4}, {"id": 4, "bbox": [438.67, 176.57, 440.75, 109.42], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [1, 4], "products": [0]}], "corefs": [], "caption": "Figure 2. Stereospeci\ufb01c cross-coupling reactions of benzylic ethers and esters. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 785, 784, 813], "ImageBB": [448, 622, 787, 776]}, "diagram_type": "single"}, {"id": 628, "width": 1332, "height": 1824, "file_name": "ol501422k-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [53.1, 716.7, 349.9, 137.3], "category_id": 1}, {"id": 1, "bbox": [438.0, 1010.0, 419.0, 144.0], "category_id": 1}, {"id": 2, "bbox": [414.0, 705.0, 443.0, 153.0], "category_id": 1}, {"id": 3, "bbox": [160.0, 289.0, 917.0, 389.0], "category_id": 4}, {"id": 4, "bbox": [914.0, 194.0, 196.0, 46.0], "category_id": 2}, {"id": 5, "bbox": [1140.0, 191.0, 110.0, 75.0], "category_id": 3}, {"id": 6, "bbox": [150.0, 202.0, 97.0, 76.0], "category_id": 3}, {"id": 7, "bbox": [558.0, 1766.0, 49.0, 43.0], "category_id": 3}, {"id": 8, "bbox": [1026.0, 1774.0, 44.0, 42.0], "category_id": 3}, {"id": 9, "bbox": [982.0, 1603.0, 347.0, 146.0], "category_id": 1}, {"id": 10, "bbox": [494.0, 1607.0, 356.0, 183.0], "category_id": 1}, {"id": 11, "bbox": [105.0, 882.0, 139.5, 44.2], "category_id": 3}, {"id": 12, "bbox": [551.0, 1491.0, 138.2, 41.0], "category_id": 3}, {"id": 13, "bbox": [54.0, 1597.0, 353.0, 141.0], "category_id": 1}, {"id": 14, "bbox": [1042.0, 1487.0, 121.8, 43.2], "category_id": 3}, {"id": 15, "bbox": [106.0, 1170.0, 137.0, 41.8], "category_id": 3}, {"id": 16, "bbox": [551.0, 1175.0, 137.2, 42.0], "category_id": 3}, {"id": 17, "bbox": [1042.0, 1175.0, 128.2, 42.4], "category_id": 3}, {"id": 18, "bbox": [44.0, 7.0, 331.3, 149.0], "category_id": 1}, {"id": 19, "bbox": [102.0, 1489.0, 143.4, 35.4], "category_id": 3}, {"id": 20, "bbox": [894.0, 1318.0, 438.0, 144.0], "category_id": 1}, {"id": 21, "bbox": [434.0, 1321.0, 423.0, 141.0], "category_id": 1}, {"id": 22, "bbox": [555.0, 890.0, 135.0, 41.4], "category_id": 3}, {"id": 23, "bbox": [109.0, 1773.0, 35.0, 46.0], "category_id": 3}, {"id": 24, "bbox": [419.74, 13.11, 135.01, 121.77], "category_id": 1}, {"id": 25, "bbox": [908.0, 4.0, 359.0, 149.0], "category_id": 1}, {"id": 26, "bbox": [569.0, 92.0, 308.0, 50.0], "category_id": 2}, {"id": 27, "bbox": [10.0, 1318.0, 397.0, 142.0], "category_id": 1}, {"id": 28, "bbox": [914.0, 1006.0, 417.0, 146.0], "category_id": 1}, {"id": 29, "bbox": [573.0, 7.0, 291.8, 38.0], "category_id": 2}, {"id": 30, "bbox": [3.0, 1011.0, 401.0, 141.0], "category_id": 1}], "reactions": [{"reactants": [18, 24], "conditions": [29, 26], "products": [25]}], "corefs": [[18, 6], [25, 5], [0, 11], [2, 22], [30, 15], [1, 16], [28, 17], [27, 19], [21, 12], [20, 14], [13, 23], [10, 7], [9, 8]], "caption": "Table 4. Nucleophilc Addition of Alkylazaarenes to tert-Butyl Nitritea ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 424, 417, 458], "ImageBB": [84, 464, 417, 920]}, "diagram_type": "single"}, {"id": 454, "width": 2808, "height": 416, "file_name": "op2001047-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1092.0, 226.0, 115.1, 56.5], "category_id": 2}, {"id": 1, "bbox": [1275.0, 27.0, 361.0, 106.1], "category_id": 2}, {"id": 2, "bbox": [723.0, 55.0, 283.0, 174.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 321.0, 2799.0, 95.0], "category_id": 4}, {"id": 4, "bbox": [1911.0, 221.0, 73.0, 58.0], "category_id": 3}, {"id": 5, "bbox": [874.0, 229.0, 73.0, 45.0], "category_id": 3}, {"id": 6, "bbox": [1364.0, 159.0, 191.0, 56.0], "category_id": 2}, {"id": 7, "bbox": [1659.0, 5.0, 428.0, 210.0], "category_id": 1}, {"id": 8, "bbox": [1064.0, 72.0, 171.0, 126.0], "category_id": 1}], "reactions": [{"reactants": [2, 8], "conditions": [1, 6], "products": [7]}], "corefs": [[2, 5], [8, 0], [7, 4]], "caption": "Table 1. Optimization of the Mizoroki Heck reaction of 4-iodoanisole (3b) and methyl vinyl ketone (MVK) under microwave batch and continuous \ufb02ow conditionsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 770, 123], "ImageBB": [71, 133, 773, 237]}, "diagram_type": "single"}, {"id": 325, "width": 1348, "height": 3692, "file_name": "ol301535j-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [588.0, 69.0, 136.0, 53.0], "category_id": 2}, {"id": 1, "bbox": [808.0, 254.0, 87.0, 42.0], "category_id": 3}, {"id": 2, "bbox": [436.0, 258.0, 34.0, 38.0], "category_id": 3}, {"id": 3, "bbox": [9.0, 3226.0, 1339.0, 466.0], "category_id": 2}, {"id": 4, "bbox": [585.0, 133.0, 132.0, 94.0], "category_id": 2}, {"id": 5, "bbox": [371.1, 18.0, 204.7, 210.2], "category_id": 1}, {"id": 6, "bbox": [755.8, 4.3, 227.7, 249.6], "category_id": 1}, {"id": 7, "bbox": [2.0, 348.5, 1346.0, 2850.5], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [0, 4], "products": [6]}], "corefs": [[5, 2], [6, 1]], "caption": "Table 2. Tandem Reactions Initiated by an R2-NH2 Intermo- lecular Aza-Michael Addition Followed by an 8-endo-tet In- tramolecular Ring-Opening of an Epoxide ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 763, 129], "ImageBB": [436, 139, 773, 1062]}, "diagram_type": "single"}, {"id": 610, "width": 1352, "height": 936, "file_name": "acs.oprd.5b00331-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1042.0, 54.0, 310.0, 483.0], "category_id": 1}, {"id": 1, "bbox": [31.0, 141.0, 259.0, 203.0], "category_id": 1}, {"id": 2, "bbox": [552.0, 801.0, 48.0, 42.0], "category_id": 3}, {"id": 3, "bbox": [998.0, 801.0, 47.0, 41.0], "category_id": 3}, {"id": 4, "bbox": [1280.0, 436.0, 49.0, 42.0], "category_id": 3}, {"id": 5, "bbox": [752.0, 435.0, 48.0, 43.0], "category_id": 3}, {"id": 6, "bbox": [149.0, 372.0, 47.0, 43.0], "category_id": 3}, {"id": 7, "bbox": [301.0, 597.0, 366.0, 311.0], "category_id": 1}, {"id": 8, "bbox": [718.0, 573.0, 353.0, 363.0], "category_id": 1}, {"id": 9, "bbox": [510.0, 86.0, 305.0, 426.0], "category_id": 1}], "reactions": [{"reactants": [1], "conditions": [], "products": [9]}, {"reactants": [9], "conditions": [], "products": [0]}], "corefs": [[1, 6], [9, 5], [0, 4], [7, 2], [8, 3]], "caption": "Figure 1. Target compounds selected as building block in the synthesis of BCPs modulator focused libraries. ", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 848, 417, 876], "ImageBB": [82, 604, 420, 838]}, "diagram_type": "single"}, {"id": 573, "width": 1348, "height": 1140, "file_name": "acs.orglett.5b00776-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [754.6, 0.0, 535.4, 395.0], "category_id": 1}, {"id": 1, "bbox": [301.0, 324.9, 290.0, 310.1], "category_id": 1}, {"id": 2, "bbox": [44.0, 312.9, 270.0, 311.1], "category_id": 1}, {"id": 3, "bbox": [1120.0, 336.0, 73.0, 55.0], "category_id": 3}, {"id": 4, "bbox": [718.0, 523.0, 587.0, 326.0], "category_id": 1}, {"id": 5, "bbox": [6.0, 963.0, 1340.0, 176.0], "category_id": 4}, {"id": 6, "bbox": [814.0, 408.0, 474.0, 67.0], "category_id": 2}, {"id": 7, "bbox": [579.0, 405.0, 195.0, 68.0], "category_id": 2}, {"id": 8, "bbox": [808.0, 874.0, 482.0, 64.0], "category_id": 2}, {"id": 9, "bbox": [1122.0, 820.0, 71.0, 59.0], "category_id": 3}, {"id": 10, "bbox": [202.0, 635.0, 69.0, 56.0], "category_id": 3}, {"id": 11, "bbox": [438.0, 639.0, 73.0, 52.0], "category_id": 3}], "reactions": [{"reactants": [2, 1], "conditions": [7], "products": [0, 4]}], "corefs": [[2, 10], [1, 11], [0, 3], [4, 9]], "caption": "Table 1. C versus N Selectivity in Reaction of AH 1a with DD 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 152, 410, 186], "ImageBB": [82, 193, 419, 478]}, "diagram_type": "single"}, {"id": 1064, "width": 2820, "height": 1056, "file_name": "jo202324f-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [698.3, 773.32, 129.78, 60.68], "category_id": 2}, {"id": 1, "bbox": [640.46, 0.0, 939.53, 50.8], "category_id": 2}, {"id": 2, "bbox": [1419.17, 845.29, 200.32, 57.86], "category_id": 2}, {"id": 3, "bbox": [1365.56, 52.21, 242.64, 255.43], "category_id": 1}, {"id": 4, "bbox": [1400.83, 769.09, 265.21, 64.91], "category_id": 2}, {"id": 5, "bbox": [1668.86, 397.95, 475.41, 272.36], "category_id": 1}, {"id": 6, "bbox": [640.46, 344.33, 674.32, 59.27], "category_id": 2}, {"id": 7, "bbox": [1400.83, 543.3, 207.37, 49.39], "category_id": 2}, {"id": 8, "bbox": [640.46, 848.12, 249.7, 52.21], "category_id": 2}, {"id": 9, "bbox": [905.67, 424.76, 466.95, 221.56], "category_id": 1}, {"id": 10, "bbox": [1904.45, 46.57, 272.27, 245.54], "category_id": 1}, {"id": 11, "bbox": [640.46, 128.42, 217.25, 141.11], "category_id": 1}, {"id": 12, "bbox": [1129.97, 206.03, 193.27, 43.75], "category_id": 2}, {"id": 13, "bbox": [1162.42, 132.65, 128.38, 59.27], "category_id": 2}, {"id": 14, "bbox": [914.14, 681.6, 521.96, 306.22], "category_id": 1}, {"id": 15, "bbox": [868.99, 142.53, 251.11, 135.47], "category_id": 1}, {"id": 16, "bbox": [1668.86, 683.01, 476.82, 330.21], "category_id": 1}, {"id": 17, "bbox": [1623.72, 136.88, 276.5, 55.04], "category_id": 2}, {"id": 18, "bbox": [640.46, 500.97, 217.25, 139.7], "category_id": 1}, {"id": 19, "bbox": [1427.63, 465.69, 176.34, 66.32], "category_id": 2}], "caption": "Scheme 1. Our Previous Works on the Cascade Reactions of Stable Sulfur Ylides with Nitroolefins", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 638, 110], "ImageBB": [82, 116, 787, 380]}, "reactions": [{"reactants": [11, 15], "conditions": [13, 12], "products": [3]}, {"reactants": [3], "conditions": [17], "products": [10]}, {"reactants": [18, 9], "conditions": [19, 7], "products": [5]}, {"reactants": [5], "conditions": [0, 8], "products": [14]}, {"reactants": [14], "conditions": [4, 2], "products": [16]}], "diagram_type": "multiple"}, {"id": 1031, "width": 1176, "height": 944, "file_name": "jo0014156-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1048.93, 895.41, 40.59, 45.88], "category_id": 3}, {"id": 1, "bbox": [1005.98, 334.16, 58.24, 50.59], "category_id": 3}, {"id": 2, "bbox": [0.0, 1173.68, 1176.0, -229.68], "category_id": 2}, {"id": 3, "bbox": [0.0, 0.0, 377.68, 357.69], "category_id": 1}, {"id": 4, "bbox": [0.0, 737.74, 234.73, 181.79], "category_id": 1}, {"id": 5, "bbox": [278.85, 317.1, 43.54, 53.53], "category_id": 3}, {"id": 6, "bbox": [758.9, 617.72, 413.57, 289.45], "category_id": 1}, {"id": 7, "bbox": [720.66, 0.0, 415.34, 353.57], "category_id": 1}, {"id": 8, "bbox": [157.66, 525.95, 400.04, 212.97], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [207, 64, 270, 78], "ImageBB": [96, 83, 390, 319]}, "reactions": [{"reactants": [3], "conditions": [], "products": [7]}, {"reactants": [7], "conditions": [], "products": [6]}, {"reactants": [6], "conditions": [], "products": [8, 4]}], "diagram_type": "tree"}, {"id": 783, "width": 1348, "height": 1684, "file_name": "jo502752u-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2.0, 202.0, 1346.0, 1482.0], "category_id": 4}, {"id": 1, "bbox": [525.0, 78.0, 267.0, 65.0], "category_id": 2}, {"id": 2, "bbox": [605.0, 6.0, 104.0, 53.0], "category_id": 2}, {"id": 3, "bbox": [228.0, 137.0, 39.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [891.0, 1.0, 293.0, 141.0], "category_id": 1}, {"id": 5, "bbox": [168.0, 3.0, 277.0, 135.0], "category_id": 1}, {"id": 6, "bbox": [944.0, 133.0, 42.0, 41.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [2, 1], "products": [4]}], "corefs": [[5, 3], [4, 6]], "caption": "Table 1. Hydration of Benzonitrilea", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 89, 285, 110], "ImageBB": [82, 116, 419, 537]}, "diagram_type": "single"}, {"id": 136, "width": 1352, "height": 536, "file_name": "op8002097-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [643.0, 333.0, 238.0, 110.0], "category_id": 2}, {"id": 1, "bbox": [1.0, 481.0, 57.0, 55.0], "category_id": 3}, {"id": 2, "bbox": [1148.0, 79.0, 199.0, 406.0], "category_id": 1}, {"id": 3, "bbox": [682.0, 256.0, 145.0, 47.0], "category_id": 2}, {"id": 4, "bbox": [189.0, 256.0, 236.0, 59.0], "category_id": 2}, {"id": 5, "bbox": [430.0, 102.0, 200.0, 390.0], "category_id": 1}, {"id": 6, "bbox": [909.0, 91.0, 203.0, 390.0], "category_id": 1}, {"id": 7, "bbox": [9.0, 91.2, 201.0, 412.8], "category_id": 1}, {"id": 8, "bbox": [431.0, 494.0, 40.0, 40.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [4], "products": [5]}, {"reactants": [5], "conditions": [3, 0], "products": [6, 2]}], "corefs": [[7, 1], [5, 8]], "caption": "Table 2. Results of enzymatic screening for ester formation (organic media) ", "pdf": {"Page": 3, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 191, 386, 218], "ImageBB": [58, 45, 396, 179]}, "diagram_type": "single"}, {"id": 468, "width": 1356, "height": 464, "file_name": "op100267p-Figure-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1077.11, 307.98, 70.8, 53.8], "category_id": 3}, {"id": 1, "bbox": [138.96, 305.84, 46.6, 56.5], "category_id": 3}, {"id": 2, "bbox": [906.4, 0.0, 431.2, 270.7], "category_id": 1}, {"id": 3, "bbox": [2.0, 41.7, 366.8, 224.9], "category_id": 1}, {"id": 4, "bbox": [395.0, 25.0, 439.8, 115.8], "category_id": 2}, {"id": 5, "bbox": [394.7, 169.62, 503.13, 107.37], "category_id": 2}], "reactions": [{"reactants": [3], "conditions": [4, 5], "products": [2]}], "corefs": [[3, 1], [2, 0]], "caption": "Figure 1. Three-step telescoped synthesis of electron-de\ufb01cient amide- substituted arylboronic acids. ", "pdf": {"Page": 1, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [437, 453, 771, 481], "ImageBB": [436, 323, 775, 439]}, "diagram_type": "single"}, {"id": 1165, "width": 1352, "height": 1344, "file_name": "ol060868f-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1000.3, 824.53, 79.81, 60.87], "category_id": 3}, {"id": 1, "bbox": [372.3, 1162.72, 277.66, 61.58], "category_id": 3}, {"id": 2, "bbox": [154.83, 1177.75, 127.46, 109.72], "category_id": 2}, {"id": 3, "bbox": [372.65, 1235.84, 271.05, 54.86], "category_id": 3}, {"id": 4, "bbox": [710.16, 900.96, 284.06, 107.55], "category_id": 2}, {"id": 5, "bbox": [698.66, 570.88, 525.51, 242.82], "category_id": 1}, {"id": 6, "bbox": [424.74, 140.01, 117.01, 64.94], "category_id": 2}, {"id": 7, "bbox": [144.06, 79.81, 107.54, 71.7], "category_id": 3}, {"id": 8, "bbox": [131.21, 641.22, 516.05, 495.8], "category_id": 1}, {"id": 9, "bbox": [566.1, 362.55, 463.29, 118.37], "category_id": 2}, {"id": 10, "bbox": [1004.36, 260.41, 85.22, 60.2], "category_id": 3}, {"id": 11, "bbox": [802.81, 1031.5, 129.18, 77.11], "category_id": 2}, {"id": 12, "bbox": [300.97, 0.0, 368.6, 107.55], "category_id": 2}, {"id": 13, "bbox": [1069.97, 382.84, 109.56, 69.67], "category_id": 2}, {"id": 14, "bbox": [765.61, 2.71, 442.33, 247.56], "category_id": 1}], "caption": "Scheme 4. Synthesis of Nucleoside Analogues 17 and 18", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [453, 408, 760, 421], "ImageBB": [439, 426, 777, 762]}, "reactions": [{"reactants": [7], "conditions": [12, 6], "products": [14]}, {"reactants": [14], "conditions": [9, 13], "products": [5]}, {"reactants": [5], "conditions": [4, 11], "products": [8]}], "diagram_type": "tree"}, {"id": 1002, "width": 1284, "height": 404, "file_name": "ja806814c-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [644.89, 47.58, 138.74, 39.86], "category_id": 2}, {"id": 1, "bbox": [189.48, 48.22, 135.53, 39.22], "category_id": 2}, {"id": 2, "bbox": [1018.72, 3.86, 261.43, 153.02], "category_id": 1}, {"id": 3, "bbox": [836.3, 265.54, 143.24, 134.38], "category_id": 1}, {"id": 4, "bbox": [915.31, 161.38, 57.16, 41.8], "category_id": 2}, {"id": 5, "bbox": [0.0, 8.36, 168.93, 149.17], "category_id": 1}, {"id": 6, "bbox": [366.12, 12.22, 247.94, 163.95], "category_id": 1}, {"id": 7, "bbox": [414.94, 313.12, 181.13, 43.08], "category_id": 2}, {"id": 8, "bbox": [836.3, 17.36, 150.95, 107.37], "category_id": 1}], "caption": "Scheme 2. Proposed Mechanism of Methanol Formation", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 569, 340, 581], "ImageBB": [66, 593, 387, 694]}, "reactions": [{"reactants": [5], "conditions": [1], "products": [6]}, {"reactants": [6], "conditions": [0], "products": [8, 2]}, {"reactants": [8], "conditions": [4], "products": [3]}, {"reactants": [3], "conditions": [], "products": [7]}], "diagram_type": "tree"}, {"id": 1137, "width": 1204, "height": 388, "file_name": "ol0069002-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 116.73, 42.16, 49.34], "category_id": 3}, {"id": 1, "bbox": [656.51, 92.06, 36.74, 37.31], "category_id": 2}, {"id": 2, "bbox": [1015.48, 323.11, 115.64, 51.75], "category_id": 3}, {"id": 3, "bbox": [156.0, 5.42, 408.96, 359.21], "category_id": 1}, {"id": 4, "bbox": [770.34, 2.41, 433.66, 306.86], "category_id": 1}, {"id": 5, "bbox": [83.72, 92.06, 34.93, 38.51], "category_id": 2}, {"id": 6, "bbox": [548.09, 279.19, 239.21, 47.21], "category_id": 3}, {"id": 7, "bbox": [440.88, 294.23, 35.54, 47.54], "category_id": 2}, {"id": 8, "bbox": [548.41, 332.49, 276.94, 45.4], "category_id": 3}], "caption": "Scheme 3a", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [578, 494, 635, 508], "ImageBB": [457, 513, 758, 610]}, "reactions": [{"reactants": [0], "conditions": [5], "products": [3]}, {"reactants": [3], "conditions": [1], "products": [4]}], "diagram_type": "single"}, {"id": 1375, "width": 1340, "height": 708, "file_name": "op990050s-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [268.8, 437.25, 47.6, 50.29], "category_id": 3}, {"id": 1, "bbox": [177.64, 291.72, 237.3, 146.87], "category_id": 1}, {"id": 2, "bbox": [49.6, 438.59, 41.57, 52.98], "category_id": 3}, {"id": 3, "bbox": [546.99, 413.1, 310.37, 171.68], "category_id": 1}, {"id": 4, "bbox": [1023.6, 398.35, 316.4, 244.11], "category_id": 1}, {"id": 5, "bbox": [1093.99, 341.35, 42.23, 48.95], "category_id": 3}, {"id": 6, "bbox": [1008.18, 4.02, 225.24, 324.58], "category_id": 1}, {"id": 7, "bbox": [1082.59, 659.22, 46.25, 48.29], "category_id": 3}, {"id": 8, "bbox": [0.0, 313.85, 127.36, 118.03], "category_id": 1}, {"id": 9, "bbox": [551.69, 30.85, 207.13, 306.47], "category_id": 1}], "caption": "Scheme 1", "pdf": {"Page": 1, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 299, 501, 313], "ImageBB": [441, 319, 776, 496]}, "reactions": [{"reactants": [8, 1], "conditions": [], "products": [3, 9]}, {"reactants": [9], "conditions": [], "products": [6]}, {"reactants": [3], "conditions": [], "products": [4]}], "diagram_type": "tree"}, {"id": 476, "width": 2816, "height": 948, "file_name": "op100072y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [2038.63, 248.75, 68.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [664.88, 244.0, 57.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [1337.24, 0.75, 536.36, 216.35], "category_id": 1}, {"id": 3, "bbox": [1556.88, 244.75, 54.0, 50.0], "category_id": 3}, {"id": 4, "bbox": [1908.6, 3.0, 457.4, 214.3], "category_id": 1}, {"id": 5, "bbox": [454.1, 6.0, 525.9, 216.0], "category_id": 1}, {"id": 6, "bbox": [1009.0, 144.0, 287.0, 105.0], "category_id": 2}, {"id": 7, "bbox": [994.0, 50.0, 307.0, 75.0], "category_id": 2}, {"id": 8, "bbox": [11.0, 313.0, 2734.0, 635.0], "category_id": 4}], "reactions": [{"reactants": [5], "conditions": [7, 6], "products": [2, 4]}], "corefs": [[5, 1], [2, 3], [4, 0]], "caption": "Table 1. Hydrogenolysis vs dechlorination selectivity varying solvent or inorganic additives", "pdf": {"Page": 4, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 358, 558, 372], "ImageBB": [58, 372, 762, 609]}, "diagram_type": "single"}, {"id": 531, "width": 1344, "height": 1020, "file_name": "jo000745n-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [911.3, 25.0, 394.6, 206.1], "category_id": 1}, {"id": 1, "bbox": [664.3, 39.8, 192.3, 61.4], "category_id": 2}, {"id": 2, "bbox": [702.0, 136.0, 142.7, 60.0], "category_id": 2}, {"id": 3, "bbox": [139.7, 135.9, 87.3, 62.1], "category_id": 2}, {"id": 4, "bbox": [391.0, 195.0, 56.2, 45.1], "category_id": 3}, {"id": 5, "bbox": [1020.6, 235.0, 123.4, 46.6], "category_id": 3}, {"id": 6, "bbox": [309.0, 36.0, 314.8, 153.0], "category_id": 1}, {"id": 7, "bbox": [17.0, 289.0, 1327.0, 731.0], "category_id": 4}, {"id": 8, "bbox": [30.94, 93.27, 45.89, 53.29], "category_id": 3}, {"id": 9, "bbox": [94.0, 25.0, 175.0, 77.0], "category_id": 2}], "reactions": [{"reactants": [8], "conditions": [9, 3], "products": [6]}, {"reactants": [6], "conditions": [1, 2], "products": [0]}], "corefs": [[6, 4], [0, 5]], "caption": "Table 4. Preparation of Protected Thioureas 43-47 from         Diphenylethylenediamine 7 through the         Ethoxycarbonylated Ethylenediamine 42 ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 601, 409, 638], "ImageBB": [74, 640, 410, 895]}, "diagram_type": "single"}, {"id": 713, "width": 1352, "height": 396, "file_name": "ol034469l-Figure-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1033.0, 159.1, 190.0, 218.0], "category_id": 1}, {"id": 1, "bbox": [329.0, 210.9, 148.2, 48.1], "category_id": 2}, {"id": 2, "bbox": [133.0, 139.0, 185.0, 257.0], "category_id": 1}, {"id": 3, "bbox": [524.4, 200.1, 288.6, 136.4], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [1], "products": [3]}, {"reactants": [3], "conditions": [], "products": [0]}], "corefs": [], "caption": "Figure 2. Model for diastereoselectivity.", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 868, 654, 881], "ImageBB": [439, 757, 777, 856]}, "diagram_type": "single"}, {"id": 180, "width": 1288, "height": 1288, "file_name": "op0602270-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [411.0, 139.6, 465.1, 69.4], "category_id": 2}, {"id": 1, "bbox": [407.0, 17.4, 445.9, 73.6], "category_id": 2}, {"id": 2, "bbox": [75.0, 229.0, 217.8, 56.0], "category_id": 3}, {"id": 3, "bbox": [933.4, 7.0, 354.6, 217.1], "category_id": 1}, {"id": 4, "bbox": [3.0, 4.5, 348.7, 230.5], "category_id": 1}, {"id": 5, "bbox": [1079.0, 225.0, 70.0, 62.0], "category_id": 3}, {"id": 6, "bbox": [1.0, 315.0, 1287.0, 973.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [1, 0], "products": [3]}], "corefs": [[4, 2], [3, 5]], "caption": "Figure 4. Dependency of hydrogen consumption versus reac- tion time. Reactions were carried out under isobaric conditions (1.0 bar) at 25 \u00b0C. [Rh(cod)2]BF4 (0.0072 mmol) and 0.015 mmol ligand 6a were stirred for 10 min under hydrogen atmosphere in 10.0 mL of methanol. Afterwards the substrate (0.72 mmol) was added in 1.0 mL of methanol. The conversions and ee\u2019s were determined by GC (50 m Chiraldex \u03b2-PM, 130 \u00b0C, (S)-7a 15.1 min, (R)-7a 16.4 min). ", "pdf": {"Page": 6, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 378, 409, 489], "ImageBB": [81, 53, 403, 375]}, "diagram_type": "single"}, {"id": 1257, "width": 1356, "height": 1592, "file_name": "op050061n-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.23, 1412.01, 50.19, 41.42], "category_id": 3}, {"id": 1, "bbox": [348.94, 1109.38, 326.64, 326.53], "category_id": 1}, {"id": 2, "bbox": [90.82, 684.11, 235.02, 268.38], "category_id": 1}, {"id": 3, "bbox": [0.0, 1513.16, 562.45, 78.84], "category_id": 2}, {"id": 4, "bbox": [0.0, 1105.4, 296.36, 328.12], "category_id": 1}, {"id": 5, "bbox": [86.04, 425.28, 319.47, 160.87], "category_id": 1}, {"id": 6, "bbox": [169.69, 972.4, 41.43, 43.01], "category_id": 3}, {"id": 7, "bbox": [1238.83, 1414.4, 51.78, 39.03], "category_id": 3}, {"id": 8, "bbox": [219.09, 602.87, 38.24, 40.62], "category_id": 3}, {"id": 9, "bbox": [1131.28, 1112.57, 224.72, 285.11], "category_id": 1}, {"id": 10, "bbox": [1155.18, 425.28, 31.07, 36.63], "category_id": 3}, {"id": 11, "bbox": [172.88, 1412.81, 50.99, 40.62], "category_id": 3}, {"id": 12, "bbox": [696.29, 1052.04, 301.94, 384.66], "category_id": 1}, {"id": 13, "bbox": [839.7, 3.19, 489.15, 453.94], "category_id": 1}, {"id": 14, "bbox": [872.36, 1412.81, 48.6, 40.62], "category_id": 3}, {"id": 15, "bbox": [579.18, 595.71, 461.28, 269.18], "category_id": 1}, {"id": 16, "bbox": [751.26, 860.91, 50.2, 41.41], "category_id": 3}], "caption": "Scheme 2. New synthesis route for 1", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 285, 67], "ImageBB": [73, 71, 412, 469]}, "reactions": [{"reactants": [13], "conditions": [], "products": [15, 9]}, {"reactants": [15], "conditions": [], "products": [5, 2]}, {"reactants": [9], "conditions": [], "products": [12]}, {"reactants": [12], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [4]}], "diagram_type": "tree"}, {"id": 1279, "width": 1352, "height": 968, "file_name": "op100197g-Scheme-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [669.57, 39.92, 275.27, 258.47], "category_id": 1}, {"id": 1, "bbox": [514.02, 901.93, 59.51, 66.07], "category_id": 3}, {"id": 2, "bbox": [802.14, 426.27, 54.1, 61.57], "category_id": 3}, {"id": 3, "bbox": [426.77, 828.18, 207.64, 56.84], "category_id": 2}, {"id": 4, "bbox": [59.52, 299.74, 159.61, 48.04], "category_id": 2}, {"id": 5, "bbox": [980.01, 42.63, 115.66, 87.28], "category_id": 2}, {"id": 6, "bbox": [0.0, 359.28, 406.48, 63.61], "category_id": 2}, {"id": 7, "bbox": [144.06, 420.86, 58.84, 62.92], "category_id": 3}, {"id": 8, "bbox": [1000.3, 527.09, 351.7, 288.24], "category_id": 1}, {"id": 9, "bbox": [1130.84, 901.93, 50.72, 64.96], "category_id": 3}, {"id": 10, "bbox": [363.19, 527.09, 305.03, 286.88], "category_id": 1}, {"id": 11, "bbox": [0.0, 2.71, 305.03, 284.85], "category_id": 1}, {"id": 12, "bbox": [363.19, 45.33, 230.63, 111.65], "category_id": 2}], "caption": "Scheme 2", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [58, 65, 396, 307]}, "reactions": [{"reactants": [11], "conditions": [12], "products": [0]}, {"reactants": [0], "conditions": [5], "products": [10]}, {"reactants": [10], "conditions": [], "products": [8]}], "diagram_type": "multiple"}, {"id": 109, "width": 1344, "height": 632, "file_name": "ja001164i-Table-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [520.4, 31.49, 202.84, 41.56], "category_id": 2}, {"id": 1, "bbox": [3.15, 274.1, 1337.42, 357.9], "category_id": 4}, {"id": 2, "bbox": [1136.1, 203.92, 22.29, 32.43], "category_id": 3}, {"id": 3, "bbox": [175.52, 202.91, 23.28, 33.45], "category_id": 3}, {"id": 4, "bbox": [1026.55, 6.13, 220.09, 173.42], "category_id": 1}, {"id": 5, "bbox": [97.42, 5.11, 300.22, 173.43], "category_id": 1}, {"id": 6, "bbox": [826.73, 33.52, 134.88, 35.47], "category_id": 2}, {"id": 7, "bbox": [480.84, 111.62, 267.76, 74.02], "category_id": 2}], "reactions": [{"reactants": [5], "conditions": [0, 7, 6], "products": [4]}], "corefs": [[5, 3], [4, 2]], "caption": "Table 4. Enantioselective Protonation of 5f-i by (R)-1\u201aSnCl4a", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 64, 385, 78], "ImageBB": [74, 86, 410, 244]}, "diagram_type": "single"}, {"id": 1251, "width": 1176, "height": 1368, "file_name": "op049899l-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [258.66, 483.15, 223.76, 293.58], "category_id": 1}, {"id": 1, "bbox": [325.72, 792.47, 60.9, 45.16], "category_id": 3}, {"id": 2, "bbox": [559.06, 411.29, 184.08, 89.65], "category_id": 2}, {"id": 3, "bbox": [509.8, 1148.33, 277.82, 137.55], "category_id": 2}, {"id": 4, "bbox": [492.0, 1025.14, 318.88, 93.08], "category_id": 2}, {"id": 5, "bbox": [363.36, 231.99, 121.12, 86.91], "category_id": 2}, {"id": 6, "bbox": [323.67, 80.75, 195.71, 93.07], "category_id": 2}, {"id": 7, "bbox": [815.67, 1003.25, 360.33, 276.47], "category_id": 1}, {"id": 8, "bbox": [907.37, 303.85, 154.65, 45.85], "category_id": 2}, {"id": 9, "bbox": [957.51, 881.97, 105.11, 44.34], "category_id": 2}, {"id": 10, "bbox": [842.36, 427.71, 273.03, 355.86], "category_id": 1}, {"id": 11, "bbox": [281.24, 1296.14, 54.06, 40.38], "category_id": 3}, {"id": 12, "bbox": [210.08, 984.77, 226.5, 306.58], "category_id": 1}, {"id": 13, "bbox": [4.11, 15.06, 270.29, 271.68], "category_id": 1}, {"id": 14, "bbox": [84.17, 315.48, 30.79, 38.32], "category_id": 3}, {"id": 15, "bbox": [942.95, 789.73, 49.27, 44.48], "category_id": 3}, {"id": 16, "bbox": [963.48, 963.55, 92.38, 50.65], "category_id": 2}, {"id": 17, "bbox": [911.7, 1322.15, 51.1, 41.74], "category_id": 3}, {"id": 18, "bbox": [669.92, 299.74, 30.79, 39.01], "category_id": 3}, {"id": 19, "bbox": [575.49, 6.84, 268.92, 270.32], "category_id": 1}, {"id": 20, "bbox": [884.1, 144.4, 192.29, 125.23], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 375, 501, 389], "ImageBB": [461, 393, 755, 735]}, "reactions": [{"reactants": [13], "conditions": [6, 5], "products": [19]}, {"reactants": [19], "conditions": [2], "products": [0]}, {"reactants": [19, 20], "conditions": [8], "products": [10]}, {"reactants": [10], "conditions": [9, 16], "products": [7]}, {"reactants": [7], "conditions": [4, 3], "products": [12]}], "diagram_type": "tree"}, {"id": 769, "width": 1348, "height": 1156, "file_name": "jo9602433-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [963.0, 700.0, 60.0, 65.0], "category_id": 3}, {"id": 1, "bbox": [224.0, 84.0, 136.0, 121.4], "category_id": 2}, {"id": 2, "bbox": [326.0, 702.0, 36.0, 46.0], "category_id": 3}, {"id": 3, "bbox": [234.0, 0.0, 133.0, 48.0], "category_id": 2}, {"id": 4, "bbox": [0.0, 29.0, 127.0, 89.0], "category_id": 2}, {"id": 5, "bbox": [1090.83, 517.63, 255.68, 105.37], "category_id": 2}, {"id": 6, "bbox": [435.35, 623.0, 192.15, 61.99], "category_id": 2}, {"id": 7, "bbox": [15.41, 299.14, 257.23, 106.92], "category_id": 2}, {"id": 8, "bbox": [6.8, 777.5, 1335.0, 376.5], "category_id": 4}, {"id": 9, "bbox": [630.9, 261.8, 664.4, 415.8], "category_id": 1}, {"id": 10, "bbox": [16.0, 192.2, 550.3, 507.0], "category_id": 1}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [10, 9]}], "corefs": [[10, 2], [9, 0]], "caption": "Table 3. Treatment of (E)-4 with BTMBr3 or Br2", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [89, 261, 372, 274], "ImageBB": [63, 280, 400, 569]}, "diagram_type": "multiple"}, {"id": 5, "width": 1356, "height": 464, "file_name": "jacs.5b11315-Figure-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [293.25, 44.31, 101.58, 122.36], "category_id": 2}, {"id": 1, "bbox": [79.38, 47.68, 156.99, 143.22], "category_id": 1}, {"id": 2, "bbox": [476.82, 43.44, 292.08, 289.39], "category_id": 1}, {"id": 3, "bbox": [966.06, 55.56, 351.82, 262.64], "category_id": 1}, {"id": 4, "bbox": [314.9, 193.24, 62.61, 37.5], "category_id": 2}, {"id": 5, "bbox": [808.46, 55.56, 100.72, 119.68], "category_id": 2}, {"id": 6, "bbox": [817.12, 194.11, 84.26, 46.07], "category_id": 2}, {"id": 7, "bbox": [354.73, 395.86, 511.15, 43.48], "category_id": 2}, {"id": 8, "bbox": [1205.05, 417.51, 115.43, 38.28], "category_id": 4}, {"id": 9, "bbox": [81.11, 274.64, 171.71, 47.02], "category_id": 2}, {"id": 10, "bbox": [32.62, 106.65, 28.88, 35.69], "category_id": 3}, {"id": 11, "bbox": [732.27, 320.53, 32.3, 37.5], "category_id": 3}, {"id": 12, "bbox": [1276.92, 314.38, 32.3, 40.19], "category_id": 3}, {"id": 13, "bbox": [439.59, 158.61, 53.95, 50.49], "category_id": 2}], "reactions": [{"reactants": [1, 9], "conditions": [0, 4], "products": [2]}, {"reactants": [2], "conditions": [5, 6], "products": [3]}, {"reactants": [1, 9], "conditions": [7], "products": [3]}], "corefs": [[2, 11], [3, 12]], "caption": "Figure 4. Syntheses of 5 and 6.", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 714, 600, 728], "ImageBB": [448, 589, 787, 705]}, "diagram_type": "graph"}, {"id": 1335, "width": 1356, "height": 1124, "file_name": "op4003467-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [346.63, 274.71, 68.51, 57.66], "category_id": 3}, {"id": 1, "bbox": [986.98, 274.71, 63.09, 55.62], "category_id": 3}, {"id": 2, "bbox": [798.41, 16.28, 318.81, 284.88], "category_id": 1}, {"id": 3, "bbox": [322.89, 760.37, 181.12, 190.61], "category_id": 2}, {"id": 4, "bbox": [944.93, 699.33, 68.51, 51.55], "category_id": 3}, {"id": 5, "bbox": [219.1, 71.22, 316.11, 170.93], "category_id": 1}, {"id": 6, "bbox": [563.7, 80.04, 147.88, 67.15], "category_id": 2}, {"id": 7, "bbox": [799.08, 390.7, 324.25, 316.09], "category_id": 1}, {"id": 8, "bbox": [564.38, 651.17, 67.83, 54.26], "category_id": 3}, {"id": 9, "bbox": [492.47, 1028.98, 55.63, 52.23], "category_id": 3}, {"id": 10, "bbox": [551.49, 876.36, 137.02, 63.76], "category_id": 2}, {"id": 11, "bbox": [374.44, 392.74, 306.61, 272.67], "category_id": 1}, {"id": 12, "bbox": [558.95, 189.25, 172.3, 93.6], "category_id": 1}, {"id": 13, "bbox": [217.75, 646.42, 202.14, 65.12], "category_id": 2}, {"id": 14, "bbox": [234.71, 462.6, 118.7, 52.91], "category_id": 2}, {"id": 15, "bbox": [234.71, 560.95, 139.73, 61.05], "category_id": 2}], "caption": "Scheme 3. 3,3-Dimethyl-2,3-dihydro-4-hydroxybenzofuran", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 515, 773, 530], "ImageBB": [448, 537, 787, 818]}, "reactions": [{"reactants": [5, 12], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [14, 15, 13], "products": [11, 7]}, {"reactants": [11], "conditions": [3, 10], "products": [9]}], "diagram_type": "tree"}, {"id": 672, "width": 1356, "height": 2528, "file_name": "ol401812h-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [518.0, 98.0, 331.0, 147.5], "category_id": 2}, {"id": 1, "bbox": [998.0, 200.0, 33.0, 40.0], "category_id": 3}, {"id": 2, "bbox": [925.0, 4.0, 181.0, 137.0], "category_id": 1}, {"id": 3, "bbox": [3.0, 294.0, 1351.0, 2061.0], "category_id": 4}, {"id": 4, "bbox": [514.0, 1.0, 323.0, 80.0], "category_id": 2}, {"id": 5, "bbox": [246.6, 1.0, 178.4, 103.5], "category_id": 1}, {"id": 6, "bbox": [286.0, 202.0, 131.0, 46.0], "category_id": 2}, {"id": 7, "bbox": [257.0, 200.0, 31.0, 44.0], "category_id": 3}], "reactions": [{"reactants": [5], "conditions": [4, 0], "products": [2]}], "corefs": [[5, 7], [2, 1]], "caption": "Table 2. Substrate Scope of Epoxidation", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 87, 653, 100], "ImageBB": [436, 112, 775, 744]}, "diagram_type": "single"}, {"id": 1011, "width": 960, "height": 972, "file_name": "ja980022+-Scheme-c12.png", "license": 0, "bboxes": [{"id": 0, "bbox": [756.82, 739.09, 69.02, 50.57], "category_id": 3}, {"id": 1, "bbox": [291.16, 237.77, 49.09, 54.46], "category_id": 3}, {"id": 2, "bbox": [113.74, 425.46, 347.54, 297.1], "category_id": 1}, {"id": 3, "bbox": [787.44, 241.66, 51.04, 52.03], "category_id": 3}, {"id": 4, "bbox": [0.0, 194.98, 44.23, 49.6], "category_id": 3}, {"id": 5, "bbox": [150.68, 0.0, 331.99, 293.69], "category_id": 1}, {"id": 6, "bbox": [582.32, 441.51, 376.22, 307.3], "category_id": 1}, {"id": 7, "bbox": [361.15, 726.45, 63.68, 48.62], "category_id": 3}, {"id": 8, "bbox": [34.03, 796.47, 493.85, 175.53], "category_id": 1}, {"id": 9, "bbox": [0.0, 92.39, 44.23, 52.51], "category_id": 3}, {"id": 10, "bbox": [583.78, 0.0, 374.76, 296.12], "category_id": 1}], "caption": "Scheme 12", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [440, 277, 503, 291], "ImageBB": [488, 296, 728, 539]}, "reactions": [{"reactants": [9, 4], "conditions": [], "products": [5]}, {"reactants": [5], "conditions": [], "products": [10]}, {"reactants": [5], "conditions": [], "products": [2]}, {"reactants": [2], "conditions": [], "products": [6]}, {"reactants": [10], "conditions": [], "products": [6]}], "diagram_type": "graph"}, {"id": 250, "width": 1228, "height": 1876, "file_name": "ol802669r-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [847.0, 213.5, 334.1, 182.8], "category_id": 1}, {"id": 1, "bbox": [998.0, 144.0, 44.0, 46.0], "category_id": 3}, {"id": 2, "bbox": [980.0, 392.0, 47.0, 40.0], "category_id": 3}, {"id": 3, "bbox": [140.0, 310.0, 34.0, 44.0], "category_id": 3}, {"id": 4, "bbox": [0.0, 482.1, 1228.0, 1393.9], "category_id": 4}, {"id": 5, "bbox": [848.47, 0.0, 374.7, 149.0], "category_id": 1}, {"id": 6, "bbox": [391.0, 85.0, 385.0, 111.0], "category_id": 2}, {"id": 7, "bbox": [393.0, 203.0, 325.0, 98.9], "category_id": 2}, {"id": 8, "bbox": [2.8, 104.8, 345.2, 206.2], "category_id": 1}], "reactions": [{"reactants": [8], "conditions": [6, 7], "products": [5, 0]}], "corefs": [[8, 3], [5, 1], [0, 2]], "caption": "Table 2. Synthesis of Substituted 3,4-Dihydro-2(1H)- quinolinonesa ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 73, 700, 102], "ImageBB": [440, 111, 747, 580]}, "diagram_type": "single"}, {"id": 1188, "width": 1704, "height": 652, "file_name": "ol5000692-Scheme-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [302.61, 79.28, 167.08, 43.48], "category_id": 1}, {"id": 1, "bbox": [289.82, 156.86, 169.64, 58.82], "category_id": 2}, {"id": 2, "bbox": [1023.76, 7.67, 243.8, 292.41], "category_id": 1}, {"id": 3, "bbox": [588.17, 34.1, 274.49, 235.29], "category_id": 1}, {"id": 4, "bbox": [1278.64, 105.71, 80.13, 41.77], "category_id": 2}, {"id": 5, "bbox": [1379.23, 23.02, 245.49, 261.72], "category_id": 1}, {"id": 6, "bbox": [883.97, 92.92, 111.66, 52.01], "category_id": 2}], "caption": "Scheme 1. Formation of Iridium Amino-carbenes", "pdf": {"Page": 1, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 943, 360, 958], "ImageBB": [10, 964, 436, 1127]}, "reactions": [{"reactants": [0, 1], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [5]}], "diagram_type": "single"}, {"id": 507, "width": 1348, "height": 992, "file_name": "ol051901l-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1119.0, 265.0, 41.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [149.0, 263.0, 68.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [699.0, 43.0, 200.0, 88.0], "category_id": 2}, {"id": 3, "bbox": [32.0, 22.0, 340.0, 250.0], "category_id": 1}, {"id": 4, "bbox": [475.88, 170.16, 203.45, 59.84], "category_id": 3}, {"id": 5, "bbox": [17.0, 359.0, 1327.0, 633.0], "category_id": 4}, {"id": 6, "bbox": [748.0, 148.4, 97.6, 48.6], "category_id": 2}, {"id": 7, "bbox": [499.3, 104.0, 160.1, 58.9], "category_id": 2}, {"id": 8, "bbox": [975.9, 3.0, 333.1, 294.0], "category_id": 1}], "reactions": [{"reactants": [3, 7], "conditions": [2, 6], "products": [8]}], "corefs": [[3, 1], [7, 4], [8, 0]], "caption": "Table 3. 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The Discovery Chemistry synthesis of 3", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 370, 110], "ImageBB": [82, 116, 420, 443]}, "reactions": [{"reactants": [20], "conditions": [3, 12], "products": [16]}, {"reactants": [16, 1], "conditions": [4], "products": [15]}, {"reactants": [15], "conditions": [5, 6, 11], "products": [18]}, {"reactants": [18], "conditions": [14, 9], "products": [7]}, {"reactants": [7], "conditions": [2, 19], "products": [22]}], "diagram_type": "multiple"}, {"id": 1346, "width": 1284, "height": 732, "file_name": "op7001694-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [443.2, 63.58, 214.54, 150.94], "category_id": 1}, {"id": 1, "bbox": [226.74, 677.59, 44.32, 52.67], "category_id": 3}, {"id": 2, "bbox": [854.29, 360.31, 405.94, 299.3], "category_id": 1}, {"id": 3, "bbox": [926.23, 50.74, 263.35, 127.17], "category_id": 1}, {"id": 4, "bbox": [563.96, 435.46, 74.51, 58.44], "category_id": 2}, {"id": 5, "bbox": [1030.93, 682.09, 41.1, 46.24], "category_id": 3}, {"id": 6, "bbox": [1006.52, 277.46, 41.75, 45.6], "category_id": 3}, {"id": 7, "bbox": [23.77, 401.42, 405.94, 202.95], "category_id": 1}, {"id": 8, "bbox": [3.85, 1.93, 290.33, 226.07], "category_id": 1}], "caption": "Scheme 4", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 46, 119, 60], "ImageBB": [66, 65, 387, 248]}, "reactions": [{"reactants": [8], "conditions": [], "products": [0]}, {"reactants": [0], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [6], "products": [2]}, {"reactants": [2], "conditions": [4], "products": [7]}], "diagram_type": "tree"}, {"id": 1336, "width": 3396, "height": 1172, "file_name": "op4003467-Scheme-c5.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1447.04, 296.6, 61.46, 51.22], "category_id": 3}, {"id": 1, "bbox": [1892.2, 16.99, 277.2, 45.81], "category_id": 2}, {"id": 2, "bbox": [2355.5, 383.97, 243.74, 109.53], "category_id": 2}, {"id": 3, "bbox": [1483.1, 361.88, 293.9, 57.77], "category_id": 2}, {"id": 4, "bbox": [1257.1, 397.56, 144.45, 125.72], "category_id": 2}, {"id": 5, "bbox": [2342.71, 803.62, 62.86, 61.16], "category_id": 3}, {"id": 6, "bbox": [1262.25, 61.16, 280.31, 265.04], "category_id": 1}, {"id": 7, "bbox": [2150.74, 560.66, 332.98, 280.33], "category_id": 1}, {"id": 8, "bbox": [2561.86, 118.93, 74.75, 61.16], "category_id": 3}, {"id": 9, "bbox": [883.4, 125.72, 57.76, 64.57], "category_id": 3}, {"id": 10, "bbox": [2342.71, 295.62, 64.56, 54.37], "category_id": 3}, {"id": 11, "bbox": [761.08, 416.25, 339.77, 460.42], "category_id": 1}, {"id": 12, "bbox": [1141.63, 667.7, 135.9, 127.42], "category_id": 2}, {"id": 13, "bbox": [1612.21, 56.07, 315.98, 270.13], "category_id": 1}, {"id": 14, "bbox": [1036.3, 73.06, 152.89, 64.56], "category_id": 2}, {"id": 15, "bbox": [1036.3, 844.39, 66.25, 57.77], "category_id": 3}, {"id": 16, "bbox": [1432.13, 847.79, 67.95, 54.37], "category_id": 3}, {"id": 17, "bbox": [1036.3, 164.8, 163.09, 78.15], "category_id": 2}, {"id": 18, "bbox": [1262.25, 567.46, 298.99, 273.53], "category_id": 1}, {"id": 19, "bbox": [1793.98, 293.92, 71.36, 57.77], "category_id": 3}, {"id": 20, "bbox": [1967.27, 168.2, 149.5, 127.42], "category_id": 2}, {"id": 21, "bbox": [1967.27, 81.55, 142.7, 59.46], "category_id": 2}, {"id": 22, "bbox": [2150.74, 378.87, 135.91, 117.23], "category_id": 2}, {"id": 23, "bbox": [2201.71, 56.07, 299.0, 273.53], "category_id": 1}, {"id": 24, "bbox": [1141.63, 592.94, 113.82, 59.47], "category_id": 2}], "caption": "Scheme 5. 7-Bromo-5-chloro-4-methoxy-3,3-dimethyl-2,3-dihydrobenzofuran", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 802, 510, 817], "ImageBB": [10, 834, 859, 1127]}, "reactions": [{"reactants": [9], "conditions": [14, 17], "products": [6, 13]}, {"reactants": [6], "conditions": [4], "products": [18]}, {"reactants": [18], "conditions": [24, 12], "products": [11]}, {"reactants": [13], "conditions": [21, 20], "products": [23, 8]}, {"reactants": [23], "conditions": [22, 2], "products": [7]}], "diagram_type": "graph"}, {"id": 200, "width": 1356, "height": 1156, "file_name": "op049889k-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [995.0, 0.0, 360.0, 334.0], "category_id": 1}, {"id": 1, "bbox": [608.1, 18.8, 366.9, 328.2], "category_id": 1}, {"id": 2, "bbox": [174.4, 178.8, 363.1, 152.8], "category_id": 1}, {"id": 3, "bbox": [10.0, 423.6, 1344.0, 732.4], "category_id": 4}, {"id": 4, "bbox": [340.0, 321.0, 57.3, 58.4], "category_id": 3}, {"id": 5, "bbox": [716.8, 334.0, 87.2, 54.1], "category_id": 3}, {"id": 6, "bbox": [1177.4, 350.1, 86.9, 55.8], "category_id": 3}, {"id": 7, "bbox": [0.0, 139.0, 45.3, 53.0], "category_id": 3}], "reactions": [{"reactants": [7], "conditions": [2], "products": [1, 0]}], "corefs": [[2, 4], [1, 5], [0, 6]], "caption": "Table 1. Cycloaddition optimization", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 53, 273, 67], "ImageBB": [73, 71, 412, 361]}, "diagram_type": "single"}, {"id": 590, "width": 1356, "height": 1144, "file_name": "acs.oprd.6b00180-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [159.0, 212.3, 48.8, 55.7], "category_id": 3}, {"id": 1, "bbox": [1210.3, 212.7, 55.1, 50.3], "category_id": 3}, {"id": 2, "bbox": [0.0, 65.0, 288.1, 160.2], "category_id": 1}, {"id": 3, "bbox": [380.6, 75.6, 249.4, 146.1], "category_id": 1}, {"id": 4, "bbox": [666.9, 80.3, 281.1, 56.7], "category_id": 2}, {"id": 5, "bbox": [706.96, 155.36, 202.44, 51.34], "category_id": 2}, {"id": 6, "bbox": [13.0, 283.0, 1343.0, 861.0], "category_id": 4}, {"id": 7, "bbox": [989.0, 0.0, 362.0, 237.0], "category_id": 1}], "reactions": [{"reactants": [2, 3], "conditions": [4, 5], "products": [7]}], "corefs": [[2, 0], [7, 1]], "caption": "Table 3. Screening Conditions for 100 mL Scale Pd(OAc)2 Catalyzed Suzuki Reaction of 4-Bromoanisole (1) and PhB(OH)2 in H2Oa ", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 363, 783, 408], "ImageBB": [448, 414, 787, 700]}, "diagram_type": "single"}, {"id": 1280, "width": 928, "height": 936, "file_name": "op100205s-Scheme-c10.png", "license": 0, "bboxes": [{"id": 0, "bbox": [815.42, 307.16, 112.58, 60.4], "category_id": 2}, {"id": 1, "bbox": [569.67, 558.14, 304.93, 377.86], "category_id": 1}, {"id": 2, "bbox": [790.61, 842.35, 113.75, 55.72], "category_id": 2}, {"id": 3, "bbox": [108.13, 22.48, 283.67, 370.84], "category_id": 1}, {"id": 4, "bbox": [300.52, 265.02, 93.15, 54.32], "category_id": 2}, {"id": 5, "bbox": [584.18, 21.54, 280.86, 371.78], "category_id": 1}, {"id": 6, "bbox": [278.98, 625.56, 203.63, 105.35], "category_id": 2}], "caption": "Scheme 10. LiOAc-catalyzed Hunsdiecker reaction of 17a", "pdf": {"Page": 5, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [425, 311, 747, 325], "ImageBB": [408, 65, 640, 299]}, "reactions": [{"reactants": [3], "conditions": [], "products": [5]}, {"reactants": [3], "conditions": [6], "products": [1]}], "diagram_type": "tree"}, {"id": 425, "width": 1348, "height": 568, "file_name": "op300235t-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [204.0, 395.0, 59.0, 51.0], "category_id": 3}, {"id": 1, "bbox": [1161.0, 392.0, 61.0, 54.0], "category_id": 3}, {"id": 2, "bbox": [46.0, 9.0, 309.0, 391.0], "category_id": 1}, {"id": 3, "bbox": [457.2, 9.0, 339.4, 391.0], "category_id": 1}, {"id": 4, "bbox": [640.0, 395.0, 60.0, 51.0], "category_id": 3}, {"id": 5, "bbox": [951.0, 14.0, 348.0, 381.0], "category_id": 1}], "reactions": [{"reactants": [2], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [5]}], "corefs": [[2, 0], [3, 4], [5, 1]], "caption": "Table 3. Halogenation via organometallationa", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 564, 341, 585], "ImageBB": [82, 591, 419, 733]}, "diagram_type": "single"}, {"id": 1317, "width": 1356, "height": 1792, "file_name": "op300213s-Scheme-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [175.65, 934.1, 89.61, 52.89], "category_id": 2}, {"id": 1, "bbox": [475.86, 1068.7, 305.59, 275.97], "category_id": 1}, {"id": 2, "bbox": [148.76, 0.0, 316.35, 290.7], "category_id": 1}, {"id": 3, "bbox": [516.19, 504.1, 306.49, 291.05], "category_id": 1}, {"id": 4, "bbox": [951.72, 1307.02, 355.78, 52.89], "category_id": 2}, {"id": 5, "bbox": [246.28, 369.59, 71.58, 39.26], "category_id": 2}, {"id": 6, "bbox": [495.68, 1009.26, 60.04, 39.26], "category_id": 2}, {"id": 7, "bbox": [768.17, 485.06, 60.04, 36.94], "category_id": 2}, {"id": 8, "bbox": [0.0, 1052.43, 326.2, 284.17], "category_id": 1}, {"id": 9, "bbox": [1224.16, 197.22, 93.2, 59.16], "category_id": 2}, {"id": 10, "bbox": [656.89, 372.03, 343.23, 51.09], "category_id": 2}, {"id": 11, "bbox": [1201.75, 1530.24, 87.83, 56.47], "category_id": 2}, {"id": 12, "bbox": [48.39, 838.18, 345.92, 49.3], "category_id": 2}, {"id": 13, "bbox": [1011.77, 992.37, 319.03, 285.07], "category_id": 1}, {"id": 14, "bbox": [660.47, 24.2, 320.83, 330.79], "category_id": 1}, {"id": 15, "bbox": [1031.48, 488.56, 315.45, 300.31], "category_id": 1}, {"id": 16, "bbox": [589.67, 1514.1, 236.59, 240.25], "category_id": 1}, {"id": 17, "bbox": [56.46, 503.8, 312.76, 285.07], "category_id": 1}], "caption": "Scheme 3. Reaction mechanism showing base hydrolysis of TACDNB ", "pdf": {"Page": 4, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 413, 783, 443], "ImageBB": [448, 449, 787, 897]}, "reactions": [{"reactants": [2, 5], "conditions": [], "products": [14]}, {"reactants": [14], "conditions": [9], "products": [15]}, {"reactants": [15], "conditions": [], "products": [3]}, {"reactants": [3], "conditions": [], "products": [15]}, {"reactants": [3, 7], "conditions": [], "products": [17]}, {"reactants": [17], "conditions": [0], "products": [8]}, {"reactants": [8], "conditions": [], "products": [1]}, {"reactants": [1], "conditions": [], "products": [8]}], "diagram_type": "tree"}, {"id": 74, "width": 1344, "height": 1668, "file_name": "ja206047h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [348.08, 100.39, 165.04, 102.33], "category_id": 1}, {"id": 1, "bbox": [1073.39, 108.75, 257.01, 156.68], "category_id": 1}, {"id": 2, "bbox": [356.94, 272.45, 117.5, 39.1], "category_id": 2}, {"id": 3, "bbox": [66.44, 271.75, 116.1, 41.2], "category_id": 2}, {"id": 4, "bbox": [15.74, 92.03, 261.19, 165.04], "category_id": 1}, {"id": 5, "bbox": [189.23, 271.8, 45.89, 34.7], "category_id": 3}, {"id": 6, "bbox": [586.37, 192.36, 411.68, 77.25], "category_id": 2}, {"id": 7, "bbox": [686.7, 4.24, 198.48, 171.31], "category_id": 1}, {"id": 8, "bbox": [1187.86, 272.45, 43.3, 33.5], "category_id": 3}, {"id": 9, "bbox": [1.11, 351.22, 1339.74, 1312.57], "category_id": 4}, {"id": 10, "bbox": [477.68, 271.79, 29.12, 33.41], "category_id": 3}], "reactions": [{"reactants": [4, 0], "conditions": [7, 6], "products": [1]}], "corefs": [[4, 5], [0, 10], [1, 8]], "caption": "Table 1. Optimization of Catalytic Enantioselective Arylation", "pdf": {"Page": 2, "DPI": 100, "Width": 844, "Height": 1112, "CaptionBB": [71, 92, 396, 108], "ImageBB": [71, 117, 407, 534]}, "diagram_type": "single"}, {"id": 787, "width": 1352, "height": 496, "file_name": "jo501913z-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 373.0, 1352.0, 123.0], "category_id": 4}, {"id": 1, "bbox": [0.0, 34.0, 184.0, 212.0], "category_id": 1}, {"id": 2, "bbox": [360.0, 0.0, 140.0, 247.0], "category_id": 1}, {"id": 3, "bbox": [918.0, 16.0, 432.0, 216.0], "category_id": 1}, {"id": 4, "bbox": [560.0, 113.0, 254.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [1105.0, 298.0, 60.0, 53.0], "category_id": 3}, {"id": 6, "bbox": [659.0, 50.0, 33.0, 41.0], "category_id": 3}, {"id": 7, "bbox": [389.0, 299.0, 62.0, 50.0], "category_id": 3}, {"id": 8, "bbox": [34.0, 299.0, 55.0, 52.0], "category_id": 3}, {"id": 9, "bbox": [584.0, 199.0, 202.0, 97.0], "category_id": 2}], "reactions": [{"reactants": [1, 2], "conditions": [6, 4, 9], "products": [3]}], "corefs": [[1, 8], [2, 7], [3, 5]], "caption": "Table 3. Claisen\u2212Schmidt Condensation of Acetophenone and Benzaldehyde ", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 172, 411, 202], "ImageBB": [82, 208, 420, 332]}, "diagram_type": "single"}, {"id": 626, "width": 1480, "height": 2100, "file_name": "ol501424f-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [331.5, 214.86, 38.97, 49.85], "category_id": 3}, {"id": 1, "bbox": [646.89, 214.86, 43.51, 49.85], "category_id": 3}, {"id": 2, "bbox": [1195.2, 224.83, 41.69, 48.04], "category_id": 3}, {"id": 3, "bbox": [719.1, 249.2, 395.6, 252.4], "category_id": 1}, {"id": 4, "bbox": [1071.56, 4.56, 305.0, 215.0], "category_id": 1}, {"id": 5, "bbox": [809.0, 60.0, 254.0, 86.0], "category_id": 2}, {"id": 6, "bbox": [520.0, 50.0, 275.0, 132.0], "category_id": 1}, {"id": 7, "bbox": [857.0, 163.0, 148.0, 43.0], "category_id": 2}, {"id": 8, "bbox": [235.0, 67.0, 245.0, 141.0], "category_id": 1}, {"id": 9, "bbox": [134.0, 524.0, 1346.0, 1576.0], "category_id": 4}], "reactions": [{"reactants": [8, 6], "conditions": [5, 7], "products": [4]}], "corefs": [[8, 0], [6, 1], [4, 2]], "caption": "Table 1. Substrate Scope of NHC-Catalyzed aza-DA Reactiona ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 737, 125], "ImageBB": [416, 131, 786, 656]}, "diagram_type": "single"}, {"id": 487, "width": 1344, "height": 1160, "file_name": "ol060664z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1076.0, 223.0, 46.0, 48.0], "category_id": 3}, {"id": 1, "bbox": [86.0, 225.0, 42.0, 44.0], "category_id": 3}, {"id": 2, "bbox": [355.0, 5.0, 567.0, 164.0], "category_id": 2}, {"id": 3, "bbox": [558.0, 178.0, 164.0, 56.0], "category_id": 2}, {"id": 4, "bbox": [2.0, 307.9, 1342.0, 852.1], "category_id": 4}, {"id": 5, "bbox": [957.0, 7.1, 317.1, 248.7], "category_id": 1}, {"id": 6, "bbox": [71.3, 1.6, 270.4, 274.0], "category_id": 1}], "reactions": [{"reactants": [6], "conditions": [2, 3], "products": [5]}], "corefs": [[6, 1], [5, 0]], "caption": "Table 2. Formation of Pyrroles 3 from 1 and Amines 2a", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 75, 372, 89], "ImageBB": [74, 98, 410, 388]}, "diagram_type": "single"}, {"id": 251, "width": 1352, "height": 1196, "file_name": "ol802669r-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [152.0, 257.0, 62.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [1069.0, 258.0, 62.0, 57.0], "category_id": 3}, {"id": 2, "bbox": [63.0, 56.0, 301.0, 208.0], "category_id": 1}, {"id": 3, "bbox": [0.0, 332.0, 1348.0, 864.0], "category_id": 4}, {"id": 4, "bbox": [470.0, 0.0, 300.0, 147.0], "category_id": 2}, {"id": 5, "bbox": [938.0, 69.0, 351.0, 167.2], "category_id": 1}, {"id": 6, "bbox": [447.0, 162.0, 342.0, 62.2], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [4, 6], "products": [5]}], "corefs": [[2, 0], [5, 1]], "caption": "Table 1. Optimization of the Pd(0)-Catalyzed Cyclopropane Ring-Expansion Reaction of 1ba ", "pdf": {"Page": 2, "DPI": 100, "Width": 818, "Height": 1088, "CaptionBB": [58, 75, 369, 102], "ImageBB": [58, 111, 396, 410]}, "diagram_type": "single"}, {"id": 47, "width": 1348, "height": 396, "file_name": "ja410533y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [411.22, 6.65, 145.75, 135.42], "category_id": 1}, {"id": 1, "bbox": [439.63, 164.17, 45.9, 35.57], "category_id": 3}, {"id": 2, "bbox": [126.3, 204.63, 168.13, 39.02], "category_id": 2}, {"id": 3, "bbox": [393.14, 205.49, 137.15, 38.16], "category_id": 2}, {"id": 4, "bbox": [189.14, 165.04, 45.9, 34.71], "category_id": 3}, {"id": 5, "bbox": [1001.72, 25.59, 214.62, 136.28], "category_id": 1}, {"id": 6, "bbox": [7.13, 279.88, 1334.78, 116.12], "category_id": 4}, {"id": 7, "bbox": [1071.45, 190.0, 46.76, 37.29], "category_id": 3}, {"id": 8, "bbox": [612.65, 19.56, 316.19, 77.75], "category_id": 2}, {"id": 9, "bbox": [658.27, 133.19, 224.94, 118.2], "category_id": 2}, {"id": 10, "bbox": [128.88, 27.31, 162.97, 125.09], "category_id": 1}], "reactions": [{"reactants": [10, 0], "conditions": [8, 9], "products": [5]}], "corefs": [[10, 4], [0, 1], [5, 7]], "caption": "Table 1. Selected Optimization Experiments in the Ruthenium-Catalyzed C\u2212C Coupling of Diol 1b and Methyl Acrylate 2aa ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 784, 140], "ImageBB": [449, 146, 786, 245]}, "diagram_type": "single"}, {"id": 1202, "width": 1352, "height": 960, "file_name": "ol503404p-Scheme-c4.png", "license": 0, "bboxes": [{"id": 0, "bbox": [273.92, 148.72, 103.48, 59.48], "category_id": 3}, {"id": 1, "bbox": [703.39, 836.87, 201.55, 43.27], "category_id": 2}, {"id": 2, "bbox": [399.04, 519.83, 175.85, 80.45], "category_id": 2}, {"id": 3, "bbox": [334.79, 623.26, 346.96, 277.16], "category_id": 1}, {"id": 4, "bbox": [610.06, 122.35, 252.27, 61.52], "category_id": 2}, {"id": 5, "bbox": [332.59, 432.16, 39.18, 46.1], "category_id": 3}, {"id": 6, "bbox": [1168.12, 510.53, 51.86, 47.25], "category_id": 3}, {"id": 7, "bbox": [952.96, 505.64, 150.82, 48.67], "category_id": 2}, {"id": 8, "bbox": [998.95, 107.48, 158.26, 60.16], "category_id": 2}, {"id": 9, "bbox": [546.48, 0.0, 146.09, 54.75], "category_id": 2}, {"id": 10, "bbox": [705.42, 738.18, 183.96, 80.44], "category_id": 2}, {"id": 11, "bbox": [794.02, 211.58, 217.11, 44.62], "category_id": 2}, {"id": 12, "bbox": [66.96, 205.5, 468.02, 294.05], "category_id": 1}, {"id": 13, "bbox": [1011.13, 840.93, 50.72, 55.43], "category_id": 3}, {"id": 14, "bbox": [952.96, 160.89, 328.02, 300.13], "category_id": 1}, {"id": 15, "bbox": [546.48, 211.58, 129.86, 62.19], "category_id": 2}, {"id": 16, "bbox": [334.79, 65.57, 238.74, 70.3], "category_id": 2}, {"id": 17, "bbox": [1108.52, 389.37, 58.16, 60.16], "category_id": 3}, {"id": 18, "bbox": [890.06, 48.67, 67.63, 50.02], "category_id": 3}, {"id": 19, "bbox": [855.57, 580.9, 372.66, 319.52], "category_id": 1}, {"id": 20, "bbox": [429.47, 866.62, 51.41, 50.69], "category_id": 3}], "caption": "Scheme 4. Proposed Mechanism", "pdf": {"Page": 3, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 692, 263, 707], "ImageBB": [82, 713, 420, 953]}, "reactions": [{"reactants": [3], "conditions": [2], "products": [12]}, {"reactants": [12, 15], "conditions": [], "products": [0, 4]}, {"reactants": [9, 16], "conditions": [], "products": [4]}, {"reactants": [4, 18], "conditions": [], "products": [8, 14]}, {"reactants": [14, 6], "conditions": [7], "products": [19]}, {"reactants": [19], "conditions": [10, 1], "products": [3]}], "diagram_type": "graph"}, {"id": 1067, "width": 1356, "height": 812, "file_name": "jo300771f-Scheme-c9.png", "license": 0, "bboxes": [{"id": 0, "bbox": [563.02, 676.8, 232.28, 41.2], "category_id": 3}, {"id": 1, "bbox": [309.32, 2.71, 392.38, 53.49], "category_id": 1}, {"id": 2, "bbox": [88.18, 561.15, 224.53, 54.96], "category_id": 2}, {"id": 3, "bbox": [385.49, 62.96, 241.34, 96.12], "category_id": 2}, {"id": 4, "bbox": [101.2, 346.22, 195.32, 47.04], "category_id": 1}, {"id": 5, "bbox": [563.4, 720.5, 177.96, 46.02], "category_id": 3}, {"id": 6, "bbox": [925.93, 252.41, 57.66, 56.32], "category_id": 3}, {"id": 7, "bbox": [459.24, 171.67, 97.0, 45.46], "category_id": 2}, {"id": 8, "bbox": [381.23, 323.66, 642.38, 365.05], "category_id": 1}, {"id": 9, "bbox": [187.22, 255.81, 61.73, 48.17], "category_id": 3}, {"id": 10, "bbox": [679.7, 0.0, 641.7, 312.12], "category_id": 1}, {"id": 11, "bbox": [332.39, 670.39, 139.06, 99.74], "category_id": 2}, {"id": 12, "bbox": [38.67, 80.07, 304.57, 164.2], "category_id": 1}, {"id": 13, "bbox": [61.73, 398.6, 274.05, 143.55], "category_id": 2}], "caption": "Scheme 9. Preparation of 9c", "pdf": {"Page": 5, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 611, 110], "ImageBB": [448, 116, 787, 319]}, "reactions": [{"reactants": [12], "conditions": [1, 3, 7], "products": [10]}, {"reactants": [10], "conditions": [4, 13, 2], "products": [8]}, {"reactants": [0], "conditions": [11], "products": [5]}], "diagram_type": "multiple"}, {"id": 204, "width": 1348, "height": 988, "file_name": "op034181b-Table-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [1011.35, 215.35, 42.0, 53.0], "category_id": 3}, {"id": 1, "bbox": [377.89, 168.0, 265.91, 102.7], "category_id": 2}, {"id": 2, "bbox": [118.3, 204.32, 51.4, 56.4], "category_id": 3}, {"id": 3, "bbox": [324.0, 3.0, 384.4, 133.0], "category_id": 1}, {"id": 4, "bbox": [135.0, 13.0, 141.8, 281.0], "category_id": 1}, {"id": 5, "bbox": [718.95, 78.0, 500.55, 131.0], "category_id": 1}, {"id": 6, "bbox": [527.0, 91.0, 50.0, 46.0], "category_id": 3}, {"id": 7, "bbox": [5.0, 311.0, 1343.0, 677.0], "category_id": 4}], "reactions": [{"reactants": [4], "conditions": [3, 1], "products": [5]}], "corefs": [[4, 2], [3, 6], [5, 0]], "caption": "Table 3. Suzuki coupling results", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 271, 257, 285], "ImageBB": [74, 288, 410, 535]}, "diagram_type": "single"}, {"id": 231, "width": 1184, "height": 468, "file_name": "op000111i-Figure-c3.png", "license": 0, "bboxes": [{"id": 0, "bbox": [55.7, 236.1, 179.1, 132.7], "category_id": 1}, {"id": 1, "bbox": [434.0, 101.0, 139.8, 54.0], "category_id": 2}, {"id": 2, "bbox": [58.0, 5.5, 181.5, 131.9], "category_id": 1}, {"id": 3, "bbox": [762.5, 225.0, 184.8, 138.5], "category_id": 1}, {"id": 4, "bbox": [748.9, 7.0, 176.4, 129.3], "category_id": 1}, {"id": 5, "bbox": [1076.29, 31.46, 85.0, 63.0], "category_id": 2}, {"id": 6, "bbox": [401.0, 219.0, 220.0, 52.0], "category_id": 2}, {"id": 7, "bbox": [1071.0, 267.0, 113.0, 59.0], "category_id": 2}, {"id": 8, "bbox": [394.0, 19.0, 227.0, 57.0], "category_id": 2}, {"id": 9, "bbox": [4.0, 408.0, 656.0, 60.0], "category_id": 2}], "reactions": [{"reactants": [2], "conditions": [8, 1], "products": [4]}, {"reactants": [0], "conditions": [6], "products": [3]}], "corefs": [], "caption": "Figure 3. Catalysed and uncatalyzed reduction of prochiral ketones by borane. 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Strategy for synthetic diversification of monoterpene indole alkaloids using Pd-catalyzed Suzuki Miyaura coupling reaction. Alkaloid analogs with chlorine and bromine at the 7-position of the indole ring were obtained by culturing transgenic tryptophan decarboxylase-suppressed hairy root cultures in the presence of 7-chlorotryptamine 1a or 7-bromotryptamine 1b (a). Alkaloid analogs with chlorine at the 6-position of the indole ring were obtained by culturing hairy root cultures that express a mutant strictosidine synthase enzyme (V214M) in the presence of 6-chlorotryptamine 1c (b). Alkaloid analogs with chlorine at the 7-position of the indole ring could also be obtained from hairy root cultures that express prokaryotic halogenases, RebH and RebF (c). 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Rates of Catalysis for the Oxidation of Bromide by Hydrogen Peroxide in the Presence of Phenylseleno-Containing Molecules As Determined by the Rate of Bromination of Cyclohexene ", "pdf": {"Page": 4, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 178, 401, 237], "ImageBB": [73, 238, 411, 502]}, "diagram_type": "single"}, {"id": 770, "width": 1348, "height": 1072, "file_name": "jo9602433-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [472.81, 462.75, 185.37, 57.48], "category_id": 2}, {"id": 1, "bbox": [1119.46, 472.81, 191.12, 58.92], "category_id": 2}, {"id": 2, "bbox": [308.0, 646.0, 69.0, 56.0], "category_id": 3}, {"id": 3, "bbox": [734.3, 275.1, 491.6, 370.3], "category_id": 1}, {"id": 4, "bbox": [960.0, 656.0, 66.7, 52.5], "category_id": 3}, {"id": 5, "bbox": [93.2, 259.0, 478.8, 372.4], "category_id": 1}, {"id": 6, "bbox": [33.0, 55.0, 126.0, 72.0], "category_id": 3}, {"id": 7, "bbox": [6.0, 756.0, 1342.0, 316.0], "category_id": 4}, {"id": 8, "bbox": [242.0, 0.0, 215.0, 56.0], "category_id": 2}, {"id": 9, "bbox": [283.0, 104.0, 183.0, 57.0], "category_id": 2}, {"id": 10, "bbox": [324.0, 179.0, 79.0, 51.0], "category_id": 2}], "reactions": [{"reactants": [6], "conditions": [8, 9, 10], "products": [5, 3]}], "corefs": [[5, 2], [3, 4]], "caption": "Table 2. Treatment of (Z)-3 with BTMABr3 or Br2", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [451, 670, 742, 683], "ImageBB": [429, 391, 766, 659]}, "diagram_type": "multiple"}, {"id": 95, "width": 2128, "height": 1584, "file_name": "ja0516864-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [630.45, 475.0, 22.55, 33.27], "category_id": 3}, {"id": 1, "bbox": [403.41, 602.7, 1384.4, 403.28], "category_id": 4}, {"id": 2, "bbox": [439.22, 1536.16, 27.94, 35.35], "category_id": 3}, {"id": 3, "bbox": [1619.3, 1475.0, 172.49, 98.37], "category_id": 3}, {"id": 4, "bbox": [1109.87, 1475.03, 305.83, 102.04], "category_id": 3}, {"id": 5, "bbox": [828.27, 1536.16, 26.09, 33.5], "category_id": 3}, {"id": 6, "bbox": [4.22, 101.67, 392.88, 116.87], "category_id": 1}, {"id": 7, "bbox": [98.71, 272.11, 233.59, 96.49], "category_id": 1}, {"id": 8, "bbox": [495.17, 94.26, 389.23, 324.36], "category_id": 1}, {"id": 9, "bbox": [1197.3, 88.7, 389.22, 326.21], "category_id": 1}, {"id": 10, "bbox": [1710.5, 7.19, 320.65, 444.78], "category_id": 1}, {"id": 11, "bbox": [930.54, 160.96, 240.99, 44.64], "category_id": 2}, {"id": 12, "bbox": [989.82, 292.49, 142.8, 35.35], "category_id": 2}, {"id": 13, "bbox": [1365.75, 474.1, 21.66, 33.27], "category_id": 3}, {"id": 14, "bbox": [1869.65, 475.0, 17.19, 33.27], "category_id": 3}, {"id": 15, "bbox": [287.31, 1089.68, 313.24, 416.99], "category_id": 1}, {"id": 16, "bbox": [674.5, 1085.97, 315.1, 413.29], "category_id": 1}, {"id": 17, "bbox": [1089.49, 1119.32, 291.01, 268.78], "category_id": 1}, {"id": 18, "bbox": [1491.52, 1130.44, 389.18, 159.47], "category_id": 1}, {"id": 19, "bbox": [1982.83, 331.4, 139.1, 37.2], "category_id": 1}], "reactions": [{"reactants": [6, 7], "conditions": [], "products": [8]}, {"reactants": [8], "conditions": [11, 12], "products": [9]}, {"reactants": [9], "conditions": [], "products": [10]}], "corefs": [[8, 0], [9, 13], [10, 14], [15, 2], [16, 5], [17, 4], [18, 3]], "caption": "Table 1. Selected Experimental NMR Spectroscopic Data of Aryl-Substituted Vinyl Cations. NMR Chemical Shifts \u03b4 versus TMS, Coupling Constants 1J (Hz) in Bracketsa ", "pdf": {"Page": 3, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 487, 766, 511], "ImageBB": [159, 80, 691, 476]}, "diagram_type": "single"}, {"id": 344, "width": 1348, "height": 1452, "file_name": "ol202395s-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [148.7, 366.9, 65.6, 67.4], "category_id": 3}, {"id": 1, "bbox": [475.11, 371.0, 64.0, 58.0], "category_id": 3}, {"id": 2, "bbox": [1084.0, 368.0, 62.4, 55.0], "category_id": 3}, {"id": 3, "bbox": [381.7, 1.2, 283.3, 277.2], "category_id": 1}, {"id": 4, "bbox": [17.7, 3.0, 349.3, 277.0], "category_id": 1}, {"id": 5, "bbox": [747.0, 118.0, 112.0, 60.3], "category_id": 2}, {"id": 6, "bbox": [668.0, 199.8, 313.0, 125.5], "category_id": 2}, {"id": 7, "bbox": [962.0, 21.0, 386.0, 350.0], "category_id": 1}, {"id": 8, "bbox": [2.0, 511.4, 1346.0, 940.6], "category_id": 4}], "reactions": [{"reactants": [4, 3], "conditions": [5, 6], "products": [7]}], "corefs": [[4, 0], [3, 1], [7, 2]], "caption": "Table 1. Reaction of P-Alkenyl-\u03bb5-phosphazenes and Aryne Precursors in the Presence of CsFa ", "pdf": {"Page": 3, "DPI": 100, "Width": 843, "Height": 1113, "CaptionBB": [437, 85, 756, 115], "ImageBB": [436, 126, 773, 489]}, "diagram_type": "single"}, {"id": 635, "width": 1348, "height": 1100, "file_name": "ol501165h-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [574.1, 746.0, 261.9, 258.2], "category_id": 1}, {"id": 1, "bbox": [221.0, 475.0, 286.6, 211.8], "category_id": 1}, {"id": 2, "bbox": [830.88, 130.0, 318.7, 261.0], "category_id": 1}, {"id": 3, "bbox": [273.1, 154.0, 266.9, 210.7], "category_id": 1}, {"id": 4, "bbox": [337.0, 25.6, 170.0, 52.4], "category_id": 1}, {"id": 5, "bbox": [555.0, 148.0, 269.0, 219.2], "category_id": 1}, {"id": 6, "bbox": [577.0, 349.3, 72.0, 39.7], "category_id": 3}, {"id": 7, "bbox": [881.6, 659.9, 163.0, 48.6], "category_id": 3}, {"id": 8, "bbox": [518.0, 62.0, 413.0, 50.0], "category_id": 2}, {"id": 9, "bbox": [549.0, 4.0, 320.0, 43.0], "category_id": 2}, {"id": 10, "bbox": [951.0, 31.0, 116.0, 42.0], "category_id": 3}, {"id": 11, "bbox": [7.0, 1028.0, 1311.0, 72.0], "category_id": 4}, {"id": 12, "bbox": [581.0, 475.0, 247.0, 179.0], "category_id": 1}, {"id": 13, "bbox": [887.0, 437.0, 258.0, 206.0], "category_id": 1}, {"id": 14, "bbox": [273.0, 716.0, 250.0, 213.0], "category_id": 1}, {"id": 15, "bbox": [594.0, 958.0, 68.0, 36.0], "category_id": 3}, {"id": 16, "bbox": [244.0, 663.0, 72.0, 33.0], "category_id": 3}, {"id": 17, "bbox": [880.0, 743.0, 262.0, 225.7], "category_id": 1}, {"id": 18, "bbox": [896.0, 957.0, 67.0, 36.0], "category_id": 3}, {"id": 19, "bbox": [828.8, 343.6, 235.2, 90.4], "category_id": 3}, {"id": 20, "bbox": [191.7, 345.0, 263.3, 130.3], "category_id": 3}, {"id": 21, "bbox": [189.3, 916.0, 254.7, 78.0], "category_id": 3}, {"id": 22, "bbox": [564.86, 652.04, 265.08, 89.3], "category_id": 3}, {"id": 23, "bbox": [267.18, 25.49, 39.69, 52.45], "category_id": 3}], "reactions": [{"reactants": [23, 4], "conditions": [9, 8], "products": [10]}], "corefs": [[3, 20], [5, 6], [2, 19], [1, 16], [12, 22], [13, 7], [14, 21], [0, 15], [17, 18]], "caption": "Table 1. Cyclocarbopalladation/Stille Coupling", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [82, 95, 347, 110], "ImageBB": [82, 116, 419, 391]}, "diagram_type": "single"}, {"id": 649, "width": 1356, "height": 2340, "file_name": "ol500121z-Table-c2.png", "license": 0, "bboxes": [{"id": 0, "bbox": [996.0, 294.0, 233.0, 100.0], "category_id": 1}, {"id": 1, "bbox": [204.0, 211.0, 91.0, 36.0], "category_id": 3}, {"id": 2, "bbox": [82.0, 946.0, 1214.0, 1234.9], "category_id": 4}, {"id": 3, "bbox": [489.0, 163.0, 76.0, 36.0], "category_id": 3}, {"id": 4, "bbox": [1080.0, 192.0, 26.0, 35.0], "category_id": 3}, {"id": 5, "bbox": [1086.0, 428.0, 26.0, 32.0], "category_id": 3}, {"id": 6, "bbox": [643.0, 133.0, 290.0, 89.0], "category_id": 2}, {"id": 7, "bbox": [702.0, 63.0, 172.0, 40.0], "category_id": 2}, {"id": 8, "bbox": [1014.0, 0.0, 195.0, 179.0], "category_id": 1}, {"id": 9, "bbox": [481.0, 99.0, 92.0, 38.0], "category_id": 1}, {"id": 10, "bbox": [136.0, 85.0, 253.0, 107.0], "category_id": 1}, {"id": 11, "bbox": [611.0, 255.0, 353.0, 289.0], "category_id": 3}, {"id": 12, "bbox": [120.0, 260.0, 596.0, 665.0], "category_id": 3}], "reactions": [{"reactants": [10, 9], "conditions": [7, 6], "products": [8, 0]}], "corefs": [[10, 1], [10, 12], [9, 3], [9, 11], [8, 4], [0, 5]], "caption": "Table 2. [Pd(cod)(C3H5)]BF4/bpy-Catalyzed Double Alkylation of 1 with 2 ", "pdf": {"Page": 2, "DPI": 100, "Width": 869, "Height": 1137, "CaptionBB": [449, 95, 748, 125], "ImageBB": [448, 131, 787, 716]}, "diagram_type": "single"}, {"id": 877, "width": 1352, "height": 640, "file_name": "ol701624y-Table-c1.png", "license": 0, "bboxes": [{"id": 0, "bbox": [0.0, 301.0, 1352.0, 339.0], "category_id": 4}, {"id": 1, "bbox": [71.0, 0.0, 390.0, 129.0], "category_id": 1}, {"id": 2, "bbox": [870.0, 0.0, 409.0, 219.0], "category_id": 1}, {"id": 3, "bbox": [869.37, 165.48, 145.9, 54.39], "category_id": 2}, {"id": 4, "bbox": [493.0, 8.0, 299.0, 54.0], "category_id": 2}, {"id": 5, "bbox": [489.0, 99.0, 309.0, 122.0], "category_id": 2}, {"id": 6, "bbox": [208.0, 154.0, 82.0, 45.0], "category_id": 3}, {"id": 7, "bbox": [1068.0, 233.0, 88.0, 45.0], "category_id": 3}], "reactions": [{"reactants": [1], "conditions": [4, 5], "products": [2]}], "corefs": [[1, 6], [2, 7]], "caption": "Table 1.", "pdf": {"Page": 2, "DPI": 100, "Width": 850, "Height": 1100, "CaptionBB": [74, 449, 120, 462], "ImageBB": [73, 466, 411, 626]}, "diagram_type": "single"}], "roles": [{"id": 1, "name": "reactants"}, {"id": 2, "name": "conditions"}, {"id": 3, "name": "products"}]}